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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Numerical and experimental analysis of precooled desiccant system

This paper presents a numerical and experimental study of four novel, desiccant air-conditioning systems based on pre-cooling of the ambient air. The purpose of the study is to: 1) establish which configuration is most profitable for the future studies through numerical and experimental methods; 2) verify the concept of precooled system and confirm that it is working in experimental conditions (for this purpose two prototypes of evaporative cooling units were developed and compared for different operation arrangements with desiccant wheel); 3) Analyze practical aspects of the systems, which includes water consumption analysis, economic analysis and establishing operational modes during a cooling season in temperate climate conditions (the proposed solution has a significant advantage during operation in a temperate climate, since it can utilize its first evaporative cooler the only source of cooling energy when the humidity of outdoor air allows to to meet the latent cooling load). Four arrangements of the system with different dew point evaporative air cooler prototypes were selected and developed for comparative analysis. The system was simulated as a whole, also, each component was individually tested on measurement station. develop the optimal arrangement of the system through numerical and experimental analysis. Four different performance indicators were considered: thermal COP (Coefficient Of Performance), the ERR (Energy Efficiency Ratio), coefficient a describing the potential in compensating indoor cooling loads, water consumption ratio. Also costs of the systems were compared through economic analysis. It was established that arrangement which is characterized by best-averaged performance in terms of all considered factors is a unit combined with two different types of evaporative coolers (marked as System B)- this is caused by the favorable arrangement of two units, where one is better suited to the pre-cooler role, while the other is better suited as the post-cooler.

42 ENGINEERING↗
DOE OSTI2025

Codon bias, nucleotide selection, and genome size predict in situ bacterial growth rate and transcription in rewetted soil

In soils, the first rain after a prolonged dry period represents a major pulse event impacting soil microbial community function, yet we lack a full understanding of the genomic traits associated with the microbial response to rewetting. Genomic traits such as codon usage bias and genome size have been linked to bacterial growth in soils—however, often through measurements in culture. Here, we used metagenome-assembled genomes (MAGs) with 18 O-water stable isotope probing and metatranscriptomics to track genomic traits associated with growth and transcription of soil microorganisms over one week following rewetting of a grassland soil. We found that codon bias in ribosomal protein genes was the strongest predictor of growth rate. We also found higher growth rates in bacteria with smaller genomes, suggesting that reduced genome size enables a faster response to pulses in soil bacteria. Faster transcriptional upregulation of ribosomal protein genes was associated with high codon bias and increased nucleotide skew. We found that several of these relationships existed within phyla, indicating that these associations between genomic traits and activity could be generalized characteristics of soil bacteria. Finally, we used publicly available metagenomes to assess the distribution of codon bias across a pH gradient and found that microbial communities in higher pH soils—which are often more water limited and pulse driven—have higher codon usage bias in their ribosomal protein genes. Together, these results provide evidence that genomic characteristics affect soil microbial activity during rewetting and pose a potential fitness advantage for soil bacteria where water and nutrient availability are episodic.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Estimating Ice Water Content for Winter Storms from Millimeter-Wavelength Radar Measurements Using a Synthesis of Polarimetric and Dual-Frequency Radar Observations

The potential of millimeter-wavelength radar-based ice water content (IWC) estimation is demonstrated using a Ka-band Scanning Polarimetric Radar (KASPR) for the U.S. northeast coast winter storms. Two IWC relations for Ka-band polarimetric radar measurements are proposed: one that uses a combination of the radar reflectivity Z and the estimated total number concentration of snow particles N t and the other based on the joint use of Z, specific differential phase K DP , and the degree of riming f rim . A key element of the algorithms is to obtain the “Rayleigh-equivalent” value of Z measured at the Ka band, i.e., the corresponding Z at a longer radar wavelength for which Rayleigh scattering takes place. This is achieved via polarimetric retrieval of the mean volume diameter D m and incorporating the relationship between the dual-wavelength ratio DWR S/Ka and D m . Those techniques allow for retrievals from single millimeter-wavelength radar measurements and do not necessarily require the dual-wavelength ratio (DWR) measurements, if the DWR–D m relation and Rayleigh assumption for Ka-band K DP are valid. Comparison between the quasivertical profile product obtained from KASPR and the columnar vertical profile product generated from the nearby WSR-88D S-band radar measurements demonstrates that the DWR S/Ka can be estimated from the two close radars without the need for collocated radar beams and synchronized antenna scanning and can be used for determining the Rayleigh-equivalent value of Z. As a result, the performance of the suggested techniques is evaluated for seven winter storms using surface disdrometer and snow accumulation measurements.

Cloud retrieval↗
DOE OSTI2024

Water aging and the quality of organic carbon sources drive niche partitioning of the active bathypelagic prokaryotic microbiome

Abstract Due to the scarcity of organic matter (OM) sources in the bathypelagic (1000–4000 m depth), prokaryotic metabolism is believed to be concentrated on particles originating from the surface. However, the structure of active bathypelagic prokaryotic communities and how it changes across environmental gradients remains unexplored. Using a combination of 16S rRNA gene and transcripts sequencing, metagenomics, and substrate uptake potential measurements, here we aimed to explore how water masses aging and the quality of OM influence the structure of the active microbiome, and the potential implications for community function. We found that the relative contribution of taxa with a free‐living lifestyle to the active microbiome increased in older water masses that were enriched in recalcitrant OM, suggesting that these prokaryotes may also play a substantial role in the bathypelagic metabolism of vast areas of the ocean. In comparison to particle‐associated prokaryotes, free‐living prokaryotes exhibited lower potential metabolic rates, and harbored a limited number of two‐component sensory systems, suggesting they have less ability to sense and respond to environmental cues. In contrast, particle‐associated prokaryotes carried genes for particle colonization and carbohydrate utilization that were absent in prokaryotes with a free‐living lifestyle. Consistently, we observed that prokaryotic communities inhabiting older waters displayed reduced abilities to colonize particles, and higher capabilities to use complex carbon sources, compared to communities in waters with a higher proportion of labile OM. Our results provide evidence of regionalization of the bathypelagic active prokaryotic microbiome, unveiling a niche partitioning based on the quality of OM.

Marine & Freshwater Biology↗
DOE OSTI2023

Rational design of stable functional metal–organic frameworks

Functional porous metal–organic frameworks (MOFs) have been explored for a number of potential applications in catalysis, chemical sensing, water capture, gas storage, and separation. MOFs are among the most promising candidates to address challenges facing our society related to energy and environment, but the successful implementation of functional porous MOF materials are contingent on their stability; therefore, the rational design of stable MOFs plays an important role towards the development of functional porous MOFs. In this Focus article, we summarize progress in the rational design and synthesis of stable MOFs with controllable pores and functionalities. The implementation of reticular chemistry allows for the rational top-down design of stable porous MOFs with targeted topological networks and pore structures from the pre-selected building blocks. We highlight the reticular synthesis and applications of stable MOFs: (1) MOFs based on high valent metal ions (e.g., Al 3+ , Cr 3+ , Fe 3+ , Ti 4+ and Zr 4+ ) and carboxylate ligands; (2) MOFs based on low valent metal ions (e.g., Ni 2+ , Cu 2+ , and Zn 2+ ) and azolate linkers. We envision that the synthetic strategies, including modulated synthesis and post-synthetic modification, can potentially be extended to other more complex systems like metal-phosphonate framework materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Direct Laser Writing of Multimetal Bifunctional Catalysts for Overall Water Splitting

Water electrolysis is of interest as a sustainable way to produce clean hydrogen and oxygen fuel and help mitigate the rising problems of climate change while meeting global energy demands. High-efficiency, stable, and earth-abundant bifunctional catalysts are needed to enable more effective electrochemical cells for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Here, we investigate the synthesis, composition, performance, and mechanism of multimetal catalysts serving dual functionality in both OER and HER of water electrolysis. Through a laser synthesis method, we synthesized heterogeneous catalysts of nanocrystalline multimetallic alloy pockets embedded within an amorphous oxide matrix. We evaluated the performance and composition of a range of mixed transition-metal oxide materials for both OER and HER, ultimately synthesizing a Cr 0.01 Fe 0.27 Co 0.34 Ni 0.38 O x /C y catalyst that has a stable, high-rate, and competitive overall water splitting performance of 1.76 V at 100 mA cm –2 in an alkaline medium. Using density functional theory to gain insight as the active site and mechanism, we propose that the inclusion of a minor amount of Cr increases the degeneracy of energetic states that lowers the cost of forming the O 2 p–d bond and H 1 s–d bond due to the hybridization of s, p, and d orbitals from Cr. Using a two-electrode water electrolysis cell with a constant potential of 1.636 V to mimic the setup for fuel production, we found the catalyst to be stable at 14–15 mA cm –2 for 40 h. Furthermore, this laser synthesis method allowing for facile and rapid synthesis of complex multimetal systems demonstrates how doping a Fe, Co, and Ni heterogeneous amorphous/nanocrystalline structure with small amounts of Cr is important for bifunctional catalytic behavior, particularly for increasing HER functionality in advancing our understanding for future electrocatalytic design.

08 HYDROGEN↗
DOE OSTI2024

Synthesis of rhenium coatings on 316 stainless steel and their electrochemical behavior towards water oxidation in saline environments

The production of electrolytic hydrogen or Green Hydrogen has attracted the attention of scientists as a potential enabler of sustainable energy production. The cleavage of the water molecule requires high energy, in order to produce hydrogen and oxygen through their corresponding half reactions, the hydrogen evolution and oxygen evolution reactions. Further, this latter reaction has been studied in more detail, since its slow kinetics make the water electrolysis less efficient, and, for instance, delay the formation of hydrogen in the counter compartment of the electrolytic cell. In this work, a study of the oxygen evolution reaction is presented. For this, a series of rhenium catalysts deposited onto stainless steel 316 are studied with the aim of analyzing the effect of the pure metal (Re) and the metal with heteroatoms (Re-C, Re-B, and Re-O). As one of the problems worldwide is the scarcity of freshwater, the study focuses on the performance of this series of catalysts in highly saline environments, representative of seawater. The synthesis and electrochemical performance is shown, giving high expectations that these electrocatalysts could be potential electrocatalysts in marine environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Development and Demonstration of a Prototype Molten Salt Sampling System

Molten salt reactors (MSRs) offer potential operability and safety advantages when compared to commercial light water reactors (LWRs). However, operating experience with MSRs is sparse in comparison to what exists for LWRs. Further, the chemical and isotopic composition of the fuel and/or coolant salt is dynamic and difficult to characterize continuously, posing potential safety, operability, and safeguards unknowns that need to be addressed. A molten salt sampling system (MSSS) is regarded as a necessary subsystem within first generation MSRs used to obtain samples of salt for chemical and isotopic analysis in support of the need to monitor and control salt composition during operation. The MSSS is being developed using the Safety-in-Design (SiD) methodology, which incorporates incremental integration of safety analysis into the design process. The MSSS conceptual design emerging from the application of the early stages of the SiD methodology consists of a sample collection system and its housing, a freeze port, and inert gas control and delivery systems. This article describes the prototypes developed to test the functions of these MSSS subsystems, presents the results of testing in both dry and molten salt environments (including reliability data collection performed in accordance with the principles of SiD and the development of a semiquantitative fault tree model), and summarizes the opportunities for future design and testing enhancements based on the results of prototype testing.

molten salt reactor↗
DOE OSTI2023

An innovative approach for atrazine electrochemical oxidation modelling: Process parameter effect, intermediate formation and kinetic constant assessment

Water reuse for irrigation activities is becoming a crucial worldwide challenge due to the depletion of water sources. Anyway, agricultural drainage can potentially contain dangerous contaminants such as metals, pesticides, and herbicides, including atrazine. To address the need for agriculture wastewater purification, we investigated atrazine removal from simulated wastewater by electro-oxidation using platinum-coated titanium electrodes on a lab-scale experimental apparatus. The effects of electrolyte composition and concentration, i.e. ionic strength and applied current density on atrazine removal, were investigated. The results demonstrated that the electrochemical oxidation of the herbicide occurred through two routes, depending on the presence or absence of oxidizing chlorine species. The generation of intermediates during the treatment was monitored and quantified by evaluating the effect of an inert electrolyte (NaClO 4 ) versus an oxidizable chlorine species (NaCl). In both experimental conditions, five intermediates were identified, including desethyl-atrazine (DEA), hydroxyatrazine (ATZ-OH), desisopropyl-atrazine (DIA) and desethyl-desisopropyl-atrazine (DEDIA). A degradation mechanism and a model for describing hydroxyl radicals and active chlorine species contributions at ATZ oxidation were also proposed. Intermediate evolution profiles suggest that ATZ degradation can be considered as a series–parallel reaction system. Finally, the energy requirement assessment for ATZ removal was carried out. The highest ATZ removal (≅98%) was achieved with NaCl = 0.08 M, J = 60 A/m −2 , and E C = 5.83 kWh m −3 . Results highlight that atrazine removal was improved when an active chlorine species (NaCl) was present in the water solution. Moreover, the addition of chlorine species during electro-oxidation is an energy-saving strategy. Collectively, electro-oxidation technique can be efficiently applied to treat polluted water in order to meet the needs of recycling water quality and reduce resource consumption.

Electro-chemical oxidation↗
DOE OSTI2020

A short tutorial on uranium electropolishing

Electropolishing of uranium metal is best performed in a simple aqueous solution of phosphoric acid. With +3 to +10 volts of bias potential applied to the uranium (anode) relative to a Pt counter electrode (cathode). As summarized in a Pourbaix stability diagram, these conditions yield dissolution of the U surface as UOX containing solution species without the possibility of injecting hydrogen into the metal surface. However, if the uranium is biased to negative potentials relative to the counter electrode then water may be reduced at the U surface and hydrogen gas becomes available for reaction with the U metal. The stability diagram may be modified if there are other complexing species present in solution and the potential scale shifted if a different metal is use for the counter electrode. These effects can be understood in a known way as long as solution and electrochemical cell conditions are recognized.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2024

Controlling Product Selectivity in Photochemical CO 2 Reduction with the Redox Potential of the Photosensitizer

The ability to selectively reduce CO 2 to a particular product or mixture of products is expected to play a key role in mitigation strategies aiming to alleviate the devastating impact of this greenhouse gas in our climate and oceans. Among those, the production of liquid solar fuels from CO 2 and H 2 O will likely need cascade strategies involving multiple catalysts carrying out different functions. This will require that the catalysts doing the initial CO 2 reduction steps deliver the right product or products to downstream catalysts. CO, H 2 and formate are the most common products in CO 2 reduction by molecular catalysts. Here, in this work, we demonstrate control over the selectivity of C 1 products in photochemical CO 2 reduction with the same catalyst, simply by changing the redox potential of the photosensitizer and/or the water concentration. Turnover numbers for CO generation with one of the photosensitizers under anhydrous conditions reached 85,000, one of the largest values reported to date. A combination of experimental results and DFT calculations show that control of the selectivity is achieved, in part, due to the interplay between regimes under kinetic or thermodynamic control. These regimes are largely dictated by the proton sources and the CO 2 reduction byproducts generated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Scalable Solar Fuels Production in A Reactor Train System by Thermochemical Redox Cycling of Novel Nonstoichiometric Perovskites

Hydrogen production via two-step thermochemical water splitting redox cycles using nonstoichiometric redox-active metal oxides has the potential to dramatically increase fuel production rates. At moderate-to-low water splitting temperatures, surface reaction kinetics co-limit the process. In such cases, stable and high surface area microstructures that allow exploitation of the full thermodynamic potential of the materials are essential as is tight thermal integration of the reactor module. This project’s goals were the development of novel nonstoichiometric perovskite oxides with high stability and favorable thermodynamic and kinetic properties, to optimize their microstructure for maximizing the fuel productivity, and to build a prototype reactor train system (RTS) comprising at least one reactor to meet specific performance targets: (1) capable of an in-house solar thermochemical hydrogen (STCH) productivity ≥ 12 mL g -1 for stable continuous operation ≥ 20 cycles; and (2) demonstration of scalable solar fuels production at practical solar reactor level in an industrial-scale concentrated solar tower (CST) using developed perovskites to achieve a hydrogen production rate ≥ 1 g h -1 .

08 HYDROGEN↗
DOE OSTI2020

BESS-STAIR: a framework to estimate daily, 30m, and all-weather crop evapotranspiration using multi-source satellite data for the US Corn Belt

Abstract. With increasing crop water demands and drought threats, mapping andmonitoring of cropland evapotranspiration (ET) at high spatial and temporalresolutions become increasingly critical for water management andsustainability. However, estimating ET from satellites for precise waterresource management is still challenging due to the limitations in bothexisting ET models and satellite input data. Specifically, the process of ETis complex and difficult to model, and existing satellite remote-sensing datacould not fulfill high resolutions in both space and time. To address theabove two issues, this study presents a new high spatiotemporal resolution ETmapping framework, i.e., BESS-STAIR, which integrates a satellite-drivenwater–carbon–energy coupled biophysical model, BESS (Breathing Earth SystemSimulator), with a generic and fully automated fusion algorithm, STAIR(SaTallite dAta IntegRation). In this framework, STAIR provides daily 30'mmultispectral surface reflectance by fusing Landsat and MODIS satellite datato derive a fine-resolution leaf area index and visible/near-infrared albedo,all of which, along with coarse-resolution meteorological and CO 2 data, are used to drive BESS to estimate gap-free 30 m resolution daily ET.We applied BESS-STAIR from 2000 through 2017 in six areas across the US CornBelt and validated BESS-STAIR ET estimations using flux-tower measurementsover 12 sites (85 site years). Results showed that BESS-STAIR daily ETachieved an overall R2=0.75, with root mean square error RMSE=0.93 mm d -1 and relative error RE =27.9 % when benchmarkedwith the flux measurements. In addition, BESS-STAIR ET estimations capturedthe spatial patterns, seasonal cycles, and interannual dynamics well indifferent sub-regions. The high performance of the BESS-STAIR frameworkprimarily resulted from (1) the implementation of coupled constraints onwater, carbon, and energy in BESS, (2) high-quality daily 30 m data from theSTAIR fusion algorithm, and (3) BESS's applicability under all-skyconditions. BESS-STAIR is calibration-free and has great potentials to be areliable tool for water resource management and precision agricultureapplications for the US Corn Belt and even worldwide given the globalcoverage of its input data.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Water and Ammonia Desorption from 5A Zeolite

Demonstrate adsorption and desorption characteristics of water and ammonia on 5A zeolite during regeneration conditions using a Thermogravimetric analyzer (TGA) on samples previously evaluated by residual gas analyzer (RGA)/mass balance. Molecular sieve (zeolite) adsorbents have the following characteristics: Crystalline alumino-silicates containing pores or 'cages' that adsorb water or other molecules. Polar compound are adsorbed with high loading even at very low concentrations of the fluid. A 5A molecular sieve was chosen for its ability to adsorb both water and ammonia (NH{sub 3}) from a carrier gas stream. Preliminary RGA/mass balance testing indicated: 5A zeolite captured both NH{sub 3} and water as anticipated based on molecular size; Reloading showed limited success after zeolite heated beyond manufacturer recommended operating conditions: Steam dealumination theorized cause; Tests were reprioritized to focus on NH{sub 3} removal and end of life potential holdup of NH{sub 3} and water on 5A zeolite material. TGA measures a sample's weight and volatile composition as it is heated or cooled in a furnace. TGA heats sample to release volatile materials, (change in mass is measured). MS detects/measures low levels of impurities. Perform TGA desorption of zeolite samples taken at the following conditions tested with RGA (RGA results not shown here): Initial Bakeout conditions: hydrogen carrier gas, slowly raise temp to approximately 300 deg. C until desired moisture content <<100 ppm is achieved. Water loading (re-loading): argon carrier gas through bubbler until breach is observed. Ammonia loading (re-loading): hydrogen carrier gas through system. Regenerations/End of life conditions: hydrogen carrier gas, raise temp to approximately 300 deg. C, then slowly to 450 deg. C (end of life). After end of life testing less than 4% of the total mass was residual ammonia or water at bakeout conditions. Peak water and ammonia removal occurred around 275 deg. C and 150 deg. C respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Geoelectric Characterization of Hyporheic Exchange Flow in the Bedrock‐Lined Streambed of East Fork Poplar Creek, Oak Ridge, Tennessee

Abstract A multimethod geoelectric survey was implemented between January and March 2022 along a 220‐m long reach of the bedrock‐lined streambed of East Fork Poplar Creek in Oak Ridge, Tennessee to identify locations of surface‐water and groundwater exchange and characterize the subsurface flow paths that convey water between the stream and flood plain. A waterborne self‐potential (WaSP) survey was completed in January 2022 to measure the electric streaming‐potential field in the stream. Electric resistivity tomography (ERT) was performed in March 2022 on the flood plain adjacent to the WaSP survey reach to map the electric resistivity distribution and characterize the hydrogeology and subsurface flow paths that facilitate surface‐water and groundwater exchange in the bedrock‐lined stream. The combination of WaSP and ERT data support the qualitative interpretation that surface‐water and groundwater exchange likely occurs along fractures in outcropping bedrock and along two fault lines that intersect the limestone creek bed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Advanced Frost Sensor for HVAC Applications

Frost is a common problem in heating, ventilation, and air conditioning (HVAC) systems that can degrade their efficiencies, leading to excessive electricity consumption. Appropriate defrosting is therefore essential for heat pumps and refrigeration systems. However, these systems typically run the defrost cycle based on a predetermined time interval, a method that does not accurately identify the amount of frost and thus consume excessive electricity. To substantially improve defrosting initiation and termination, this paper describes development of a smart sensor based on a capacitive sensing technique that can quantify frost accumulation and difference between frost, ice, and water. The reported sensor adopts interdigitated comb electrodes and can be updated to a potential multifunctional sensor array for the enhancing identification of frost, ice, and water with the integrated measurement of surface temperature, frost capacitance, and resistance. The proposed frost sensor is potentially expected to have widespread applications in HVAC systems, including heat pumps, refrigerators, and commercial refrigeration systems.

Gao, Zhiming↗
DOE OSTI2022

Best Practices in PEC Water Splitting: How to Reliably Measure Solar-to-Hydrogen Efficiency of Photoelectrodes

Photoelectrochemical (PEC) water splitting, which utilizes sunlight and water to produce hydrogen fuel, is potentially one of the most sustainable routes to clean energy. One challenge to success is that, to date, similar materials and devices measured in different labs or by different operators lead to quantitatively different results, due to the lack of accepted standard operating procedures and established protocols for PEC efficiency testing. With the aim of disseminating good practices within the PEC community, we provide a vetted protocol that describes how to prepare integrated components and accurately measure their solar-to-hydrogen (STH) efficiency (η STH ). This protocol provides details on electrode fabrication, η STH test device assembly, light source calibration, hydrogen evolution measurement, and initial material qualification by photocurrent measurements under monochromatic and broadband illumination. Common pitfalls in translating experimental results from any lab to an accurate STH efficiency under an AM1.5G reference spectrum are discussed. A III–V tandem photocathode is used to exemplify the process, though with small modifications, the protocol can be applied to photoanodes as well. Dissemination of PEC best practices will help those approaching the field and provide guidance for comparing the results obtained at different lab sites by different groups.

08 HYDROGEN↗
DOE OSTI2020

Geothermal Deep Direct Use for Turbine Inlet Cooling in East Texas

The National Renewable Energy Laboratory (NREL), the Southern Methodist University Geothermal Laboratory (SMU), Eastman Chemical (Longview, TX), and TAS (Houston, TX) evaluated the feasibility of using geothermal heat to improve the performance of a natural-gas power plant in East Texas. The area of interest is the Eastman Chemical plant in Longview, Texas, which is on the northwestern margin of a geologic region known as the Sabine Uplift. The feasibility study focused on determining the potential for accessing a subsurface hot-water geothermal resource within a 10-km radius of the site to provide thermal energy for absorption chillers. Wells within a 20-km radius are included for broader geological comparison to determine the heat flow, temperature-at-depth, field porosity and permeability. The lithologies of most interest are the Lower Cretaceous Trinity Group and Upper Jurassic Cotton Valley Group. The deeper Cotton Valley formations are hotter (averaging 117 to 130°C), yet permeability and porosity are low. The shallower Trinity Group contains more variability in permeability and porosity and lower temperatures averaging about 98 to 117°C. The shallower formations are considered despite the lower temperature because of increased ability to produce larger volumes of water and extract enough heat before reinjection. The complete SMU analysis is available in the National Geothermal Data System (NGDS). Tapping such deep geothermal sources for direct heating (as opposed to power generation) is known as geothermal deep direct use (DDU). Geothermal DDU has potential across a wide swath of the United States but is underutilized due to challenging project economics associated with developing a deep geothermal resource for what are typically small-scale, variable-demand projects. This project examines the feasibility of geothermal energy integration in a natural-gas combined cycle power station in East Texas. The DDU resource is tapped to drive absorption chillers (24/7) for production of chilled water at 5-10°C (41-50°F). This chilled water is stored until needed, which allows for continuous operation with a relatively small-capacity geothermal/absorption chiller system. When conditions are favorable, the chilled water is dispatched to cool the air entering the compressor stage of a gas combustion turbine. This process, known as turbine inlet cooling (TIC), boosts power production during periods of high temperature and high-power demand. Such systems can enhance grid reliability and reduce the cost for peak-demand power. A simulation model of the power plant was developed in IPSEpro software and validated against operational data from the plant. This model allowed the team to estimate the additional power that could be produced by applying TIC under different operating and ambient conditions. Absorption chiller performance was estimated from vendor sources to determine the production rate of chilled water from the geothermal resource. Geothermal drilling and development costs were estimated using NREL's GEOPHIRES 2.0. The expected lower drilling costs in this region led to an estimated cost of geothermal heat of about $4/MMBtu (1.4 cents/kWh t ). The estimated cost for the absorption chillers and TIC hardware were obtained from literature sources and project partners. Hourly data were obtained for weather, natural gas and electricity prices, and plant operating state for 2017, which served as a representative year. NREL estimated the capital cost, operating cost, and additional electricity production and revenue for different combinations of geothermal capacity, chiller capacity, and water storage-tank size. The analysis drove toward smaller geothermal and chiller systems to reduce equipment cost. A relatively low-cost water storage tank accumulated the near-continuous chilled water output for later use when TIC was most valued.

15 GEOTHERMAL ENERGY↗