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At least 649 records · Page 36

Monitoring cure of composite resins using frequency dependent electromagnetic sensing techniques

A nondestructive in situ measurement technique has been developed for monitoring and measuring the cure processing properties of composite resins. Frequency dependent electromagnetic sensors (FDEMS) were used to directly measure resin viscosity during cure. The effects of the cure cycle and resin aging on the viscosity during cure were investigated using the sensor. Viscosity measurements obtained using the sensor are compared with the viscosities calculated by the Loos-Springer cure process model. Good overall agreement was obtained except for the aged resin samples.

Kranbuehl, D. E.↗

Properties of three graphite/toughened resin composites

Results are presented from an experimental evaluation of IM7/977-2, IM7/F655, and T800/F3900. Data presented include ply-level (unidirectional laminate) strength and moduli, unnotched and notched (open hole) tension and compression properties of quasi-isotropic laminates, and compression-after-impact strengths. These data are compared with properties of other toughened (IM7/8551-7 and IM6/18081) and brittle (T300/5208) graphite-epoxy materials. The IM7/977-2, IM7/F655, and T800/F3900 materials are substantially stronger and more damage tolerant than widely used first generation composite materials such as T300/5208. The T800/F3900 outperforms IM7/977-2 and IM7/F655 materials in tolerance to projectile impacts. Compression-after-impact strengths were found to be dependent on impactor velocity for a given impact energy. The open hole compression properties of all three materials are degraded by the combination of heat and moisture.

Smith, Donald L.↗

Improving processing and toughness of a high performance composite matrix through an interpenetrating polymer network. VI

A simultaneous semi-interpenetrating polymer network (semi-IPN) concept is presented which combines easy-to-process, but brittle, thermosetting polyimides with tough, but difficult to process, linear thermoplastic polyimides. The combination results in a semi-IPN with the easy processability of a thermoset and good toughness of a thermoplastic. Four simultaneous semi-IPN systems were developed from commercially available NR-150B2 combined with each of the four Thermid materials (LR-600, AL-600, MC-600, and FA-700). It is concluded that there is a significant improvement in resin fracture toughness of Thermid-polyimide-based semi-IPN systems and some improvement in composite microcracking resistance compared to Thermid LR-600. Excellent composite mechanical properties have been achieved. These new semi-IPN materials have the potential to be used as composite matrices, adhesives, and molding materials.

Pater, Ruth H.↗

The effect of processing and compositional changes on the tribology of PM212 in air

The effects of processing and compositional variations on the tribological performance of PM212 were studied. PM212 is a self lubricating powder metallurgy composite, comprised of a wear resistant metal bonded chromium carbide matrix, containing the solid lubricants barium fluoride/calcium fluoride eutectic and silver. Several composites were formulated which had lubricant, matrix, and processing variations. Processing variations included sintering and hot isostatic pressing. Pins fabricated from the composites were slid against superalloys disks in a pin-on-disk tribometer to study the tribological properties. Several composites exhibited low friction and wear in sliding against a nickel based superalloy. The tribological performance by several different composites showed that the composition of PM212 can be altered without dramatically affecting performance.

Bogdanski, Michael S.↗

Noncontact Determination of Antisymmetric Plate Wave Velocity in Ceramic Matrix Composites

High-temperature materials are of increasing importance in the development of more efficient engines and components for the aeronautics industry. In particular, ceramic matrix composite (CMC) and metal matrix composite (MMC) structures are under active development for these applications. The acousto-ultrasonic (AU) method has been shown to be useful for assessing mechanical properties in composite structures. In particular, plate wave analysis can characterize composites in terms of their stiffness moduli. It is desirable to monitor changes in mechanical properties that occur during thermomechanical testing and to monitor the health of components whose geometry or position make them hard to reach with conventional ultrasonic probes. In such applications, it would be useful to apply AU without coupling directly to the test surface. For a number of years, lasers have been under investigation as remote ultrasonic input sources and ultrasound detectors. The use of an ultrasonic transducer coupled through an air gap has also been under study. So far at the NASA Lewis Research Center, we have been more successful in using lasers as ultrasonic sources than as output devices. On the other hand, we have been more successful in using an air-coupled piezoelectric transducer as an output device than as an input device. For this reason, we studied the laser in/air-coupled-transducer out combination-using a pulsed NdYAG laser as the ultrasonic source and an air-coupled-transducer as the detector. The present work is focused on one of the AU parameters of interest, the ultrasonic velocity of the antisymmetric plate-wave mode. This easily identified antisymmetric pulse can be used to determine shear and flexure modulus. It was chosen for this initial work because the pulse arrival times are likely to be the most precise. The following schematic illustrates our experimental arrangement for using laser in/air-transducer out on SiC/SiC composite tensile specimens. The NdYAG pulse was directed downward by a 90 infrared prism to the top of the specimen, but at the edge of one end. An energy sensor measured a single pulse at 13 millijoules (mJ) before it passed through the prism, which attenuated 15 percent of its energy. It also provided an output trigger for the waveform time-delay synthesizer.

Kautz, Harold E.↗

Microstructure and orientation effects on properties of discontinuous silicon carbide/aluminum composites

Composite panels containing up to 40 vol % discontinuous silicon carbide SiC whisker, nodule, or particulate reinforcement in several aluminum matrices are commercially fabricated and the mechanical properties and microstructual characteristics are evaluated. The yield and tensile strengths and the ductility are controlled primarily by the matrix alloy, the temper condition, and the reinforcement content. Particulate and nodule reinforcements are as effective as whisker reinforcement. Increased ductility is attributed to purer, more uniform starting materials and to more mechanical working during fabrication. Comparing mechanical properties with those of other aluminum alloys shows that these low cost, lightweight composites demonstrate very good potential for application to aerospace structures.

Mcdanels, D. L.↗

Distributed Sensing of Composite Over-wrapped Pressure Vessel Using Fiber-Bragg Gratings at Ambient and Cryogenic Temperatures

Fiber Bragg gratings are use to monitor the structural properties of composite pressure vessels. These gratings optically inscribed into the core of a single mode fiber are used as a tool to monitor the stress strain relation in laminate structure. The fiber Bragg sensors are both embedded within the composite laminates and bonded to the surface of the vessel with varying orientations with respect to the carbon fiber in the epoxy matrix. The response of these fiber-optic sensors is investigated by pressurizing the cylinder up to its burst pressure of around 2800 psi. This is done at both ambient and cryogenic temperatures using water and liquid nitrogen. The recorded response is compared with the response from conventional strain gauge also present on the vessel. Additionally, several vessels were tested that had been damaged to simulate different type of events, such as cut tow, delimitation and impact damage.

Grant, Joseph↗

Distributed sensing of Composite Over-wrapped Pressure Vessel using Fiber-Bragg Gratings at Ambient and Cryogenic Temperatures

Fiber Bragg gratings are use to monitor the structural properties of composite pressure vessels. These gratings optically inscribed into the core of a single mode fiber are used as a tool to monitor the stress strain relation in laminate structure. The fiber Bragg sensors are both embedded within the composite laminates and bonded to the surface of the vessel with varying orientations with respect to the carbon fiber in the epoxy matrix. The response of these fiber-optic sensors is investigated by pressurizing the cylinder up to its burst pressure of around 2800 psi. This is done at both ambient and cryogenic temperatures using water and liquid nitrogen. The recorded response is compared with the response from conventional strain gauge also present on the vessel. Additionally, several vessels were tested that had been damaged to simulate different type of events, such as cut tow, delimitation and impact damage.

Grant, Joseph↗

Multiscale Modeling of Carbon/Phenolic Composite Thermal Protection Materials: Atomistic to Effective Properties

Next generation ablative thermal protection systems are expected to consist of 3D woven composite architectures. It is well known that composites can be tailored to achieve desired mechanical and thermal properties in various directions and thus can be made fit-for-purpose if the proper combination of constituent materials and microstructures can be realized. In the present work, the first, multiscale, atomistically-informed, computational analysis of mechanical and thermal properties of a present day - Carbon/Phenolic composite Thermal Protection System (TPS) material is conducted. Model results are compared to measured in-plane and out-of-plane mechanical and thermal properties to validate the computational approach. Results indicate that given sufficient microstructural fidelity, along with lowerscale, constituent properties derived from molecular dynamics simulations, accurate composite level (effective) thermo-elastic properties can be obtained. This suggests that next generation TPS properties can be accurately estimated via atomistically informed multiscale analysis.

Materials Science↗

Predicting Fractures In Fiber/Matrix Composites

NASA technical memorandum discusses status of emerging methodology of computational simulation of fractures in fiber/matrix composite structural components. Part of methodology consists of step-by-step procedures to simulate fractures in individual and mixed models in variety of generic composite-material components. Another part of methodology embodied in computer program CODSTRAN, which incorporates mathematical models of mechanical properties of composites and of fracture mechanics. Authors assert methodology ready for widespread application.

Chamis, C. C.↗

Simulating Microfracture In Metal-Matrix Composites

Computational procedures developed for simulating microfracture in metal-matrix/fiber composite materials under mechanical and/or thermal loads at ambient and high temperatures. Procedures evaluate microfracture behavior of composites, establish hierarchies and sequences of fracture modes, and examine influences of compliant layers and partial debonding on properties of composites and on initiation of microfractures in them.

Mital, Subodh K.↗

Considerations Concerning the Development and Testing of In-situ Materials for Martian Exploration

Natural Martian surface materials are evaluated for their potential use as radiation shields for manned Mars missions. The modified radiation fluences behind various kinds of Martian rocks and regolith are determined by solving the Boltzmann equation using NASA Langley s HZETRN code along with the 1977 Solar Minimum galactic cosmic ray environmental model. To make structural shielding composite materials from constituents of the Mars atmosphere and from Martian regolith for Martian surface habitats, schemes for synthesizing polyimide from the Mars atmosphere and for processing Martian regolith/polyimide composites are proposed. Theoretical predictions of the shielding properties of these composites are computed to assess their shielding effectiveness. Adding high-performance polymer binders to Martian regolith to enhance structural properties enhances the shielding properties of these composites because of the added hydrogenous constituents. Laboratory testing of regolith simulant/polyimide composites is planned to validate this prediction.

Kim, M.-H. Y.↗

Investigation of sources, properties and preparation of distillate test fuels

Distillate test fuel blends were generated for prescribed variations in composition and physical properties. Fuels covering a wide range in properties and composition which would provide a matrix of fuels for possible use in future combustion research programs were identified. Except for tetralin the blending components were all from typical refinery streams. Property variation blends span a boiling range within 150 C to 335 C, freezing point -23 C to -43 C, aromatic content 20 to 50 volume percent, hydrogen content 11.8 to 14.2 mass percent, viscosity 4 and 11 cSt (-20 C), and naphthalenes 8 and 16 volume percent. Composition variation blends were made with two base stocks, one paraffinic and the other napthenic. To each base stock was added each of three aromatic type fuels (alkyl benzenes, tetralin, and naphthalenes) for assigned initial boiling point, final boiling point, and hydrogen content. The hydrogen content was 13.5 mass percent for the paraffinic base stock blends and 12.5 mass percent and 11.5 mass percent for the naphthenic base stock blends. Sample 5-gallon quantities of all blends were prepared and analyzed.

Bowden, J. N.↗

Dispersion of borax in plastic is excellent fire-retardant heat insulator

A mix of borax powder and a chlorinated anhydrous polyester resin yields a plastic composition that is fire-retardant, yields a minimum of toxic gases when heated, and exhibits high thermal insulating properties. This composition can be used as a coating or can be converted into laminated or cast shapes.

Evans, H.↗

Evaluation of low-cost aluminum composites for aircraft engine structural applications

Panels of discontinuous SiC composites, with several aluminum matrices, were fabricated and evaluated. Modulus, yield strength and tensile strength results indicated that the properties of composites containing SiC whisker, nodule or particulate reinforcements were similar. The modulus of the composites was controlled by the volume percentage of the SiC reinforcement content, while the strength and ductility were controlled by both the reinforcement content and the matrix alloy. The feasibility of fabricating structural shapes by both wire performs and direct casting was demonstrated for Al2O3/Al composites. The feasibility of fabricating high performance composites into structural shapes by low pressure hot molding was demonstrated for B4C-coated B/Al composites.

Mcdanels, D. L.↗

An infiltration/cure model for manufacture of fabric composites by the resin infusion process

A 1-D infiltration/cure model was developed to simulate fabrication of advanced textile composites by the resin film infusion process. The simulation model relates the applied temperature and pressure processing cycles, along with the experimentally measured compaction and permeability characteristics of the fabric preforms, to the temperature distribution, the resin degree of cure and viscosity, and the infiltration flow front position as a function of time. The model also predicts the final panel thickness, fiber volume fraction, and resin mass for full saturation as a function of compaction pressure. Composite panels were fabricated using the RTM (Resin Transfer Molding) film infusion technique from knitted, knitted/stitched, and 2-D woven carbon preforms and Hercules 3501-6 resin. Fabric composites were fabricated at different compaction pressures and temperature cycles to determine the effects of the processing on the properties. The composites were C-scanned and micrographed to determine the quality of each panel. Advanced cure cycles, developed from the RTM simulation model, were used to reduce the total cure cycle times by a factor of 3 and the total infiltration times by a factor of 2.

Weideman, Mark H.↗

Dry Preform Stitching Using Temporary Vacuum Consolidation

Stitched composites (composite parts stitched in a dry preform state that are infused with resin and cured to a final shape) offer a variety of benefits for modern aircraft structures. In this document one means of stitching dry fabric preforms in a state of temporary vacuum consolidation is discussed. This vacuum consolidation allows for the completion of stitching procedures while the dry preform thickness is temporarily reduced to a thickness reflective of its final cured thickness. Here, a temporary vacuum consolidation process enabling stitching of preforms of unconsolidated nominal thickness greater than the maximum allowable stitching thickness for the Integrated Structural Assembly of Advanced Composite (ISAAC) system is explored as a use case for such processes. Temporary vacuum consolidation processes may lead to simplified manufacturing processes or desirable composite material properties in the future.

Stitched Composites↗