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Platform under growth region stabilizes melt for more uniform crystal growth. In new crucible, platform just below growth interface so melt is too shallow to support convection. Critical depth for onset of pertinent instability calculated from heat flux through surface of melt, volume coefficient of thermal expansion, thermal conductivity, thermal diffusivity, and kinematic viscosity.
The objectives of this work are to develop growth techniques and theory leading to improved bulk growth of semiconductor single crystals. Ground based experiments will be complemented by experiments carried out in the low-g environment provided by the space shuttle. Analytical studies and laboratory investigations are being conducted to better define the causes of crystalline defects and inhomogeneities. The compound semiconductor lead-tin-telluride is being used as the modeling material. Theoretical techniques are being developed to predict the thermal and solutal fields which are present during bulk growth from a melt. Techniques for measuring the thermophysical properties of semiconductors at high temperatures have been developed. During the past year electrochemical etching techniques have been developed for delineation of inhomogeneous regions in crystals. Thermal diffusivity measurements have been completed for the solid and liquid phases of PbTe and PbSnTe. Preliminary results have been obtained on the effects on crystal morphology of gravity, interface shape and interaction between the melt and the container.
The graded interface between an ion-plated film and a substrate is discussed as well as the friction and wear properties of ion-plated gold. X-ray photoelectron spectroscopy (XPS) depth profiling and microhardness depth profiling were used to investigate the interface. The friction and wear properties of ion-plated and vapor-deposited gold films were studied both in an ultra high vacuum system to maximize adhesion and in oil to minimize adhesion. The results indicate that the solubility of gold on the substrate material controls the depth of the graded interface. Thermal diffusion and chemical diffusion mechanisms are thought to be involved in the formation of the gold-nickel interface. In iron-gold graded interfaces the gold was primarily dispersed in the iron and thus formed a physically bonded interface. The hardness of the gold film was influenced by its depth and was also related to the composition gradient between the gold and the substrate. The graded nickel-gold interface exhibited the highest hardness because of an alloy hardening effect. The effects of film thickness on adhesion and friction were established.
The analysis begins with a seasonal energy balance model (EBM) for Mars. This is used to compute surface temperature versus x = sin(latitude) and time over the seasonal cycle. The core model also computes the evolving boundaries of the CO2 icecaps, net sublimational/condensation rates, and the resulting seasonal pressure wave. Model results are compared with surface temperature and pressure history data at Viking lander sites, indicating fairly good agreement when meridional heat transport is represented by a thermal diffusion coefficient D approx. 0.015 W/sq. m/K. Condensational wind distributions are also computed. An analytic model of Martian wind circulation is then proposed, as an extension of the EMB, which incorporates vertical wind profiles containing an x-dependent function evaluated by substitution in the equation defining the diffusion coefficient. This leads to a parameterization of D(x) and of the meridional circulation which recovers the high surface winds predicted by dynamic Mars atmosphere models (approx. 10 m/sec). Peak diffusion coefficients, D approx. 0.6 w/sq m/K, are found over strong Hadley zones - some 40 times larger than those of high-latitude baroclinic eddies. When the wind parameterization is used to find streamline patterns over Martian seasons, the resulting picture shows overturning hemispheric Hadley cells crossing the equator during solstices, and attaining peak intensities during the south summer dust storm season, while condensational winds are most important near the polar caps.
The geoid and topographic fields of the central Pacific were delineated and shown to correlate closely at intermediate wavelengths (500 to 2500 km). The associated admittance shows that anomalies having wavelengths less than about 1000 km are probably supported by the elastic strength of the lithosphere. Larger wavelength anomalies are due to dynamic effects in the sublithosphere. Direct modeling of small scale convection in the asthenosphere shows that the amplitudes of observed geoid and topographic anomalies can be independently matched, but that the observed admittance cannot. Only by imposing an initial regional variation in the thermal regime is it possible to match the admittance. It is proposed that this variation may be due to differences in the onset time of convection beneath the lithosphere of different ages. That is, convection beneath thickening lithosphere is strongly dependent on the rate of thickening (V) relative to the rise time for convection. The critical Rayleigh number contains the length scale K/V, where K is thermal diffusivity. Young, fast growing lithosphere stabilizes the underlying asthenosphere unless it has an unusually low viscosity. Lithosphere of different age, separated by fracture zones, will go unstable at different times, producing regional horizontal temperature gradient that may strongly influence convection. Laboratory and numerical experiments are proposed to study this form of convection and its influence on the geoid.
The theoretical and experimental framework for thickness measurements of thin metal films by low frequency thermal waves is described. Although it is assumed that the films are opaque and the substrates are comparatively poor thermal conductors, the theory is easily extended to other cases of technological interest. A brief description is given of the thermal waves and the experimental arrangement and parameters. The usefulness of the technique is illustrated for making absolute measurements of the thermal diffusivities of isotropic substrate materials. This measurement on pure elemental solids provides a check on the three dimensional theory in the limiting case of zero film thickness. The theoretical framework is then presented, along with numerical calculations and corresponding experimental results for the case of copper films on a glass substrate.
A modified multi-level soil moisture and surface temperature model is presented for use as in defining lower boundary conditions in mesoscale weather models. Account is taken of the hydraulic and thermal diffusion properties of the soil, their variations with soil type, and the mixing ratio at the surface. Techniques are defined for integrating the surface input into the multi-level scheme. Sample simulation runs were performed with the modified model and the original model defined by Pielke, et al. (1977, 1981). The models were applied to regional weather forecasting over soils composed of sand and clay loam. The new form of the model avoided iterations necessary in the earlier version of the model and achieved convergence at reasonable profiles for surface temperature and moisture in regions where the earlier version of the model failed.
The IRAS sky survey yielded a very extensive picture of bright diffuse thermal emission from interplanetary dust grains at wavelengths from 12 to 100 micrometers. These data provide insights into the character, spatial distribution, and perhaps origin of these particles which both confirm and expand upon those gained from previous zodiacal light studies. The zodiacal emission is a major component of the large scale infrared brightness of the sky at all IRAS wavelengths. It must therefore be carefully characterized both to facilitate study of large-angular-scale sources in the Galaxy and beyond using IRAS data, and to permit optimum design of future space infrared instrument.
Thermal Remote Anemometer Device developed for remote, noncontacting, passive measurement of thermal properties of sample. Model heated locally by scanning laser beam and cooled by wind in tunnel. Thermal image of model analyzed to deduce pattern of airflow around model. For materials applications, system used for evaluation of thin films and determination of thermal diffusivity and adhesive-layer contact. For medical applications, measures perfusion through skin to characterize blood flow and used to determine viabilities of grafts and to characterize tissues.
After 10 years of extensive research on crystalline-silicon flat-plate photovoltaic modules, the emphasis of recent reliability research has shifted to the emerging first-generation thin-film amorphous-silicon modules. These modules share much in common with their crystalline precursors, but also include many materials and processes that demand the development of reliability technologies. Key research thrusts include light-induced effects, cell corrosion, thermal diffusion, hot-spot heating, and electrical isolation of the cells from the module exterior. Research goals and recent achievements are described in each of these areas.
Particle impact and frictional heating tests of metals in high pressure oxygen, are conducted in support of the design of an advanced rocket engine oxygen turbopump. Materials having a wide range of thermodynamic properties including heat of combustion and thermal diffusivity were compared in their resistance to ignition and sustained burning. Copper, nickel and their alloys were found superior to iron based and stainless steel alloys. Some materials became more difficult to ignite as oxygen pressure was increased from 7 to 21 MPa (1000 to 3000 psia).
The research performed at the Center for Reactive Flow and Dynamical Systems in the Laboratory for Computational Physics and Fluid Dynamics, at the Naval Research Laboratory, in support of the NASA Microgravity Science and Applications Program is described. The primary focus was on investigating fundamental questions concerning the propagation and extinction of premixed flames in Earth gravity and in microgravity environments. The approach was to use detailed time-dependent, multispecies, numerical models as tools to simulate flames in different gravity environments. The models include a detailed chemical kinetics mechanism consisting of elementary reactions among the eight reactive species involved in hydrogen combustion, coupled to algorithms for convection, thermal conduction, viscosity, molecular and thermal diffusion, and external forces. The external force, gravity, can be put in any direction relative to flame propagation and can have a range of values. A combination of one-dimensional and two-dimensional simulations was used to investigate the effects of curvature and dilution on ignition and propagation of flames, to help resolve fundamental questions on the existence of flammability limits when there are no external losses or buoyancy forces in the system, to understand the mechanism leading to cellular instability, and to study the effects of gravity on the transition to cellular structure. A flame in a microgravity environment can be extinguished without external losses, and the mechanism leading to cellular structure is not preferential diffusion but a thermo-diffusive instability. The simulations have also lead to a better understanding of the interactions between buoyancy forces and the processes leading to thermo-diffusive instability.
Data on solar luminosity variations are compiled in graphs and analyzed, with a focus on the SMM satellite bolometric measurements and other observations made since 1983. Consideration is given to total irradiance measurements in integrated light; emission-line variability in the visible, UV, and IR; mechanisms contributing to the solar variability (sunspots, faculae, rotation, oscillations, granulation, and active networks); the role of the solar magnetic cycle; and other observable parameters indicating variability. Also discussed are the effects of solar variations on the earth climate and the implications of the observations for theoretical models of convective-envelope processes (thermal diffusion near the surface and magnetic pressure in the interior).
The role of gravity-dependent convection in the steady-state growth of dendrites in undercooled melts is investigated theoretically. The model described by Huang and Glicksman (1981) is extended and refined, using the concept of a thermal diffusion boundary layer (Burton et al., 1987) to characterize the dendritic interface. Theoretical predictions are presented in graphs and shown to be in good general agreement with published experimental data on succinonitrile. The need for careful space experiments to clarify the role of nongravity-dependent convection is indicated.
Problems on the identification of two-dimensional spatial domains arising in the detection and characterization of structural flaws in materials are considered. For a thermal diffusion system with external boundary input, observations of the temperature on the surface are used in an output least square approach. Parameter estimation techniques based on the method of mappings are discussed, and approximation schemes are developed based on a finite-element Galerkin approach. Theoretical convergence results for computational techniques are given, and the results are applied to the identification of two kinds of boundary shapes.
Equations derived to improve analysis of experimental data in flash method for measurement of thermal diffusivity and heat capacity. In flash method, pulse of radiant energy from flashlamp or other source deposited on front face of small, thin specimen, and temperature of rear face monitored as function of time. New equations account for both losses and exponentially decaying pulses.
An investigation into the heat sink effects due to weldment irregularities and fixtures used in the variable polarity plasma arc (VPPA) process was conducted. A basic two-dimensional model was created to represent the net heat sink effect of surplus material using Duhamel's theorem to superpose the effects of an infinite number of line heat sinks of variable strength. Parameters were identified that influence the importance of heat sink effects. A characteristic length, proportional to the thermal diffusivity of the weldment material divided by the weld torch travel rate, correlated with heat sinking observations. Four tests were performed on 2219-T87 aluminum plates to which blocks of excess material were mounted in order to demonstrate heat sink effects. Although the basic model overpredicted these effects, it correctly indicated the trends shown in the experimental study and is judged worth further refinement.
The results of X-band noise temperature tests on two types of antenna surface panels are presented. The first type tested was a solid antenna panel, while the second type was a perforated panel with 3/16-in.-diameter holes. Measurements were made at 8.45 GHz using an X-band radiometric system. Included in this article are measured noise temperature contributions from: (1) thermal diffusive white paint on solid and perforated panels, and (2) water sprayed on both painted and unpainted perforated panels. Experiments on perforated panels were restricted to the 3/16-in.-diameter hole panels formerly used on Deep Space Network 64-m antennas. Rigorous calibration equations, applicable to a variety of antenna panel and dichroic plate test configurations, are presented. It was demonstrated that an accurate, stable radiometric measurement system of the type used for the results of this research makes it possible to obtain information that would be much more difficult to obtain using other techniques.