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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2026

Highly Porous Polyimide Gel for Use as Battery Separator with Room Temperature Ionic Liquid Electrolytes

Advanced aerospace vehicular concepts require advances in many existing technologies, including space power and energy storage systems. Batteries represent one of the major areas in need of improvement, both in terms of energy density and safety, with growing concerns over the fire safety of commercial lithium-ion batteries. This has prompted efforts to develop nonflammable battery components, namely the electrolyte and separator. Existing commercial lithium-ion batteries utilize polyolefin microporous membranes as separators with an electrolyte consisting of a lithium salt dissolved in a mixture of cyclic carbonate solvents. This separator/electrolyte combination has ionic conductivities in the range of 10 −2 to 10 −3 S/cm. However, the cyclic carbonate solvents are inherently flammable. Room-temperature ionic liquids (RTILs) appear to be a safer alternative. They offer good ionic conductivities and are inherently nonvolatile and nonflammable, giving them a safety advantage. However, many promising RTILs for battery electrolytes are not compatible with commercial polyolefin separator materials. Alternative separator materials, such as polyimides, are non-flammable and are capable of accepting RTILs into their structure. Polyimide gels, with a composition of 4,4′-oxydianiline, 3,3′,4,4′-tetracarboxylic dianhydride and cross-linked with Desmodur N3300A, possess an open-porous, fibrillar network architecture which offers a high degree of porosity (typically greater than 85% porosity) for lithium-ion transport and conduction, as well as good mechanical properties. Furthermore, these polyimide gels are compatible with selected imidazolium-based RTILs. Nonflammable separator/electrolyte systems with room-temperature conductivities in the range of 10 −3 S/cm have been evaluated. It has been demonstrated that 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide was the most promising among six RTILs screened, in terms of both ionic conductivity and constant current cycling.

Polyimide↗
NASA NTRS1971

Room temperature measurements of electrical resistivity and thermal conductivity of various graphites

Room temperature thermal conductivity measurements were completed on 10 graphite samples selected from the lot of 120 to uniformly span the range of electrical resistivity values. From these data and other measurements a thermal conductivity-electrical conductivity correlation was established to predict room temperature thermal conductivity values for the graphite samples. The correlation, expressed by a parabolic equation, represents available thermal and electrical conductivity data to about + or - 8%.

Mcelroy, D. L.↗
NASA NTRS1972

Infrared absorptivities of transition metals at room and liquid-helium temperatures.

Evaluation of experimental data concerning the normal spectral absorptivities of the transition metals, nickel, iron, platinum, and chromium, at both room and liquid-helium temperatures in the wavelength range from 2.5 to 50 microns. The absorptivities were derived from reflectivity measurements made relative to a room-temperature vapor-deposited gold reference mirror. The absorptivity of the gold reference mirror was measured calorimetrically, by use of infrared laser sources. Investigation of various methods of sample-surface preparation resulted in the choice of a vacuum-annealing process as the final stage. The experimental results are discussed on the basis of the anomalous-skin-effect theory modified for multiple conduction bands. As predicted, the results approach a single-band model toward the longer wavelengths. Agreement between theory and experiment is considerably improved by taking into account the modification of the relaxation time due to the photon-electron-phonon interaction proposed by Holstein (1954) and Gurzhi (1958); but, particularly at helium temperatures, the calculated curve is consistently below the experimental results.

Jones, M. C.↗
NASA NTRS1972

Direction-specific adaptation effects acquired in a slow rotation room

Thirty-eight subjects were required to execute 120 head movements in a slow rotation room at each 1-rpm increase in velocity of the room between 0 and 6 rpm and, after a single-step gradual return to zero velocity, execute 120 head movements either immediately after the return or after delay periods varying from 1 to 24 hours unless, at any time, more than mild symptoms of motion sickness were elicited. A second stress profile differed by the sequential addition of an incremental adaptation schedule in which the direction of rotation was reversed. The experimental findings demonstrated the acquisition of direction-specific adaptation effects that underwent spontaneous decay with a short time constant (hours). Speculations are presented which could account for the simultaneous acquisition of short-term and long-term adaptation effects. The findings support the theory that motion sickness, although a consequence of vestibular stimulation, has its immediate origin in nonvestibular systems, implying a faculative or temporary linkage between the vestibular and nonvestibular systems.

Graybiel, A.↗
NASA NTRS1972

Direction-specific adaptation effects acquired in a slow rotation room.

Thirty-eight subjects were required to execute 120 head movements in a slow rotation room at each 1-rpm increase in velocity of the room between 0 and 6 rpm and, after a single-step gradual return to zero velocity, execute 120 head movements either immediately after return or after delay periods varying from 1 to 24 hours unless, at any time, more than mild symptoms of motion sickness were elicited. A second stress profile differed by the sequential addition of an incremental adaptation schedule (identical to the first) in which the direction of rotation was reversed. The experimental findings demonstrated the acquisition of direction-specific adaptation effects that underwent spontaneous decay with a short time constant (hours). With their disappearance a nondirection-specific adaptation was revealed with a long-time constant (days). Speculations are presented which could account for the simultaneous acquisition of short-term and long-term adaptation effects.

Graybiel, A.↗
NASA NTRS1972

The acoustic response of rooms with open windows to airborne sounds.

The objective of the work described in this and the companion paper was to establish a theory for predicting the sound field generated in a room by a sonic boom incident on an open window. In this paper, some basic theoretical results are presented. First, the case of a normally incident harmonic wave was considered. Expressions for the pressure field were obtained by viewing the room as a terminated duct and by using a Green function method. The concept of mode excitation distribution functions was formulated and used to match the boundary conditions. This concept has been extended for oblique incidence. A modified form of Laplace transform technique was used to obtain expressions in the time domain for transient signals.

Vaidya, P. G.↗
NASA NTRS1974

New theory on the reverberation of rooms

The inadequacy of the various theories which have been proposed for finding the reverberation time of rooms can be explained by an attempt to examine what might occur at a listening point when image sources of determined acoustic power are added to the actual source. The number and locations of the image sources are stipulated. The intensity of sound at the listening point can be calculated by means of approximations whose conditions for validity are given. This leads to the proposal of a new expression for the reverberation time, yielding results which fall between those obtained through use of the Eyring and Millington formulae; these results are made to depend on the shape of the room by means of a new definition of the mean free path.

Pujolle, J.↗
NASA NTRS1974

Complex soundproofing of industrial rooms

Some structures treated for sound absorption are described that are used to soundproof industrial rooms with a very high noise level. Soundproofing treatments for the walls and coilings or only for the ceilings are considered. In the case of relatively small rooms having a noise source with a high level, complex treatments involve, in addition to soundproofing of the walls and ceiling, suspended panels specially oriented with respect to the noise source. The efficiency of the adopted solutions is compared with calculated damping values.

Pocsa, V.↗
NASA NTRS1980

Mechanical property characterization of Borsic/aluminum laminates at room and elevated temperatures

Six Borsic/aluminum laminate orientations exposed to a braze temperature cycle were tested in tension, compression, and shear to determine tangent modulus, maximum stress and strain, and Poisson's ratio of the laminates at room and elevated temperatures. Mechanical properties in tension were determined from flat tensile and sandwich beam tests. Room temperature flat tensile tests were performed on laminates in the as-received condition to compare with specimens exposed to a braze temperature cycle. Sandwich beam tests were also used to determine mechanical properties in compression. Shear properties were determined from biaxially loaded, picture frame shear specimens. Results are presented by using functional relations between stress and strain and tangent modulus and strain, and in tables by indicating maximum stress and strain and Poisson's ratio.

Mcwithey, R. R.↗
NASA NTRS1981

A study of low-noise preamplifier systems for use with room temperature mercuric iodide /HgI2/ X-ray detectors

An analysis of different preamplification systems for use with room temperature mercuric iodide X-ray detectors has been performed. Resistor-, drain-, and light-feedback preamplifiers have been studied. Energy resolution values of 295 eV (FWHM) for an Fe-55 source (5.9 keV) and 225 eV (FWHM) for a pulser have been obtained with both the detector and the input FET at room temperature using a pulsed-light feedback preamplifier. Improvement in energy resolution by cooling the input FET using a small Peltier element has been discussed.

Iwanczyk, J. S.↗
NASA NTRS1983

Human factors aspects of control room design

A plan for the design and analysis of a multistation control room is reviewed. It is found that acceptance of the computer based information system by the uses in the control room is mandatory for mission and system success. Criteria to improve computer/user interface include: match of system input/output with user; reliability, compatibility and maintainability; easy to learn and little training needed; self descriptive system; system under user control; transparent language, format and organization; corresponds to user expectations; adaptable to user experience level; fault tolerant; dialog capability user communications needs reflected in flexibility, complexity, power and information load; integrated system; and documentation.

Jenkins, J. P.↗
NASA NTRS1982

Experimental verification of the Neuber relation at room and elevated temperatures

The accuracy of the Neuber equation at room temperature and 1,200 F as experimentally determined under cyclic load conditions with hold times. All strains were measured with an interferometric technique at both the local and remote regions of notched specimens. At room temperature, strains were obtained for the initial response at one load level and for cyclically stable conditions at four load levels. Stresses in notched members were simulated by subjecting smooth specimens to he same strains as were recorded on the notched specimen. Local stress-strain response was then predicted with excellent accuracy by subjecting a smooth specimen to limits established by the Neuber equation. Data at 1,200 F were obtained with the same experimental techniques but only in the cyclically stable conditions. The Neuber prediction at this temperature gave relatively accurate results in terms of predicting stress and strain points.

Lucas, L. J.↗
NASA NTRS1983

Experimental Verification of the Number Relation at Room and Elevated Temperatures

The accuracy of the Neuber equation for predicting notch root stress-strain behavior at room temperature and at 650 C was experimentally investigated. Strains on notched specimens were measured with a non-contacting, interferometric technique and stresses were simulated with smooth specimens. Predictions of notch root stress-strain response were made from the Neuber Equation and smooth specimen behavior. Neuber predictions gave very accurate results at room temperature. However, the predicted interaction of creep and stress relaxation differed from experimentally measured behavior at 650 C.

Lucas, L. J.↗
NASA NTRS1985

Collection and analysis of NASA clean room air samples

The environment of the HALOE assembly clean room at NASA Langley Research Center is analyzed to determine the background levels of airborne organic compounds. Sampling is accomplished by pumping the clean room air through absorbing cartridges. For volatile organics, cartridges are thermally desorbed and then analyzed by gas chromatography and mass spectrometry, compounds are identified by searching the EPA/NIH data base using an interactive operator INCOS computer search algorithm. For semivolatile organics, cartridges are solvent entracted and concentrated extracts are analyzed by gas chromatography-electron capture detection, compound identification is made by matching gas chromatogram retention times with known standards. The detection limits for the semivolatile organics are; 0.89 ng cu m for dioctylphlhalate (DOP) and 1.6 ng cu m for polychlorinated biphenyls (PCB). The detection limit for volatile organics ranges from 1 to 50 parts per trillion. Only trace quantities of organics are detected, the DOP levels do not exceed 2.5 ng cu m and the PCB levels do not exceed 454 ng cu m.

Sheldon, L. S.↗
NASA NTRS1987

Room temperature tensile ductility in powder processed B2 FeAl alloys

It has been shown that it is possible to obtain significant room temperature tensile ductility in FeAl alloys using iron-rich deviations from stoichiometry. A comparison of the room temperature tensile and compressive behaviors of Fe-50 at. pct Al and Fe-40 at. pct Al shows that FeAl is brittle at higher Al contents because it fractures along grain boundaries before general yielding. Lower aluminum contents reduce the yield stress substantially and hence some ductility is observed before fracture. Addition of boron results in measurable improvements in ductility of Fe-40 at. pct Al and is accompanied by an increase in transgranular tearing on the fracture surface, suggesting a grain boundary strengthening mechanism. Increasing the cooling rate following annealing at 1273 K results in a large increase in the yield strength and a corresponding decrease in ductility.

Crimp, M. A.↗
NASA NTRS1988

Multiplexed 256 element InGaAs detector arrays for 0.8-1.7-micron room-temperature operation

InGaAs photodetectors have been configured into linear arrays of 30 x 30 micron photodetectors spaced 50 microns apart. The devices have typical responsivities of 0.9 A/W (86-percent QE) at 1.3 microns and exhibit room temperature dark currents below 100 pA. A 256-element array has been mounted in a Reticon multiplexer and configured into a PAR optical multichannel analyzer to extend spectral response out to 1.7 microns. Individual InGaAs detectors have been fabricated for response out to 2.2 microns with dark current below 1 microA (-1V) and 50-percent QE at room temperature.

Olsen, G. H.↗
NASA NTRS1989

Qualification of room-temperature-curing structural adhesives for use on JPL spacecraft

An evaluation is made of the comparative advantages of numerous room temperature-cure structural primers and adhesives applicable to spacecraft structures. The EA 9394 adhesive and BR 127 primer were chosen for use in all primary structure bonding on the Galileo spacecraft, in virtue of adequate room-temperature lap shear and peel strengths and superior mechanical properties above 200 F. EA 9394 also offers superior work life, shelf-life, and storage properties, by comparison with the EA 934 alternative.

Carpenter, Alain↗