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53 records · Page 3

Thermomechanical Multiaxial Fatigue Testing Capability Developed

Structural components in aeronautical gas turbine engines typically experience multiaxial states of stress under nonisothermal conditions. To estimate the durability of the various components in the engine, one must characterize the cyclic deformation and fatigue behavior of the materials used under thermal and complex mechanical loading conditions. To this end, a testing protocol and associated test control software were developed at the NASA Lewis Research Center for thermomechanical axial-torsional fatigue tests. These tests are to be performed on thin-walled, tubular specimens fabricated from the cobalt-based superalloy Haynes 188. The software is written in C and runs on an MS-DOS based microcomputer.

Source record↗

Effect of a chromium-containing fuel additive on hot corrosion

Four cast superalloys (one cobalt-base and three nickel-base) were tested at 900 C for 100 h in Mach 0.3 combustion gases. 5 ppm of synthetic sea salt were added to the gases in the combustion chamber. Several types of thermal cycle and washing procedures were employed. Similar tests were made with the addition of 300 ppm of a chromium-containing fuel additive. In both sets of tests the extent of hot corrosion was evaluated by specific weight change and metal recession. In general, the chromium additive in the fuel reduced the extent of hot (salt) corrosion but did not eliminate it. The percentage reduction of hot corrosion attack was similar for all four alloys. As great a reduction of hot corrosion was achieved by reducing the number of thermal cycles during the test from 100 to 5 or 6. The effect of washing the alloys every ten cycles as opposed to the end of the test was erratic; some alloys were attacked slightly more, others somewhat less. A NiCrAlY coating was found to be more effective in reducing hot corrosion than either the fuel additive or the washing schedule.

Lowell, C. E.↗

Thermal-stress fatigue behavior of twenty-six superalloys

The comparative thermal-stress fatigue resistances of 26 nickeland cobalt-base alloys were determined by fluidized bed tests. Cycles to cracking differed by almost three orders of magnitude for these materials, with directional solidification and surface protection showing definite benefit. The alloy-coating combination with the highest thermal-stress fatigue resistance was directionally solidified NASA TAZ-8A with an RT-SP coating. Its oxidation resistance was also excellent, showing approximately a 1/2 percent weight loss after 14,000 fluidized bed cycles.

Bizon, P. T.↗

Determination of hydrogen permeability in commercial and modified superalloys

The results of hydrogen permeability measurements on several iron- and cobalt-base alloys as well as on two long-ranged ordered alloys over the range of 705 to 870 C (1300 to 1600 F) are summarized. The test alloys included wrought alloys N-155, IN 800, A-286, 19-9DL, and 19-9DL modifications with aluminum, niobium, and misch metal. In addition, XF-818, CRM-6D, SA-F11, and HS-31 were evaluated. Two wrought long-range ordered alloys, Ni3Al and (Fe,Ni)3(V,Al) were also evaluated. All tests were conducted at 20.7 MPa pressure in either pure and/or 1% CO2-doped H2 for test periods as long as 133 h. Detailed analyses were conducted to determine the relative permeability rankings of these alloys and the effect of doping, exit surface oxidation, specimen design variations, and test duration on permeability coefficient, and permeation activation energies were determined. The two long-range ordered alloys had the lowest permeability coefficients in pure H2 when compared with the eight commercial alloys and their modifications. With CO2 doping, significant decrease in permeability was observed in commercial alloys--no doped tests were conducted with the long-range ordered alloys.

Bhattacharyya, S.↗

Effect of heating method on stress-rupture life

The effect of radiant(furnace), resistance(electric current), burner(hot gas stream), and a combination of resistance and burner heating on intermediate time (100 to 300 hr) stress-rupture life and reduction of area was evaluated. All heating methods were studied using the nickel-based alloy Udimet 700 while all but burner heating were evaluated with the cobalt-based alloy Mar-M 509. Limited test results of eight other superalloys were also included in this study. Resistance heated specimens had about 20 to 30 percent of the stress-rupture life of radiant heated specimens. The limited burner heating data showed about a 50 percent life reduction as compared to the radiant heated tests. A metallurgical examination gave no explanation for these reductions.

Bizon, P. T.↗

Hot corrosion of four superalloys - HA-188, S-57, IN-617, and TD-NiCrAl

Cyclic oxidation and hot corrosion tests of two cobalt-base and two nickel-base alloys are reported. The alloys were exposed to maximum temperatures of 900 and 1000 C in a Mach 0.3 burner rig whose flame was doped with various concentrations of sea salt and sodium sulfate for hot corrosion tests. The test data were subjected to a regression analysis for the development of model equations relating corrosion to temperature and for the effects of salt concentration and composition on corrosion. The corrosion resistance varied with temperature, sea salt concentration, and salt composition, concluding that the S-57 cobalt-base alloy was the most hot corrosion-resistant alloy, and the TD-NiCrAl nickel-base alloy was the least resistant. However, under straight oxidation conditions, the TD-NiCrAl was most resistant, while S-57 was the least resistant alloy.

Santoro, G. J.↗

Thermomechanical and bithermal fatigue behavior of cast B1900 + Hf and wrought Haynes 188

High temperature thermomechanical and bithermal fatigue behavior was investigated for two superalloys: cast nickel-base B1900+Hf and wrought cobalt-base Haynes 188. Experimental results were generated to support development of an advanced thermal fatigue life prediction method. Strain controlled thermomechanical and load-controlled, strain-limited, bithermal fatigue tests were used to determine the fatigue crack initiation and cyclic stress-strain response characteristics of superalloys. Bithermal temperatures of 483 and 871 C were used for B1900+Hf, and 316 and 760 C for Haynes 188. Thermomechanical fatigue tests were conducted by using maximum and minimum temperatures corresponding to those for the bithermal experiments. Lives cover the range from about 10 to 3000 cycles to failure. Isothermal fatigue results obtained previously are also discussed.

Halford, Gary R.↗

Creep-rupture behavior of iron superalloys in high-pressure hydrogen

The creep-rupture properties of five iron-base and one cobalt-base high temperature alloys were investigated to assess the feasibility of using the alloys as construction materials in a Stirling engine. The alloys were heat treated and hardness measurements were taken. Typical microstructures of the alloys are shown. The creep-rupture properties of the alloys were determined at 760 and 815 C in 15.0 MPa H2 for 200 to 1000 hours. Plots of rupture life versus stress for the six superalloys are presented along with creep strain-time plots.

Bhattacharyya, S.↗

Impacts of Superalloys on the Surface Quality of Additively Manufactured Channels

Abstract Gas turbines feature many components that require superalloys capable of handling extreme thermal environments. Increasing the selection of materials available for these components is important to their use in these extremely high-temperature environments. This study investigated two recently developed materials intended to be used for additive manufacturing (AM), with one superalloy based on cobalt and the other on nickel. Sets of four test coupons were built using the materials, in addition to the commonly used Inconel-718, on multiple laser powder bed fusion machines. Several build conditions were varied between coupon sets, including coupon orientation, contour settings, and upskin and downskin treatment. Each set of test coupons featured four unique cooling designs to explore how different cooling technologies would be impacted by the variations in build conditions. After being built, coupons were computed tomography (CT) scanned to determine accuracy to design intent and quantify the surface roughness. The CT scans indicated that horizontally built test coupons had a significantly higher deviation from design intent and higher surface roughness than those built vertically. Results also indicated that the cobalt-based alloy consistently had a smoother surface quality with lower surface roughness compared to the nickel-based alloy. After geometric characterization, the cooling performance of the test coupons was measured experimentally. Pressure losses were found to correlate with increases in surface roughness; however, in some cases, the convective heat transfer did not increase proportionally to the pressure loss as a result of surface features significantly blocking the flow without proportionally increasing convective heat transfer.

Engineering↗

Progress in superalloys

Strength and workability of high temperature nickel-base, cobalt-base, and cobalt-refractory metal superalloys

SUPERALLOY↗

Advanced protective coating for superalloys

Superior oxidation protection for nickel-base alloys at temperatures up to 1367 K was obtained with cobalt-base alloy coating. Coating had 25 Cr, 14 Al, and 0.5 Y weight percent composition. Coating was applied by electron beam vapor deposition to thickness of 76 to 127 microns.

Elam, R. C.↗

Evaluation of coatings for cobalt- and nickel-base superalloys, volume 2

The final results of an oxidation-reduction rig evaluation of aluminide coatings are presented, as applied to 1N-100 and B1900 nickel-base and X-10 and WI-52 cobalt-base alloys. Burner rigs were used which operated on JP-5 fuel and air, producing a gas velocity of 0.85 (2000 to 2500 ft/sec) at the specimen's leading edge. One-hour heating cycles were used with three minutes of air blast cooling. Results of testing at temperatures ranging from T sub max of 1850 to 2050 F indicate that coated B1900 has the longest oxidation life at all temperatures, followed by IN-100X-40WI-52, based on a weight change criterion. Coatings on nickel-base alloys provided more than twice the life of coating on cobalt-base alloys at comparable temperatures. The coatings with higher aluminum content and comparable thickness had longer lives. Silicon appeared to be a beneficial additive in the nickel-base alloy coatings for long term, low temperature life, but not for short term, high temperature performance. Chromium was identified in all coatings. Extrapolating the life results obtained to 1600 F, all the selected coatings on the four alloys would be protective for at least 10,000 hours.

Moore, V. S.↗

Embrittlement of nickel-, cobalt-, and iron-base superalloys by exposure to hydrogen

Five nickel-base alloys (Inconel 718, Udimet 700, Rene 41, Hastelloy X, and TD-NiCr), one cobalt-base alloy (L-605), and an iron-base alloy (A-286) were exposed in hydrogen at 0.1 MN/sq m (15 psi) at several temperatures in the range from 430 to 980 C for as long as 1000 hours. These alloys were embrittled to varying degrees by such exposures in hydrogen. Embrittlement was found to be: (1) sensitive to strain rate, (2) reversible, (3) caused by large concentrations of absorbed hydrogen, and (4) not associated with any detectable microstructural changes in the alloys. These observations are consistent with a mechanism of internal reversible hydrogen embrittlement.

Gray, H. R.↗

Creep and residual mechanical properties of cast superalloys and oxide dispersion strengthened alloys

Tensile, stress-rupture, creep, and residual tensile properties after creep testing were determined for two typical cast superalloys and four advanced oxide dispersion strengthened (ODS) alloys. The superalloys examined included the nickel-base alloy B-1900 and the cobalt-base alloy MAR-M509. The nickel-base ODS MA-757 (Ni-16CR-4Al-0.6Y2O3 and the iron-base ODS alloy MA-956 (Fe-20Cr-5Al-0.8Y2O3) were extensively studied, while limited testing was conducted on the ODS nickel-base alloys STCA (Ni-16Cr-4.5Al-2Y2O3) with a without Ta and YD-NiCrAl (Ni-16Cr-5Al-2Y2O3). Elevated temperature testing was conducted from 114 to 1477 K except for STCA and YD-NiCrAl alloys, which were only tested at 1366 K. The residual tensile properties of B-1900 and MAR-M509 are not reduced by prior creep testing (strains at least up to 1 percent), while the room temperature tensile properties of ODS nickel-base alloys can be reduced by small amounts of prior creep strain (less than 0.5 percent). The iron-base ODS alloy MA-956 does not appear to be susceptible to creep degradation at least up to strains of about 0.25 percent. However, MA-956 exhibits unusual creep behavior which apparently involves crack nucleation and growth.

Whittenberger, J. D.↗

Analysis of thermoelectric properties of high-temperature complex alloys of nickel-base, iron-base and cobalt-base groups

The thermoelectric properties alloys of the nickel-base, iron-base, and cobalt-base groups containing from 1% to 25% 106 chromium were compared and correlated with the following material characteristics: atomic percent of the principle alloy constituent; ratio of concentration of two constituents; alloy physical property (electrical resistivity); alloy phase structure (percent precipitate or percent hardener content); alloy electronic structure (electron concentration). For solid-solution-type alloys the most consistent correlation was obtained with electron concentration, for precipitation-hardenable alloys of the nickel-base superalloy group, the thermoelectric potential correlated with hardener content in the alloy structure. For solid-solution-type alloys, no problems were found with thermoelectric stability to 1000; for precipitation-hardenable alloys, thermoelectric stability was dependent on phase stability. The effects of the compositional range of alloy constituents on temperature measurement uncertainty are discussed.

Holanda, R.↗

Superior Ballistic Impact Resistance Achieved by the Co-Base Alloy Haynes 25

The fan case in a jet engine is required to contain a fan blade in the rare event of a blade loss during operation. Because of its function, the fan case is the largest structural component in high-bypass-ratio turbofan engines used in commercial aircraft. Therefore, the use of lighter and stronger materials would be advantageous in most engines and is practically a necessity in the latest generation of high-bypass engines. Small panels, 7 in. wide by 7 in. long, of a number of metallic alloys were impact tested at room temperature with a 0.50-caliber blunt-nose titanium alloy projectile at the NASA Glenn Research Center (ref. 1). These metallic systems included several high-strength aluminum (Al) alloys, Al-based laminates, aluminum metal matrix composites (Al-MMCs), nickel-base superalloys (Inconel 718 and 625), several titanium (Ti) alloys in different heat treated conditions, 304L stainless steel, a stainless-steel-based laminate, and a high strength steel (Nitronic 60). It was determined that a simple Co-base alloy (Haynes 25) had the best impact resistance on an areal weight basis. Haynes 25 was at least 10 percent better than IMI 550, the best titanium alloy tested to date, and it was far superior to other metals, especially at higher impact velocities (greater than 1100 ft/sec). Because this material could be ideal for fan containment applications in supersonic aircraft as a replacement for titanium, impact tests were also conducted at 371 oC and compared with results from alloys tested at elevated temperature under previous programs (i.e., Inconel 718, Ti-6242, M-152, Timetal 21S, and Aeromet 100). Although cobalt-base alloys are used in some high-temperature engine applications, to our knowledge they are not used in any containment systems. Advantages of cobalt over titanium include lower cost, easier processing, better high-temperature strength, and no fire hazard if tip rub occurs. Future plans include testing of lightweight sandwich panels with Haynes 25 as a core material in the form of a foam or lattice block structure and scaling up the current tests by using blade-simulating projectiles impacting large plates and half rings.

Hebsur, Mohan G.↗