Engineering PapersSearch

SEARCH · Engineering Papers

Results for “Oxidative coupling of methane”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

3,224 records · Page 3

Decadal-Scale Hydrothermal Alteration of Basalt: Implications for Long-Term Reactivity in Subsurface Technologies

Global demands to secure critical mineral supply chains and managing water resources require innovative resource management strategies. Subsurface basalt reservoirs offer a dual-purpose application, where CO2 enhanced critical metal recovery can be coupled with water remediation strategies for the extraction of economically important and environmentally relevant elements. This study utilizes static batch experiments conducted on Columbia River Basalt Group samples to evaluate long-term fluid–rock interactions relevant to coupled subsurface applications. Samples were reacted under elevated temperature and pressure conditions, for 296 and 4,061 days, providing a unique dataset to assess geochemical evolution, element partitioning, and aqueous chemistry over decadal timescales. The alteration was dominated by silicate, aluminosilicate, and oxide phases. Progressive hydrothermal alteration increased the cation exchange capacity through the formation of secondary minerals (e.g. clays and zeolites), influencing solute retention, ion exchange behavior, and aqueous chemistry. Grain-scale and bulk analyses revealed selective cation release and retention patterns, establishing a mechanistic baseline for predicting element mobility. These geochemical constraints inform the prospective use of CO2-enhanced metal recovery for critical resources (e.g. Co, Ni, Mn, Mg, Ti, Fe) and associated water-quality impacts, providing a foundation for the design and management of engineered fluid–rock systems in basalt reservoirs.

Gibson, Marie N.

Thermochemical Stability of Ca2Yb8(SiO4)6O2 Apatite in Presence of Molten Calcium-Magnesium-Aluminosilicate (CMAS)

Thermochemical stability of ytterbium silicon oxyapatite Ca 2 Yb 8 (SiO 4 ) 6 O 2 (CYbS) in the presence of molten calcium-magnesium aluminosilicate (CMAS) has been investigated at elevated temperatures for consideration as a thermal and environmental barrier coating (T/EBC) material. CYbS apatite powder was synthesized from the constituent oxides via a solid-state reaction method. Hot-pressed apatite substrates were exposed to molten CMAS at 1200, 1300, and 1400 °C for 1, 10, and 50 h. Development of phases in the interaction region of the heat-treated specimens was monitored using scanning electron microscopy, transmission electron microscopy, high-angle annular dark-field imaging, selected area electron diffraction, and energy dispersive x-ray spectroscopy. Monoclinic cyclosilicate Ca 3 Yb 2 (Si 3 O 9 ) 2 formed from interaction of CYbS apatite with CaO in the CMAS melt at the apatite-CMAS reaction front and continued to nucleate and grow within the residual CMAS in diffusion couples annealed for 1 to 50 h at 1200 °C as well as in those heat treated at 1300 °C for 1 h. Residual CMAS was depleted of Ca when cyclosilicate was present. Dendritic wollastonite (CaSiO3) was observed within the residual CMAS in couples annealed at 1200 and 1300 °C. Ingress of molten CMAS, because of its exponential decrease in viscosity, occurred through open pores and along the grain boundaries of the apatite substrates without any detectable chemical reaction at 1300 and 1400 °C. Results of this study indicate that Ca 2 Yb 8 (SiO 4 ) 6 O 2 apatite has the potential to mitigate the CMAS corrosion up to about 1200 °C but not at higher temperatures.

Narottam P Bansal

Coupled, Transient Simulations of the Interaction Between Power and Secondary Flowpaths in Gas Turbines

This paper presents a coupled analysis of the interaction between mainpath and secondary flowpaths in gas turbines using transient simulations. Some of the topics include: 1) Need for Coupled Analysis; 2) Primary-Secondary Coupling Schematic; 3) Secondary Flow Requirement; 4) Objectives of Present Methodology; 5) Current Methodologies Recap; 6) Proposed Coupled Code Methodology; 7) Description of SCISEAL Code; 8) Description of Turbo Code; 9) Code Coupling/Interface Issues; and 10) Current Interface Strategy. This paper is presented in viewgraph form.

M M Athavale

Temperature as a control knob on spin-orbit coupling

Spin-orbit coupling (SOC) governs many physical phenomena. Through ab initio molecular dynamics simulations, Lu and Sun demonstrated that structural disorder at elevated temperatures substantially reduces the effective SOC contribution that stabilizes band inversion, driving a topological-to-normal-insulator transition in Bi2Se3. Their work identifies temperature as a meaningful control parameter for SOC-mediated topology and other properties.

Liang, Liangbo [ORNL] (ORCID:0000000311990049)

Ferroresonant Flux-Coupled Battery Charger

Portable battery charger operates at about 20 kHz to take advantage of relatively low weight and low acoustical noise of ferroresonant circuits operating in this frequency range. Charger split into stationary unit connected to powerline and mobile unit connected to battery or other load. Power transferred to mobile unit by magnetic coupling between mating transformer halves. Advantage where sparking at electrical connection might pose explosion hazard or where operator disabled and cannot manipulate plug into wall outlet. Likely applications for charger include wheelchairs and robots.

Mclyman, C. W.

Complex-Valued Intermolecular Coupling Enables Directional Exciton Transport in Excitonic Circuits

Molecular systems capable of directing the flow of excitons are key to the development and optimization of optoelectronic materials. The transport of excitons across multiple molecules is governed by an intermolecular electronic coupling network. In this article, we consider the effects of complex-valued intermolecular electronic coupling on exciton transport. Here, we present a molecular motif capable of generating complex-valued coupling under excitation with circularly polarized light. We use theoretical modeling and simulation to illustrate how complex coupling can be leveraged to drive the rotational flux of excitons in cyclic molecular networks and direct the exciton population in branched molecular networks.

chromophores