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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Ground Calibration of the Astro-H (Hitomi) Soft X-Ray Spectrometer

The Astro-H (Hitomi) Soft X-ray Spectrometer (SXS) was a pioneering imaging x-ray spectrometer with 5 eV energy resolution at 6 keV. The instrument used a microcalorimeter array at the focus of a high-throughput soft x-ray telescope to enable high-resolution non-dispersive spectroscopy in the soft x-ray waveband (0.3-12 keV). We present the suite of ground calibration measurements acquired from 2012-2015, including characterization of the detector system, anti-coincidence detector, optical blocking filters, and filter-wheel filters. The calibration of the 36-pixel silicon thermistor microcalorimeter array includes parameterizations of the energy gain scale and line spread function for each event grade over a range of instrument operating conditions, as well as quantum efficiency measurements. The x-ray transmission of the set of five Al/polyimide thin-film optical blocking filters mounted inside the SXS dewar has been modeled based on measurements at synchrotron beamlines, including with high spectral resolution at the C, N, O, and Al K-edges. In addition, we present the x-ray transmission of the dewar gate valve and of the filters mounted on the SXS filter wheel (external to the dewar), including beryllium, polyimide, and neutral density filters.

detectors↗
NASA NTRS2019

Photoionization Emission Models for the Cyg X-3 X-Ray Spectrum

We present model fits to the X-ray line spectrum of the well-known high-mass X-ray binary Cyg X-3. The primary observational data set is a spectrum taken with the Chandra X-ray Observatory High Energy Transmission Grating in 2006, though we compare it to all the other observations of this source taken so far by this instrument. We show that the density must be 1012 cm−3 in the region responsible for most of the emission. We discuss the influence of the dust scattering halo on the broadband spectrum, and we argue that dust scattering and extinction is not the most likely origin for the narrow feature seen near the Si K edge. We identify the features of a wind in the profiles of the strong resonance lines and show that the wind is more apparent in the lines from the lighter elements. We argue that this wind is most likely associated with the companion star. We show that the intensities of most lines can be fitted, crudely, by a single-component photoionized model. However, the iron K lines do not fit with this model. We show that the iron K line variability as a function of orbital phase is different from the lower-energy lines, which indicates that the lines arise in physically distinct regions. We discuss the interpretation of these results in the context of what is known about the system and similar systems.

Kallman, T.↗
NASA NTRS1999

The Astro-E/XRS Blocking Filter Calibration

We describe the transmission calibration of the Astro-E XRS blocking filters. The XRS instrument has five aluminized polyimide blocking filters. These filters are located at thermal stages ranging from 200 K to 60 mK. They are each about 1000 A thick. XRS will have high energy resolution which will enable it to see some of the extended fine structure around the oxygen and aluminum K edges of these filters. Thus, we are conducting a high spectral resolution calibration of the filters near these energies to resolve out extended flue structure and absorption lines.

Audley, Michael D.↗
NASA NTRS1993

BBXRT and Ginga observations of the Seyfert 1 galaxy Markarian 335

We present new X-ray observations of Mrk 335 in the 0.4-10 keV band using BBXRT and in the 2-20 keV band with Ginga. The BBXRT data show a break to a softer spectrum below about 1 keV. The Ginga data show evidence for variability in absorption, uncorrelated with flux changes of the continuum source. The inconsistency between the opacity observed at the iron K edge and at softer X-ray energies implies that the absorber has an ionization state about FeXV. We suggest that the nuclear emission can be explained by a self-consistent pair cascade model as developed by Zdziarski et al. (1990) and Zdziarski and Coppi (1991), where the compactness parameter inferred from the spectral fits to both data sets is in good agreement with the value calculated from the ratio of observed X-ray luminosity and variability time scale.

Turner, T. J.↗
NASA NTRS2006

Dynamics of the Shocked Gas in the Eta Carinae System as Seen by Chandra

We report on a series of X-ray spectra of the supermassive star Eta Carinae obtained by the High Energy Transmission Grating Spectrometer on the CHANDRA X-ray observatory before, during and after the star's X-ray minimum in the summer of 2003. The X-ray spectra show significant variations in emission measure and absorption, in the strength of the iron K edge and fluorescent iron emission, but show little change in the distribution of emission measure with temperature. The CHANDRA spectra also resolve emission from Si, S, Fe and other elements in H-like and He-like configurations. The HETGS spectra show that these lines change in centroid energy along with evidence of changes in the forbidden-to-intercombination ratios of the He-like triplets. These spectra offer strong support that the X-ray emission originates within a shock cone around an unseen, massive companion. The variations of the X-ray line spectrum provide a direct measure of the dynamics of the shocked gas in this cone and also evidence that the hottest region of the shock is not always in collisional ionization equilibrium. We discuss these results in light of the recent discovery of He II 4686 emission and the reported discovery of FUV emission from the companion star. This work was supported by SAO/Chandra grant GO3-4008A.

Corcoran, M. F.↗
NASA NTRS1973

Diffuse Cosmic X-rays Below 1 Kev

Measurements of low energy diffuse X-rays are discussed. Particular attention was given to the energy region below 280 eV, the carbon K edge. Spatial structure, nature of local emission, and X-ray extragalactic origin are also discussed.

Kraushaar, W. L.↗
NASA NTRS1973

Diffuse cosmic X-rays below 1 keV

A description is given of low energy soft diffuse X-ray flux in the energy region below 280 eV, the carbon-K edge. Spatial structure, nature of local emission, and intensity are also discussed.

Kraushaar, W. L.↗
NASA NTRS1981

A Module Experimental Process System Development Unit (MEPSDU)

The technical readiness of a cost effective process sequence that has the potential for the production of flat plate photovoltaic modules which met the price goal in 1986 of $.70 or less per Watt peak was demonstrated. The proposed process sequence was reviewed and laboratory verification experiments were conducted. The preliminary process includes the following features: semicrystalline silicon (10 cm by 10 cm) as the silicon input material; spray on dopant diffusion source; Al paste BSF formation; spray on AR coating; electroless Ni plate solder dip metallization; laser scribe edges; K & S tabbing and stringing machine; and laminated EVA modules.

Source record↗
NASA NTRS1983

A search for X-ray emission from optically quiet, compact radio sources

A search for X-ray emission from optically quiet, compact radio sources reveals that such sources are significantly weaker X-ray emitters than are optically identified objects with comparable radio properties. For the radio samples examined here, the X-ray luminosity, relative to the radio, is typically at least 3 times lower in the optically quiet, compact radio sources than in the optically identified ones. Possible reasons for the distinction between optically quiet, compact radio sources and other compact radio sources are discussed. If strong nonthermal sources occur in the nuclei of dust-rich galaxies and do not eliminate the dust and gas of the interstellar medium, a few percent of such sources should be optically faint and red (due to extinction by dust) and X-ray weak (due to K-edge absorption). However, many optically quiet, compact radio sources are apparently 'blazars' with particularly sharp high-frequency breaks in their synchrotron spectra.

Ledden, J. E.↗
NASA NTRS1984

Variable X-ray absorption in the QSO MR 2251 - 178

The monitoring proportional counter of the Einstein Observatory has been used to observe the QSO MR 2251 - 178 on two occasions, approximately 1 year apart, in the 2-10 keV range. Evidence is found for an increase in the absorbing column density by a large factor over the 1 year interval. Simultaneous measurements with the high resolution imager are used to further constrain the soft X-ray flux and to show that the highly absorbed spectrum must have excess emission below 1 keV. A model is presented in which photoionization by the X-ray continuum ionizes a cloud or shell of material, so that the emergent spectrum is transparent below the K-edge of O VII at 739 eV, but is highly absorbed above this energy.

Halpern, J. P.↗
NASA NTRS1984

Soft X-ray opacity in hot and photoionized gases

New calculations are presented of the soft X-ray opacity of gas having cosmic elemental abundances, but in a variety of ionization states. Coronal ionization equilibrium is considered over the range of temperatures 10 to the 4th to 3 x 10 to the 8th K and photoionization equilibrium with power-law and thermal bremsstrahlung spectra over a wide range of ionization parameters. The results are displayed in illustrative figures. For temperatures and ionization parameters commonly found in astrophysical plasmas, the opacity (particularly to photons of equal to or less than 1 keV) can be diminished by substantial factors relative to the state in which all atoms are neutral. As the dominant ionization stages change, the positions and contrasts of prominent K-edges also change.

Krolik, J. H.↗
NASA NTRS1990

Nature and origin of interstellar diamond from the Allende CV3 meteorite

Data and experimental evidence which support the contention that the C delta diamonds may result from grain-grain collisions in supernova shocks in the interstellar medium are presented. Fragments of the Allende CV3 chondrite were acid-treated. A whitish powder was obtained. For the Analytical Electron Microscopy (AEM) a small drop of ethanol suspension was transferred onto holey carbon support films on 3 mm EM grids. The AEM was performed on transmission-thin fragments of the material which overlay holes in the film, to eliminate interference from the substrate. Electron Spectroscopy for Chemical Analysis (ESCA) was performed on a large aliquot of C. Diamond was identified by selected area electron diffraction. Scanning Transmission Electron Microscope / Energy Dispersive X-ray (STEM-EDS) microanalyses of the C delta diamond, using a light-element detector, show that oxygen and possibly nitrogen are the only impurities consistently present. ESCA spectra from bulk C delta material confirm the presence of N at a level of 0.35 percent or less. Under UV irradiation a yellow-red fluorescence is observed, consistent with that of natural diamonds containing substitutional N. Electron Energy Loss Spectra (EELS) were recorded at 2 eV resolution from the C delta diamond, high pressure synthetic diamond, a diamond film produced in a low pressure plasma by chemical vapor deposition (CVD) on a heated silicon substrate (Roy, 1987), graphite, and amorphous arc sputtered carbon. Comparison of the carbon K edge shape and fine structure shows the Allende C delta phase to be largely diamond, but with a significant pre-edge absorption feature indicative of transitions of C 1s electrons into pi asterisk orbitals which are absent in the purely sp(3)-bonded diamond but present in graphite and amorphous carbon.

Blake, David↗
NASA NTRS1990

On diamond, graphitic and amorphous carbons in primitive extraterrestrial solar system materials

Carbon is among the most abundant elements in the universe and carbon chemistry in meteorites and comets is an important key to understanding many Solar System and interstellar processes. Yet, the mineralogical properties and interrelations between various structural forms of elemental carbon remain ambiguous. Crystalline elemental carbons include rhombohedral graphite, hexagonal graphite, cubic diamond, hexagonal diamond (i.e., lonsdaleite or carbon-2H) and chaoite. Elemental carbon also occurs as amorphous carbon and poorly graphitized (or turbostratic) carbon but of all the forms of elemental carbon only graphite is stable under physical conditions that prevail in small Solar System bodies and in the interstellar medium. The recent discovery of cubic diamond in carbonaceous chondrites and hexagonal diamond in chondritic interplanetary dust particles (IDPs) have created a renewed interest in the crystalline elemental carbons that were not formed by shock processes on a parent body. Another technique, Raman spectroscopy, confirms a widespread occurrence of disordered graphite in the Allende carbonaceous chondrite and in chondritic IDPs. Elemental carbons have also been identified by their characteristic K-edge features in electron energy loss spectra (EELS). However, the spectroscopic data do not necessarily coincide with those obtained by selected area electron diffraction (SAED). In order to interpret these data in terms of rational crystalline structures, it may be useful to consider the principles underlying electron diffraction and spectroscopic analyses. Electron diffraction depends on electron scattering, on the type of atom and the distance between atoms in a crystal lattice. Spectroscopic data are a function of the type of atom and the energy of bonds between atoms. Also, SAED is a bulk sampling technique when compared to techniques such as Raman spectroscopy or EELS. Thus, it appears that combined analyses provide contradictory results and that amorphous, or short-range ordered, carbon identified by conventional TEM imaging and SAED may show evidence for sp(3) bonds in EELS spectra. It is suggested that complex, nanometer-scale, mineralogical interrelations are common to all elemental carbons irrespective of their origin. The subsequent thermal history, or energy balance, will determine the ultimate microstructure.

Rietmeijer, Frans J. M.↗
NASA NTRS1990

Single- and double-photoionization cross sections of atomic nitrogen from threshold to 31 A

The relative photoionization cross section of atomic nitrogen for the production of singly and doubly charged ions has been measured from 44.3 to 275 A and from 520 to 852 A. The results have been made absolute by normalization to one-half of the molecular nitrogen cross section at short wavelengths. The smoothed atomic nitrogen cross sections sigma can be accurately represented, at short wavelengths, by the equation sigma(Mb) = 36,700 x (E exp-2.3) as a function of the photon energy E (eV), thereby allowing the cross sections to be extrapolated to the nitrogen K edge at 31 A.

Samson, James A. R.↗
NASA NTRS1990

Multistep fluorescence gated proportional counters

A proportional counter is introduced in which the levels of energy and spatial resolutions and background rejection permit the application of the device to X-ray astronomy. A multistep approach is employed in which photons cause a signal that triggers the system and measures the energy of the incident photon. The multistep approach permits good energy resolution from parallel geometry and from the imaging stage due to coupling of the imaging and amplification stages. The design also employs fluorescence gating to reduce background, a method that is compatible with the multistep technique. Use of the proportional counter is reported for NASA's supernova campaign, and the pair background is below 0.0001 counts/sq cm sec keV at the xenon k-edge. Potential improvements and applications are listed including the CASES, POF, and EXOSS mission programs.

Ramsey, Brian D.↗
NASA NTRS1993

Applications of x ray absorption fine structure to the in situ study of the effect of cobalt in nickel hydrous oxide electrodes for fuel cells and rechargeable batteries

Electronic and structural aspects of composite nickel-cobalt hydrous oxides have been examined in alkaline solutions using in situ X-ray absorption fine structure (XAFS). The results obtained have indicated that cobalt in this material is present as cobaltic ions regardless of the oxidation state of nickel in the lattice. Furthermore, careful analysis of the Co K-edge Extended X-ray absorption fine structure data reveals that the co-electrodeposition procedure generates a single phase, mixed metal hydrous oxide, in which cobaltic ions occupy nickel sites in the NiO2 sheet-like layers and not two intermixed phases each consisting of a single metal hydrous oxide.

Kim, Sunghyun↗
NASA NTRS1994

X-Ray Absorption Spectroscopy in High Temperature Oxidation of Metals and Alloys

An experimental technique is described that allows for the joint study of the kinetics and of the oxide structure during the high temperature oxidation of metal surfaces. Oxygen is supplied at the metal through an electrochemical oxygen pump and the oxygen pressure, at the metal surface, is measured during oxidation by a YSZ (yttria stabilized zirconia) oxygen sensor. XAS (x-ray absorption spectroscopy) is performed in fluorescence mode at the cation K edge and after each oxidation step. An appropriate analysis of the XAS spectra could provide information on both the oxidation kinetics and oxide structure. Experimental data on the high temperature oxidation of nickel, cobalt, and Fe(64%)Ni(36%) alloy, at low oxygen pressure, are reported and analyzed according to the proposed data reduction. These results indicate the presented technique to be particularly suitable for studying the hot corrosion of oxide film too thick for common surface spectroscopy (AUGER, ESCA) and too thin for conventional thermogravimetric technique.

Daniele Gozzi↗
NASA NTRS1994

The X-ray and ultraviolet absorbing outflow in 3C 351

3C 351 (z = 0.371), and X-ray-'quiet' quasar, is one of the few quasars showing signs of a 'warm absorber' in its X-ray spectrum; i.e., partially ionized absorbing material in the line of sight whose opacity depends on its ionization structure. The main feature in the X-ray spectrum is a K-edge due to O VII or O VIII. 3C 351 also shows unusually strong, blueshifted, associated, absorption lines in the ultraviolet (Bahcall et al. 1993) including O VI (lambda lambda 1031, 1037). This high ionization state strongly suggests an identification with the X-ray absorber and a site within the active nucleus. In this paper we demonstrate that the X-ray and UV absorption is due to the same material. This is the first confirmed UV/X-ray absorber. Physical conditions of the absorber are determined through the combination of constraints derived from both the X-ray and UV analysis. This highly ionized, outflowing, low-density, high-column density absorber situated outside the broad emission line region (BELR) is a previously unknown component of nuclear material. We rule out the identification of the absorber with a BELR cloud as the physical conditions in the two regions are inconsistent with one another. The effect of the X-ray quietness and IR upturn in the 3C 351 continuum on the BELR is also investigated. The strengths of the high-ionization lines of C IV lambda-1549 and O VI lambda-1034 with respect to Lyman-alpha are systematically lower (up to a factor of 10) in the material ionized by the 3C 351 continuum as compared to those produced by the 'standard' quasar continuum, the strongest effect being on the strength of O VI lambda-1034. We find that for a 3C 351-like continuum, C III) lambda-1909 ceases to be a density indicator.

Mathur, Smita↗