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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Challenge and Opportunity of Advanced Materials and Chemistries for Electrochemical Energy Storages Development of NASA Future Missions

The energy demanding for NASA's future missions, and the challenges and opportunities to achieve these energy goals will be presented. The research capabilities, facilities and activities at NASA Glenn Research Center will also be discussed. The opportunity for university faculty and students to participate in NASA energy-related programs will be discussed at well.

Wu, James J.↗
NASA NTRS2018

Experimental Investigation of Roughness Effects on Transition on Blunt Spherical Capsule Shapes

The present contribution reviews recent experimental results of roughness effects on boundary layer transition on capsule geometries with spherical windward geometries. Experiments in three wind tunnel facilities are considered. The ACE Tunnel of Texas AM University, USA, provided Mach 6 experiments with distributed roughness at relatively low Reynolds numbers, 2.5 · 10(exp 5) < Re(sub d) < 5 · 10(exp 5), with d denoting the capsule diameter. The observed boundary layer transition compared well with correlations based on transient growth theory, even though the roughness heights were in the order of boundary layer thickness. Larger Reynolds numbers, 1 · 10(exp 6) < Re(sub d) < 3·10(exp 6), could be assessed in the hypersonic Ludwieg tube, HLB, of TU Braunschweig, Germany. Transition is observed at rather low, subcritical roughness values in the order of 20 μm for a roughness patch placed about the geometric center of the capsule model. These experiments varied fluctuation levels of the freestream. The authors assume that the observed transitions that occur downstream of the subcritical roughness patch are due to freestream disturbances in the tunnel, which interact with small roughness heights. Additional experiments in the HLB facility with patches of larger roughness height support the relevance of transient growth theory for low-to-medium roughness heights, relative to boundary layer thickness. The effects of Reynolds numbers and total flow enthalpy on transition with isolated roughness were investigated in the HIEST facility of JAXA, Japan. Here, a model insert with roughness elements of varying height for tripping transition to turbulence was employed. The results are compared to known trip effectiveness correlations for isolated roughness. Overall, the transient growth correlation seems to represent roughness-induced transition behavior on the ACE and HLB entry capsule shapes with roughness over the entire capsule surface. These experiment are however for perfect gases. Comparable experiments on roughness induced transition in a high-enthalpy facility are still needed to confirm the validity of transient-growth correlation for vehicle design.

Radespiel, Rolf↗
DOE OSTI2025

Firewalls from General Covariance

I define “horizon normalcy” as the approximate validity of semiclassical gravity and effective field theory for the description of observers that approach or cross a black hole horizon. If black holes return information, then horizon normalcy must fail substantially, at least in some global states. It has been proposed that horizon normalcy persists, so long as the Hawking radiation remains in a computationally simple state. Here I argue that state-dependent horizon normalcy—independent of the underlying mechanism and independent of the class of radiation states asserted to guarantee normalcy—requires a breakdown of general covariance far from the black hole, or else horizon normalcy will depend on the infinite future of the exterior. This is because the radiation can be in different states at different events, all spacelike to the horizon crossing event whose normalcy is at stake. I discuss a related effect in AdS/CFT, and I argue that its resolution by timefolds is of no help here.

General relativity↗
DOE OSTI2022

Sub-percentage measure of distances to redshift of 0.1 by a new cosmic ruler

ABSTRACT Distance-redshift diagrams probe expansion history of the Universe. We show that the stellar mass-binding energy (massE) relation of galaxies proposed in our previous study offers a new distance ruler at cosmic scales. By using elliptical galaxies in the main galaxy sample of the Sloan Digital Sky Survey Data Release 7, we construct a distance-redshift diagram over the redshift range from 0.05 to 0.2 with the massE ruler. The best-fit dark energy density is 0.675 ± 0.079 for flat Λ-cold dark matter (ΛCDM) model, consistent with those by other probes. At the median redshift of 0.11, the median distance is estimated to have a fractional error of 0.34 per cent, much lower than those by supernova (SN) Ia and baryonic acoustic oscillation (BAO) and even exceeding their future capability at this redshift. The above low-$\mathit{ z}$ measurement is useful for probing dark energy that dominates at the late Universe. For a flat dark energy equation of state model (flat wCDM), the massE alone constrains w to an error that is only a factor of 2.2, 1.7, and 1.3 times larger than those by BAO, SN Ia, and cosmic microwave background (CMB), respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1992

Studies of dynamic processes related to active experiments in space plasmas

This is the final report for grant NAGw-2055, 'Studies of Dynamic Processes Related to Active Experiments in Space Plasmas', covering research performed at the University of Michigan. The grant was awarded to study: (1) theoretical and data analysis of data from the CHARGE-2 rocket experiment (1keV; 1-46 mA electron beam ejections) and the Spacelab-2 shuttle experiment (1keV; 100 mA); (2) studies of the interaction of an electron beam, emitted from an ionospheric platform, with the ambient neutral atmosphere and plasma by means of a newly developed computer simulation model, relating model predictions with CHARGE-2 observations of return currents observed during electron beam emissions; and (3) development of a self-consistent model for the charge distribution on a moving conducting tether in a magnetized plasma and for the potential structure in the plasma surrounding the tether. Our main results include: (1) the computer code developed for the interaction of electrons beams with the neutral atmosphere and plasma is able to model observed return fluxes to the CHARGE-2 sounding rocket payload; and (2) a 3-D electromagnetic and relativistic particle simulation code was developed.

Banks, Peter M.↗
NASA NTRS2011

Lunabotics Mining Competition: Inspiration Through Accomplishment

NASA's Lunabotics Mining Competition is designed to promote the development of interest in space activities and STEM (Science, Technology, Engineering, and Mathematics) fields. The competition uses excavation, a necessary first step towards extracting resources from the regolith and building bases on the moon. The unique physical properties of lunar regolith and the reduced 1/6th gravity, vacuum environment make excavation a difficult technical challenge. Advances in lunar regolith mining have the potential to significantly contribute to our nation's space vision and NASA space exploration operations. The competition is conducted annually by NASA at the Kennedy Space Center Visitor Complex. The teams that can use telerobotic or autonomous operation to excavate a lunar regolith geotechnical simulant, herein after referred to as Black Point-1 (or BP-1) and score the most points (calculated as an average of two separate 10-minute timed competition attempts) will eam points towards the Joe Kosmo Award for Excellence and the scores will reflect ranking in the on-site mining category of the competition. The minimum excavation requirement is 10.0 kg during each competition attempt and the robotic excavator, referred to as the "Lunabot", must meet all specifications. This paper will review the achievements of the Lunabotics Mining Competition in 2010 and 2011, and present the new rules for 2012. By providing a framework for robotic design and fabrication, which culminates in a live competition event, university students have been able to produce sophisticated lunabots which are tele-operated. Multi-disciplinary teams are encouraged and the extreme sense of accomplishment provides a unique source of inspiration to the participating students, which has been shown to translate into increased interest in STEM careers. Our industrial sponsors (Caterpillar, Newmont Mining, Harris, Honeybee Robotics) have all stated that there is a strong need for skills in the workforce related to robotics and automated machines. In 2010, 22 United States (US) universities competed, and in May 2011 the competition was opened to international participation, with 46 Universities attending. There were 12 international teams and 34 US teams. This combined total directly inspired an estimated 544 university students. More students and the public were engaged via internet broadcasting and social networking media. This is expected to be of value for actual future space missions, as knowledge is gained from testing many innovative prototypes in simulated lunar regolith. More information is available at www.nasa.gov/lunabotics/.

Mueller, Robert P.↗
DOE OSTI2025

Selection Effect in Dark Energy Survey Y1

The discovery that the Universe expansion is accelerated poses one of the most profound mysteries in physics. Cosmic acceleration could be a sign of the fact that General Relativity breaks down on cosmological scales and has to be replaced, or it could arise from an unknown form of energy that currently dominates our Universe. That is what we call dark energy and in this case the problem moves to the discovery of its nature. Dark Energy Survey aims to study the nature of dark energy and to test General Relativity and cosmological models. The cluster analysis of the first run of DES leads to results which are incomparable with what other surveys have obtained. In particular it turns out that the matter density of the Universe is $Ω_m = 0.179^{+0.031}_{−0.038}$, very different from the 0.3 value expected. In this work we build a procedure that can be followed in order to understand whether the solution of DES Y1 problem could be a selection effect or not.

43 PARTICLE ACCELERATORS↗
DOE OSTI2026

Charge Transport in Solvated Donor–Acceptor Functionalized Peptoids: Molecular Dynamics and Rate Theory

Scalable solar-energy conversion requires photoactive materials that combine the efficiency of natural photosynthetic systems with the stability and processability needed for practical applications. Achieving reliable charge transport in soft, self-assembled organic materials remains challenging, as structural fluctuations and environmental effects strongly influence charge-transfer (CT) rates. Here, we present a broadly applicable computational framework for evaluating CT rates in the condensed phase, combining Fermi’s golden rule rate theory with inputs from all-atom molecular dynamics (MD) simulations and first-principles electronic-structure calculations. The approach does not rely on system-specific parametrization and is applicable to a wide range of soft and disordered materials. We demonstrate the applicability and usefulness of the framework on redox-active peptoids functionalized with iron–porphyrin (Fe–P) complexes, a bioinspired platform with programmable donor–acceptor units and tunable three-dimensional organization. The calculated CT rates exhibit strong sensitivity to molecular conformation, with variations spanning several orders of magnitude. This dependence is shown to arise from the pronounced variation in diabatic electronic coupling with the relative orientations and separations of the Fe–P complexes across the conformational ensemble. The framework provides a consistent route for connecting atomistic structure to CT kinetics in the condensed phase and enables analysis of structure–rate relations in organic semiconducting systems.

Charge transfer↗
DOE OSTI2025

Nanoscopic Plugs Block Hydrogen Crossover in Submicron Thick Proton-Conducting SiO 2 Membranes for Water Electrolysis

Zero-gap electrolyzers based on submicron thick proton-conducting oxide membranes (POMs) represent a promising approach to increasing the efficiency of H 2 production from water electrolysis while moving away from conventional perfluorosulfonic acid (PFSA) membranes. A critical barrier to the commercialization of such electrolyzers is that the ultrathin nature of POMs, which is necessary to achieve low cell resistance, makes them more susceptible to defects that can lead to unacceptably high rates of H 2 crossover. Herein, we demonstrate an approach to mitigate this problem through selective deposition of carbon-containing silicon oxide (SiO x C y ) “nanoplugs” into the defects of submicron thick SiO 2 membranes using a facile electrochemically mediated deposition process. Selective deposition of nanoplugs within the defects was verified by multiple characterization techniques, while scanning electrochemical microscopy (SECM) was used to confirm selective plugging of H 2 -crossover hotspots associated with defects at identical locations. Thanks to the use of nanoplugs, the H 2 permeance of 250 nm thick SiO 2 membranes was reduced by 5 to 6 orders of magnitude compared to the unmodified atomic layer deposition (ALD) SiO 2 membranes while having negligible impact on the ionic resistance of the membrane. These plug-modified membranes also enabled safe and stable operation of a zero-gap full cell electrolysis cell, in contrast to cells lacking nanoplugs that produced anode effluent streams having H 2 concentrations near or exceeding the lower flammability limit (LFL) of H 2 . Furthermore, beyond water electrolysis, this defect-sealing strategy has the potential to be broadly implemented in other applications, such as fuel cells and flow batteries, offering a versatile solution to mitigate crossover-related performance losses.

ALD SiO2↗
DOE OSTI2026

Ion-Electron Coupling-Driven Redox Behavior in Metal–Organic Frameworks

Redox-active metal–organic frameworks (MOFs) have long been proposed as electronic transport platforms, yet the microscopic origin of their conductivity remains debated. A theoretical demonstration reveals charge transport in a Zn(pyrazole–naphthalene diimide (NDI)) MOF arising not from delocalized band-like states but from redox hopping between discrete linker sites. Using ab initio molecular dynamics simulations combined with electronic structure analysis, we established a direct link among electron injection, structural reorganization, and transport. Electron accumulation proceeds sequentially and site-selectively from imide and carbonyl groups of the NDI core progressively involving pyrazole N atoms at higher reduction states, through a hierarchy of redox-active sites. In contrast, Zn nodes remain essentially redox-inactive, which confirms their structural role. Density-of-states analysis corroborates a transport regime dominated by linker-centered states with evolving p-character upon reduction, resulting in dynamically reconfigured conduction networks. Real-time trajectories reveal anisotropic linker-to-linker electron transfer modulated by counterion coordination. This cooperative ion–electron regime emerges from potential energy surface collapse into a single low-barrier transition (ΔG ‡ ≈ 45 meV), where ionic and electronic motions evolve adiabatically on the same free-energy landscape. Elucidating redox conductivity in Zn(pyrazole–NDI) MOFs provides a theoretical framework for use in neuromorphic computing and related technologies.

Charge transfer↗
DOE OSTI2025

Formation of tungsten ethylidene complexes from diethyl complexes through a proton-catalyzed rearrangement of ethylene

Here, W(NAr) 2 Et 2 (Ar = 2,6-diisopropylphenyl) reacts with two equivalents of R F9 OH (OR F9 = OC(CF 3 ) 3 ) to yield W(NAr)(ArNH 2 )(OR F9 )2(C 2 H 4 ) complexes and ethane. In solution W(NAr)(ArNH 2 )(OR F9 ) 2 (C 2 H 4 ) decomposes to give R F9 OH, ethane, W(NAr)(OR F9 ) 2 (C 2 H 4 ), and W(NAr)(NHAr′)(ArNH 2 )(OR F9 ), in which Ar′ contains a dehydrogenated isopropyl group (Ar′ = (2-i-Pr)(6-CMe=CH 2 )C 6 H 3 ) coordinated to the metal. On a similar time scale W(NAr)(OR F9 ) 2 (CHCH 3 ) complexes are formed from W(NAr)(OR F9 ) 2 (C 2 H 4 ) through an ArNH 2 -catalyzed rearrangement of the ethylene ligand. W(NAr)(NHAr′)(ArNH 2 )(OR F9 ) reacts with cyclohexene to form methylenecyclohexene and complexes that contain an NHAr″ ligand where Ar″ is a disubstituted (methyl/aryl) alkylidene, (2-i-Pr)(6-CMe)C 6 H 3 ) that is tethered to the metal through the amido nitrogen. In contrast to W(NAr)(ArNH 2 )(OR F9 ) 2 (C 2 H 4 ), analogous OR F6 (OCMe(CF 3 ) 2 ) and OR F3 (OCMe 2 (CF 3 )) complexes are relatively stable at 22 °C.

Maji, Milan [University of California, Riverside, ↗
DOE OSTI2023

QuarkNet Center Summer Internship for High School Students – FY2019

The purpose of this CRADA is to provide the contractual vehicle for Fermilab to receive funds from the College of DuPage in support of high school student research working with the Fermilab/University of Chicago QuarkNet Center, beginning with the effective date of this CRADA and continuing through 2019. Local QuarkNet Centers provide professional development programs to high school teachers and high energy physics research opportunities to high school teachers and students who participate in the local programs. The Office of Education and Public Engagement at Fermi National Accelerator Laboratory (Fermilab) administers a local QuarkNet Center program on behalf of both Fermilab and the University of Chicago.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1988

The infrared universe revealed by IRAS

Some of the astrophysical phenomena revealed by IRAS are reviewed. The relation of IRAS data to understanding the origin of the interplanetary dust cloud, to the discovery of protoplanetary disks around other stars, to understanding the birth and death of stars, and to comprehending the energetics of the interstellar medium are addressed. Extragalactic results suggesting that IRAS may have found the birthplace of quasars are examined, and the surprising cosmological implications of the IRAS catalog are considered.

Beichman, C. A.↗
DOE OSTI2024

Calibration Plan

PhD project update presentation to be given to Texas Tech University advisor.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1987

Gamma-ray bursts from superconducting cosmic strings at large redshifts

The relation between cusp events and gamma-rays bursts is investigated. The optical depth of the universe to X-rays and gamma-rays of various energies is calculated and discussed. The cosmological evolution of cosmic strings is examined, and the energetics and time-scales related to the cusp phenomena are estimated. It is noted that it is possible to have energy bursts with a duration of a few seconds or less from cusps at z = 1000; the maximum amount of energy associated with such an event is limited to 10 to the 7th ergs/sq cm.

Babul, Arif↗
NASA NTRS2002

Chromosome aberrations in human lymphocytes induced by 250 MeV protons: effects of dose, dose rate and shielding

Although the space radiation environment consists predominantly of energetic protons, astronauts inside a spacecraft are chronically exposed to both primary particles as well as secondary particles that are generated when the primary particles penetrate the spacecraft shielding. Secondary neutrons and secondary charged particles can have an LET value that is greater than the primary protons and, therefore, produce a higher relative biological effectiveness (RBE). Using the accelerator facility at Loma Linda University, we exposed human lymphocytes in vitro to 250 MeV protons with doses ranging from 0 to 60 cGy at three different dose rates: a low dose rate of 7.5 cGy/h, an intermediate dose rate of 30 cGy/h and a high dose rate of 70 cGy/min. The effect of 15 g/cm2 aluminum shielding on the induction of chromosome aberrations was investigated for each dose rate. After exposure, lymphocytes were incubated in growth medium containing phytohemagglutinin (PHA) and chromosome spreads were collected using a chemical-induced premature chromosome condensation (PCC) technique. Aberrations were analyzed using the fluorescence in situ hybridization (FISH) technique with three different colored chromosome-painting probes. The frequency of reciprocal and complex-type chromosome exchanges were compared in shielded and unshielded samples. c2002 COSPAR. Published by Elsevier Science Ltd. All rights reserved.

Non-NASA Center↗
DOE OSTI2020

Terry Turbopump Expanded Operating Band Modeling and Simulation Efforts in Fiscal Year 2020 - Progress Report

The Terry Turbine Expanded Operating Band Project is currently conducting testing at Texas A&M University as part of a revised experimental program meant to supplant previous full-scale testing plans under the headings of Milestone 5 and Milestone 6. In consultation with Sandia National Laboratories technical staff and with modeling and simulation support from the same, the hybrid Milestone 5&6 plan is moving forward with experiments aimed at addressing knowledge gaps regarding scale, working fluid, and turbopump self-regulation. Modeling and simulation efforts at Sandia National Laboratories in FY20 fell under the broad umbrella of Milestone 7 and consisted exclusively of MELCOR-related tasks aimed at: 1) Constructing/improving input models of Texas A&M University experiments, 2) Constructing a generic boiling water reactor input model according to best practices with systems-level Teny turbine capabilities, and 3) Adding code capability in order to leverage experimental data/findings, address bugs, and improve general code robustness Project impacts of the Covid-19 pandemic have fortunately been minimal thus far but are mentioned as necessary when discussing the hybrid Milestone 5&6 progress as well as the corresponding Milestone 7 modeling and simulation progress.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2023

Beyond – ΛCDM constraints from the full shape clustering measurements from BOSS and eBOSS

We analyse the full shape of anisotropic clustering measurements from the extended Baryon Oscillation Spectroscopic Survey quasar sample together with the combined galaxy sample from the Baryon Oscillation Spectroscopic Survey. We obtain constraints on the cosmological parameters independent of the Hubble parameter h for the extensions of the Lambda cold dark matter (ΛCDM) models, focusing on cosmologies with free dark energy equation of state parameter w. We combine the clustering constraints with those from the latest cosmic microwave background data from Planck to obtain joint constraints for these cosmologies for w and the additional extension parameters – its time evolution w a , the physical curvature density ω K and the neutrino mass sum Σm ν . Our joint constraints are consistent with a flat ΛCDM cosmological model within 68 per cent confidence limits. We demonstrate that the Planck data are able to place tight constraints on the clustering amplitude today, σ 12 , in cosmologies with varying w and present the first constraints for the clustering amplitude for such cosmologies, which is found to be slightly higher than the ΛCDM value. Additionally, we show that when we vary w and allow for non-flat cosmologies and the physical curvature density is used, Planck prefers a curved universe at 4σ significance, which is ~2σ higher than when using the relative curvature density Ω K . Finally, when w is varied freely, clustering provides only a modest improvement (of 0.021 eV) on the upper limit of Σm ν .

79 ASTRONOMY AND ASTROPHYSICS↗