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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Optical current monitor

An optical current monitor for detecting a current traveling through conductive material. The optical current monitor comprises a light source for emitting light at an output level; a lens configured to receive the light; Faraday material positioned near the conductive material and configured to receive light that has passed through the lens, thereby producing rotated light; a polarizer configured to polarize the rotated light; a photodetector configured to receive the rotated light and output a signal as a function of the rotated light; and a feedback system. The feedback system is configured to receive the signal from the photodetector and modify the output level of the light source based on the signal so that the signal remains at a reference level when the current is not traveling through the conductive material.

Laughlin, Daric Gray↗
NASA NTRS1993

Design application and development of spacecraft in LEO utilizing LDEF results

In general, the results from the Long Duration Exposure Facility (LDEF) have provided much useful information on material sensitivity in the low-Earth orbit (LEO) environment. This is particularly true for selected materials such as thermal control coatings, composites, polymers, fasteners and solar cells. However, LDEF material sensitivity data for other materials like glasses, glass coatings, lubricants, adhesives and seal materials were limited. Some of this important LDEF material sensitivity data has not yet been addressed in detail at the LDEF meetings. The type of material information needed in the design and development of a new spacecraft in LEO depends to a large extent on program phase. In early program phases it is only necessary to have material sensitivity data to determine what materials may or may not work. Later program phases require details on the material strength, optical properties, and/or other long term survivability requirements for materials in LEO. Unfortunately, documentation of exposure results for many materials sensitivity experiments that flew on LDEF has not yet been summarized in a convenient form for use by multiple users. Documentation of this data in a form convenient for scientists, engineers as well as technicians remains a significant area of concern for the aerospace industry. Many of the material experiments that flew on LDEF were only designed to measure material sensitivity for one year in an LEO environment. However, some materials expected to survive one year simply did not survive the 5.8 years that LDEF eventually remained in orbit. Therefore the survivability of several materials in an LEO environment was determined by default. Most of the LDEF materials experiments were not designed to establish long term material survivability data. This long term material survivability data is particularly useful in later program phases of spacecraft development. The lack of more controlled materials experiments to determine long term material survivability was one of the major limitations of many LDEF experiments. The identified need for this critical information on the long term survivability offers a challenge to possible future LDEF type experiments.

Rauch, George B., Jr.↗
NASA NTRS1974

Rain droplet erosion mechanisms in transparent plastic materials

Tests were conducted to determine the damaging effects of rain erosion on optically transparent materials. The rotating arm test equipment used for the tests is described. Typical transparent materials such as those found in windshields, infrared windows, lasers, and television systems were tested. Nominal velocities of 400, 500, and 600 miles per hour and rainfall conditions of one inch per hour simulated rainfall were used in the tests. It was determined that an 80 percent reduction in laser transmittance can occur in plastics submitted to rain erosion. Significant results of the environmental tests are explained.

Schmitt, G. F., Jr.↗
DOE OSTI2022

Method of evaluating pH using a metallic nanoparticle incorporated nanocomposite-based optical pH sensor

A method for evaluating the pH of an aqueous solution by utilizing the optical properties of a pH sensing material comprised of plurality of optically active nanoparticles dispersed in matrix material. The optically active nanoparticles have an electronic conductivity greater than about 10−1 S/cm and generally have an average nanoparticle diameter of less that about 500 nanometers, and the matrix material is a material which experiences a change in surface charge density over a pH range from 2.0 to 12.0 of at least 1%. The method comprises contacting the pH sensing material and the aqueous solution, illuminating the pH sensing material, and monitoring an optical signal generated through comparison of incident light and exiting light to determine the optical transmission, absorption, reflection, and/or scattering of the pH sensitive material. The optical signal of the pH sensitive material varies in response to the pH of the aqueous solution.

Ohodnicki, Jr., Paul R.↗
NASA NTRS1990

Velocity-Resolved Far-Infrared Spectra of [Fe 2]: Evidence for Mixing and Clumping in SN 1987A

We present approx. 400 km/s resolution profiles of the 17.94 and 25.99 micron [Fe II] transitions from SN 1987A at t approx. 400 days after core collapse. These observations used the facility cooled grating spectrometer aboard NASA's Kuiper Airborne Observatory. The two profiles are similar and have FWHM line widths of approx. 2700 km/s. The higher signal-to-noise 18 micron profile is somewhat asymmetric, falling off more steeply on the redshifted side than on the blue. Gaussian fits to the profiles yield an average centroid velocity of 280 +/- 140 km/s relative to the Large Magellanic Cloud. The wings of the profiles extend to velocities is approx. greater than 3000 km/s. This shows that a significant fraction of the iron has been mixed outward into the hydrogen-rich envelope, which has a minimum expansion velocity of 2100-2400 km/s. Both profiles also contain an unresolved 3-5 sigma emission feature on the redshifted wing at nu(LSR) approx. + 3900 km/s. We interpret this feature as emission from a high-velocity clump of material containing approx. 3% of the total iron mass. The total line flux of the 26 micron ground-state transition yields an optically thin, singly ionized iron mass of 0.026 solar mass, relatively independent of the assumed temperature. This is significantly less than the 0.06 Me of Fe+ determined from the decline of the optical light curve and the ionization of measured nickel lines, implying that the iron transitions still have appreciable optical depth. However, because of the small change in the 26 micron line flux from our measurement at 250 days, and the similarity of our profiles to the 1.26 micron [Fe II] profile, most of the emission is believed to originate from optically thin material with a temperature of 4406 +/- 400 K. A comparison of the data with spherically symmetric models indicates a power-law density exponent of -3.2 +/- 1.1 and a minimum expansion velocity of 650 +/- 650 km/s for this optically thin component. The [Fe II] line fluxes and profiles also imply that the remainder of the material has high optical depth and is distributed in clumps throughout the ejecta, rather than being concentrated at low velocities in the center of a smooth density distribution.

Haas, Michael R.↗
DOE OSTI2020

Optical imprinting of superlattices in two-dimensional materials

We propose a novel optical method to imprint superlattice structures in two-dimensional electronic systems. By changing the shape of the optical field, we synthesize various lattice structures with different spatial symmetry, periodicity, and strength. We find that the wide optical tunability allows one to tune different properties of the effective band structure, including Chern number, energy bandwidths, and band gaps. We consider the high-frequency regime where the electronic system can remain in the quasi-equilibrium phase for an extended amount of time. The spatiotemporal reconfigurablity of our approach opens up new possibilities to control light-matter interaction to generate novel electronic states and optoelectronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Entropy-defect synergy for dual luminescence mechanism in spinel: Time-resolved anti-counterfeiting and fingerprint visualization

Multimodal luminescent materials, while promising for anti-counterfeiting, often lack dynamic time-dependent responses and controllable spatial distribution, limiting their encryption capabilities in the spatiotemporal dimension. Here, this work presents a coordinated control strategy based on entropy and defect engineering, and uses a backpropagation (BP) neural network for material screening to successfully prepare spinel Mg 0.8 (Fe 0.04 Co 0.04 Ni 0.04 Cu 0.04 Zn 0.04 )Cr 2 O 4 (MgA 5 CO) phosphors with time-dependent dynamic luminescence behavior. This phosphor simultaneously activated the d-d transition luminescence (∼618 nm) derived from Co 2+ /Cr 3+ and the defect luminescence (∼398 nm) related to zinc vacancies (V Zn ) in a single-phase solid solution. The phosphor exhibits a time-dependent color evolution from pink to purple under fixed-wavelength excitation, due to the different excited-state dynamics and decay lifetimes associated with the d-d transition and defect luminescence. Structural characterization and spectral analysis confirmed the existence of V Zn and its significant role in defect luminescence process. The fluorescent and dynamic luminescent properties of entropy-based spinel oxide enable its use in advanced anti-counterfeiting applications like fingerprint recognition and color-changing dedicated anti-counterfeiting mark, showing promise in high-end and time-dynamic anti-counterfeiting fields. This research not only developed a new type of fluorescent dynamic anti-counterfeiting material, but also provided a new idea for constructing advanced optical functional materials with multiple luminescence mechanisms.

Defect project↗
DOE OSTI2024

A database of thermally activated delayed fluorescent molecules auto-generated from scientific literature with ChemDataExtractor

A database of thermally activated delayed fluorescent (TADF) molecules was automatically generated from the scientific literature. It consists of 25,482 data records with an overall precision of 82%. Among these, 5,349 records have chemical names in the form of SMILES strings which are represented with 91% accuracy; these are grouped in a subsidiary database. Each data record contains one of the following four properties: maximum emission wavelength (λ EM ), photoluminescence quantum yield (PLQY), singlet-triplet energy splitting (ΔE ST ), and delayed lifetime (τ D ). The databases were created through text mining using ChemDataExtractor, a chemistry-aware natural-language-processing toolkit, which has been adapted for TADF research. The text-mined corpus consisted of 2,733 papers from the Royal Society of Chemistry and Elsevier. To the best of our knowledge, these databases are the first databases that have been auto-generated for TADF molecules from existing publications. The databases have been publicly released for experimental and computational applications in the TADF research field.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2016

Erosion Data from the MISSE 8 Polymers Experiment After 2 Years of Space Exposure on the International Space Station

The Polymers Experiment was exposed to the low Earth orbit (LEO) space environment for 2.14 and 2.0 years as part of the Materials International Space Station Experiment 8 (MISSE 8) and the Optical Reflector Materials Experiment-III (ORMatE-III), respectively. The experiment contained 42 samples, which were flown in either ram, wake, or zenith orientations. The primary objective was to determine the effect of solar exposure on the atomic oxygen erosion yield (Ey) of fluoropolymers. This paper provides an overview of the experiment with details on the polymers flown, the characterization techniques used, the atomic oxygen fluence for each exposure orientation, and the LEO Ey results. The Ey values for the fluoropolymers range from 1.45 x 10(exp -25) cm(exp 3)/atom for white Tedlar Registered Trademark (polyvinyl fluoride with white titanium dioxide pigment) flown in the ram orientation to 6.32 x 10(exp -24) cm(exp 3)/atom for aluminized-Teflon Registered Trademark fluorinated ethylene propylene (Al-FEP) flown in the zenith orientation. Erosion yield data for FEP flown in ram, wake and zenith orientations are compared, and the Ey was found to be highly dependent on orientation, hence environmental exposure. Teflon FEP had an order of magnitude higher Ey when flown in the zenith direction (6.32 x10(exp -24) cm(exp3)/atom) as compared to the ram direction (2.37 x 10(exp -25) cm(exp 3)/atom). The Ey of FEP was found to increase with a direct correlation to the solar exposure/AO fluence ratio showing the effect of solar radiation and/or heating due to solar exposure on FEP erosion. In addition, back-surface carbon painted FEP (C-FEP) flown in the zenith orientation had a significantly higher Ey than clear FEP or Al-FEP further indicating that heating has a significant impact on the erosion of FEP, particularly in the zenith orientation.

Solar radiation↗
NASA NTRSDate not supplied

On-Orbit Measurements of Solar Exclusion Angle for Modular Agile Scalable Optical Terminal (MAScOT) on the ILLUMA-T Mission

The Integrated LCRD Low-Earth Orbit User Modem and Amplifier Terminal (ILLUMA-T) optical communications payload operated on the International Space Station (ISS) for 8 months, concluding in June 2024. ILLUMA-T made the ISS the first space-based user to communicate with NASA’s Laser Communications Relay Demonstration (LCRD). ILLUMA-T was also the first flight demonstration of the Modular, Agile, Scalable Optical Terminal (MAScOT) which will also be used in the Orion Artemis II Optical Communications (O2O) program, where it will provide an optical communications link for the crew aboard the Artemis II mission. Often optical and radio frequency communications systems have outages when they are pointing close to the Sun, where unwanted incident and scattered solar energy significantly reduces or prohibits operations. The MAScOT was designed to reduce the impact of any solar scatter through optical design, material choices, surface treatments and high cleanliness levels. Based on optical scattering models, a solar exclusion angle of 10 degrees was established for ILLUMA-T. This paper presents optical scattering modeling predictions, pre-launch laboratory testing results, and on-orbit measurements of solar scatter at angles ranging from 3 to 25 degrees.

optical communications↗
NASA NTRS2000

Optical Analysis of Transparent Polymeric Material Exposed to Simulated Space Environment

Many innovations in spacecraft power and propulsion have been recently tested at NASA, particularly in non-chemical propulsion. One improvement in solar array technology is solar concentration using thin polymer film Fresnel lenses. Weight and cost savings were proven with the Solar Concentrator Arrays with Refractive Linear Element Technology (SCARLET)-II array on NASA's Deep Space I spacecraft. The Fresnel lens concentrates solar energy onto high-efficiency solar cells, decreasing the area of solar cells needed for power. Continued efficiency of this power system relies on the thin film's durability in the space environment and maintaining transmission in the 300 - 1000 nm bandwidth. Various polymeric materials have been tested for use in solar concentrators, including Lexan(TM), polyethylene terephthalate (PET), several formulations of Tefzel(Tm) and Teflon(TM), and DC 93-500, the material selected for SCARLET-II. Also tested were several innovative materials including Langley Research Center's CPI and CP2 polymers and atomic oxygen- resistant polymers developed by Triton Systems, Inc. The Environmental Effects Group of the Marshall Space Flight Center's Materials, Processes, and Manufacturing Department exposed these materials to simulated space environment and evaluated them for any change in optical transmission. Samples were exposed to a minimum of 1000 equivalent Sun hours of near-UV radiation (250 - 400 nm wavelength). Materials that appeared robust after near-UV exposure were then exposed to charged particle radiation equivalent to a five-year dose in geosynchronous orbit. These exposures were performed in MSFC's Combined Environmental Effects Test Chamber, a unique facility with the capability to expose materials simultaneously or sequentially to protons, low-energy electrons, high-energy electrons, near UV radiation and vacuum UV radiation. Reflectance measurements can be made on the samples in vacuum. Prolonged exposure to the space environment will decrease the polymer film's transmission and thus reduce the conversion efficiency. A method was developed to normalize the transmission loss and thus rank the materials according to their tolerance to space environmental exposure. Spectral results and the material ranking according to transmission loss are presented.

Edwards, David L.↗
DOE OSTI2022

Gate-tunable modulation of the optical properties of multilayer graphene by the reversible intercalation of ionic liquid anions

We demonstrate a substantial modulation of the optical properties of multilayer graphene (~100 layers) using a simple device consisting of a multilayer graphene/polymer electrolyte membrane/gold film stack. Applying a voltage of 3–4 V drives the intercalation of anion [TFSI] - [ion liquid diethylmethyl(2-methoxyethyl)ammonium bis(trifluoromethylsulfonyl)imide [DEME][TFSI]] resulting in the reversible modulation of the properties of this optically dense material. Upon intercalation, we observe an abrupt shift of 35 cm -1 in the G band Raman mode, an abrupt increase in FTIR reflectance over the wavelength range from 1.67 to 5 $μ$m (2000–6000 cm -1 ), and an abrupt increase in luminescent background observed in the Raman spectra of graphene. Furthermore, all of these abrupt changes in the optical properties of this material arise from the intercalation of the TFSI - ion and the associated change in the free carrier density (Δ$n$ = 10 20 cm -3 ). Suppression of the 2D band Raman mode observed around 3 V corresponds to Pauli blocking of the double resonance Raman process and indicates a modulation of the Fermi energy of Δ$E$ F = 1.1 eV.

42 ENGINEERING↗
NASA NTRS1992

Degradation of optical components in a space environment

The objective of the Phillips Laboratory (PL) Long Duration Exposure Facility (LDEF) experiment is to determine the adverse effects of the natural space environment on laser optical component and coating materials. The LDEF experiment provides a unique opportunity for the study of optical material response to an extended low earth orbit space exposure. The PL samples consist of 10 sets of the six materials each. The materials are uncoated fused silica, magnesium fluoride coated fused silica, uncoated molybdenum, molybdenum coated with chromium, silver and thorium fluoride, diamond turned copper, and diamond turned nickel plated copper. Performance degradation will be correlated to establish trends between sample location, duration of exposure, atomic oxygen exposure and other space environmental conditions. This paper discusses the results of the tests thus far performed on the LDEF samples and the plans for the future.

Dehainaut, Linda L.↗