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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Global Precipitation Means and Variations with the New Version of GPCP

Knowledge of global precipitation means, patterns and variations is essential for understanding the global water cycle. The observation-based global analysis of the Global Precipitation Climatology Project (GPCP) has been a key input to many such studies, including those related to means of the global (and regional) water and energy cycles. A new version (Version 3.1) of the GPCP monthly analysis is now available (1983-2019), with finer spatial resolution (0.5º latitude/longitude), updated satellite algorithms, latest gauge analysis over land from the Global Precipitation Climatology Center (GPCC), and with ocean climatologies adjusted using information from the Tropical Rainfall Measuring Mission (TRMM), the Global Precipitation Measurement (GPM) mission and CloudSat. The presentation will give key findings from the new analysis, compare with the previous version, link to studies of the water cycle and compare to CMIP6 climate model results. The GPCP Monthly V3.1 analysis uses a Tropical Composite Climatology (TCC) using 22 years (1998-2019) of TRMM and GPM-based surface precipitation estimates from passive microwave, radar and combined passive microwave and radar observations to adjust the long-term mean values in the tropics over ocean. At higher latitudes over ocean climatological values of merged CloudSat and GPM combined passive microwave and radar surface precipitation estimates are used. The result of the new algorithms and procedures is an ocean mean value 60º N to 60º S of 3.2 mm/d, an increase of 7% from the older V2.3. Over land the gauge analysis (from GPCC in Germany), combined with satellite estimates results in a small decrease (~ 0.5%) from the previous version, giving a total global precipitation mean of 2.81 mm/d for V3.1, an increase of 4.5%. Variations from inter-annual to trend scales over most of the ocean are driven by the Colorado State University (CSU) Goddard Profiling (GPROF) algorithm applied to SSMI/SSMIS satellite data. The new GPCP version retains a near zero trend of global precipitation, with significant positive trends in the deep tropics along the Pacific ITCZ and elsewhere, countered by middle latitude decreases, very similar to the previous version of the GPCP Monthly analysis. The pattern of trends is similar to that of AMIP climate model results, driven by observed SSTs for the period in question, but very different from results for “free-running” CMIP historical ensembles, likely due in part to the relatively short comparison period and effects of inter-decadal variations in the GPCP and AMIP results that are not in the “history” models. Interannual variations are also nearly the same in the new version, but with finer detail, although ENSO variations over the ocean have slightly larger amplitude than before, an effect likely related to the change in ocean satellite algorithm used in Version 3. For precipitation intensity (percentiles) at the monthly scale, especially in the tropics, GPCP shows a positive trend for the upper one third of the percentiles (Pct ≥ 70th) and a much weaker positive trend for the lowest percentiles (Pct ≤ 10th), while negative trends appear for the middle one-half percentiles (20th-65th). AMIP results agree with those from the GPCP in terms of the sign of the changes/trends for high and intermediate percentiles. The CMIP historical results also agree in the sign of the trends, but the trends are weaker. Comparisons with other types of CMIP historical simulations including the GHG-only, aerosol-only, and nature-only runs suggest that the observed changes/trends in precipitation amount and intensity during the GPCP period are dominated by a combination of the effects of the Pacific Decadal Oscillation (PDO) and anthropogenic GHG-related surface warming.

Robert Adler↗
DOE OSTI2023

Atomic layer deposition with passivation treatment

A method includes: 1) performing an atomic layer deposition cycle including (a) introducing precursors into a deposition chamber housing a substrate to deposit a material on the substrate; and (b) introducing a passivation gas into the deposition chamber to passivate a surface of the material; and 2) repeating 1) a plurality of times to form a film of the material.

Prinz, Friedrich B.↗
NASA NTRS1990

Interface properties of various passivations of HgCdTe

The effects of different surface treatments of the p-type Hg(x-1)Cd(x)Te (x about 0.2) alloy, including anodic-sulfide, anodic-oxide, and ZnS coatings, on the surface charge density and surface mobility were investigated. Measurements of surface recombination velocities in samples passivated by either a ZnS coating on a freshly etched surface or by anodic native sulfide combined with deposited ZnS showed essentially the same temperature dependence down to 50 K. For the same original material, both the surface state density and the activation energy were found to be similar. It is suggested that, for both passivations, the surface is controlled by traps that can be related to lattice defects, such as vacancies.

Schacham, S. E.↗
NASA NTRS1974

Passivation of pigment particles for thermal control coatings

Various redox couple surface additives are studied which increase the photostability of coprecipitated zinc orthotitanate pigment. The electron spin resonance technique was used to examine the characteristic photodamage centers. Results indicate that cerium surface redox additive completely passivates the pigment at the surface concentrations studied. Less passivation occurs with the iridium chloride and the iron cyanide redox couples.

Sancier, K. M.↗
NASA NTRS2021

Surface Melting Over the Greenland Ice Sheet Derived From Enhanced Resolution Passive Microwave Brightness Temperatures (1979–2019)

Surface melting is a major component of the Greenland ice sheet surface mass balance, and it affects sea level rise through direct runoff and the modulation of ice dynamics and hydrological processes, supraglacially, englacially and subglacially. Passive microwave (PMW) brightness temperature observations are of paramount importance in studying the spatial and temporal evolution of surface melting due to their long temporal coverage (1979–present) and high temporal resolution (daily). However, a major limitation of PMW datasets has been the relatively coarse spatial resolution, which has historically been of the order of tens of kilometers. Here, we use a newly released PMW dataset (37 GHz, horizontal polarization) made available through a NASA “Making Earth System Data Records for Use in Research Environments” (MeASUREs) program to study the spatiotemporal evolution of surface melting over the Greenland ice sheet at an enhanced spatial resolution of 3.125 km. We assess the outputs of different detection algorithms using data collected by automatic weather stations (AWSs) and the outputs of the Modèle Atmosphérique Régional (MAR) regional climate model. We found that sporadic melting is well captured using a dynamic algorithm based on the outputs of the Microwave Emission Model of Layered Snowpack (MEMLS), whereas a fixed threshold of 245 K is capable of detecting persistent melt. Our results indicate that, during the reference period from 1979 to 2019 (from 1988 to 2019), surface melting over the ice sheet increased in terms of both duration, up to 4.5 (2.9) d per decade, and extension, up to 6.9 % (3.6 %) of the entire ice sheet surface extent per decade, according to the MEMLS algorithm. Furthermore, the melting season started up to 4.0 (2.5) d earlier and ended 7.0 (3.9) d later per decade. We also explored the information content of the enhanced-resolution dataset with respect to the one at 25 km and MAR outputs using a semi-variogram approach. We found that the enhanced product is more sensitive to local-scale processes, thereby confirming the potential of this new enhanced product for monitoring surface melting over Greenland at a higher spatial resolution than the historical products and for monitoring its impact on sea level rise. This offers the opportunity to improve our understanding of the processes driving melting, to validate modeled melt extent at high resolution and, potentially, to assimilate these data in climate models.

Surface melting↗
NASA NTRS2004

Microwave Remote Sensing Modeling of Ocean Surface Salinity and Winds Using an Empirical Sea Surface Spectrum

Active and passive microwave remote sensing techniques have been investigated for the remote sensing of ocean surface wind and salinity. We revised an ocean surface spectrum using the CMOD-5 geophysical model function (GMF) for the European Remote Sensing (ERS) C-band scatterometer and the Ku-band GMF for the NASA SeaWinds scatterometer. The predictions of microwave brightness temperatures from this model agree well with satellite, aircraft and tower-based microwave radiometer data. This suggests that the impact of surface roughness on microwave brightness temperatures and radar scattering coefficients of sea surfaces can be consistently characterized by a roughness spectrum, providing physical basis for using combined active and passive remote sensing techniques for ocean surface wind and salinity remote sensing.

Sea surface spectrum↗
NASA NTRS1992

Botswana water and surface energy balance research program. Part 2: Large scale moisture and passive microwaves

The Botswana water and surface energy balance research program was developed to study and evaluate the integrated use of multispectral satellite remote sensing for monitoring the hydrological status of the Earth's surface. The research program consisted of two major, mutually related components: a surface energy balance modeling component, built around an extensive field campaign; and a passive microwave research component which consisted of a retrospective study of large scale moisture conditions and Nimbus scanning multichannel microwave radiometer microwave signatures. The integrated approach of both components are explained in general and activities performed within the passive microwave research component are summarized. The microwave theory is discussed taking into account: soil dielectric constant, emissivity, soil roughness effects, vegetation effects, optical depth, single scattering albedo, and wavelength effects. The study site is described. The soil moisture data and its processing are considered. The relation between observed large scale soil moisture and normalized brightness temperatures is discussed. Vegetation characteristics and inverse modeling of soil emissivity is considered.

Vandegriend, A. A.↗
DOE OSTI2024

Screen-Printed Complex Ag Inks for Si HJT Metallization

Metallization using reactive metal inks has recently attracted significant research interest due to its advantages in cost of materials and manufacturing, while still achieving performance comparable to traditional fire-through particle pastes. Here, we present for the first time the use of reactive silver (Ag) inks via industrial screen-printing and inkjet printing methods for the metallization of different Si surfaces used in tunneling oxide passivating contacts (TOPCon) and Silicon heterojunction (SHJ) solar cells. Printed Ag lines exhibit a conductivity of ~5 Mu O·cm, which is approximately 3 times that of bulk Ag (1.59 µO·cm). The printed metal has a thickness of ~0.5-1.5 Mu m, an order of magnitude smaller than the current fire-through metal finger thickness (~15 Mu m). Contact resistivity measurements of the screen-printed and inkjet-printed samples on a transparent conducting oxide (TCO) surface show a very low value of ~0.2-12 mO·cm 2. Photoluminescence images of the metallized samples demonstrate minimal surface passivation degradation compared to the non-metallized areas (?iVoc <3.5 mV). Scanning electron microscopy images (SEM) reveal the structure of the printed metals on the Si surfaces as porous but much denser than fire-through Ag by nanoparticle paste. In the final presentation, we will showcase our results of printing these reactive Ag inks on high-efficiency heterojunction and TOPCon solar cells with full-area M6 wafers. Additionally, the adhesion of these reactive Ag inks on different Si surfaces according to ASTM D3359-17, as well as the performance of solar cells after standard IEC 61215 freeze/thaw and damp heat tests, will be presented. These new metal inks show promising potential as an alternative to the currently dominant particle-based pastes, offering lower Ag consumption and lower processing temperatures without compromising performance.

heterojunction solar cells↗
NASA NTRS1993

Progress in p(+)n InP solar cells fabricated by thermal diffusion

The performance results of our most recently thermally diffused InP solar cells using the p(+)n (Cd,S) structures are presented. We have succeeded in fabricating cells with measured AMO, 25 C V(sub oc) exceeding 880 mV (bare cells) which to the best of our knowledge is higher than previously reported V(sub oc) values for any InP homojunction solar cells. The cells were fabricated by thinning the emitter, after Au-Zn front contacting, from its initial thickness of about 4.5 microns to about 0.6 microns. After thinning, the exposed surface of the emitter was passivated by a thin (approximately 50A) P-rich oxide. Based on the measured EQY and J(sub sc)-V(sub oc) characteristics of our experimental high V(sub oc) p(+)n InP solar cells, we project that reducing the emitter thickness to 0.3 microns, using an optimized AR coating, maintaining the surface hole concentration of 3 x 10(exp 18)cm(sup -3), reducing the grid shadowing from actual 10.55 percent to 6 percent and reducing the contact resistance will increase the actual measured 12.57 percent AMO 25 C efficiency to about 20.1 percent. By using our state-of-the-art p(+)n structures which have a surface hole concentration of 4 x 10(exp 18)cm(sup -3) and slightly improving the front surface passivation, an even higher practically achievable AMO, 25 C efficiency of 21.3 percent is projected.

Flood, D. J.↗
NASA NTRS2012

Estimating Sea Surface Salinity and Wind Using Combined Passive and Active L-Band Microwave Observations

Several L-band microwave radiometer and radar missions have been, or will be, operating in space for land and ocean observations. These include the NASA Aquarius mission and the Soil Moisture Active Passive (SMAP) mission, both of which use combined passive/ active L-band instruments. Aquarius s passive/active L-band microwave sensor has been designed to map the salinity field at the surface of the ocean from space. SMAP s primary objectives are for soil moisture and freeze/thaw detection, but it will operate continuously over the ocean, and hence will have significant potential for ocean surface research. In this innovation, an algorithm has been developed to retrieve simultaneously ocean surface salinity and wind from combined passive/active L-band microwave observations of sea surfaces. The algorithm takes advantage of the differing response of brightness temperatures and radar backscatter to salinity, wind speed, and direction, thus minimizing the least squares error (LSE) measure, which signifies the difference between measurements and model functions of brightness temperatures and radar backscatter. The algorithm uses the conjugate gradient method to search for the local minima of the LSE. Three LSE measures with different measurement combinations have been tested. The first LSE measure uses passive microwave data only with retrieval errors reaching 1 to 2 psu (practical salinity units) for salinity, and 1 to 2 m/s for wind speed. The second LSE measure uses both passive and active microwave data for vertical and horizontal polarizations. The addition of active microwave data significantly improves the retrieval accuracy by about a factor of five. To mitigate the impact of Faraday rotation on satellite observations, the third LSE measure uses measurement combinations invariant under the Faraday rotation. For Aquarius, the expected RMS SSS (sea surface salinity) error will be less than about 0.2 psu for low winds, and increases to 0.3 psu at 25 m/s wind speed for warm waters (25 C). To achieve the required 0.2 psu accuracy, the impact of sea surface roughness (e.g. wind-generated ripples) on the observed brightness temperature has to be corrected to better than one tenth of a degree Kelvin. With this algorithm, the accuracy of retrieved wind speed will be high, varying from a few tenths to 0.6 m/s. The expected direction accuracy is also excellent (less than 10 ) for mid to high winds, but degrades for lower speeds (less than 7 m/s).

Yueh, Simon H.↗
NASA NTRS2019

Enhancing GPM Passive and Combined Microwave Algorithms with Dynamic Surface Information for Drizzle Retrieval and Improved Precipitation Detection Over Land

Following the 2014 launch of the Global Precipitation Measurement Mission (GPM), an unprecedented combination of coincident active and passive microwave observations are available for state of the art precipitation retrieval. The GPM Combined Algorithm forms the backbone of this effort, optimizing geophysical variables for agreement with the full suite of multi-spectral information content. These combined retrievals are then utilized, along with a radiative transfer model, as a database applied for retrievals across a constellation of passive microwave radiometers of varying frequencies. By keeping such retrievals related through the transfer standard of the combined algorithm, level 3 products such as the Integrated Multi-satellitE Retrievals for GPM (IMERG) are able to provide consistent global products for users at the higher temporal resolution required for hydrological applications. In initial versions of the combined product, precipitation retrievals are carried out only in the presence of a signal from the active radar. As a result, light precipitation and drizzle below the threshold of DPR sensitivity are not included in any of the products down the chain from the constellation to IMERG. In this work, the effects of enhancing the retrievals with a surface emissivity and non-raining water vapor retrieval using the passive observations are explored. Over both ocean and land, the surface retrieval is used to identify areas with high probability of light precipitation and drizzle which is then quantified using techniques derived from the higher sensitivity CloudSat mission. Results indicate successful inclusion of drizzle in the retrievals that can then be included in the constellation databases, as well as improvement in passive microwave false positive precipitation signals over land in cases where surface scattering was misinterpreted as precipitation signal. The inclusion of the dynamic surface information also creates a more robust, radiometrically consistent retrieval scheme for process studies and hydrologic applications.

Ringerud, Sarah↗
DOE OSTI2023

Mooring latch for marine structures

A mooring latch includes a passive foundation portion and a latching portion. The latching portion includes a mechanism, a conical surface shaped to mate with a conical surface of the passive portion, a connector for connection to a mooring structure and permitting rotation about a horizontal axis. The mechanism has a latched configuration that mates the conical surfaces and permits rotations about a shared vertical axis of the conical surfaces. A mooring line threaded through the passive and latching portions and equipped with one or more stops may be used to guide the latching portion to or from the passive portion and to actuate latching or unlatching or the mooring latch.

Siegel, Stefan G.↗
DOE OSTI2022

Stability-limiting heterointerfaces of perovskite photovoltaics

Optoelectronic devices consist of heterointerfaces formed between dissimilar semiconducting materials. The relative energy level alignment between contacting semiconductors determinately affects the heterointerface charge injection and extraction dynamics. For perovskite solar cells (PSCs), the heterointerface between the top perovskite surface and a charge-transporting material (CTM) is often treated for defect passivation to improve PSC stability and performance. However, such surface treatments could also affect the heterointerface energetics. Here we show that surface treatments may induce a negative work function shift (i.e. more n-type), which activates halide migration to aggravate PSC instability. Therefore, despite the beneficial effects of surface passivation, this detrimental side effect limits the maximum stability improvement attainable for PSCs treated in these ways. Furthermore, this trade-off between the beneficial and detrimental effects should guide further work on improving PSC stability via surface treatments.

14 SOLAR ENERGY↗
NASA NTRS2012

Low Cost, Low Power, Passive Muon Telescope for Interrogating Martian Sub-Surface

It has been demonstrated on Earth that a low power, passive muon detector can penetrate deep into geological structures up to several kilometers in size providing high density images of their interiors. Muon tomography is an entirely new class of planetary instrumentation that is ideally suited to address key areas in Mars Science, such as: the search for life and habitable environments, the distribution and state of water and ice and the level of geologic activity on Mars today.

Muons↗
DOE OSTI2023

Nucleation dependence of atomic layer deposition on diamond surface termination

Surface termination and interfacial interactions are critical for advanced solid-state quantum applications. Here, in this paper, we demonstrate that atomic layer deposition (ALD) can both provide valuable insight on the chemical environment of the surface, having sufficient sensitivity to distinguish between the common diamond (001) surface termination types and passivate these interfaces as desired. We selected diamond substrates exhibiting both smooth and anomalously rough surfaces to probe the effect of morphology on ALD nucleation. We use high resolution in situ spectroscopic ellipsometry to monitor the surface reaction with sub-angstrom resolution, to evaluate the nucleation of an ALD Al 2 O 3 process as a function of different ex and in situ treatments to the diamond surface. In situ water dosing and high vacuum annealing provided the most favorable environment for nucleation of dimethylaluminum isopropoxide and water ALD. Hydrogen termination passivated both smooth and rough surfaces while triacid cleaning passivated the smooth surface only, with striking effectiveness.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗