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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

A Novel Process for Carbon Dioxide Conversion to Fuel

In this project, TDA developed a new mixed metal oxide-based sorbent that converts CO2 (captured from coal fired power plants) to CO, which can then be combined with renewable H2 generated by water electrolysis or H2 from steam methane reforming to produce different liquid fuels. TDA’s absorbent-based CO2 conversion process uses a redox process, which splits the catalytic reforming of methane with CO2 reaction into two stages: CO2 reduction to CO and CH4 reforming into H2 and CO which eliminates the equilibrium limitations. The CO produced in the two-stage reactor system can then be further reacted with renewable H2 to produce methanol, naphtha, diesel, or gasoline. We worked with the Advanced Power & Energy Program (APEP) of University of California, Irvine (UCI) to design and develop the liquid fuel synthesis process that is built around this new material. We demonstrated the techno-economic viability of the new sorbent based redox process to convert CO2 into synthesis gas by demonstrating continuous carbon dioxide reduction in a prototype test system for over 585 hours while converting up to 10 kg CO2/day. With the successful completion of the R&D effort, the technology is now ready for a larger pilot-scale demonstration and the technology readiness has been raised from TRL 3 to TRL 5. In collaboration with UCI, we completed a high-fidelity process design and economic analysis. The required sale price (RSP) for gasoline (Case 1 NG-MTG) is $4.91/gal and naphtha and diesel (Case 2 NG-FT) are $4.23/gal and $6.07/gal, respectively, on a 2011 dollar basis. To put these costs in perspective, the California prices in current dollars (with its strict specifications) for regular grade gasoline from last year to current year have varied from a low of $3.10/gal in January 2021 to a high of $5.76/gal in March 2022, while prices for diesel from last year to current year have varied from a low of $3.40/gal in January 2021 to a high of $6.41/gal in May 2022 according to the U.S. Energy Information Agency data. It should be noted that the gasoline and diesel produced by these designs of Case 1 and Case 2 would be of very high quality and both nitrogen and sulfur free. These RSPs are based on a cost of imported electricity of $64/MWh based on the low-end current wind generated electricity cost (Genevieve 2011). This cost is by far the largest component of the variable costs used in computing the RSPs. A sensitivity analysis of these RSPs to the cost of imported electricity shows that the cost of the imported electricity has a significant effect on the RSPs. The life cycle analysis (LCA) shows that the total cradle-to-gate CO2 emissions for both liquid fuels (diesel and gasoline) were negative, indicating that overall more CO2 is consumed than released during production of the fuel from CO2 feed stack for both cases (-296 kgCO2 per MT gasoline for Case 1 and -705 kgCO2 per MT diesel for Case 2). On a cradle-to-grave comparison, the use of diesel produced using TDA’s process (2,457 kgCO2 per MT diesel) would release 37.6% less CO2 compared to petroleum based diesel (3,937 kgCO2 per MT diesel) while the use of gasoline produced using TDA’s process (2,792 kgCO2 per MT gasoline) would release 29.3% less CO2 compared to petroleum based gasoline (3,946 kgCO2 per MT gasoline). With the successful completion of the R&D effort, the technology is now ready for a bench-scale demonstration and the technology readiness has been raised from TRL 3 (Analytical and experimental critical function and/or characteristic proof of concept) to TRL 5 (Laboratory scale similar system validation in relevant environment).

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2026

Opportunities for bioenergy crops to support transitions from irrigated agriculture and conserve the U.S. High Plains Aquifer

This study investigates potential economic and groundwater driven transitions from irrigated maize production—the dominant irrigated cropping system in the High Plains Aquifer (HPA) region—to alternative crops such as sorghum and switchgrass, two common bioenergy feedstocks. Unsustainable groundwater extraction in the U.S. High Plains presents critical challenges including reduced irrigation capacities, diminished crop yields, lower land values, and escalating energy costs. Using a spatially explicit optimization framework combined with comprehensive economic and hydrogeological data, we evaluate optimal land-use strategies and irrigation system investments over a 30-year planning period. Results indicate significant regional variability in the future economic viability of irrigated agriculture, driven by differences in aquifer recharge rates, groundwater availability, and market conditions. Nebraska and parts of northern Texas can sustain irrigated maize profitability due to relatively favorable groundwater conditions and lower land rents, respectively. In contrast, many portions of Kansas and southern Texas are more likely to transition to dryland agriculture within two decades. Colorado and New Mexico show potential for significant adoption of switchgrass production as an alternative biomass-based energy crop. Overall, over the 30-year horizon, our model implies that approximately 23% of currently irrigated maize area across the HPA region may transition to dryland farming under business-as-usual conditions. This transition is complemented by a threefold increase in non-irrigated sorghum production, from 0.20 to 0.77 Mt yr−1, indicating that groundwater-driven shifts in agricultural production may support a larger regional base for bioenergy feedstocks. The study also reveals opportunities for producers to optimize economic returns and biomass production potential.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1998

X-33 Telemetry Best Source Selection, Processing, Display, and Simulation Model Comparison

The X-33 program requires the use of multiple telemetry ground stations to cover the launch, ascent, transition, descent, and approach phases for the flights from Edwards AFB to landings at Dugway Proving Grounds, UT and Malmstrom AFB, MT. This paper will discuss the X-33 telemetry requirements and design, including information on fixed and mobile telemetry systems, best source selection, and support for Range Safety Officers. A best source selection system will be utilized to automatically determine the best source based on the frame synchronization status of the incoming telemetry streams. These systems will be used to select the best source at the landing sites and at NASA Dryden Flight Research Center to determine the overall best source between the launch site, intermediate sites, and landing site sources. The best source at the landing sites will be decommutated to display critical flight safety parameters for the Range Safety Officers. The overall best source will be sent to the Lockheed Martin's Operational Control Center at Edwards AFB for performance monitoring by X-33 program personnel and for monitoring of critical flight safety parameters by the primary Range Safety Officer. The real-time telemetry data (received signal strength, etc.) from each of the primary ground stations will also be compared during each nu'ssion with simulation data generated using the Dynamic Ground Station Analysis software program. An overall assessment of the accuracy of the model will occur after each mission. Acknowledgment: The work described in this paper was NASA supported through cooperative agreement NCC8-115 with Lockheed Martin Skunk Works.

Burkes, Darryl A.↗
DOE OSTI2022

The Cypress Sandstone Seal System

The Cypress Sandstone is the youngest and shallowest unit in the Illinois Basin that was featured in the United States Carbon Utilization and Storage Atlas IV as a target for saline carbon storage with an estimated 0.2 to 2.3 GT of storage potential. Additional research on a residual oil zone (ROZ) developed within the Cypress Sandstone has delineated 27 prospects with approximately 290.8 million m3 (1.8 billion barrels) of oil in place. 21 to 31 million m 3 (144 to 196 million barrels) of oil is estimated to be recoverable using carbon dioxide enhanced oil recovery (CO 2 -EOR). Storage of CO 2 associated with EOR in these ROZ prospects alone, not accounting for associated main pay zones (MPZs), underlying brine formation, or intervals adjacent to or between prospects, is estimated to be up to 10.4 billion tonnes. The Cypress Sandstone is thus well understood to be a CO 2 injection target, both for EOR and associated storage. However, the seal system overlying the Cypress Sandstone is poorly understood. Unlike deeper formations such as the Mt. Simon Sandstone or the St. Peter Sandstone which are either in use as a CO 2 sink or being characterized for prospective storage, respectively, the Cypress is not overlain by hundreds of feet of impermeable shale. Rather, the Cypress is overlain by a lithologically variable interval that is composed generally of shales and limestones with some sandstone in the part of the Basin where the Cypress is deep enough to facilitate CO 2 storage. Also, due to its status as one of the shallowest and most prolific oil reservoirs in the Basin, the seal system overlying the Cypress Sandstone has a relatively high number of legacy well penetrations. The purpose of this report is to characterize the Cypress Sandstone seal system using well logs and available core. Gross thickness, lithology (facies), and mineralogy of seals is described and mapped across the Basin. The column height of CO 2 that can be held is calculated using capillary pressure data from a representative core.

02 PETROLEUM↗
NASA NTRS1994

Heterogeneous Reactions of ClONO2, HCl, and HOCl on Liquid Sulfuric Acid Surfaces

The heterogeneous reactions of ClONO2 + H2O yields HNO3 + HOCl (1), ClONO2 + HCl yields C12 + HNO3 (2), and HOCl + HCl yields Cl2 + H2O (3) on liquid sulfuric acid surfaces have been studied using a fast flow reactor coupled to a quadrupole mass spectrometer. The main objectives of the study are to investigate: (a) the temperature dependence of these reactions at a fixed H2O partial pressure typical of the lower stratosphere (that is, by changing temperature at a constant water partial pressure, the H2SO4 content of the surfaces is also changed), (b) the relative importance or competition between reactions 1 and 2, and (c) the effect of HNO3 on the reaction probabilities due to the formation of a H2SO4/HNO3/H2O ternary system. The measurements show that all the reactions depend markedly on temperature at a fixed H2O partial pressure: they proceed efficiently at temperatures near 200 K and much slower at temperatures near 220 K. The reaction probability (gamma(sub 1)) for ClONO2 hydrolysis approaches 0.01 at temperatures below 200 K, whereas the values for gamma(sub 2) and gamma(sub 3) are on the order of a few tenths at 200 K. Although detailed mechanisms for these reactions are still unknown, the present data indicate that the competition between ClONO2 hydrolysis and ClONO2 reaction with HCl may depend on temperature (or H2SO4 Wt %): in the presence of gaseous HCl at stratospheric concentrations, reaction 2 is dominant at lower temperatures (less than 200 K), but reaction 1 becomes important at temperatures above 210 K. Furthermore, reaction probability measurements performed on the H2SO4/HNO3/ H2O ternary solutions do not exhibit noticeable deviation from those performed on the H2SO4/H2O binary system, suggesting little effect of HNO3 in sulfate aerosols on the ClONO2 and HOCl reactions with HCl. The results reveal that significant reductions in the chlorine-containing reservoir species (such as ClONO2 and HCl) can take place on stratospheric sulfate aerosols at high latitudes in winter and early spring, even at temperatures too warm for Polar Stratospheric Clouds (PSCs) to form or in regions where nucleation of PSCs is sparse. This is particularly true under elevated sulfuric acid loading, such as that after the eruption of Mt. Pinatubo. Comparisons between our results and those presently available have also been made.

Zhang, Renyi↗
DOE OSTI2022

Advancing Geophysical Techniques to Image a Stratigraphic Hydrothermal Resource

Sedimentary-hosted geothermal energy systems are permeable structural, structural-stratigraphic, and/or stratigraphic horizons with sufficient temperature for direct use and/or electricity generation. Sedimentary-hosted (i.e., stratigraphic) geothermal reservoirs may be present in multiple locations across the central and eastern Great Basin of the USA, thereby constituting a potentially large base of untapped, economically accessible energy resources. Sandia National Laboratories has partnered with a multi disciplinary group of collaborators to evaluate a stratigraphic system in Steptoe Valley, Nevada using both established and novel geophysical imaging techniques. The goal of this study is to inform an optimized strategy for subsequent exploration and development of this resource and analogous ones. Building from prior Nevada Play Fairway Analysis (PFA), this team is primarily 1) collecting additional geophysical data, 2) employing novel joint geophysical inversion/modeling techniques to update existing 3D geologic models, and 3) integrating the geophysical results to produce a working, geologically constrained thermo-hydrological reservoir model. Prior PFA work highlights Steptoe Valley as a favorable resource basin that likely has both sedimentary and hydrothermal characteristics. However, there remains significant uncertainty on the nature and architecture of the resource(s) at depth, which increases the risk in exploratory drilling. Newly acquired gravity, magnetic, magnetotelluric, and controlled-source electromagnetic data products, in conjunction with new and preexisting geoscientific measurements and observations, are being integrated and evaluated for efficacy in understanding stratigraphic geothermal resources and mitigating exploration risk. Furthermore, the influence of hydrothermal activity on sedimentary-hosted reservoirs in favorable structural settings, and whether fault-controlled systems may locally enhance temperature and permeability in some deep stratigraphic reservoirs, will also be evaluated.

Geothermal, Sedimentary Heat, Geophysics, Seismic,↗
NASA NTRS1992

SAGE II measurements of early Pinatubo aerosols

SAGE II satellite measurements of the Mt. Pinatubo eruption cloud in the stratosphere during June, July, and early August 1991 show that aerosols in the tropics reached as high as 29 km altitude with most of the cloud between 20 and 25 km. The most optically thick portions of the cloud covered latitudes from 10 deg S to 30 deg N during the early part of this period. By late July, high stratospheric optical depths were observed to at least 70 deg N, with the high values north of about 30 deg N from layers below 20 km. High pressure systems in both hemispheres were observed to be correlated with the movement of volcanic material at 21 km into the westerly jet stream at high southern latitudes and similarly to high northern latitudes at 16 km. By August, the entire Southern Hemisphere had experienced a 10-fold increase in optical depth relative to early July due to layers above 20 km. Initial mass calculations using SAGE II data place the aerosol produced from this eruption at 20 to 30 megatons, well above the 12 megatons produced by El Chichon.

Mccormick, M. P.↗
DOE OSTI2022

NCSU Industrial Assessment Center

Renewable energy technologies are becoming more attractive and gaining more attention as the world becomes increasingly aware of the negative impacts of global warming and greenhouse gas (GHG) emissions. Two such emerging technologies are geothermal heat pumps (GHP) and solar thermal heating which can be used for heating and cooling of buildings. GHP systems are a well-studied technology that have been proven to be more efficient than traditional air-source heat pumps for space conditioning of buildings. Solar thermal heating has become more common as a way to heat domestic hot water (DHW) in homes, but the two technologies are not often combined. This study presents the findings of combining an open-loop GHP with 100 ft2 of flat plate solar thermal panels and a 5,655-gallon sensible water storage tank for space heating and DHW heating needs of a residential home in Bozeman, MT, USA. The goal of this system was to use energy from the solar panels and storage tank first to decrease pumping energy from the GHP well. The open loop system was designed to be a backup system to the solar thermal panels and sensible storage tank. An actual home was modeled to determine potential energy and cost savings of such a system compared to a traditional propane boiler. Then, a case study was performed on the installed system from January to June 2021. Results obtained from April 2nd to June 5th, 2021 indicated that the combination system supplied all necessary heat, and that heat was supplied from the thermal storage tank 55% of the time. This represents a savings of 330 kWh of energy and $36 compared to operating just the open loop geothermal system. From April 2nd to June 5th the combination system consumed a total of 2,510 kWh of energy and cost $274 to operate. Based on data obtained, there is significant potential for energy savings compared to a propane boiler, however only small potential for cost savings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2022

Measurement of Surface Deformation Related to the December 2018 Mt. Etna Eruption Using Time-Series Interferometry and Magma Modeling for Hazard Zone Mapping

Mount Etna has erupted several times since it was first formed. Recently, Mount Etna began erupting again over 24–27 December 2018. Because it erupts frequently, Mount Etna should be observed on a frequent basis. From June 2018 to October 2019, 34 and 56 interferometric synthetic aperture radar (InSAR) images were acquired from the ascending and descending tracks of the Sentinel-1 satellite, respectively. We employed the Stanford Method for Persistent Scatterers (StaMPS) and a refined small baseline subset (SBAS) InSAR method to produce a surface deformation time-series map. In the time-series analysis, the phase signal remained unaltered with time. The Okada model was then applied to the result to generate a modeled interferogram, and the Q-LavHA program was run to generate a lava flow prediction model. A direct comparison of the results showed that Persistent Scatterers Interferometry (PSI)-StaMPS and the refined SBAS technique were comparable in terms of the displacement pattern, with slightly different velocity values obtained for individual points. In particular, a velocity range of −25 to 21 cm/yr was obtained from PSI-StaMPS, whereas a range of −30 to 25 cm/yr was obtained from the refined SBAS method. Upon computation of the vertical and east-west displacement components based on ascending and descending track data using both methods, deformation velocities of 51.5 and 52.5 cm/yr in the westerly direction on the western flank of Mount Etna were obtained from PSI-StaMPS and the refined SBAS method, respectively, whereas on the eastern flank, deformation toward the east was estimated to occur at a velocity of 50.1 or 54.2 cm/yr, respectively. PSIStaMPS estimated a vertical deformation velocity of −5.3 to 18.3 cm/yr, whereas the refined SBAS method produced a velocity range of approximately −7 to 19 cm/yr. The interferogram obtained via Okada modeling showed two fault sources in the 2018 Mount Etna eruption and a total volume change of approximately 12.39 × 10 6 m 3 . From the modeling results, a lava flow prediction model was generated using the Q-LavHA program. The approaches described in this study can be used by government officials, authorities, and other decision-makers to monitor and assess the risk of volcanic activity in the region.

Suci Ramayanti↗
NASA NTRS2013

Net Shape Spin Formed Cryogenic Aluminum Lithium Cryogenic Tank Domes for Lower Cost Higher Performance Launch Vehicles

With the goal of lower cost (simplified manufacturing and lower part count) and higher performance (higher strength to weight alloys) the NASA Technical Maturation Program in 2006 funded a proposal to investigate spin forming of space launch vehicle cryogenic tank domes. The project funding continued under the NASA Exploration Technology Development Program through completion in FY12. The first phase of the project involved spin forming of eight, 1 meter diameter "path finder" domes. Half of these were processed using a concave spin form process (MT Aerospace, Augsburg Germany) and the other half using a convex process (Spincraft, Boston MA). The convex process has been used to produce the Ares Common Bulkhead and the concave process has been used to produce dome caps for the Space Shuttle light weight external tank and domes for the NASDA H2. Aluminum Lithium material was chosen because of its higher strength to weight ratio than the Aluminum 2219 baseline. Aluminum lithium, in order to obtain the desired temper (T8), requires a cold stretch after the solution heat treatment and quench. This requirement favors the concave spin form process which was selected for scale up. This paper describes the results of processing four, 5.5 meter diameter (upper stage scale) net shaped spin formed Aluminum Lithium domes. In order to allow scalability beyond the limits of foundry and rolling mills (about 12 foot width) the circular blank contained one friction stir weld (heavy lifter scales require a flat blank containing two welds). Mechanical properties data (tensile, fracture toughness, stress corrosion, and simulated service testing) for the parent metal and weld will also be discussed.

Curreri, Peter A.↗
NASA NTRS2000

The AGN Content of the Micron all Sky Survey

The Two Micron All Sky Survey (2MASS) began routine operations from its northern facility on Mt. Hopkins, AZ in June of 1997, and from its southern facility on Cerro Tololo, Chile in March of 1998. At each site, highly automated 1.3 m telescopes equipped with identical 3-channel cameras, are systematically imaging the sky in three near infrared wavelength bands, J (1.25 um), H (1.65 um) and K-s (2.17 um). The Survey will ultimately produce an Image Atlas containing nearly two million 512 x 1024 pixel images (1 arcsec/pix) in the three colors, a highly complete and reliable catalog containing approx. 300 million point sources having SNR greater than 10 photometry at J less or = 15.8, H less or = 15.1 and K-s less or = 14.3 mag. and an astrometric accuracy greater than 0.511 RMS, and a catalog of 1-2 million resolved sources, primarily galaxies, having SNR greater than 10 photometric accuracy at J less than or = 15.5, H less than or = 14.8 and K-s less than or = 13.5 mag. The 2MASS Sampler, an introductory set of data, was released to the community in December of 1998 (see http://www.ipac.caltech.edu/2mass/). We review the near IR and optical/IR properties of "conventional" QSOs from UV and optical samples, and estimate the number that will be detected by 2MASS. We also discuss 2MASS's ability to test for for new populations of extremely red AGN that have been missed by UV and Visual surveys, as suggested by from IRAS and radio studies. Results of spectroscopic follow-up of 2MASS-selected new AGN candidates will also be presented.

Cutri, R. M.↗
DOE OSTI2022

Wabash CarbonSAFE. Geologic Analysis of the Potosi Dolomite Reservoir Interval and Potential Confining Units, at the Wabash #1 Well, Vigo Co., Indiana, Subtask 7.2, Technical Report

The Wabash CarbonSAFE project drilled the Wabash #1 stratigraphic test well (ID# 168045) at the Wabash Valley Resources (WVR) IGCC facility in Vigo County, Indiana, to evaluate the feasibility of commercial-scale CO 2 storage near the site. The Mt. Simon Sandstone was the initial target for storage evaluation and was found to have generally poor reservoir qualities in the Wabash #1 well. Focus was then placed on the secondary target, the Potosi Dolomite. For storage and containment evaluation an extensive suite of geophysical logs was collected throughout the borehole, and whole cores were obtained from the Mt. Simon Sandstone, Eau Claire Formation, and Maquoketa Group. The Maquoketa Group is identified as a regionally extensive secondary sealing interval above the Mt. Simon Sandstone and as a primary seal for the Potosi Dolomite storage complex. Due to concerns over potential lost circulation zones in the Potosi Dolomite during drilling, no core samples or Formation Micro Imager (FMI) logs were acquired in the Potosi Dolomite. However, cased hole well testing was performed over a 20 feet (6 m) interval within the Potosi Dolomite during which a fluid swab sample was obtained. Approximately 35 miles of 2D seismic information was acquired in the project area near Wabash #1 to aid in reservoir and caprock characterization. The highly porous and permeable zones in the Potosi Dolomite and lower Oneota Dolomite observed within the Wabash #1 well are, for the purpose of this report, considered the same reservoir package and referred to as the Potosi reservoir interval. This report presents a regional depositional context for the Potosi reservoir interval, the overlying confining zones in the Knox Group, and Maquoketa Group primary seal. This context is developed through detailed information obtained from the Wabash #1 well such as lithologic data collected from cuttings and core, geophysical logging, geomechanical analysis of core samples, and well testing and fluid sampling within the Potosi reservoir interval. Information discussed in this report was compiled as a basis for the development of static and dynamic geologic models of the Potosi Dolomite storage complex. The static and dynamic modeling of CO 2 injection in the Potosi reservoir interval are discussed in a separate report (Dessenberger et al., 2022) under the Wabash CarbonSAFE project.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
NASA NTRS2016

Enabling the Direct Detection of Earth-Sized Exoplanets with the LBTI HOSTS Project: A Progress Report

NASA has funded a project called the Hunt for Observable Signatures of Terrestrial Systems (HOSTS) to survey nearby solar type stars to determine the amount of warm zodiacal dust in their habitable zones. The goal is not only to determine the luminosity distribution function but also to know which individual stars have the least amount of zodiacal dust. It is important to have this information for future missions that directly image exoplanets as this dust is the main source of astrophysical noise for them. The HOSTS project utilizes the Large Binocular Telescope Interferometer (LBTI), which consists of two 8.4-m apertures separated by a 14.4-m baseline on Mt. Graham, Arizona. The LBTI operates in a nulling mode in the mid-infrared spectral window (8-13 micrometers), in which light from the two telescopes is coherently combined with a 180 degree phase shift between them, producing a dark fringe at the location of the target star. In doing so the starlight is greatly reduced, increasing the contrast, analogous to a coronagraph operating at shorter wavelengths. The LBTI is a unique instrument, having only three warm reflections before the starlight reaches cold mirrors, giving it the best photometric sensitivity of any interferometer operating in the mid-infrared. It also has a superb Adaptive Optics (AO) system giving it Strehl ratios greater than 98% at 10 micrometers. In 2014 into early 2015 LBTI was undergoing commissioning. The HOSTS. project team passed its Operational Readiness Review (ORR) in April 2015. The team recently published papers on the target sample, modeling of the nulled disk images, and initial results such as the detection of warm dust around eta Corvi. Recently a paper was published on the data pipeline and on-sky performance. An additional paper is in preparation on Beta Leo. We will discuss the scientific and programmatic context for the LBTI project, and we will report recent progress, new results, and plans for the science verification phase that started in February 2016, and for the survey.

Hunt for Observable Signatures of Terrestrial Syst↗
DOE OSTI2026

Advanced Mooring Lines for Marine Energy Workshop – Summary Report

This report summarizes the outcomes of the virtual Advanced Mooring Lines for Marine Energy Workshop. The workshop convened experts from industry, academia, and national laboratories to identify key challenges associated with the deployment of synthetic mooring lines for marine energy applications. Discussions focused on four technical areas—materials, failure and degradation, testing, and modeling. Despite the significant promise of leveraging synthetic mooring systems for marine energy applications, discussion highlighted broader research and development needed to address the lack of validated long-term performance data, insufficient structural health monitoring frameworks, limited large-scale testing capabilities, and gaps in predictive modeling. Overall, the workshop emphasized the importance of coordinated research and development efforts to advance reliable, durable, and cost-effective synthetic mooring solutions for marine energy applications.

16 TIDAL AND WAVE POWER↗
NASA NTRS1991

CCD photometry of 2060 Chiron, 1991 January

Observations of 2060 Chiron was performed on 7 to 8 Jan. 1991 with the Mt. Palomar 1.52 m telescope in the Gunn-R passband. On-chip field stars were used to perform differential reductions. The repeatability of the 5.9 hour light curve was excellent, both within a night and from night to night. No evidence for short-term secular variations similar to those seen last year by both Luu and Jewitt (1990) and Buratti and Dunbar (1991) is seen in the new light curve. Chiron's rotational light curve appears strikingly similar to that obtained a year earlier by Luu and Jewitt (1990), both in amplitude and shape. Both light curves show strongly correlated changes over a timescale of perhaps 15 minutes. These same features were marginally visible in the 1986 light curve. Such behavior is believed to be evidence that Chiron may be more aspherical than the 4 percent intensity variation might otherwise indicate, and favors a viewing geometry where the subearth latitude is rather low. Chiron was much fainter in 1985, when a partial light curve was obtained by Marcialis. Due to the lower sampling rate of these early data, no conclusions can be made regarding the high-frequency light curve structure back then. All three of these light curves differ significantly from that obtained by Buratti and Dunbar (1991), one week before the observations of Luu and Jewitt. The Chiron field was calibrated using Landolt standards on Ut 15 Mar. 1991. A mean R-magnitude of 15.6 + or - 0.1 was found. Variability of 2060 Chiron was demonstrated over timescales of minutes, hours, and years. An intense campaign was urged to monitor the photometric behavior of Chiron throughout the 1990s.

Buratti, B. J.↗
NASA NTRS1992

Early Archean spherule beds of possible impact origin from Barberton, South Africa: A detailed mineralogical and geochemical study

The Barberton Greenstone belt is a 3.5- to 3.2-Ga-old formation situated in the Swaziland Supergroup near Barberton, northeast Transvaal, South Africa. The belt includes a lower, predominantly volcanic sequence, and an upper sedimentary sequence (e.g., the Fig Tree Group). Within this upper sedimentary sequence, Lowe and Byerly identified a series of different beds of spherules with diameters of around 0.5-2 mm. Lowe and Byerly and Lowe et al. have interpreted these spherules to be condensates of rock vapor produced by large meteorite impacts in the early Archean. We have collected a series of samples from drill cores from the Mt. Morgan and Princeton sections near Barberton, as well as samples taken from underground exposures in the Sheba and Agnes mines. These samples seem much better preserved than the surface samples described by Lowe and Byerly and Lowe et al. Over a scale of just under 30 cm, several well-defined spherule beds are visible, interspaced with shales and/or layers of banded iron formation. Some spherules have clearly been deposited on top of a sedimentary unit because the shale layer shows indentions from the overlying spherules. Although fresher than the surface samples (e.g., spherule bed S-2), there is abundant evidence for extensive alteration, presumably by hydrothermal processes. In some sections of the cores sulfide mineralization is common. For our mineralogical and petrographical studies we have prepared detailed thin sections of all core and underground samples (as well as some surface samples from the S-2 layer for comparison). For geochemical work, layers with thicknesses in the order of 1-5 mm were separated from selected core and underground samples. The chemical analyses are being performed using neutron activation analysis in order to obtain data for about 35 trace elements in each sample. Major elements are being determined by XRF and plasma spectrometry. To clarify the history of the sulfide mineralization, sulfur isotopic compositions are being determined.

Koeberl, Christian↗
NASA NTRS2000

Towards a Comprehensive Dynamic-chemistry Assimilation for Eos-Chem: Plans and Status in NASA's Data Assimilation Office

In order to support the EOS-Chem project, a comprehensive assimilation package for the coupled chemical-dynamical system is being developed by the Data Assimilation Office at NASA GSFC. This involves development of a coupled chemistry/meteorology model and of data assimilation techniques for trace species and meteorology. The model is being developed using the flux-form semi-Lagrangian dynamical core of Lin and Rood, the physical parameterizations from the NCAR Community Climate Model, and atmospheric chemistry modules from the Atmospheric Chemistry and Dynamics branch at NASA GSFC. To date the following results have been obtained: (i) multi-annual simulations with the dynamics-radiation model show the credibility of the package for atmospheric simulations; (ii) initial simulations including a limited number of middle atmospheric trace gases reveal the realistic nature of transport mechanisms, although there is still a need for some improvements. Samples of these results will be shown. A meteorological assimilation system is currently being constructed using the model; this will form the basis for the proposed meteorological/chemical assimilation package. The latter part of the presentation will focus on areas targeted for development in the near and far terms, with the objective of Providing a comprehensive assimilation package for the EOS-Chem science experiment. The first stage will target ozone assimilation. The plans also encompass a reanalysis (ReSTS) for the 1991-1995 period, which includes the Mt. Pinatubo eruption and the time when a large number of UARS observations were available. One of the most challenging aspects of future developments will be to couple theoretical advances in tracer assimilation with the practical considerations of a real environment and eventually a near-real-time assimilation system.

Pawson, Steven↗
DOE OSTI2025

Combining Observations and Models: A Review of the CARDAMOM Framework for Data‐Constrained Terrestrial Ecosystem Modeling

The rapid increase in the volume and variety of terrestrial biosphere observations (i.e., remote sensing data and in situ measurements) offers a unique opportunity to derive ecological insights, refine process‐based models, and improve forecasting for decision support. However, despite their potential, ecological observations have primarily been used to benchmark process‐based models, as many past and current models lack the capability to directly integrate observations and their associated uncertainties for parameterization. In contrast, data assimilation frameworks such as the CARbon DAta MOdel fraMework (CARDAMOM) and its suite of process‐based models, known as the Data Assimilation Linked Ecosystem Carbon Model (DALEC), are specifically designed for model‐data fusion. This review, motivated by a recent CARDAMOM community workshop, examines the development and applications of CARDAMOM, with an emphasis on its role in advancing ecosystem process understanding. CARDAMOM employs a Bayesian approach, using a Markov Chain Monte Carlo algorithm to enable data‐driven calibration of DALEC parameters and initial states (i.e., carbon pool sizes) through observation operators. CARDAMOM's unique ability to retrieve localized model process parameters from diverse datasets—ranging from in situ measurements to global satellite observations—makes it a highly flexible tool for analyzing spatially variable ecosystem responses to environmental change. However, assimilating these data also presents challenges, including data quality issues that propagate into model skill, as well as trade‐offs between model complexity, parameter equifinality, and predictive performance. We discuss potential solutions to these challenges, such as reducing parameter equifinality by incorporating new observations. This review also offers community recommendations for incorporating emerging datasets, integrating machine learning techniques, strengthening collaboration with remote sensing, field, and modeling communities, and expanding CARDAMOM's relevance for localized ecosystem monitoring and decision‐making. CARDAMOM enables a deep, mechanistic understanding of terrestrial ecosystem dynamics that cannot be achieved through empirical analyses of observational datasets or weakly constrained models alone.

Bayesian inference↗