Simultaneous stratospheric measurements of H2O, HDO, and CH4 from balloon-borne and aircraft infrared solar absorption spectra and tunable diode laser laboratory spectra of HDO
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Interest in high resolution spectrometers for the submillimeter wavelength range from 100 micron to 1,000 micron is mostly stimulated by molecular spectroscopy in radioastronomy and atmospheric physics, and by plasma diagnostic experiments. Schottky diodes in waveguide mixer technology and InSb-hot electron bolometers are successfully used in the 0.5 to a few millimeter range whereas tandem Fabry-Perot spectrometers combined with photoconductive detectors (Ge:Sb and Ge:Ga) are used for the 100 micron range. Recent research on heterodyne spectrometers, with Schottky diodes in an open structure mixer and a molecular laser as local oscillators, which can be used over the whole wavelength range is summarized.
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The measurement of wave dynamics in the upper mesosphere using a solid-state laser to excite the resonance fluorescence line of sodium is examined. Two Nd:YAG lasers are employed to produce the sodium resonance line. The method involves mixing the 1064 nm radiation with that from a second Nd:YAG operating at 1319 nm in a nonlinear infrared crystal to directly produce 589 nm radiation by sum frequency generation. The use of the transmitter to measure the sodium layer from the Space Shuttle Platform is proposed. A diagram of the laser transmitter is presented.
Parallel lasers interact in shared space to alter output wavelength. New device consists of two stripe lasers in aluminum gallium arsenide chip. Parallel stripes close enough so light from lower laser coupled into upper laser and vice versa. Lasers operated by low-duty-cycle current pulses. Lasing threshold of each about 100 mA. Currents controlled independently. Useful in optical communications systems employing wavelength-division multiplexing.
The EGRET telescope, one of the instruments to be carried on NASA's Gamma Ray Observatory, is designed to explore the high-energy portion (20-24,000 MeV) of the electromagnetic spectrum. A calibration source of gamma-rays over this wide energy range has been used together with an appropriate set of intensity-monitoring instruments, to conduct a calibration of the EGRET telescope over this energy range for the full telescope aperture. The calibration method and an overview of the results are described.
The characteristics of nonradiative transitions between the 4T2 and 2E excited states of trivalent-chromium-ion-activated ruby (containing 0.04 percent Cr2O3 by weight) and alexandrite (containing 0.4 at. percent chromium ion) laser crystals were studied using the technique described by Gayen et al. (1985). In this technique, a 527-nm pulse excites the 4T2 band of the Cr(3+), and the subsequent population kinetics among excited states is monitored by an IR picosecond probe pulse as a function of pump-probe delay. In ruby, a resolution-limited sharp rise in the excited state population was followed by a long-lifetime decay, leading to an upper limit of 7 ps for the 4T2-state nonradiative lifetime. In alexandrite, a longer rise time was followed by a multicomponent decay. A theoretical model is proposed for explaining the induced absorption and the transition dynamics observed in these crystals.
A solid etalon has been designed and fabricated from a 50-mm diameter wafer of optical-quality lithium niobate. The finished etalon has a free spectral range of 0.325 nm at 588 nm. The parallel faces are coated with silver, and the central 15-mm aperture of the etalon has a finesse of 18.6. The reflective faces double as electrodes, and application of voltage will shift the passband. This feature was used in a servo circuit to stabilize the passband against temperature and tilt-induced drifts to better than three parts in one billion. Operated in the stabilized mode for day-long sessions, this filter alternately samples the wings of a narrow atomic absorption line in the solar spectrum and produces a signal proportional to velocity on the solar disk. The Fourier transform of this signal yields information on acoustic waves in the solar interior.
Most of the cometary radicals are thought to be formed in the coma by photodissociation processes. Successful modeling of the coma requires a detailed knowledge of the products that are formed from the various parent molecules and the energy partitioning among these products. This information has to be obtained as a function of wavelength, because the sun is not a monochromatic source. In this review, the status of the experimental knowledge of some key molecules is discussed, along with the prospects of some new laboratory techniques that can fill in the gaps in the present knowledge.
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Movable probe and tuning wall adjusted to obtain resonance at microwave frequency used to generate plasma in cell at one end of microwave cavity. Electroless discharge without disadvantages of dc-cathode-discharge and RF-induction methods. To achieve precise positioning, coaxial probe extends into microwave cavity through tube.
Heterodyne frequency measurements have been made on selected groups of nitrogen dioxide rovibronic transitions between 1580.8 and 1650.7/cm. The groups are separated by 7 to 10/cm, and the intent is to provide a limited (and interim) calibration table for the region. In addition to a table of measured frequencies in the region, figures of spectra in the vicinity of the measured lines are included to provide a map for identifying the transitions measured.
A method for growing crystals of LiYF4 using an HF pretreatment and purification system is described. In addition, spectrum analyses were performed on eight crystals of type LiNbO3:Mg,Cr,RE, which were grown in order to investigate the use of lithium niobate as a laser host material.
During this reporting period, work proceeded in two directions. The first was the development of crystal growth procedures for rare earth doped LiYF4 crystals. The procedures for growth and pre-growth treatment of starting materials for undoped LiYF4 crystals were established and good optical quality materials were grown. A significant amount of time was spent trying to establish the optimum growth parameters for Yb(3+)-doped crystals. Unfortunately, it has proven difficult to obtain large size boules of high optical quality crystals of LiYF4 with doping concentrations of Yb(3+) of several percent. Because of these problems, this research is to be changed to attempt doping with other trivalent rare earth ions such as Ho, Er, and Tm. The second research area was investigating the potential of LiNbO3:Mg,Cr and LiNbO3:Mg,Cr,Yb as possible laser materials. The results are summarized.
A generalized theory for optical heterodyne spectroscopy with phase modulated laser radiation is used which allows the calculation of signal line shapes for frequency modulation spectroscopy of Lorentzian gas absorption lines. In particular, synthetic spectral line shapes for both single-tone and two-tone modulation of lead-salt diode lasers are presented in which the contributions from both amplitude and frequency modulations are included.
Field and laboratory measurements of species of atmospheric interest made as part of the JPL diode laser spectroscopy program are presented. Stratospheric measurements of NO2, NO, CO2, and H2O made in November 1985 using the BLISS instrument are reported, together with recent laboratory measurements of spectral line parameters of HNO3 and HO2NO2. In addition, a novel diode laser instrument concept for the in situ sensing of Titan's atmosphere is described for the Saturn Orbiter/Titan Probe (SOTP) Cassini Mission.
Three techniques (peak single-pass gain, fluoresence band narrowing, and lifetime shortening) for determining the effects of stimulated emission on the spectra of solid-state vibronic laser materials have been compared. The methods were employed to determine the pump energy density and population inversion at threshold, the stimulated emission cross section, and the gain coefficient for two potential vibronic laser materials. An effective shortening of the fluorescence lifetime is predicted at high excitation levels, with a distinct threshold where stimulated emission processes become important.