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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Cost Competitive Process of Battery Grade Oxides Preparation from Aged LIBs

The increasing demand for lithium-ion batteries (LIBs) is driving development of advanced recycling and refining methods. In this project, new cathode active materials are prepared from recycled lithium battery materials and subsequently electrochemically evaluated in coin cells. In detail, scrap LIBs were mechanically processed into a metal rich black mass, then reductive acid leached into an aqueous metal solution, and finally high-purity metal hydroxide precursor materials were prepared by selective electrochemical flow precipitation. Closed-loop LIB recycling into active electrode materials will enable US manufacturers to break their reliance on foreign sources of critical materials. For example, electroextraction process used here has potential to significantly reduce chemical & water use as well as waste production as compared to traditional metallurgic techniques. To this end, electroextracted materials refined from used batteries were collected and processed to be tested as precursor cathode active material (pCAM). For this project, two samples of high purity recycled NMC hydroxide (~1 kg each) were received from N th Cycle’s Ohio demonstration facility. The NMC compositions of the two materials are similar, and the levels of impurities have been confirmed. Indeed, impurities like copper, boron and sodium are present in quantities that could negatively impact battery performance. However, some studies have demonstrated that the control of the quantity of elements like copper or boron may improve the electrochemistry properties of Lithium-NMC batteries. The principal objective is to determine the electrochemical performance of these 2 NMC hydroxide batches and clearly determine the effect of the impurities on the performance.

25 ENERGY STORAGE↗

Recycling of Post-Consumer Waste Polystyrene Using Commercial Plastic Additives

Photothermal conversion can promote plastic depolymerization (chemical recycling to a monomer) through light-to-heat conversion. The highly localized temperature gradient near the photothermal agent surface allows selective heating with spatial control not observed with bulk pyrolysis. However, identifying and incorporating practical photothermal agents into plastics for end-of-life depolymerization have not been realized. Interestingly, plastics containing carbon black as a pigment present an ideal opportunity for photothermal conversion recycling. Herein, we use visible light to depolymerize polystyrene plastics into styrene monomers by using the dye in commercial black plastics. A model system is evaluated by synthesizing polystyrene–carbon black composites and depolymerizing under white LED light irradiation, producing styrene monomer in up to 60% yield. Excitingly, unmodified postconsumer black polystyrene samples are successfully depolymerized to a styrene monomer without adding catalysts or solvents. Using focused solar irradiation, yields up to 80% are observed in just 5 min. Furthermore, combining multiple types of polystyrene plastics with a small percentage of black polystyrene plastic enables full depolymerization of the mixture. This simple method leverages existing plastic additives to actualize a closed-loop economy of all-colored plastics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fabrication of a Nb-Ti Superconducting Closed-Loop Coil for the Next-Generation 45 GHz ECR Ion Source MARS-D

Electron Cyclotron Resonance Ion Sources (ECRISs) that utilize Nb-Ti superconducting coils for 28 GHz frequencies have been operating effectively for over twenty years. However, transitioning to higher frequencies demands stronger magnetic fields, and the conventional racetrack-and-solenoid ECRIS structures have reached their maximum capability with Nb-Ti. To address this, a Mixed Axial and Radial field System Demonstrator (MARS-D) is being developed at Lawrence Berkeley National Laboratory (LBNL). This system features an innovative Closed-Loop Coil (CLC) design that optimizes the use of the conductor fields, enabling the application of Nb-Ti in the next-generation 45 GHz ECRISs. The fabrication of the hexagonal CLC is particularly challenging due to its complex winding path and shape, the stiffness of the Nb-Ti superconducting wire, and the small bending radius. Here, to address these challenges, a series of unique fixtures and tools, as well as a pre-over-bending method, were developed for winding the CLC. To validate the winding fixtures, tools, procedures, and materials used in the coil assembly, a 4-layer practice CLC was wound, epoxy-impregnated, and then cold-tested using liquid nitrogen. The full-size MARS-D CLC is in the process of winding. This paper presents the structure of the MARS-D CLC, the winding fixtures and tools, the winding procedures, the quality control, the impregnation, the test results, and the potential future improvements.

ECR ion sources↗

Adaptive laboratory evolution and genetic engineering improved terephthalate utilization in Pseudomonas putida KT2440

Poly(ethylene terephthalate) (PET) is one of the most ubiquitous plastics and can be depolymerized through biological and chemo-catalytic routes to its constituent monomers, terephthalic acid (TPA) and ethylene glycol (EG). TPA and EG can be re-synthesized into PET for closed-loop recycling or microbially converted into higher-value products for open-loop recycling. Here, in this study, we expand on our previous efforts engineering and applying Pseudomonas putida KT2440 for PET conversion by employing adaptive laboratory evolution (ALE) to improve TPA catabolism. Three P. putida strains with varying degrees of metabolic engineering for EG catabolism underwent an automation-enabled ALE campaign on TPA, a TPA and EG mixture, and glucose as a control. ALE increased the growth rate on TPA and TPA-EG mixtures by 4.1- and 3.5-fold, respectively, in approximately 350 generations. Evolved isolates were collected at the midpoints and endpoints of 39 independent ALE experiments, and growth rates were increased by 0.15 and 0.20 h -1 on TPA and a TPA-EG, respectively, in the best performing isolates. Whole-genome re-sequencing identified multiple converged mutations, including loss-of-function mutations to global regulators gacS, gacA, and turA along with large duplication and intergenic deletion events that impacted the heterologously-expressed tphAB II catabolic genes. Reverse engineering of these targets confirmed causality, and a strain with all three regulators deleted and second copies of tphAB II and tpaK displayed improved TPA utilization compared to the base strain. Taken together, an iterative strain engineering process involving heterologous pathway engineering, ALE, whole genome sequencing, and genome editing identified five genetic interventions that improve P. putida growth on TPA, aimed at developing enhanced whole-cell biocatalysts for PET upcycling.

36 MATERIALS SCIENCE↗

Closed-loop Dynamics of In-core Thermionic Reactor Systems

Using a point model of an in-core thermionic converter, alternative schemes for providing closed loop reactor control were investigated. It was found that schemes based on variable gain power regulation buffers which use the reactor current as the control variable provide complete protection from thermionic burnout and also provide a virtually constant voltage to the user. A side benefit is that the emitter temperature transients are small-even for a complete electric load drop the emitter temperature transient is less than 100 deg K. The current regulation scheme was selected for further study with a distributed parameter model which was developed to account for variations in thermionic and heat transfer properties along the length of a cylindrical converter. It was found that even though the emitter temperature distribution is about 200 deg K along the converter length, the dynamic properties are unchanged when using the current control scheme.

Sawyer, C. D.↗

An improved general algorithm for arbitrary pole assignment.

A new pole-placement algorithm for multi-input controllable systems is presented. The algorithm can be used to obtain real-valued feedback gains for arbitrarily specified real and complex, distinct or multiple eigenvalues. The multi-input controllable time-invariant system is converted to a single-input system. Pole assignment is achieved by making use of certain properties of the equation TF - AT = D, where A is the open-loop system matrix and F represents a matrix having the desired closed-loop eigenvalues.

Willner, L.↗

Effects of display format on pilot describing function and remnant

As part of a program to develop a comprehensive theory of manual control displays, six display formats were used by three instrument-rated pilots to regulate against random disturbances with a controlled element under both foveal and 10 deg parafoveal viewing conditions. The six display formats were: CRT line, CRT thermometer bar, 14-bar quantized on a CRT, a rotary dial and pointer, and two variations of a moving scale tape-drive. All were scaled to equivalent movement and apparent brightness. Measures included overall performance, describing functions, error remnant power spectra, critical instability scores, and subjective display ratings. The results show that the main effect of display format is on the loop closure properties. Less desirable displays induce lower bandwidth closures with consequent effects on the closed-loop remnant and performance.

Jex, H. R.↗

Floating-point system quantization errors in digital control systems

The results are reported of research into the effects on system operation of signal quantization in a digital control system. The investigation considered digital controllers (filters) operating in floating-point arithmetic in either open-loop or closed-loop systems. An error analysis technique is developed, and is implemented by a digital computer program that is based on a digital simulation of the system. As an output the program gives the programing form required for minimum system quantization errors (either maximum of rms errors), and the maximum and rms errors that appear in the system output for a given bit configuration. The program can be integrated into existing digital simulations of a system.

Phillips, C. L.↗

Hardware realization of sampled-data controllers

This paper examines the hardware implementation process for digital controllers (filters), beginning with the desired z-domain transfer function of the digital compensator and ending in the selection of a hardware realization scheme. The final hardware realization is shown to be affected by quantization noise, dynamic range considerations, limit cycles, coefficient roundoff, and filter structure. A design example is included to illustrate the implementation process for a digital rate filter for vehicle control of the space shuttle. This paper develops open-loop techniques which may be extended to the closed-loop case.

Nagle, H. T., Jr.↗

Development and demonstration of a flutter-suppression system using active controls

The application of active control technology to suppress flutter was demonstrated successfully in the transonic dynamics tunnel with a delta-wing model. The model was a simplified version of a proposed supersonic transport wing design. An active flutter suppression method based on an aerodynamic energy criterion was verified by using three different control laws. The first two control laws utilized both leading-edge and trailing-edge active control surfaces, whereas the third control law required only a single trailing-edge active control surface. At a Mach number of 0.9 the experimental results demonstrated increases in the flutter dynamic pressure from 12.5 percent to 30 percent with active controls. Analytical methods were developed to predict both open-loop and closed-loop stability, and the results agreed reasonably well with the experimental results.

Sandford, M. C.↗

Floating-point system quantization errors in digital control systems

This paper considers digital controllers (filters) operating in floating-point arithmetic in either open-loop or closed-loop systems. A quantization error analysis technique is developed, and is implemented by a digital computer program that is based on a digital simulation of the system. The program can be integrated into existing digital simulations of a system.

Phillips, C. L.↗

Functional structure and dynamics of the human nervous system

The status of an effort to define the directions needed to take in extending pilot models is reported. These models are needed to perform closed-loop (man-in-the-loop) feedback flight control system designs and to develop cockpit display requirements. The approach taken is to develop a hypothetical working model of the human nervous system by reviewing the current literature in neurology and psychology and to develop a computer model of this hypothetical working model.

Lawrence, J. A.↗

Self-tuning regulators for multicyclic control of helicopter vibration

A class of algorithms for the multicyclic control of helicopter vibration and loads is derived and discussed. This class is characterized by a linear, quasi-static, frequency-domain model of the helicopter response to control; identification of the helicopter model by least-squared-error or Kalman filter methods; and a minimum variance or quadratic performance function controller. Previous research on such controllers is reviewed. The derivations and discussions cover the helicopter model; the identification problem, including both off-line and on-line (recursive) algorithms; the control problem, including both open-loop and closed-loop feedback; and the various regulator configurations possible within this class. Conclusions from analysis and numerical simulations of the regulators provide guidance in the design and selection of algorithms for further development, including wind tunnel and flight tests.

Johnson, W.↗

Analytical verification of undesirable properties of direct model reference adaptive control algorithms

The present investigation is concerned with a new method, called 'final approach analysis', which has been developed to analyze the dynamic properties of a class of direct adaptive control algorithms. Particular attention is given to the robustness of these algorithms to a number of aspects. These aspects are related to the generation of high frequencies in the plant control signal, to excessive bandwidth of the adaptive control loop resulting in excitation of unmodeled dynamics, and, consequently, leading to dynamic instability of the closed-loop adaptive system, and, thirdly, to noise corrupted measurements. The final approach analysis is useful because it can be used in a constructive way to adjust the adaptive gains so as to limit the closed-loop system bandwidth and to ameliorate some of the undesirable characteristics of existing adaptive algorithms.

Rohrs, C. E.↗

Simulation studies of alternate longitudinal control systems for the space shuttle orbiter in the landing regime

Simulations of the space shuttle orbiter in the landing task were conducted by the NASA Ames-Dryden Flight Research Facility using the Ames Research Center vertical motion simulator (VMS) and the total in-flight simulator (TIFS) variable-stability aircraft. Several new control systems designed to improve the orbiter longitudinal response characteristics were investigated. These systems improved the flightpath response by increasing the amount of pitch-rate overshoot. Reduction in the overall time delay was also investigated. During these evaluations, different preferences were noted for the baseline or the new systems depending on the pilot background. The trained astronauts were quite proficient with the baseline system and found the new systems to be less desirable than the baseline. On the other hand, the pilots without extensive flight training with the orbiter had a strong preference for the new systems. This paper presents the results of the VMS and TIFS simulations. A hypothesis is presented regarding the control strategies of the two pilot groups and how this influenced their control systems preferences. Interpretations of these control strategies are made in terms of open-loop aircraft response characteristics as well as pilot-vehicle closed-loop characteristics.

Powers, B. G.↗

Closed-loop, pilot/vehicle analysis of the approach and landing task

In the case of approach and landing, it is universally accepted that the pilot uses more than one vehicle response, or output, to close his control loops. Therefore, to model this task, a multi-loop analysis technique is required. The analysis problem has been in obtaining reasonable analytic estimates of the describing functions representing the pilot's loop compensation. Once these pilot describing functions are obtained, appropriate performance and workload metrics must then be developed for the landing task. The optimal control approach provides a powerful technique for obtaining the necessary describing functions, once the appropriate task objective is defined in terms of a quadratic objective function. An approach is presented through the use of a simple, reasonable objective function and model-based metrics to evaluate loop performance and pilot workload. The results of an analysis of the LAHOS (Landing and Approach of Higher Order Systems) study performed by R.E. Smith is also presented.

Anderson, M. R.↗

Integrated aeroservoelastic tailoring of lifting surfaces

An approach to the integration of two design activities, structural design and active control design, for a highly idealized aeroservoelastic system is presented. The particular design goal for this study is the maximization of the stable airspeed envelope of an idealized model of an aeroservoelastic system through rational and systematic variation of structural and control design parameters. The steady-state linear quadratic regulator is used to model the control subsystem; the structural subsystem is assigned characteristic design parameters, such as shear center position. The application of the procedure described here produces optimally controlled structures with stability characteristics superior to those of open-loop and initial closed-loop designs.

Zeiler, T. A.↗