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At least 361 records · Page 20

High temperature thermal energy storage in moving sand

Several high-temperature (to 500 C) heat-storage systems using sand as the storage medium are described. The advantages of sand as a storage medium include low cost for sand, widespread availability, non-toxicity, non-degradation characteristics, easy containment, and safety. The systems considered include: stationary sand with closely spaced tubes throughout the volume, the use of a fluidized bed, use of conveyor belt transporter, and the use of a blower rapid transport system. For a stationary sand bed, very close spacing of heat transfer tubes throughout the volume is required, manifesting as high power related system cost. The suggestion of moving sand past or around pipes is intended to reduce the power related costs at the penalty of added system complexity. Preliminary system cost estimates are offered. These rough calculations indicate that mobile sand heat storage systems cost less than the stationary sand approach.

Turner, R. H.↗

Thermal fatigue and oxidation data for directionally solidified MAR-M 246 turbine blades

Thermal fatigue and oxidation data were obtained for 11 plasma spray coated and 13 uncoated directionally solidified and single crystal MAR-M 246 blades. Blade coatings on the airfoil included several metal-oxide thermal barrier layers based on Al2O3, Cr2O3, or ZrO2. The 24 turbine blades were tested simultaneously for 3000 cycles in fluidized beds maintained at 950 and 25 C using a symmetrical 360 set thermal cycle. In 3000 cycles, only uncoated turbine blades exhibited cracking on the trailing edge near the platform; 3 of the 13 uncoated blades did not crack. Cracking occurred over the range 400 to 2750 cycles, with single crystal blades indicating the poorest thermal fatigue resistance. Oxidation of the uncoated blades was limited in 3000 cycles. All coatings indicated microscopically visible spalling at the trailing edge radius after 3000 cycles. Severe general spalling on the airfoil was observed for two multilayered coatings.

Hill, V. L.↗

Cogeneration Technology Alternatives Study (CTAS). Volume 1: Summary report

Large savings can be made in industry by cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed-cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum-based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules for determining performance and cost in individual plants and on a national level. It was found that: (1) atmospheric and pressurized fluidized bed steam turbine systems were the most attractive of the direct coal-fired systems; and (2) open-cycle gas turbines with heat recovery steam generators and combined-cycles with NO(x) emission reduction and moderately increased firing temperatures were the most attractive of the coal-derived liquid-fired systems.

Gerlaugh, H. E.↗

Thermal fatigue and oxidation data of oxide dispersion-strengthened alloys

Thermal fatigue and oxidation data were obtained 24 specimens representing 9 discrete oxide dispersion-strengthened alloy compositions or fabricating techniques. Double edge wedge specimens, both bare metal and coated for each systems, were cycled between fluidized beds maintained at 1130 C with a three minute immersion in each bed. The systems included alloys identified as 262 in hardness of HRC 38; 264 in hardness of HRC 38, 40 and 43; 265 HRC 39, 266 of HRC 37 and 40; 754; and 956. Specimens in the bare condition of 265 HRC 39 and 266 HRC 37 survived 6000 cycles without cracking on the small radius of the double edge wedge specimen. A coated specimen of 262 HRC 38, 266 HRC 37 and 266 HRC40 also survived 6000 cycles without cracking. A duplicate coated specimen of 262 HRC 38 alloy survived 5250 cycles before cracks appeared. All the alloys showed little weight change compared compared to alloys tested in prior programs.

Hofer, K. E.↗

Improved PFB operations: 400-hour turbine test results

A pressurized fluidized bed (PFB) coal-burning reactor was used to provide hot effluent gases for operation of a small gas turbine. Preliminary tests determined the optimum operating conditions that would result in minimum bed particle carryover in the combustion gases. Solids were removed from the gases before they could be transported into the test turbine by use of a modified two stage cyclone separator. Design changes and refined operation procedures resulted in a significant decrease in particle carryover, from 2800 to 93 ppm (1.5 to 0.05 grains/std cu ft), with minimal drop in gas temperature and pressure. The achievement of stable burn conditions and low solids loadings made possible a 400 hr test of small superalloy rotor, 15 cm (6 in.) in diameter, operating in the effluent. Blades removed and examined metallographically after 200 hr exhibited accelerated oxidation over most of the blade surface, with subsurface alumina penetration to 20 micron m. After 400 hours, average erosion loss was about 25 micron m (1 mil). Sulfide particles, indicating hot corrosion, were present in depletion zones, and their presence corresponded in general to the areas of adherent solids deposit. Sulfidation appears to be a materials problem equal in importance to erosion.

Rollbuhler, R. J.↗

Preliminary comparative assessment of land use for the Satellite Power System (SPS) and alternative electric energy technologies

A preliminary comparative assessment of land use for the satellite power system (SPS), other solar technologies, and alternative electric energy technologies was conducted. The alternative technologies are coal gasification/combined-cycle, coal fluidized-bed combustion (FBC), light water reactor (LWR), liquid metal fast breeder reactor (LMFBR), terrestrial photovoltaics (TPV), solar thermal electric (STE), and ocean thermal energy conversion (OTEC). The major issues of a land use assessment are the quantity, purpose, duration, location, and costs of the required land use. The phased methodology described treats the first four issues, but not the costs. Several past efforts are comparative or single technology assessment are reviewed briefly. The current state of knowledge about land use is described for each technology. Conclusions are drawn regarding deficiencies in the data on comparative land use and needs for further research.

Newsom, D. E.↗

The erosion/corrosion of small superalloy turbine rotors operating in the effluent of a PFB coal combustor

The operation of a turbine in the effluent of a pressurized fluidized bed (PFB) coal combustor presents serious materials problems. Synergistic erosion/corrosion and deposition/corrosion interactions may favor the growth of erosion-resistant oxides on blade surfaces, but brittle cracking of these oxides may be an important source of damage along heavy particle paths. Integrally cast alloy 713LC and IN792 + Hf superalloy turbine rotors in a single-stage turbine with 6% partial admittance have been operated in the effluent of a PFB coal combustor for up to 164 hr. The rotor erosion pattern exhibits heavy particle separation with severe erosion at the leading edge, pressure side center, and suction side trailing edge at the tip. The erosion distribution pattern gives a spectrum of erosion/oxidation/deposition as a function of blade position. The data suggest that preferential degradation paths may exist even under the targeted lower loadings (less than 20 ppm).

Zellars, G. R.↗

Improved PFB operations - 400-hour turbine test results

The paper deals with a 400-hr small turbine test in the effluent of a pressurized fluidized bed (PFB) at an average temperature of 770 C, an average relative gas velocity of 300 m/sec, and average solid loadings of 200 ppm. Consideration is given to combustion parameters and operating procedure as well as to the turbine system and turbine test operating procedures. Emphasis is placed on erosion/corrosion results.

Rollbuhler, R. J.↗

Coal gasifier cogeneration powerplant project

Industrial cogeneration and utility pr systems were analyzed and a conceptual design study was conducted to evaluate the economic feasibility of a coal gasifier power plant for NASA Lewis Research Center. Site location, plant size, and electric power demand were considered in criteria developed for screening and selecting candidates that could use a wide variety of coals, including that from Ohio. A fluidized bed gasifier concept was chosen as the baseline design and key components of the powerplant were technically assessed. No barriers to environmental acceptability are foreseen. If funded, the powerplant will not only meet the needs of the research center, but will reduce the commercial risk for utilities and industries by fully verifying and demonstrating the technology, thus accelerating commercialization.

Shure, L. I.↗

Chemistry of peroxide compounds

The history of Soviet research from 1866 to 1967 on peroxide compounds is reviewed. This research dealt mainly with peroxide kinetics, reactivity and characteristics, peroxide production processes, and more recently with superoxides and ozonides and emphasis on the higher oxides of group 1 and 2 elements. Solid state fluidized bed synthesis and production of high purity products based on the relative solubilities of the initial, intermediate, and final compounds and elements in liquid ammonia are discussed.

Volnov, I. I.↗

Synergistic erosion/corrosion of superalloys in PFB coal combustor effluent

Two Ni-based superalloys were exposed to the high velocity effluent of a pressurized fluidized bed coal combustor. Targets were 15 cm diameter rotors operating at 40,000 rpm and small flat plate specimens. Above an erosion rate threshold, the targets were eroded to bare metal. The presence of accelerated oxidation at lower erosion rates suggests erosion/corrosion synergism. Various mechanisms which may contribute to the observed oxide growth enhancement include erosive removal of protective oxide layers, oxide and subsurface cracking, and chemical interaction with sulfur in the gas and deposits through damaged surface layers.

Benford, S. M.↗

Thermal fatigue performance of integrally cast automotive turbine wheels

Fluidized bed thermal fatigue testing was conducted on 16 integrally cast automotive turbine wheels for 1000-10,000 (600 sec total) thermal cycles at 935/50 C. The 16 wheels consisted of 14 IN-792 + 1% Hf and 2 gatorized AF2-1DA wheels; 6 of the IN-792 + Hf wheels contained crack arrest pockets inside the blade root flange. Temperature transients during the thermal cycling were measured in three calibration tests using either 18 or 30 thermocouples per wheel. Thermal cracking based on crack length versus accumulated cycles was greatest for unpocketed wheels developing cracks in 8-13 cycles compared to 75-250 cycles for unpocketed wheels. However, pocketed wheels survived up to 10,000 cycles with crack lengths less than 20 mm, whereas two unpocketed wheels developed 45 mm long cracks in 1000-2000 cycles.

Humphreys, V. E.↗

Synergistic erosion/corrosion of superalloys in PFB coal combustor effluent

Two Ni-based superalloys were exposed to the high velocity effluent of a pressurized fluidized bed coal combustor (PFBC). Targets were 15-cm diameter rotors operating at 40,000 rpm and small flat plate specimens. Above an erosion rate threshold (approximately 10 microns/hr), the targets were eroded to bare metal. The presence of accelerated oxidation at lower erosion rates suggests erosion/corrosion synergism. Various mechanisms which may contribute to the observed oxide growth enhancement include erosive removal of protective oxide layers, oxide and subsurface cracking, and chemical interaction with sulfur in the gas and deposits through damaged surface layers.

Benford, S. M.↗

Elastic-plastic finite-element analyses of thermally cycled single-edge wedge specimens

Elastic-plastic stress-strain analyses were performed for single-edge wedge alloys subjected to thermal cycling in fluidized beds. Three cases (NASA TAZ-8A alloy under one cycling condition and 316 stainless steel alloy under two cycling conditions) were analyzed by using the MARC nonlinear, finite-element computer program. Elastic solutions from MARC showed good agreement with previously reported solutions that used the NASTRAN and ISO3DQ computer programs. The NASA TAZ-8A case exhibited no plastic strains, and the elastic and elastic-plastic analyses gave identical results. Elastic-plastic analyses of the 316 stainless steel alloy showed plastic strain reversal with a shift of the mean stresses in the compressive direction. The maximum equivalent total strain ranges for these cases were 13 to 22 percent greater than that calculated from elastic analyses.

Kaufman, A.↗

Elastic-plastic finite-element analyses of thermally cycled double-edge wedge specimens

Elastic-plastic stress-strain analyses were performed for double-edge wedge specimens subjected to thermal cycling in fluidized beds at 316 and 1088 C. Four cases involving different nickel-base alloys (IN 100, Mar M-200, NASA TAZ-8A, and Rene 80) were analyzed by using the MARC nonlinear, finite element computer program. Elastic solutions from MARC showed good agreement with previously reported solutions obtained by using the NASTRAN and ISO3DQ computer programs. Equivalent total strain ranges at the critical locations calculated by elastic analyses agreed within 3 percent with those calculated from elastic-plastic analyses. The elastic analyses always resulted in compressive mean stresses at the critical locations. However, elastic-plastic analyses showed tensile mean stresses for two of the four alloys and an increase in the compressive mean stress for the highest plastic strain case.

Kaufman, A.↗

Low NO sub x heavy fuel combustor concept program. Phase 1A: Combustion technology generation coal gas fuels

Combustion tests of two scaled burners using actual coal gas from a 25 ton/day fluidized bed coal gasifier are described. The two combustor configurations studied were a ceramic lined, staged rich/lean burner and an integral, all metal multiannual swirl burner (MASB). The tests were conducted over a range of temperature and pressures representative of current industrial combustion turbine inlet conditions. Tests on the rich lean burner were conducted at three levels of product gas heating values: 104, 197 and 254 btu/scf. Corresponding levels of NOx emissions were 5, 20 and 70 ppmv. Nitrogen was added to the fuel in the form of ammonia, and conversion efficiencies of fuel nitrogen to NOx were on the order of 4 percent to 12 percent, which is somewhat lower than the 14 percent to 18 percent conversion efficiency when src-2 liquid fuel was used. The MASB was tested only on medium btu gas (220 to 270 btu/scf), and produced approximately 80 ppmv NOx at rated engine conditions. Both burners operated similarly on actual coal gas and erbs fuel, and all heating values tested can be successfully burned in current machines.

Sherlock, T. P.↗

Effect of shear stress on cell cultures and other reactor problems

Anchorage dependent cell cultures in fluidized beds are tested. Feasibility calculations indicate the allowed parameters and estimate the shear stresses therein. In addition, the diffusion equation with first order reaction is solved for the spherical shell (double bubble) reactor with various constraints.

Schleier, H.↗