Adhesion between automatically pure metallic surfaces, part 4 Semiannual report
Contact resistance measurements to determine adhesion between atomically pure metallic surfaces
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Contact resistance measurements to determine adhesion between atomically pure metallic surfaces
Terminal characteristics of composite superconductor, taking into account heat transfer to coolant, interface thermal contact resistance and superconductor size
Static metallic adhesion model for sliding friction, using contact resistance measurements
Metals and systems for semiconductor devices metallization, evaluating conductivity, adhesion, contact resistance, deposition ease, electrochemical corrosion, reliability and stability
A theoretical analysis of the principles of interfacial thermal conductance between two heated metal surfaces in mutual contact is presented. It was determined that when heat flows from one metal to the other, the flow lines converge toward the actual contact points since the thermal conductivities of the metals are much greater than any intervening medium such as air or fluids. The converging lines cause contact resistance, which is usually high compared to the resistances offered to heat flow by metals. The resultant variation in resistance can produce unreliable equipment for aerospace and industrial applications unless the conductance can be determined accurately.
The primary objective of this research program was to determine the effects of surface cleaning and deliberate gaseous contamination on the adhesion behavior of selected candidate materials for use in the NERVA nuclear rocket engine program. Using a torsion balance technique, the relationship between the normal compressive load applied to crossed rod samples and the resultant contact resistance was used to ascertain the extent of adhesion under each set of experimental conditions. In addition to an evaluation of the static adhesion behavior of selected materials combinations, the experimental apparatus was modified to permit a similar investigation relating to the effects of specific tangential displacements of the sample wires, i.e., their sliding friction behavior. During the course of this subcontract, the materials combinations 440 C vs. 440 C. pyrographite vs ZTA graphite, Nbc (graphite) vs. Nbc (graphite), and Electrolize Inconel 718 vs. Au electroplated 302 S/S were evaluated.
Construction details, error analysis, and typical data for a rapid comparative device for thermal conductivity measurements are presented. The apparatus consists of a comparative cut-bar arrangement contained in a bell-jar. The cylinder shaped specimen is placed between two ARMCO-iron meter bars of the same diameter. The upper bar is equipped with a heater, while the lower one is terminated in a heat sink. The temperature gradient along the bars is measured with a series of copper/constantan microthermocouples, spot welded to them. The assembly is held together by loading the bars to a desired pressure, via a pneumatic cylinder. Contact resistance at the boundaries between the specimen and the meter bars is minimized by using a Hg/In/Ga alloy film at the interface and sufficient loading force. The gradients determined for the meter bars then may be extrapolated to the boundaries yielding the temperature drop along the specimen. Using two different length specimens, the magnitude of the temperature drop across the interface can be computed, or the true gradient along the specimen can be obtained from the difference in overall temperature drops and lengths.
An experimental investigation was conducted to determine the effective conductivities of four plasma-arc-sprayed, metal-ceramic gradated coatings on hydrogen-oxygen thrust chambers. The effective thermal conductivities were not a function of pressure or oxidant-to-fuel ratio. The various materials that made up these composites do not seem to affect the thermal conductivity values as much as the differences in the thermal conductivities of the parent materials would lead one to expect. Contact resistance evolving from the spraying process seems to be the controlling factor. The thermal conductivities of all the composites tested fell in the range of 0.75 to 7.5 watts per meter kelvin.
Thermophysical properties of plasma sprayed materials were determined for the following plasma sprayed materials: CaO - stabilized ZrO2, Y2O3 - stabilized ZerO2, Al2O3, HfO2 Mo, nichrome, NiAl, Mo-ZrO2, and MoAl2O3 mixtures. In all cases the thermal conductivity of the as-sprayed materials was found to be considerably lower than that of the bulk material. The flash-laser thermal diffusivity technique was used both for diffusivity determination of single-layer materials and to determine the thermal contact resistance at the interface of two-layer specimens.
This paper presents a theoretical thermal conductivity model for the uppermost layer of lunar surface material under the lunar vacuum environment. The model assumes that the lunar soil can be simulated by spherical particles in contact with each other and that the effective thermal conductivity is a function of depth, temperature, porosity, particle dimension, and mechanical-thermal properties of the solid particles. Two modes of heat transport are considered, conduction and radiation - with emphasis on the contact resistance between particles. The model gives effective conductivity values that compare favorably with the experimental data from lunar surface samples obtained on Apollo 11 and 12 missions.
An experimental investigation of the structural integrity and effective thermal conductivity of three metallic-ceramic composite coatings was conducted. These coatings were plasma sprayed onto the combustion side of water-cooled, 12.7-centimeter throat diameter, hydrogen-oxygen rocket thrust chambers operating at 2.07 to 4.14 meganewtons per square meter chamber pressure. The metallic-ceramic composites functioned for six to 17 cycles and for as long as 213 seconds of rocket operations and could have probably provided their insulating properties for many additional cycles. The effective thermal conductivity of all the coatings was in the range of 0.7472 to 4.483 w/(m)(K), which makes the coatings a very effective thermal barrier. Photomicrographic studies of cross-sectioned coolant tubes seem to indicate that the effective thermal conductivity of the coatings is controlled by contact resistance between the particles, as a result of the spraying process, and not the thermal conductivity of the bulk materials.
A thermal model is analyzed that takes into account phase changes in the nutrient material. The behavior of fluids in low gravity environments is discussed along with low gravity heat transfer. Thermal contact resistance in the Skylab food heater is analyzed. The original model is modified to include: equivalent conductance due to radiation, radial equivalent conductance, wall equivalent conductance, and equivalent heat capacity. A constant wall-temperature model is presented.
Review of the results of a program aimed at obtaining a better understanding of the long-term performance of a thermoelectric generator using silicon germanium. The results obtained concern the contact resistivity of the thermoelectric couples, the electrical resistance of the multifoil thermal insulation, and the application of resistance coatings to the unicouples in order to prevent the loss of output power due to internal shunting paths.
Microscopic aspects of interfacial reactions are discussed, such as interdiffusion, formation of intermetallic phases, generation and annihilation of lattice defects, effect of temperature, grain size, etc., which normally occur in diffusion bonding processes. Relationships between properties and microstructure in thin film couples are examined utilizing a unique combination of contact resistance measurements and characterization by transmission electron microscopy.
An idealized two-dimensional example of rapid interface flow extension is described. Initially undisturbed dissimilar isotropic, homogeneous, linearly elastic half-spaces are perfectly bonded along the interface y=0. Quantities associated with the half-space or = to 0 are denoted by the prime superscript or the subscripts 3 or 4 while those in y or = to 0 carry the subscripts 1 or 2. At time t=0 adjacent material points at x=0, y= + or - 0 are forced apart horizontally with a constant relative velocity delta v. This results in a zone of bond failure which extends symmetrically along the interface at a constant rate c. The newly created flaw surfaces are in sliding contact resisted by Coulomb friction. The friction coefficient is gamma.
Several techniques are investigated for making short conical tips on wires (whiskers) used for contacting millimeter-wave Schottky diodes. One procedure, using a phosphoric and chromic acid etching solution (PCE), is found to give good results on 12 microns phosphor-bronze wires. Full cone angles of 60 degrees-80 degrees are consistently obtained, compared with the 15 degrees-20 degrees angles obtained with the widely used sodium hydroxide etch. Methods are also described for cleaning, increasing the tip diameter (i.e. blunting), gold plating, and testing the contact resistance of the whiskers. The effects of the whisker tip shape on the electrical resistance, inductance, and capacitance of the whiskers are studied, and examples given for typical sets of parameters.
Seal allows electrical wires to pass directly from sensors inside of liquid nitrogen storage vessel to outside instruments. No splices or connectors are required, so errors created by contact resistance are avoided. With method, measurements with highly sensitive instrumentation are made with greater accuracy.
A heat exchanger of increased effectiveness is disclosed. A porous metal matrix is disposed in a metal chamber or between walls through which a heat-transfer fluid is directed. The porous metal matrix has internal bonds and is bonded to the chamber in order to remove all thermal contact resistance within the composite structure. Utilization of the invention in a rocket chamber is disclosed as a specific use. Also disclosed is a method of constructing the heat exchanger.