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At least 37 records · Page 2

The Third SeaWiFS HPLC Analysis Round-Robin Experiment (SeaHARRE-3)

Seven international laboratories specializing in the determination of marine pigment concentrations using high performance liquid chromatography (HPLC) were intercompared using in situ samples and a mixed pigment sample. The field samples were collected primarily from oligotrophic waters, although mesotrophic and eutrophic waters were also sampled to create a dynamic range in chlorophyll concentration spanning approximately two orders of magnitude (0.020 1.366 mg m^{-3}) The intercomparisons were used to establish the following: a) the uncertainties in quantitating individual pigments and higher-order variables (sums, ratios, and indices); b) the reduction in uncertainties as a result of applying quality assurance (QA) procedures; c) the importance of establishing a properly defined referencing system in the computation of uncertainties; d) the analytical benefits of performance metrics, and e) the utility of a laboratory mix in understanding method performance. In addition, the remote sensing requirements for the in situ determination of total chlorophyll a were investigated to determine whether or not the average uncertainty for this measurement is being satisfied.

Hooker, Stanford B.↗

California CO 2 Storage Assurance Facility Enterprise (C2SAFE): Final Technical Report

The California CO 2 Storage Assurance Facility Enterprise (C2SAFE) project conducted a preliminary study into the feasibility of a commercial-scale carbon dioxide (CO 2 ) storage complex located in California’s Southern San Joaquin Valley (SSJV). The work represents the first phase of a multi-phased development approach outlined by the United States Department of Energy’s (DOE’s) Carbon Storage Assurance and Facility Enterprise (CarbonSAFE) program meant to develop carbon storage sites capable of permanently storing 50 million metric tonnes of CO 2 , or greater, injected over a typical facility life of 20 to 30 years. This report represents the culmination of work performed under C2SAFE and outlines a phased implementation plan for large-scale, industrial carbon capture and permanent storage in California’s SSJV. The report is meant to be a standalone document and as such provides high-level summaries of all tasks of the project, but is also meant to complement the other three topical reports issued by the project – reports referenced herein. The study considered multiple scenarios including an east-side storage facility, a west-side storage facility, and potential multi-site storage facilities. The east-side storage facility is to be located at Clean Energy Systems, Inc.’s Kimberlina Power Plant, or nearby, and the west-side facility will be located at the California Resources Corporation’s (CRC’s) Elk Hills oil field. The majority of carbon emissions are planned to be captured from existing sources and transported to the selected and verified storage site(s). Capture from the single closest source to the eastern storage facility and the sources within the Elk Hills field would meet the CarbonSAFE storage goal of 50 million tonnes. The study has shown there is sufficient storage capacity to meet this requirement and more; thus, capture from any of the numerous additional large nearby sources would substantially leverage the CarbonSAFE investment. A comparison of preliminary CO 2 capture, transportation, and storage costs to economic value and incentives in the state shows current market conditions make it economically feasible to develop large-scale industrial storage sites in California’s SSJV. The business case for Carbon Capture and Storage (CCS) in California’s SSJV appears economically viable today for large CO 2 point sources involved in the production of transportation fuels, such as oilfield cogeneration units and steam boilers. The overall levelized CCS cost is estimated at roughly 125 per tonne of CO 2 , which includes CO 2 amine-solvent post-combustion capture, transportation, and storage. The levelized CO 2 capture cost is based on today’s technology, with no future cost reduction factored in for technology improvement. The sum of the value of incentives and revenue from California Low Carbon Fuel Standard (LCFS) credits (discounted roughly 20% from their current transaction value), sale of California cap-and-trade emission allowances, and Section 45Q tax credits—either for saline storage or the Enhanced Oil Recovery (EOR) credit plus CO 2 sales revenue—is about 165/tonne-CO 2 . The economic viability of CCS for Natural Gas Combined Cycle (NGCC) power plants in the SSJV is more site-specific. A plant providing power solely to the electric grid, if it added CCS, should be eligible for Section 45Q tax credits and could sell its excess cap-and-trade emission allowances, but it would not generate LCFS credits. Using the cost and incentive values detailed in this report, it would not be economical for such a plant to add CCS today, barring other considerations. An NGCC plant within an oilfield (e.g., CRC Elk Hills and NRG Sunrise) that provides power to the oilfield as well as to the grid should receive “partial credit” in terms of generating LCFS credits if it added CCS (pro-rated for the fraction of power going to the oilfield). Such a plant should also be eligible for Section 45Q tax credits and garner revenue from selling its excess cap-and-trade emission allowances. Using the cost and incentive values described in this report, the economic viability of adding CCS today would depend on the relative fractions of electricity supplied to the oilfield and the grid. As the value of cap-and-trade emission allowances grows over time (either by market forces or the escalating floor price), the relative fraction of power needing to remain in the oilfield to achieve “breakeven” would diminish. At some point, even plants providing all their power to the grid would be candidates for economical CCS application. The C2SAFE team has proposed to expand upon the knowledge gained during this study by conducting a detailed feasibility assessment under a follow-on phase of the program, Phase II – Feasibility. This would include detailed data collection at the two sites, analysis, reporting, stakeholder outreach, and risk mitigation activities to support the development of a commercial carbon storage complex in the SSJV.

58 GEOSCIENCES↗

A Shuttle Upper Atmosphere Mass Spectrometer /SUMS/ experiment

A magnetic mass spectrometer is currently being adapted to the Space Shuttle Orbiter to provide repeated high altitude atmosphere data to support in situ rarefied flow aerodynamics research, i.e., in the high velocity, low density flight regime. The experiment, called Shuttle Upper Atmosphere Mass Spectrometer (SUMS), is the first attempt to design mass spectrometer equipment for flight vehicle aerodynamic data extraction. The SUMS experiment will provide total freestream atmospheric quantitites, principally total mass density, above altitudes at which conventional pressure measurements are valid. Experiment concepts, the expected flight profile, tradeoffs in the design of the total system and flight data reduction plans are discussed. Development plans are based upon a SUMS first flight after the Orbiter initial development flights.

Blanchard, R. C.↗

Managing Power Systems-Induced Wildfire Risks Using Optimal Scheduled Shutoffs

The increasing demands for electricity and the increase in extreme weather conditions are putting unprecedented pressure on our electric grids. Often, this pressure leads to electrical component failures, which might ignite wildfires. This work develops a novel model to balance the reliability of power network operations and the risk of wildfire ignition by opti- mizing the operational schedule of power transmission networks considering time-varying risk measures that include exogenous and operational factors. Energy storage systems are considered to deliver power during peak wildfire hours and enable temporal load shifting. The problem is formulated as a mixed-integer linear program that maximizes a weighted sum of the served power demand and the reduction in grid-induced wildfire risk. The results demonstrate the ability of the model to significantly reduce wildfire risk without considerable load shedding.

power systems operations↗

Truncated nonlinear interferometer-based atomic force microscopes

A truncated non-linear interferometer-based atomic force microscope (AFM) includes an input port and a non-linear amplifier that renders a probe beam and a conjugate beam. The AFM includes local oscillators having a relationship with the probe beam and the conjugate beam. The displacement of the AFM's cantilever is transduced by the probe beam, and/or the conjugate beam or their respective local oscillators. The AFM's phase-sensitive detectors detect a phase modulation between the respective local oscillators and the probe beam and the conjugate beam. The detected phase modulation corresponds to the change in phase. The AFM's circuitry measures phase signals that are indicative of the cantilever displacement. The resulting measurement signals exhibit a quantum noise reduction in either the intensity difference or phase sum quadrature.

Pooser, Raphael C.↗

Managing Power Systems-Induced Wildfire Risks Using Optimal Scheduled Shutoffs: Preprint

The growing demands for electricity and the increase in extreme weather conditions are putting unprecedented pressure on our electrical grids. Oftentimes, this pressure leads to electrical components failures which might ignite wildfires. This work develops a novel model to balance the reliability of power networks operations and risks of wildfires ignition by optimizing the operational schedule of power transmission networks considering time-varying risk measures that consider exogenous and operational factors. Energy storage systems are considered to deliver power during peak wildfire hours and enable temporal load shifting. The problem is formulated as a mixed-integer linear program that maximizes a weighted sum of the served power demand and the reduction in grid-induced wildfires risk. The results demonstrate the ability of the model to reduce wildfires risks significantly without considerable load shedding.

energy scheduling↗

Lateral bearing capacity of hybrid monopile-friction wheel foundation for offshore wind turbines by centrifuge modelling

The hybrid monopile-friction wheel foundation is an innovative alternative for offshore wind turbines. The concept has wider adaptability and can be used as reinforcement method for existing monopiles. A series of centrifuge tests was performed to investigate the lateral bearing capacities of the hybrid foundation under monotonic loads. Five foundation models and two soil types were considered. According to the recorded responses, the hybrid foundation demonstrated better lateral behaviors that both lateral bearing capacity and stiffness are enhanced. Two analytical methods were proposed and compared with the centrifuge test results. The bearing capacity of the hybrid foundation is smaller than the sum of individual pile and friction wheel, and a reduction factor is suggested for both friction wheels. The friction wheel restrains rotations of monopile and provides extra restoring moments; their effects are idealized as equivalent moments acting on the pile head. The analytical results provide possible solutions in estimating the lateral bearing capacity of the innovative hybrid foundation system for offshore wind turbines by using traditional theories.

17 WIND ENERGY↗

Effect of Functional and Electron Correlation on the Structure and Spectroscopy of the Al 2 O 3 (001)–H 2 O Interface

Oxide–water interfaces are ubiquitous, with many applications in industry and the environment, yet there is a great deal of controversy over their properties and microscopic structure. This controversy stems, in part, from the unique H-bond networks formed at different surface terminations and mineral compositions. Density functional theory simulations of these interfaces require an accurate description of both the oxide mineral and water in diverse H-bond environments. Thus, herein we simulate the Al 2 O 3 (001)–H 2 O interface using the PBE, PBE-TS, RPBE, SCAN, and HSE06-TS functionals to determine how calculated interfacial properties depend on the choice of functional. We find that the structure of the first few layers of water at the surface is determined by electron correlation in a way that cannot be approximated using semiemipirical van der Waals corrections. Of the functionals investigated, we find that SCAN yields the most accurate interfacial structure, dynamics, and sum frequency generation spectrum. Furthermore, SCAN leads to a reduction in the order of the 2D H-bond network of water at the alumina surface predicted by GGA functionals, leading to a significant decrease in the anisotropy of the diffusion coefficient at the surface. We emphasize the importance of using a functional which accurately describes electron correlation for more complex oxides, such as transition-metal oxides, where electron correlation may play an even greater role in determining the structure and dynamics of the oxide–water interface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Model-size reduction for the buckling and vibration analyses of anisotropic panels

A computational procedure is presented for reducing the size of the model used in the buckling and vibration analyses of symmetric anisotropic panels to that of the corresponding orthotropic model. The key elements of the procedure are the application of an operator splitting technique through the decomposition of the material stiffness matrix of the panel into the sum of orthotropic and nonorthotropic (anisotropic) parts and the use of a reduction method through successive application of the finite element method and the classical Rayleigh-Ritz technique. The effectiveness of the procedure is demonstrated by numerical examples.

Noor, A. K.↗

Chain Length Dependence of Energies of Electron and Triplet Polarons in Oligofluorenes

Bimolecular equilibria measured the one-electron reduction potentials and triplet free energies (ΔG° T ) of oligo(9,9-dihexyl)fluorenes and a polymer with lengths of n = 1–10 and 57 repeat units. We can accurately measure one-electron potentials electrochemically only for the shorter oligomers. Starting at n = 1 the free energies change rapidly with increasing length and become constant for lengths longer than the delocalization length. Both the reduction potentials and triplet energies can be understood as the sum of a free energy for a fixed polaron and a positional entropy. Furthermore, the positional entropy increases gradually with length beyond the delocalization length due to the possible occupation sites of the charge or the triplet exciton. Our results reinforce the view that charges and triplet excitons in conjugated chains exist as polarons and find that positional entropy can replace a popular empirical model of the energetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis of heating load diversity in German residential districts and implications for the application in district heating systems

In recent years, the application of district heating systems for the heat supply of residential districts has been increasing in Germany. Central supply systems can be very efficient due to diverse energy demand profiles which may lead to reduced installed equipment capacity. Load diversity in buildings has been investigated in former studies, especially for the electricity demand. However, little is known about the influence of single building characteristics (such as building envelope or hot water demand) on the overall heating peak load of a residential district. For measuring the diversity, the peak load ratio (PLR) index is used to represent the percentage reduction of peak load of a district system from a simple sum of individual peak loads of buildings. A total of 144 residential building load profiles have been created with the dynamic building simulation software IDA ICE for a theoretical analysis in which the PLR reaches 15%. Within this study, certain district features are identified which lead to higher diversity. Furthermore, these results are used in a district heating simulation model which confronts the possible advantage of reduced installed capacity with the practical disadvantage of heat distribution losses. Likewise, the influence of load density and the districts building structure can be analyzed. This study shows that especially in districts with high load density, which consist of newly constructed buildings with low supply temperature and high influence of the hot water demand, the advantages of load diversity can be exploited.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Quantifying the effects of multiple land management practices, land cover change, and wildfire on the California landscape carbon budget with an empirical model

The effectiveness of land-based climate mitigation strategies is generally estimated on a case-by-case basis without considering interactions with other strategies or influencing factors. Here we evaluate a new, comprehensive approach that incorporates interactions among multiple management strategies, land use/cover change, wildfire, and climate, although the potential effects of climate change are not evaluated in this study. The California natural and working lands carbon and greenhouse gas model (CALAND) indicates that summing individual practice estimates of greenhouse gas impacts may underestimate emission reduction benefits in comparison with an integrated estimate. Annual per-area estimates of the potential impact of specific management practices on landscape emissions can vary based on the estimation period, which can be problematic for extrapolating such estimates over space and time. Furthermore, the actual area of implementation is a primary factor in determining potential impacts of management on landscape emissions. Nonetheless, less intensive forest management, avoided conversion to urban land, and urban forest expansion generally create the largest annual per-area reductions, while meadow restoration and forest fuel reduction and harvest practices generally create the largest increases with respect to no management. CALAND also shows that data uncertainty is too high to determine whether California land is a source or a sink of carbon emissions, but that estimating effects of management with respect to a baseline provides valid results. Important sources of this uncertainty are initial carbon density, net ecosystem carbon accumulation rates, and land use/cover change data. The appropriate choice of baseline is critical for generating valid results.

54 ENVIRONMENTAL SCIENCES↗

Noise reduction for model counterrotation propeller at cruise by reducing aft-propeller diameter

The forward propeller of a model counterrotation propeller was tested with its original aft propeller and with a reduced diameter aft propeller. Noise reductions with the reduced diameter aft propeller were measured at simulated cruise conditions. Reductions were as large as 7.5 dB for the aft-propeller passing tone and 15 dB in the harmonics at specific angles. The interaction tones, mostly the first, were reduced probably because the reduced-diameter aft-propeller blades no longer interacted with the forward propeller tip vortex. The total noise (sum of primary and interaction noise) at each harmonic was significantly reduced. The chief noise reduction at each harmonic came from reduced aft-propeller-alone noise, with the interaction tones contributing little to the totals at cruise. Total cruise noise reductions were as much as 3 dB at given angles for the blade passing tone and 10 dB for some of the harmonics. These reductions would measurably improve the fuselage interior noise levels and represent a definite cruise noise benefit from using a reduced diameter aft propeller.

Dittmar, James H.↗

Infrared Spectra of Perdeuterated Naphthalene, Phenanthrene, Chrysene, and Pyrene

Calculations are carried out using density functional theory (DFT) to determine the harmonic frequencies and intensities of perdeuterated naphthalene, phenanthrene, pyrene, and chrysene. We also report matrix- isolation spectra for these four species. The theoretical and experimental frequencies and relative intensities for the perdeuterated species are in generally good agreement. The effect of perdeuteration is to reduce the sum of the integrated intensities by a factor of about 1.75. This reduction occurs for all vibrational motions, except for the weak low frequency ring deformation modes. There is also a significant redistribution of the relative intensities between the out-of-plane C-D bands relative to those found for the out-of-plane C-H bands. The theoretical isotopic ratios provide an excellent diagnostic of the degree of C-H(C-D) involvement in the vibrational bands, allowing in most cases a clear distinction of the type of motion.

Bauschlicher, Charles W., Jr.↗

An investigation of Newton-Sketch and subsampled Newton methods

Sketching, a dimensionality reduction technique, has received much attention in the statistics community. In this paper, we study sketching in the context of Newton's method for solving finite-sum optimization problems in which the number of variables and data points are both large. In this work, we study two forms of sketching that perform dimensionality reduction in data space: Hessian subsampling and randomized Hadamard transformations. Each has its own advantages, and their relative tradeoffs have not been investigated in the optimization literature. Additionally, our study focuses on practical versions of the two methods in which the resulting linear systems of equations are solved approximately, at every iteration, using an iterative solver. The advantages of using the conjugate gradient method vs. a stochastic gradient iteration are revealed through a set of numerical experiments, and a complexity analysis of the Hessian subsampling method is presented.

97 MATHEMATICS AND COMPUTING↗

Fluoroethylene Carbonate Induces Ordered Electrolyte Interface on Silicon and Sapphire Surfaces as Revealed by Sum Frequency Generation Vibrational Spectroscopy and X-ray Reflectivity

Here, the cyclability of silicon anodes in lithium ion batteries (LIBs) is affected by the reduction of the electrolyte on the anode surface to produce a coating layer termed the solid electrolyte interphase (SEI). One of the key steps for a major improvement of LIBs is unraveling the SEI’s structure-related diffusion properties as charge and discharge rates of LIBs are diffusion-limited. To this end, we have combined two surface sensitive techniques, sum frequency generation (SFG) vibrational spectroscopy, and X-ray reflectivity (XRR), to explore the first monolayer and to probe the first several layers of electrolyte, respectively, for solutions consisting of 1 M lithium perchlorate (LiClO 4 ) salt dissolved in ethylene carbonate (EC) or fluoroethylene carbonate (FEC) and their mixtures (EC/FEC 7:3 and 1:1 wt %) on silicon and sapphire surfaces. Our results suggest that the addition of FEC to EC solution causes the first monolayer to rearrange itself more perpendicular to the anode surface, while subsequent layers are less affected and tend to maintain their, on average, surface-parallel arrangements. This fundamental understanding of the near-surface orientation of the electrolyte molecules can aid operational strategies for designing high-performance LIBs.

36 MATERIALS SCIENCE↗

Scaling, elasticity, and CLPT

The first few viewgraphs describe the general solution properties of linear elasticity theory which are given by the following two statements: (1) for stress B.C. on S(sub sigma) and zero displacement B.C. on S(sub u) the altered displacements u(sub i)(*) and the actual stresses tau(sub ij) are elastically dependent on Poisson's ratio nu alone: thus the actual displacements are given by u(sub i) = mu(exp -1)u(sub i)(*); and (2) for zero stress B.C. on S(sub sigma) and displacement B.C. on S(sub u) the actual displacements u(sub i) and the altered stresses tau(sub ij)(*) are elastically dependent on Poisson's ratio nu alone: thus the actual stresses are given by tau(sub ij) = E tau(sub ij)(*). The remaining viewgraphs describe the minimum parameter formulation of the general classical laminate theory plate problem as follows: The general CLT plate problem is expressed as a 3 x 3 system of differential equations in the displacements u, v, and w. The eighteen (six each) A(sub ij), B(sub ij), and D(sub ij) system coefficients are ply-weighted sums of the transformed reduced stiffnesses (bar-Q(sub ij))(sub k); the (bar-Q(sub ij))(sub k) in turn depend on six reduced stiffnesses (Q(sub ij))(sub k) and the material and geometry properties of the k(sup th) layer. This paper develops a method for redefining the system coefficients, the displacement components (u,v,w), and the position components (x,y) such that a minimum parameter formulation is possible. The pivotal steps in this method are (1) the reduction of (bar-Q(sub ij))(sub k) dependencies to just two constants Q(*) = (Q(12) + 2Q(66))/(Q(11)Q(22))(exp 1/2) and F(*) - (Q(22)/Q(11))(exp 1/2) in terms of ply-independent reference values Q(sub ij); (2) the reduction of the remaining portions of the A, B, and D coefficients to nondimensional ply-weighted sums (with 0 to 1 ranges) that are independent of Q(*) and F(*); and (3) the introduction of simple coordinate stretchings for u, v, w and x,y such that the process is neatly completed.

Brunelle, Eugene J.↗