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NASA NTRS1986

Melt segregation in plagioclase-poikilitic mesosiderites

The Budalan and Mincy mesosiderites contain a poikilitic-plagioclase matrix with orthopyroxene chadacrysts and interstitial-subophitic inverted pigeonite. Orthopyroxene chadacrysts in both mesosiderites are uniformly more aluminous than orthopyroxene clasts, suggesting that they were not derived from clasts by metamorphism. Interstitial inverted pigeonite is more ferroan than adjacent orthopyroxene in the matrix, consistent with the crystallization of a melt with the sequence orthopyroxene followed by pigeonite. The magnesium chadcrysts in Mincy could not have formed from a melt in equilibrium with the clasts but could have crystallized from impact melt. The most Mg chadacrysts are enclosed in large reversely zoned plagioclase crystals as a result of the undercooling in melt-lacking plagioclase clasts and associated nuclei. Mincy contains both plagioclase-poor and plagioclase-rich regions, explained by a separation of silicate melt into pools. Reckling Peak A80258, a plagioclase-poikilitic mesosiderite with a very high chadacryst/plagioclase ratio, resembles Mincy material from which melt has been extracted. It is suggested that the origin of the plagioclase-poikilitic mesosiderites is impact melting of a metal-silicate mixture.

Hewins, R. H.↗

NASA NTRS1987

Diverse eucritic pebbles in the Vaca Muerta mesosiderite

Seven 5-cm basaltic pebbles from the Vaca Muerta mesosiderite were studied by neutron activation and electron microprobe analysis, and three additional pebbles were studied petrographically. The cumulate pebbles had low REE concentrations and high Eu/Sm ratios, indicating the absence of intercumulus liquid. Siderophile interelement ratios were similar to those found in Vaca Muerta metal except for anomalously low Ir concentrations. The presence of 20 percent impact-melt breccias among the pebbles and 35-40 percent melt breccias among the mesosiderite whole-rocks suggests that the mesosiderites were more extensively impact melted than the howardites. Three alternative models to explain this greater proportion of impact-melted material among the mesosiderites are proposed.

Rubin, Alan E.↗

NASA NTRS1994

More shock recovery experiments on mesosiderite analogs

Mesosiderites, a small but unique group of stony-iron meteorites with affinities to howardites, eucrites, and pallasites, remain enigmatic in terms of their petrogenesis. They are composed of approximately equal weight proportions of Fe-Ni metal plus troilite and gabbroic, basaltic, and orthopyroxenitic materials. The metal and silicates, which display variable grain sizes and shapes, are delicately intermingled, forming irregular grain boundaries that have been attributed to a wide range of origins from subsolidus metamorphism to supersolidus igneous processes. Perhaps the most relevant question regarding the petrogenesis of mesosiderites is: what is the source and duration of heating that could produce the unequilibrated textures and chemistry of these meteorites? A leading candidate appears to be impacts of metallic core fragments with a differentiated asteroidal surface. This provides not only a suitable source of heat, but also the metal component uniquely required by mesosiderites. A series of shock recovery experiments on mesosiderite analogs has been continued. Textural and chemical similarities have been found that support an impact-derived origin for these unusual meteorites.

Rowan, L. R.↗

NASA NTRS2002

A "Mesosiderite" Rock from Northern Siberia, Russia: Not a Meteorite

A possible mesosiderite meteorite was found in the area of the Putorana Plateau, Noril'sk district, Siberia, Russia. Although this rock resembles a mesosiderite in its hand-sample aspect and in having Ni-bearing iron metal, it is not a meteorite. This inference is based on the lack of a fusion crust, the lack of cosmogenic nuclides, oxygen with terrestrial isotope ratios, and several mineral chemical criteria. Most likely, the rock is from the iron-metal-bearing basalts of the Siberian Trap basalt sequence, which are mined for their base and platinum-group metals. Mesosiderite imposters like this may be recognized by: (1) the presence of Cu metal in hand sample or as microscopic blebs in the low-Ni metal (kamacite), (2) the absence of high-Ni metal (taenite), and (3) the presence of iron carbide (cohenite) enclosing the kamacite. Even if these macroscopic tests are inconclusive, isotopic and mineral chemical tests will also distinguish rocks like this from mesosiderites.

Treiman, Allan H.↗

NASA NTRS2014

Howardites and Mesosiderites: Contrasting Polymict Breccias from Two Similar Differentiated Asteroids

Silicates in mesosiderites commonly show anomalous characteristics compared to howardites. These characteristics indicate that many of the mesosiderite lithologies were formed during and/or after metal silicate mixing. Petrologic evidence indicates that impact gardening occurred on the mesosiderite asteroid after metal-silicate mixing. Thus the anomalous materials ought to be widely distributed on that asteroid. The compositions of howardites suggest a well-mixed regolith on Vesta. The lack of distinctive mesosiderite-like materials in howardites favors separate parents for the two meteorite groups.

Mittlefehldt, D. W.↗

NASA NTRS2017

Clast Selection and Metallographic Cooling Rates: Initial Results on Type 1A and 2A Mesosiderites

We initiated a comprehensive study on selected clasts and metal of mesosiderites using SEM, electron microprobe and the complete suite of noble gases. Here we report initial results on the petrography of selected clasts and metallographic cooling rates using the central Ni method used in sev-eral publications. We focus on the approach of selecting grains in least recrystallized mesosiderites. Hence, especially (lithic) clasts in type 1A, 1B, 2A and 2B are the first choice. They provide highest primitive-ness and least annealing/metamorphism. All grains selected should be in close proximity to each other. Lithic clasts in mesosiderites are of high interest be-cause of their igneous texture and similarity to eucrites and howardite petrography. We find pyrox-enes (px) and plagioclase (plag) attached to each other which implies a common formation history. It will be interesting to see differences and similarities in their noble gas inventory (CRE ages, trapped components and closure temperature). In addition, we will investi-gate variations of the lithic clasts toward similar grains in the thick sections which are not igneous. Plag grains are the best bases for noble gas measurements con-cerning He to Ar and Ar-Ar dating since it delivers im-portant target elements. We focus on plag grains in close contact to olivine (olv) / px grains to assess weth-er both grains show noble gas patterns being similar or different. Phosphate grains are suitable for Kr and Xe measurements since they yield REE abundances (tar-get elements).

Mesosiderites↗

NASA NTRS1980

Olivines and olivine coronas in mesosiderites

The paper presents a study of olivines and their surrounding coronas in mesosiderites texturally and compositionally using optical and microprobe methods. Olivine composition ranges from Fo(58-92) and shows no consistent pattern of distribution within and between mesosiderites; olivine occurs as large single crystals or as partially recrystallized mineral clasts, except for two lithic clasts. These are Emery and Vaca Muerta, and both are shock-modified olivine orthopyroxenites. Fine-grained coronas surround olivine, except for those in impact-melt group mesosiderites and those without tridymite in their matrices. Coronas consist largely of orthopyroxene, plagioclase, clinopyroxene, chromite, merillite, and ilmenite, and are similar to the matrix, but lack metal and tridymite. Texturally the innermost parts of the corona can be divided into three stages of development: (1) radiating acicular, (2) intermediate, and (3) granular.

Nehru, C. E.↗

NASA NTRS1981

Orthopyroxene-olivine assemblages in diogenites and mesosiderites

Diogenites contain equilibrated orthopyroxene-olivine assemblages. Mn is very regularly partitioned between olivine and orthopyroxene in pallasites, diogenites and synthetic eucrite melts, with an FeO/MnO partition ratio for olivine versus orthopyroxene of 1.6 by weight over a very wide range of FeO contents. In contrast to diogenites, Fe and Mn are not regularly partitioned between the olivine and orthopyroxene of mesosiderites and these minerals were not in equilibrium. Mesosiderite olivine differs from diogenite olivine in Fe/Mn and Ca/Mn ratios. Lack of olivine-orthopyroxene equilibrium suggests that olivine in mesosiderites was derived not from a pyroxenite component analogous to diogenites but from dunites.

Hewins, R. H.↗

NASA NTRS1982

Metamorphic reactions in mesosiderites - Origin of abundant phosphate and silica

In light of a study of the Emery mesosiderite, it is determined that the high modal abundances of merrillite and tridymite in most mesosiderites are attributable to redox reactions between silicates and P-bearing Fe-Ni metal within a limited T-fO2 range at low pressure. The recalculated amounts of dissolved P and S in the metallic portion of Emery reduce the metal liquidus temperature to less than 1350 C, and the solidus to less than 800 C, so that the mixing of liquid metal with cold silicates would have resulted in silicate metamorphism rather than melting. This redox reaction and redistribution of components between metal and silicates illuminates the complexities of mesosiderite processing, with a view to the recalculation of their original components.

Harlow, G. E.↗

NASA NTRS1983

Impact versus internal origins for mesosiderites

The textures, mineral compositions, and thermal history of mesosiderites are examined to see whether they are compatible with any kind of impact process or internal process which might produce stony-iron breccias. It was proposed that cratering by metal projectiles is not an adequate origin mechanism since it would not deposit enough metal in the stony-iron breccias. It was also proposed that such mechanisms as accretion of differentiated planitesimals must be considered for mesosiderite origins. But no single model for origins is fully satisfactory. Disruption and reassembly of two colliding bodies could form stony-iron breccias at depth, but, as with the previous models, the easiest way to explain the low olivine of mesosiderites is to postulate derivation from olivine-poor chondritic material. Turbulent metal-crust mixing during core formation and crustal blocks sinking into the core withhold olivine from the breccia but do not explain how the silicate and metal liquids in subgroup IV could have failed to segregate.

Hewins, R. H.↗

NASA NTRS1985

Formation of mesosiderites by low-velocity impacts as a natural consequence of planet formation

It is argued here that, during the period of planet formation, mesosiderites originated by the low-velocity collisions of large metallic core fragments with the surface of a differentiated asteroid-size body. Relative velocities of the asteroids native to this region were low because it was distant from massive protoplanets. However, a few differentiated asteroids were destroyed by high-velocity collisions with interlopers perturbed by protoplanets into high eccentric orbits. These collisions reduced mantles and crusts to small silicate fragments, but left cores in the form of large, durable metal fragments. Mesosiderite-like pyroxenite-basalt-metal mixtures were formed when large core fragments accreted at low velocities to the regolith of an intact asteroid. Most of the olivine in mesosiderite and howardite breccias are attributed here to the mantles of the disrupted parent bodies. The low olivine contents indicate that the amount of debris accreted from disrupted asteroids was small relative to the volumes of the regoliths.

Wasson, J. T.↗

NASA NTRS1992

Classification of mafic clasts from mesosiderites - Implications for endogenous igneous processes

Results are presented from an analysis of 13 igneous pebbles from the Vaca Muerta, EET87500, and Bondoc mesosiderites, using electron microprobe and instrumental neutron activation techniques. These data, combined with literature data on compositions of 43 mesosiderite clasts were used to compile a classification scheme for the various types of mafic silicate clasts that occur in mesosiderites. These clasts were classified into five principal groups: (1) polygenic and monogenic cumulates (30 percent); (2) polygenic basalts (30 percent); (3) quench-textured rocks, comprising two compositional subgroups (those which resemble basaltic eucrites (5 percent), and those which resemble cumulate eucrites (2 percent)); (4) monogenic basalts (11 percent); and (5) ultramafic rocks, consisting mainly of large crystals of orthopyroxene (9 percent) or olivine (4 percent). The conditions under which these clasts were formed are discussed.

Rubin, Alan E.↗

NASA NTRS1993

Evolutionary history of the mesosiderite asteroid - A chronologic and petrologic synthesis

The evolutionary history of the mesosiderite parent body is composed of six principal epochs. (1) Accretion occurred about 4.56 Ga ago, and (2) initial melting occurred less than about 26 Ma after accretion. (3) Significant crustal remelting occurred more than 4.47 Ga ago, possibly during metal-silicate mixing caused by the accretion of a large metallic Fe-Ni core fragment with some overlying mantle to the MPB regolith. (4) Localized impact melting 4.5-3.9 Ga ago produced quench-textured clasts and caused mesosiderite metamorphism and the extensive melting of type-4 mesosiderites. (5) Collisional disruption and gravitational reassembly occurred about 3.9 Ga ago, causing extensive degassing of Ar and resetting the metallographic cooling rates to about 1 C/Ma. (6) Impact excavitation and ejection of deeply buried breccias occurred much less than 3.9 Ga.

Rubin, Alan E.↗

NASA NTRS2021

Mesosiderite Silicates vs. HED Polymict Breccias

The silicate portions of mesosiderites are broadly like howardites [1], and this has led to persistent interpretations that mesosiderites and howardites are derived from the same parent asteroid [2]. Yet, when examined carefully, one finds that there are substantial petrological and compositional differences between these polymict breccias. These differences indicate that separate parent asteroids are more probable [3, 4]. I will document the distinctions between these groups based on my data and literature information [5] and discuss their origins.

mesosiderite↗

NASA NTRS1978

Cooling rate based on schreibersite growth for the Emery mesosiderite

Computer simulation of diffusion-controlled growth of the large Ni-rich grains of schreibersite found in the Emery mesosiderite indicates that exsolution from kamacite occurred during cooling at the rate of 0.1 C/Myr. This finding agrees with the mesosiderite cooling rate determined by Powell (1969) from taenite-kamacite data. The cooling rate is the lowest found for any meteorite group, and implications for the cooling history, with a possibility of reheating, are considered. The procedure for computing a family of cooling rate curves is based on Randich's (1975) method.

Kulpecz, A. A., Jr.↗

NASA NTRS1979

Petrographic and chemical characterization of igneous lithic clasts from mesosiderites and howardites and comparison with eucrites and diogenites

Petrographic, electron microprobe, and instrumental neutron activation analysis (INAA) studies of igneous lithic clasts separated from mesosiderites and howardites and INAA investigation of whole rock eucrites and diogenites are presented. The trace element abundances in basaltic lithic clasts indicate more complex differentiation episodes than in eucrites which include sequential melting and expulsion of liquid from the source region and remelting of cumulate materials. Pyroxenites from mesosiderites show slight enrichments in Sc and Mn than diogenites suggesting that these pyroxenites are not fragments of diogenites. It is concluded that the heat source characteristics are spatially and temporally variable, suggesting that heating of the differentiated meteorite parent bodies may have partly come from outside the parent body.

Mittlefehldt, D. W.↗

NASA NTRS1981

Thermal history of mesosiderites revisited

The results of a fission track study of uranium-rich merrillite crystals in a number of mesosiderites are clearly incompatible with cooling rates as low as approximately 0.1 C/million years which have previously been inferred for these meteorites. Classical metallographic techniques thus appear to give erroneous results when applied to this type of meteorites. There appears to be no reason to advocate exotic scenarios to explain the thermal history of mesosiderites.

Crozaz, G.↗

NASA NTRS1980

Olivine clasts from mesosiderites and howardites - Clues to the nature of achondritic parent bodies

The compositional ranges of olivine clasts from mesosiderites and most clasts from howardites (FO90-55 and FO89-45 respectively) overlap. Only one clast in howardite Allan Hills A78006,9 (FO16) differs significantly. Differences in FeO/MnO in olivines from the two groups may be explained by different redox states of their source regions. Whether the two meteorite groups were derived from the same parent body is not clear, but the lack of Fe-rich eucritic clasts in mesosiderites together with the lack of tridymite-phosphate rich gabbros and basalts in howardites, suggests that different bodies are required since both meteorite groups are near-surface polymict breccias, which have probably sampled significant portions of their parent body surfaces.

Delaney, J. S.↗