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At least 19 records

Relationships Between HED's, Mesosiderites, and Ungrouped Achondrites: Trace Element Analyses of Mesosiderite RKPA 79015 and Ungrouped Achondrite QUE 93148

Achondritic meteorites are a diverse group of meteorites that formed by igneous activity in asteroids. These meteorites can provide important information about early differentiation processes on asteroidal bodies. The howardite-eucrite-diogenite (HED) meteorites, the largest group of achondrites, are the only group of meteorites for which a potential parent body has been identified (4 Vesta) [e.g., 1]. Mesosiderites are stony-iron meteorites composed of roughly equal amounts of metal and silicates and silicates are broadly similar to HED meteorites [2]. They may have been formed by impact-mixing of crustal and core materials of differentiated meteorite parent bodies. Chemical and oxygen isotopic compositional data suggest that the HED meteorites and silicate portions of mesosiderites originated on the same or closely related parent bodies. Pallasites and IIIAB irons also have similar oxygen isotope compositions and have been thought to be related to the HEDs [3,4]. However, recent high resolution analyses have shown that pallasites and HED's have different oxygen isotopic values, but mesosiderites and HED s have the same isotope compositions implying a close connection [5]. QUE 93148 is a small (1.1g) olivine-rich (mg 86) achondrite that contains variable amounts of orthopyroxenene (mg 87) and kamacite (6.7 wt% Ni), with minor augite [6]. This meteorite was originally classified as a lodranite [7], but it s oxygen isotopic composition precludes a genetic relationship to the acapulcoites and lodranites. And also this meteorite has a lower Mn/Mg ratio than any major group of primitive or evolved achondrites and suggested that QUE 93148 may be a piece of the deep mantle of the HED parent body [6]. To better understand the relationship between HED s, mesosiderites and related achondrites, we have measured trace elements in the individual metallic and silicate phases. In this study, abundances of a suite of elements were measured for the unusual mesosiderite RKPA 79015 and a ungrouped achondrite QUE93148.

Righter, M.↗

Modal studies of mesosiderites and related achondrites, including the new mesosiderite ALHA 77219

The Antarctic meteorite ALHA 77219 is found to be a new mesosiderite. It contains about 25% metal + troilite (+ rust) and the brecciated silicate portion is dominated by orthopyroxene (En 68-71). These features, together with the presence of olivine surrounded by coronas, and abundant tridymite + phosphate conform to the characteristics of mesosiderites. A comparison of the modal abundances of minerals in 77219 with modes of 20 mesosiderites, 14 howardites, six basaltic eucrites, three feldspar cumulate eucrites, and one orthopyroxene cumulate eucrite shows that there are major differences between mesosiderites and howardites. These differences are described in detail.

Prinz, M.↗

Compositions of large metal nodules in mesosiderites - Links to iron meteorite group IIIAB and the origin of mesosiderite subgroups

The compositions of large metal nodules in 12 mesosiderites, ranging from 3 mm to 4 cm in minimum dimensions and from 10 to 200 mg/g in silicate content, were analyzed by neutron activation; also analyzed were two additional samples (Pennyweight Point and Murchison Downs) which were originally designated iron meteorites but were later classified as Mes nodules. It was found that mesosiderites subgroups classified on the basis of metal composition are virtually the same as those based on silicate composition. The general covariation of the silicate and the metal compositional characteristics suggests that these features were established in the same process or in linked processes. A mesosiderite formation model is proposed.

Hassanzadeh, Jamshid↗

Catching Constrains on the Parent Body Genesis of Mesosiderites and a Possible Link to HED (Howardite-Eucrite-Diogenite) Meteorites - A New Hope?

Mesosiderites (MES) are a group of enigmatic stony-iron meteorites exhibiting fragmental matrix breccias and irregular textures; e.g. [1-3]. Mesosiderites contain roughly equal volumes metal (Fe-Ni) and silicates often intimately mixed together (Fig.1). The silicates mostly consist of basaltic, gabbroic, and pyroxenitic components, and appear similar to eucrites and howardites; [4-8]. But unlike HEDs - and other differentiated parent body meteorite groups e.g. ureilites - mesosiderites contain high metal abundances. Several studies have been published to reveal the processes leading to the formation of mesosiderites and attempt to classifiy them [1], [2], [10-15]. Because the silicate inclusions in mesosiderites are often strongly metamorphosed after formation, it is difficult to assess the origin of the silicates and implications for the differentiation process of their parent body [15-17]. Several workers have advanced a formation hypothesis for the mesosiderites where an impact between differentiated bodies occurred prior to 4.47 Ga ago (e.g. [13,18], which could explain the possible incomplete dispersal of the colliding bodies due to their low cosmic ray exposure ages and their special thermal history. However, [13] discuss and favor the model for formation of mesosiderites with the collision of two differentiated bodies, along with disruption events and gravitational re-assembly. The mesosiderites have numerous gabbroid melt clasts with anomalous rare-earth- element (REE) - especially positive Eu - values [19, 20]. HEDs do not show the same. However, the heating mechanisms of both mesosiderites and HED's are puzzling. Mesosiderites are remarkable, they consist of a mix of basalts, which are only found on or near planetary surfaces and undifferentiated metal [1,2]. The probable model is that an asteroid containing a metallic magma impacted onto a second asteroid covered with basalt [18,21]. The mix was then buried under an insulating regolith, and cooled slowly. During cooling and at low temperatures the redox reactions continued to occur and proceed (J.T. Wasson; in pers. comm. 2015).

Eucrite↗

Petrology and pairing of mesosiderites from Victoria Land, Antarctica

Petrological data on mesosiderites from Reckling Peak (RKP) and Allan Hills (ALH), Antarctica, are presented. The results suggest that the Allan Hills mesosiderites A77219, A81059, and A81098 are probably paired (being of similar texture, modes, and mineral composition), and ALHA 81208 is, most likely, a clast from one of these mesosiderites. RKPA 80258 is a weakly poikilitic plagioclase-poor mesosiderite, completely different from ALHA 77219, 81059, and 81098. On the other hand, RKPA 79015, 80229, 80246, and 80263 are very similar, belonging to subgroup C diogenitic mesosiderites. These mesosiderites contain orthopyroxene and recrystallized orthopyroxenite clasts in a metal-troilite matrix. The silicate fraction of mesosiderites ranged from diogenitic (RKPA 79015) to analogous to polymict eurcrite (Dyarrl Island). On the basis of petrologic data, the mesosiderite subdivision scheme was amended, making it possible to classify the formerly 'anomalous' RKPA 79015.

Hewins, Roger H.↗

Metamorphism in mesosiderites

Previous studies of mesosiderites have identified a metamorphic overprint in these meteorites. However, the effects and implications of this overprint have not yet been explored in detail. The present study documents several important textural and chemical features of the mesosiderites. The components of mesosiderites are examined, taking into account orthopyroxenites, olivine in clasts, mesosiderite mafic clasts, and metal. The characteristics of the silicate matrix of the mesosiderites is explored, and textural and chemical evidence of metamorphism is discussed, giving attention to coronas on olivine clasts, overgrowths on Mg-pyroxene clasts, rims on iron rich pyroxene grains, poikiloblasts of plagioclase, and resorption of clasts. Aspects of redox formation of merrillite are considered along with the causes and the implications of metamorphism. It is found that metamorphism has radically changed the texture of the silicate fraction of the mesosiderites.

Delaney, J. S.↗

Shock recovery analogs and the origin of mesosiderites

The origin of mesosiderites, which consist of approximately equal-weight proportions of Fe-Ni metal and silicates (gabbros, basalts, orthopyroxenites, dunites), remains an interesting and complex problem in meteoritics. There is general agreement that multiple impact events were probably involved in the formation of these brecciated stony-iron meteorites, but given the heterogeneity of mesosiderites, additional processes have been invoked to explain the unique and intricate textural and compositional makeup of mesosiderites. We conducted a series of shock recovery experiments to test the impact event(s) scenario. The results indicated significant similarities between the shocked analogs and many mesosiderites. We have compared our analogs with a suite of thin sections of Barea mesosiderite. I have conducted a series of flash heating experiments in which equal-weight proportions of gabbro and stainless steel (SS304) powders were compressed into small charges and heated under reducing conditions for short times. These experiments were used to bracket localized, peak postshock temperatures in our analog shots and to compare the mixing relations between the silicate and metal. The shock recovery experiments used porous metal-silicate powder starting mixtures, therefore our experiments are most analogous to an impact scenario where the target is an asteroidal regolith surface composed of a loose mixture of Fe-Ni metal and heterogeneous silicates. Analog experiments may really describe a secondary impact process similar to the late-stage, localized impact melting event. This leaves one of the crucial questions about mesosiderite genesis unanswered, namely what is the source of the Fe-Ni metal that is so intimately distributed in these meteorites?

Rowan, L. R.↗

Mesosiderites on Vesta: A Hyperspectral VIS-NIR Investigation

The discussion about the mesosiderite origin is an open issue since several years. Mesosiderites are mixtures of silicate mineral fragments or clasts, embedded in a FeNi metal matrix. Silicates are very similar in mineralogy and texture to howardites [1]. This led some scientists to conclude that mesosiderites could come from the same parent parent asteroid of the howardite, eucrite and diogenite (HED) meteorites [2, 3]. Other studies found a number of differences between HEDs and mesosiderite silicates that could be explained only by separate parent asteroids [4]. Recently, high precision oxygen isotope measurements of m esosiderites silicate fraction were found to be isotopically identical to the HEDs, requiring common parent body, i.e. 4 Vesta [5]. Another important element in favor of a common origin was given by the identification of a centimeter-sized mesosiderite clast in a howardite (Dar al Gani 779): a metal-rich inclusion with fragments of olivine, anorthite, and orthopyroxene plus minor amounts of chromite, tridymite, and troilite [6]. The Dawn mission with its instruments, the Infrared Mapping Spectrometer (VIR) [7], the Framing Camera [8] and the Gamma-Ray and Neutron Detector (GRaND) [9] confirmed that Vesta has a composition fully compatible with HED meteorites [10]. We investigate here the possibility to discern mesosiderite rich locations on the surface of Vesta by means of hyperspectral IR images.

Palomba, E.↗

Allan Hills A77219 - The first Antarctic mesosiderite

The abundance of orthopyroxene, inverted pigeonite, plagioclase, tridymite, kamacite, and tetrataenite, plus the whole rock analysis, indicates that ALHA 77219 is a mesosiderite. The presence of inverted pigeonite rims on orthopyroxene clasts plus the range of Fe/Mg and Fe/Mn ratios for pyroxene and olivine are characteristic of mesosiderites. All the petrographic and chemical data are consistent with classification of ALHA 77219 as a mesosiderite and, because the matrix is fine-grained and little recrystallized, as a subgroup I mesosiderite. The Fe/Mn trends in pyroxenes of mesosiderites such as ALHA 77219 can be explained by igneous fractionation of pyroxene along with metal and subsequent subsolidus reduction in the breccia.

Agosto, W. N.↗

Intrinsic oxygen fugacities of diogenites and mesosiderite clasts

Oxygen fugacities of diogenite and mesosiderite clast material were measured with the double ZrO2 cell technique between 800 and 1150 C. The samples were taken from large clasts in the diogenites Johnstown (En73) and Tatahouine (En75), and the mesosiderites Estherville (En81), West Point (Fo88) and Emery (En68). Fugacity values for all except Emery plot near the wuestite-iron buffer curve and are interpreted as indicating similar source regions and environments of crystallization for the two suites. Emery orthopyroxene records a lower fugacity, close to the fayalite-quartz-iron buffer curve, probably as a result of equilibration with the mesosiderite matrix assemblage. The similarity of redox conditions experienced by mesosiderite orthopyroxenite and diogenites is not sufficient to require a single parent body and, if the common achondrites were derived from Vesta, mesosiderites probably came from a different body.

Hewins, R. H.↗

Petrogenesis of mesosiderites. I - Origin of mafic lithologies and comparison with basaltic achondrites

New petrologic and trace element data on basaltic and gabbroic clasts in mesosiderites and basaltic achondrites, combined with existing petrologic and trace element data, have served as a basis for interpretation of the petrogenesis of mesosiderite clasts. Compared with the basaltic achondrites, the mesosiderite basaltic and gabbroic clasts contain more abundant modal tridymite and merrilite, and more commonly contain augite as a late magmatic phase. Their pyroxenes tend to be more MgO-rich, and have lower Fe/Mn ratios which are positively correlated with the Fe/Mg ratio. Some of the mesosiderite basaltic and gabbroic clasts contain xenocrystic plagioclase. The basaltic clasts commonly show superchondritic Eu/Sm ratios and slight LREE depletions. The cumulate gabbro clasts are extremely depleted in LIL, have very high Eu/Sm ratios and high Lu/Sm ratios. All of these features can be explained by a model in which the mafic lithologies of mesosiderites were formed by remelting of a mixed basalt-cumulate gabbro-metal source region near the parent body surface.

Mittlefehldt, David W.↗

Do Mesosiderites Reside on 4 VESTA? an Assessment Based on Dawn Grand Data

Almost a century ago, simple petrographic observations were used to suggest a close genetic link between eucrites and the silicates in mesosiderites [1]. Mesosiderites are composed of roughly equal proportions of silicates that are very similar in mineralogy and texture to howardites, and Fe, Ni metal (Fig. 1) [2]. This similarity has led some to conclude that mesosiderites come from the howardite, eucrite and diogenite (HED) parent asteroid [3, 4]. Subsequent petrologic study demonstrated a number of differences between mesosiderite silicates and HEDs that are more plausibly explained as requiring separate parent asteroids [5]. However, HEDs and mesosiderites are identical in oxygen isotopic composition, and this has been used to argue for a common parent 4 Vesta [6].

Mittlefehldt, D. W.↗

Mesosiderites. I - Compositions of their metallic portions and possible relationship to other metal-rich meteorite groups

The metal from 17 mesosiderites has been analyzed for Ni, Ga, Ge, and Ir by the techniques of atomic-absorption spectrometry and neutron activation. Most mesosiderite metal samples fall in a narrow compositional range: Ni, 7.0-9.0%; Ga, 13-16 ppm; Ge, 47-58 ppm; and Ir, 2.4-4.4 ppm. Most of those falling outside these ranges belong to Powell's (1971) least-metamorphosed type. Mesosiderite metal falls in the same general composition range as IIIAB irons, IIIE irons, pallasites and H-group chondrite metal. There are distinct differences in detail, however, and firm evidence for a close genetic relationship between any of these groups and the mesosiderites is lacking.

Wasson, J. T.↗

Mesosiderites and howardites - Igneous formation and possible genetic relationships

Neutron activation data are presented for major, minor, and trace elements in whole rock howardites and silicates from mesosiderites. Compositions of howardites and mesosiderites are similar and intermediate between those of eucrites and diogenites. It is indicated that mesosiderites have a higher normative silica component than howardites. It appears that this results partly from a higher content of a highly evolved igneous component and partly from in situ reduction of FeO to Fe followed by magnetic separation of metal prior to analysis. It is shown that light rare earth elements are enriched in some mesosiderites.

Mittlefehldt, D. W.↗

Silicate petrography, classification, and origin of the mesosiderites - Review and new observations

A classification of mesosiderites proposed by Powell (1971) is modified and expanded to include impact melts. A petrographic study of all 20 mesosiderites reveals that most contain a complex assemblage of mineral, lithic, and metal clasts. The occurrence of lithic fragments in most mesosiderites and the subsequent metamorphism of the group indicate that they are highly evolved meteorites. A comparison with inferred lunar analogs indicates that the bulk of the mesosiderites can be considered annealed crystalline matrix breccias and may be meteoritic equivalents of granulitic impactites described by Warner et al. (1977).

Floran, R. J.↗

The composition of mesosiderite olivine clasts and implications for the origin of pallasites

The composition of olivine clasts from the mesosiderites Emery, Mincy and Pinnaroo is investigated, and implications of the results for the origin of the pallasites, which, although chemically distinct, may be related to the diogenites, eucrites, howardites and mesosiderites, are discussed. Centimeter-sized olivines were analyzed by electron microprobe, and instrumental neutron activation analysis was performed on one olivine each from Emery and Pinnaroo and an olivine separate from the Brenham pallasite. The olivine compositions are found to range from Fa8 to Fa28, with Emery samples having values from Fa18 to Fa28, and to require essentially total melting of a source composition rich enough in FeO to produce basaltic clasts. It is argued that the mesosiderite olivines were formed in the outer few kilometers of their parent body, as were those of the pallasites, which have the same compositions as the mesosiderite olivines. A model is then developed for the origin of the pallasites as a by-product of igneous differentiation in the external heating of a chondritic parent body.

Mittlefehldt, D. W.↗

Origin of mesosiderites as a natural consequence of planet formation

The mineral composition of mesosiderites is described and a theory of the origin and evolution of these meteorites is presented. It is suggested that the asteroid parent body of the mesosiderites also formed in the inner solar system, perhaps just within the orbit of Mars. As a result of close planetary encounters, some bodies that formed near Earth or Venus were gravitationally perturbed into non-circular orbits; a few such bodies passed through the mesosiderite region at high relative velocities, colliding with and destroying a few of the native asteroids. Olivine-rich silicate mantles shattered into small pieces, but the stronger metal cores remained as large fragments. Much of the debris remained in circular orbits and accreted to the basaltic regoliths of intact native asteroids at low relative velocities. The large core fragments that collided with the crust greatly enriched restricted regions of the surface in metal. These localized regions were the mesosiderite progenitors; they accounted for only about 1% of the surface area of the parent bodies.

Wasson, J. T.↗

The case for a melt matrix in plagioclase-POIK mesosiderites

Reasons are given for reclassifying former 'poikiloblastic' mesosiderites as 'poikilitic' in order to better represent their thermal histories. Attention is focused on the plagioclase-POIK mesosiderites Bondoc, Budulan, and Mincy, which all display silicate melt matrices similar to the Palisades sill and Apollo 17 mare basalts. The poikilitic textures, resorbed olivine grains, and the crystallization sequence are sufficient to reclassify the three specimens from 3B to 4B mesosiderites. Because the 4B mesosiderites are clast-laden melt rocks, their origins were probably in impact melts, which would have combined hot melts with cold clasts.

Hewins, R. H.↗