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Atomic Clock Based On Linear Ion Trap

Highly stable atomic clock based on excitation and measurement of hyperfine transition in 199Hg+ ions confined in linear quadrupole trap by radio-frequency and static electric fields. Configuration increases stability of clock by enabling use of enough ions to obtain adequate signal while reducing non-thermal component of motion of ions in trapping field, reducing second-order Doppler shift of hyperfine transition. Features described in NPO-17758 "Linear Ion Trap for Atomic Clock." Frequency standard based on hyperfine transition described in NPO-17456, "Trapped-Mercury-Ion Frequency Standard."

Prestage, John D.↗

NASA Advanced Fuels Program

NASA with the USAF Research Laboratory and it's industry partners, has been conducting planning and research into advanced fuels. This work is sponsored under the NASA Advanced Space Transportation Program (ASTP). The current research focus is on Alternative Hydrocarbon fuels, Monopropellants, and Solid Cryogens for storing atoms of Hydrogen, Boron, Carbon, and Aluminum. Alternative hydrocarbons that are under consideration are bi cyclo propylidene, spiro pentane, and tri propargyl amine. These three fuels have been identified as initial candidates to increase the specific impulse of hydrocarbon fueled rockets by 10-15 seconds over 02/RP-1. Formulation of these propellants is proceeding this year, and rocket engine testing is planned for the near future. Monopropellant investigations are focused on dinitramine based fuels, and potential collaborations with the US Navy. The dinitramine fuel work is being conducted under an Small Business Innovation research (SBIR) contract with the team of Orbital Technologies Corp. (Madison, WI) and SRI (Menlo Park, CA). This work may lead to a high density, high specific impulse monopropellants that can simplify the operations for launch vehicles and spacecraft. Solid Cryogens are being considered to store atoms of Hydrogen, Boron, Carbon, and Aluminum. Stored atom propellants are potentially the highest specific impulse chemical rockets that may be practical. These fuels are composed of atoms, stored in solid cryogenic particles, suspended in a cryogenic liquid or gel. The fuel would be fed to a rocket engine as a slurry or gelled cryogenic liquid with the suspended particles with the trapped atoms. Testing is planned to demonstrate the formation of the particles, and then characterize the slurry flows. Rocket propellant and propulsion technology improvements can be used to reduce the development time and operational costs of new space vehicle programs. Advanced propellant technologies can make the space vehicles safer, more operable, and better performing. Five technology areas are described: Monopropellants, Alternative Hydrocarbons, Gelled Hydrogen, Metallized Gelled Propellants, and High Energy Density Materials. The benefits of these propellants for future vehicles are outlined using mission study results and the technologies are briefly discussed.

Palaszewski, Bryan↗

Upper bound on the equilibrium concentration of atomic H in solid H2

A phenomenological rate process theory has been developed for the production, storage and recombination of atomic H free radicals in a tritium-impregnated solid H2 at temperatures in the range of about 0.1 to 4 K. In this paper it is shown that the theory requires a stringent upper bound on the equilibrium concentration of trapped atomic H, namely that it cannot exceed about 0.125%, even if the temperature is reduced to an arbitrary low value and a very strong magnetic field is applied to the tritium-impregnated H2 solid.

Rosen, G.↗

A review of atomic clock technology, the performance capability of present spaceborne and terrestrial atomic clocks, and a look toward the future

Clocks have played a strong role in the development of general relativity. The concept of the proper clock is presently best realized by atomic clocks, whose development as precision instruments has evolved very rapidly in the last decades. To put a historical prospective on this progress since the year AD 1000, the time stability of various clocks expressed in terms of seconds of time error over one day of operation is shown. This stability of operation must not be confused with accuracy. Stability refers to the constancy of a clock operation as compared to that of some other clocks that serve as time references. Accuracy, on the other hand, is the ability to reproduce a previously defined frequency. The issues are outlined that must be considered when accuracy and stability of clocks and oscillators are studied. In general, the most widely used resonances result from the hyperfine interaction of the nuclear magnetic dipole moment and that of the outermost electron, which is characteristic of hydrogen and the alkali atoms. During the past decade hyperfine resonances of ions have also been used. The principal reason for both the accuracy and the stability of atomic clocks is the ability of obtaining very narrow hyperfine transition resonances by isolating the atom in some way so that only the applied stimulating microwave magnetic field is a significant source of perturbation. It is also important to make resonance transitions among hyperfine magnetic sublevels where separation is independent, at least to first order, of the magnetic field. In the case of ions stored in traps operating at high magnetic fields, one selects the trapping field to be consistent with a field-independent transition of the trapped atoms.

Vessot, Robert F. C.↗

Radial vibrations of a sodium ion inside icosahedral C60

The very high symmetry of icosahedral C60 suggests that, as a first approximation, an atom trapped inside C60 would be subject to a potential that is radially symmetric about the center. All-electron local-density-functional calculations of the total energy of a sodium ion as a function of radial displacement from the center along the fivefold axis of C60 serve to refine such a radial potential. In particular, the calculations suggest studying potentials that have minima displaced from the center. An analytic functional form for a radial potential having a positive cusp at the origin is proposed, and the s-wave radial solutions of the corresponding Schroedinger equation are examined.

Ballester, J. L.↗

A (201)Hg+ Comagnetometer for (199)Hg+ Trapped Ion Space Atomic Clocks

A method has been developed for unambiguously measuring the exact magnetic field experienced by trapped mercury ions contained within an atomic clock intended for space applications. In general, atomic clocks are insensitive to external perturbations that would change the frequency at which the clocks operate. On a space platform, these perturbative effects can be much larger than they would be on the ground, especially in dealing with the magnetic field environment. The solution is to use a different isotope of mercury held within the same trap as the clock isotope. The magnetic field can be very accurately measured with a magnetic-field-sensitive atomic transition in the added isotope. Further, this measurement can be made simultaneously with normal clock operation, thereby not degrading clock performance. Instead of using a conventional magnetometer to measure ambient fields, which would necessarily be placed some distance away from the clock atoms, first order field-sensitive atomic transition frequency changes in the atoms themselves determine the variations in the magnetic field. As a result, all ambiguity over the exact field value experienced by the atoms is removed. Atoms used in atomic clocks always have an atomic transition (often referred to as the clock transition) that is sensitive to magnetic fields only in second order, and usually have one or more transitions that are first-order field sensitive. For operating parameters used in the (199)Hg(+) clock, the latter can be five orders of magnitude or more sensitive to field fluctuations than the clock transition, thereby providing an unambiguous probe of the magnetic field strength.

Burt, Eric A.↗

Manipulating Neutral Atoms in Chip-Based Magnetic Traps

Several techniques for manipulating neutral atoms (more precisely, ultracold clouds of neutral atoms) in chip-based magnetic traps and atomic waveguides have been demonstrated. Such traps and waveguides are promising components of future quantum sensors that would offer sensitivities much greater than those of conventional sensors. Potential applications include gyroscopy and basic research in physical phenomena that involve gravitational and/or electromagnetic fields. The developed techniques make it possible to control atoms with greater versatility and dexterity than were previously possible and, hence, can be expected to contribute to the value of chip-based magnetic traps and atomic waveguides. The basic principle of these techniques is to control gradient magnetic fields with suitable timing so as to alter a trap to exert position-, velocity-, and/or time-dependent forces on atoms in the trap to obtain desired effects. The trap magnetic fields are generated by controlled electric currents flowing in both macroscopic off-chip electromagnet coils and microscopic wires on the surface of the chip. The methods are best explained in terms of examples. Rather than simply allowing atoms to expand freely into an atomic waveguide, one can give them a controllable push by switching on an externally generated or a chip-based gradient magnetic field. This push can increase the speed of the atoms, typically from about 5 to about 20 cm/s. Applying a non-linear magnetic-field gradient exerts different forces on atoms in different positions a phenomenon that one can exploit by introducing a delay between releasing atoms into the waveguide and turning on the magnetic field.

Aveline, David↗

Trapping of hydrogen atoms in X-irradiated salts at room temperature and the decay kinetics

The salts (hypophosphites, formates, a phosphite, a phosphate, and an oxalate) were X-irradiated, whereby hydrogen formed chemically by a radiolytic process becomes trapped in the solid. By room temperature vacuum extraction, the kinetics for the evolution of this trapped hydrogen was studied mass spectrometrically. All salts except two exhibited second-order kinetics. The two exceptions (NaH2PO2(H2O) and K2HPO4) showed first-order kinetics. Based on experimental results, the escape of hydrogen involves three steps: the diffusion of hydrogen atoms from the bulk to the surface, association of these atoms on the surface (rate controlling step for second-order hydrogen evolution), and the desorption of molecular hydrogen from the surface. The hydrogen does not escape if the irradiated salt is stored in air, apparently because adsorbed air molecules occupy surface sites required in the escape mechanism.

May, C. E.↗

Cycle Time Reduction in Trapped Mercury Ion Atomic Frequency Standards

The use of the mercury ion isotope (201)Hg(+) was examined for an atomic clock. Taking advantage of the faster optical pumping time in (201)Hg(+) reduces both the state preparation and the state readout times, thereby decreasing the overall cycle time of the clock and reducing the impact of medium-term LO noise on the performance of the frequency standard. The spectral overlap between the plasma discharge lamp used for (201)Hg(+) state preparation and readout is much larger than that of the lamp used for the more conventional (199)Hg(+). There has been little study of (201)Hg(+) for clock applications (in fact, all trapped ion clock work in mercury has been with (199)Hg(+); however, recently the optical pumping time in (201)Hg(+) has been measured and found to be 0.45 second, or about three times faster than in (199)Hg(+) due largely to the better spectral overlap. This can be used to reduce the overall clock cycle time by over 2 seconds, or up to a factor of 2 improvement. The use of the (201)Hg(+) for an atomic clock is totally new. Most attempts to reduce the impact of LO noise have focused on reducing the interrogation time. In the trapped ion frequency standards built so far at JPL, the optical pumping time is already at its minimum so that no enhancement can be had by shortening it. However, by using (201)Hg(+), this is no longer the case. Furthermore, integrity monitoring, the mechanism that determines whether the clock is functioning normally, cannot happen faster than the clock cycle time. Therefore, a shorter cycle time will enable quicker detection of failure modes and recovery from them.

Burt, Eric A.↗

Auger electron emission due to incident particle in Ar(+), Ne(+) and Na(+) collisions with different solid targets

The L23 Auger spectra of Ar, Ne and Na from Ar(+)-Ti, Ne(+)-Mg, Ne-A1, Na(+)-Be, Na(+)-Mg and Na(+)-A1 collisions were obtained. For Ar, L23 MM Auger electrons are emitted from the fast moving incident projectiles and a Doppler broadened structure is observed. The Ne and Na Auger spectra are due to Auger transitions with single or double 2p vancancies in the initial state of the implanted Ne atoms or surface trapped Na atoms.

Benazeth, C.↗

Development of the Science Data System for the International Space Station Cold Atom Lab

Cold Atom Laboratory (CAL) is a facility that will enable scientists to study ultra-cold quantum gases in a microgravity environment on the International Space Station (ISS) beginning in 2016. The primary science data for each experiment consists of two images taken in quick succession. The first image is of the trapped cold atoms and the second image is of the background. The two images are subtracted to obtain optical density. These raw Level 0 atom and background images are processed into the Level 1 optical density data product, and then into the Level 2 data products: atom number, Magneto-Optical Trap (MOT) lifetime, magnetic chip-trap atom lifetime, and condensate fraction. These products can also be used as diagnostics of the instrument health. With experiments being conducted for 8 hours every day, the amount of data being generated poses many technical challenges, such as downlinking and managing the required data volume. A parallel processing design is described, implemented, and benchmarked. In addition to optimizing the data pipeline, accuracy and speed in producing the Level 1 and 2 data products is key. Algorithms for feature recognition are explored, facilitating image cropping and accurate atom number calculations.

bose einstein condensate↗

New Experiment to Measure the Electron Electric Dipole Moment

An electron can possess an electric dipole moment (edm) only if time reversal symmetry (T) is violated. No edm of any particle has yet been discovered. CP-violation, equivalent to T-violation by the CPT theorem, does occur in Kaon decays and can be accounted for by the standard model. However, this mechanism leads to an electron edm d(sub e) of the order of 10(exp -38) e cm, whereas the current experimental bound on d(sub e) is about 10(exp -27) e cm. However, well-motivated extensions of the standard model such as supersymmetric theories do predict that de could be as large as the current bound. In addition, CP violation in the early universe is required to explain the preponderance of matter over anti-matter, but the exact mechanism of this CP violation is unclear. For these reasons, we are undertaking a new experimental program to determine de to an improved accuracy of 10(exp -29) e cm. Our experiment will use laser-cooled, trapped Cesium atoms to measure the atomic edm d(sub Cs) that occurs if d(sub e) is not zero. In order to do this, we will measure the energy splitting between the atoms spin states in parallel electric and magnetic fields. The signature of an edm would be a linear dependence of the splitting on the electric field E due to the interaction - d(sub Cs) dot E. Our measurement will be much more sensitive than previous measurements because atoms can be stored in the trap for tens of seconds, allowing for much narrower Zeeman resonance linewidths. Also, our method eliminates the most important systematic errors, proportional to atomic velocity, which have limited previous experiments. In this presentation, we will describe the design of our new apparatus, which is presently under construction. An important feature of our experimental apparatus is that magnetic field noise will be suppressed to a very low value of the order of 1 fT/(Hz)1/2. This requires careful attention to the Johnson noise currents in the chamber, which have not been important in previous experiments. In addition we will present estimates of the limits of the various errors that we expect for our experiment.

Kittle, Melanie↗

Atom Skimmers and Atom Lasers Utilizing Them

Atom skimmers are devices that act as low-pass velocity filters for atoms in thermal atomic beams. An atom skimmer operating in conjunction with a suitable thermal atomic-beam source (e.g., an oven in which cesium is heated) can serve as a source of slow atoms for a magneto-optical trap or other apparatus in an atomic-physics experiment. Phenomena that are studied in such apparatuses include Bose-Einstein condensation of atomic gases, spectra of trapped atoms, and collisions of slowly moving atoms. An atom skimmer includes a curved, low-thermal-conduction tube that leads from the outlet of a thermal atomic-beam source to the inlet of a magneto-optical trap or other device in which the selected low-velocity atoms are to be used. Permanent rare-earth magnets are placed around the tube in a yoke of high-magnetic-permeability material to establish a quadrupole or octupole magnetic field leading from the source to the trap. The atoms are attracted to the locus of minimum magnetic-field intensity in the middle of the tube, and the gradient of the magnetic field provides centripetal force that guides the atoms around the curve along the axis of the tube. The threshold velocity for guiding is dictated by the gradient of the magnetic field and the radius of curvature of the tube. Atoms moving at lesser velocities are successfully guided; faster atoms strike the tube wall and are lost from the beam.

Hulet, Randall↗

Atomic ion clock with two ion traps, and method to transfer ions

An atomic ion clock with a first ion trap and a second ion trap, where the second ion trap is of higher order than the first ion trap. In one embodiment, ions may be shuttled back and forth from one ion trap to the other by application of voltage ramps to the electrodes in the ion traps, where microwave interrogation takes place when the ions are in the second ion trap, and fluorescence is induced and measured when the ions are in the first ion trap. In one embodiment, the RF voltages applied to the second ion trap to contain the ions are at a higher frequency than that applied to the first ion trap. Other embodiments are described and claimed.

Prestage, John D.↗

Generation of a Cold Atom Beam from a Pyramidal Magneto-Optical Trap

We have built an atomic beam source utilizing a simple and robust design based on the pyramidal trap geometry of Kim et al. Our design allows use of a single large diameter (\le20 cm) laser beam to obtain large capture rates of atoms from a background vapor. A small (about 1mm diameter) hole in the retro-optic at the apex of the pyramid provides an extraction column for the atoms. We have operated the apparatus both as a magneto-optical trap (using an auxiliary plug laser beam), and as a cold atomic beam source. The characterization of this large pyramidal beam source will be reported, including an investigation of scaling to very large (10--20cm) high power (about 1W) laser beams which should allow significant improvements in atomic beam flux.

Bliss, J. L.↗

Ion-Atom Cold Collisions and Atomic Clocks

Collisions between ultracold neutral atoms have for some time been the subject of investigation, initially with hydrogen and more recently with laser cooled alkali atoms. Advances in laser cooling and trapping of neutral atoms in a Magneto-Optic Trap (MOT) have made cold atoms available as the starting point for many laser cooled atomic physics investigations. The most spectacularly successful of these, the observation of Bose-Einstein Condensation (BEC) in a dilute ultra-cold spin polarized atomic vapor, has accelerated the study of cold collisions. Experimental and theoretical studies of BEC and the long range interaction between cold alkali atoms is at the boundary of atomic and low temperature physics. Such studies have been difficult and would not have been possible without the development and advancement of laser cooling and trapping of neutral atoms. By contrast, ion-atom interactions at low temperature, also very difficult to study prior to modern day laser cooling, have remained largely unexplored. But now, many laboratories worldwide have almost routine access to cold neutral atoms. The combined technologies of ion trapping, together with laser cooling of neutrals has made these studies experimentally feasible and several very important, novel applications might come out of such investigations . This paper is an investigation of ion-atom interactions in the cold and ultra-cold temperature regime. Some of the collisional ion-atom interactions present at room temperature are very much reduced in the low temperature regime. Reaction rates for charge transfer between unlike atoms, A + B(+) approaches A(+) + B, are expected to fall rapidly with temperature, approximately as T(sup 5/2). Thus, cold mixtures of atoms and ions are expected to coexist for very long times, unlike room temperature mixtures of the same ion-atom combination. Thus, it seems feasible to cool ions via collisions with laser cooled atoms. Many of the conventional collisional interactions, exploited as a useful tool at room temperature and higher, are greatly enhanced at low energy. For example, collisional spin transfer from one species of polarized atoms to another has long been a useful method for polarizing a sample of atoms where no other means was available. Because optical pumping cannot be used to polarize the nuclear spin of Xe-129 or He-3 (for use in nmr imaging of the lungs), the nuclear spins are polarized via collisions with an optically pumped Rb vapor in a cell containing both gases. In another case, a spin polarized thermal Cs beam was used to polarize the hyperfine states of trapped He(+)-3 ions in order to measure their hyperfine clock transition frequency. The absence of an x-ray light source to optically pump the ground state of the He(+)-3 ion necessitated this alternative state preparation. Similarly, Cd(+) and Sr(+) ions were spin-oriented via collisions in a cell with optically pumped Rb vapor. Resonant RF spin changing transitions in the ground state of the ions were detected by changes in the Rb resonance light absorption. Because cold collision spin exchange rates scale with temperature as T(sup -1/2) this technique is expected to be a far more powerful tool than the room temperature counterpart. This factor of 100 or more enhancement in spin exchange reaction rates at low temperatures is the basis for a novel trapped ion clock where laser cooled neutrals will cool, state select and monitor the ion clock transition. The advantage over conventional direct laser cooling of trapped ions is that the very expensive and cumbersome UV laser light sources, required to excite the ionic cooling transition, are effectively replaced by simple diode lasers.

Prestage, John D.↗

Generation of a Cold Atom Beam from a Pyramidal Magneto-Optical Trap

Techniques to generate cold atom beams are of great interest in a variety of applications, from atomic frequency standards and atom optics to experimental studies of Bose-Einstein condensation. Cold atom beams have been produced by slowing thermal atomic beams using the Zeeman-slowing technique or chirped lasers, or using laser-cooling techniques to extract a slow atomic beam from the background gas in a low-pressure vapor cell. These laser-cooling techniques include "atomic funnels" or two-dimensional magneto-optical traps, as well as a variation of the conventional vapor cell magneto-optical trap called the "low-velocity intense source" (LVIS). Variations of the LVIS have been realized with unique trap geometries such as conical or pyramidal mirror traps. The present work implements a simple and robust design based on the pyramidal trap geometry and allows use of a single large diameter (<less than or = 20 cm) laser beam to obtain large capture rates of atoms from the background vapor. The four 45 deg mirrors are truncated just before the apex of the pyramid, and the 1 sq cm region at the center of the incident laser beam is retro-reflected by lambda /4 plate with a high-reflectance gold coating on the second surface. A small (1 mm diameter) hole in this retro-optic forms an extraction column for the atoms while maintaining a low conductance between the source region and an adjacent UHV chamber.

Kohel, J.↗