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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

The reduction correction in North America

An inverse Poisson integral technique was used to determine a gravity field on the geoid which, when continued by analytic free space methods to the topographic surface, agrees with the observed field. The computation is performed in three stages, each stage refining the previous solution using data at progressively increasing resolution (1 x 1 deg, 5 x 5', 5/8 x 5/8') from a decreasing area of integration. Reduction corrections are computed at 5/8 x 5/8' granularity by differencing the geoidal and surface values, smoothed by low-pass filtering and sub-sampled at 5' intervals. The 1 x 1 deg averages of the reduction corrections thus obtained for 172 1 x 1 deg squares in western North America are discussed. The 1 x 1 deg mean reduction corrections are predominantly positive, varying from -3 to +15 mgal, with values in excess of 5 mgal for 26 squares. Their mean and rms values are +2.4 and 3.6 mgal respectively and they correlate well with the mean terrain corrections. The mean and rms contributions from the three stages of computation are: 1 x 1 deg stage +0.15 and 0.7 mgal; 5 x 5' stage + 1.0 and 1.6 mgal; and 5/8 x 5/8' stage +1.3 and 1.8 mgal. These results reflect a tendency for the contributions to become larger and more systematically positive as the wavelengths involved become shorter. The results are discussed in terms of two mechanisms; the first is a tendency for the absolute values of both positive and negative anomalies to become larger when continued downwards and, the second, a non-linear rectification, due to the correlation between gravity anomaly and topographic height, which results in the values continued to a level surface being systematically more positive than those on the topography.

Martzen, P. D.↗
NASA NTRS1992

Oceanwide gravity anomalies from Geos-3, Seasat and Geosat altimeter data

Three kinds of satellite altimeter data have been combined, along with 5 x 5 arcmin bathymetric data, to calculate a 0.125 deg ocean wide gridded set of 2.3 x 10 exp 6 free-air gravity anomalies. The procedure used was least squares collocation that yields the predicted anomaly and standard deviation. The value of including the bathymetric data was shown in a test around the Dowd Seamount where the root mean square (rms) difference between ship gravity measurements decreased from +/- 40 mgal to +/- 20 mgal when the bathymetry was included. Comparisons between the predicted anomalies and ship gravity data is described in three cases. In the Banda Sea the rms differences were +/- 20 mgal for two lines. In the South Atlantic rms differences over lines of 2000 km in length were +/- 7 mgal. For cruise data in the Antarctica region the discrepancies were +/- 12 mgal. Comparisons of anomalies derived from the Geosat geodetic mission data by Marks and McAdoo (1992) with ship dta gave differences of +/- 6 mgal showing the value of the much denser Geosat geodetic mission altimeter data.

Rapp, Richard H.↗
DOE OSTI2024

Effect of relative humidity on the interlayer spacing of phosphate intercalated Mg, Al layered double hydroxide (hydrotalcite‐like) crystals

Abstract The availability of water and the type of interlayer anions present affect the arrangement and interlayer spacing of layered double hydroxide (LDH). A systematic study of the effect of relative humidity (RH) on the basal spacing of phosphate intercalated, magnesium aluminum LDHs (MgAl–PO 4 LDH) was conducted, confirming that MgAl‐PO 4 LDH exhibit distinct interlayer spacing corresponding to separate low‐ and high‐hydration states produced when exposed to low and high humidity conditions. The transition from the low‐ to high‐hydration form begins when RH exceeds 33% and is accompanied by the transition from one to two interlayers of water. An improved understanding of the effect of RH on MgAl–PO 4 LDHs will enable more accurate atomistic modeling and experimental characterization of MgAl–PO 4 LDHs and may lead to improvements in the tunability of MgAl‐PO 4 LDHs for commercial applications such as slow‐release fertilizer.

Reed, Titus↗
DOE OSTI2023

Study on the Thermal Stabilizing Process of Layered Double Hydroxides in PVC Resin

Poly(vinyl chloride) (PVC) is widely used in various fields and requires the use of thermal stabilizers to enhance its thermal stability during processing because of its poor thermal stability. Layered double hydroxides (LDHs) are widely considered to be one kind of highly efficient and environmentally friendly PVC thermal stabilizer. To investigate the thermal stabilizing process of layered double hydroxides (LDHs) in PVC resin, PVC and MgAl-LDHs powders with different interlayer anions (CO 3 2- , Cl - , and NO 3 - ) were physically mixed and aged at 180 °C. The structure of LDHs at different aging times was studied using XRD, SEM, and FT-IR. The results show that the thermal stabilizing process of LDHs on PVC mainly has three stages. In the first stage, the layers of LDHs undergo a reaction with HCl, which is released during the thermal decomposition of PVC. Subsequently, the ion exchange process occurs between Cl - and interlayer CO 3 2- , resulting in the formation of MgAl-Cl-LDHs. Finally, the layers of MgAl-Cl-LDHs react with HCl slowly. During the thermal stabilizing process of MgAl-Cl-LDHs, the peak intensity of XRD reduces slightly, and no new XRD peak emerges. It indicates that only the first step happens for MgAl-Cl-LDHs. The TG-DTA analysis of LDHs indicates that the interaction of LDHs with different interlayer anions has the following order: NO 3 - < CO 3 2- < Cl - , according to the early coloring in the thermal aging test of PVC composites. The results of the thermal aging tests suggest that LDHs with a weak interaction between interlayer anions and layers can enhance the early stability of PVC significantly. Furthermore, the thermal aging test demonstrates that LDHs with high HCl absorption capacities exhibit superior long-term stabilizing effects on PVC resin. This finding provides a valuable hint for designing an LDHs/PVC resin with a novel structure and excellent thermal stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2003

Effect of Varying Crustal Thickness on CHAMP Geopotential Data

To determine the effect of crustal thickness variation on satellite-altitude geopotential anomalies we compared two regions of Europe with vastly different values, Central/Southern Finland and the Pannonian Basin. Crustal thickness exceeds 62 km in Finland and is less than 26 km in the Pannonian Basin. Heat-flow maps indicate that the thinner and more active crust of the Pannonian Basin has a value nearly three times that of the Finnish Svecofennian Province. Ground based gravity mapping in Hungary shows that the free-air gravity anomalies across the Pannonian Basin are near 0 to +20 mGal with shorter wavelength anomalies from +40 to less than +60 mGal and some 0 to greater than -20 mGal. Larger anomalies are detected in the mountainous areas. The minor value anomalies can indicate the isostatic equilibrium for Hungary (the central part of the Pannonian Basin). Gravity data over Finland are complicated by de-glaciation. CHAMP gravity data (400 km) indicates a west-east positive gradient of greater than 4 mGal across Central/Southern Finland and an ovoid positive anomaly (approximately 4 mGal) quasi-coincidental with the magnetic anomaly traversing the Pannonian Basin. CHAMP magnetic data (425 km) reveal elongated semicircular negative anomalies for both regions with South-Central Finland having larger amplitude (less than -6 nT) than that over the Pannonian Basin, Hungary (less than -5 nT). In both regions subducted oceanic lithosphere has been proposed as the anomalous body.

Taylor, P. T.↗
NASA NTRS2003

Effect of Varying Crustal Thickness on CHAMP Geopotential Data

Tn determine the effect of crustal thickness variation on satellite-altitude geopotential anomalies we compared two regions of Europe with vastly different values, South and Central Finland and the Pannonian Basin. In our study regions, crustal thickness exceeds 44 km in Finland and is less than 26 km in the Pannonian Basin. Heat-flow data indicate that the thinner and more active crust of the Pannonian Basin has a value nearly three times that of the Finnish Svecofennian Province. An ovoid positive CHAMP gravity anomaly (-4 mGal) is quasi-coincidental with the CHAMP magnetic anomaly traverses the Pannonian Basin while ground based gravity mapping in Hungary shows that the free-air gravity anomalies across the Pannonian Basin are near 0 to +20 mGal with shorter wavelength anomalies from +40 to less than +60 mGal and some 0 to greater than -20 mGal. Larger anomalies are detected in the mountainous areas. The minor value anomalies can indicate the isostatic equilibrium for Hungary (the central part of the Pannonian Basin). Gravity data over Finland bear overprint of de-glaciation. CHAMP gravity data indicates a west-east positive gradient of less than 4 mGal across South and Central Finland. CHAMP magnetic data (400 km) reveal elongated semi-circular negative anomalies for both regions with South-Central Finland having larger amplitude (less than -6 nT) than that over the Pannonian Basin, Hungary (less than -5 nT). In the latter subducted oceanic lithosphere has been proposed as the anomalous body.

Taylor, Patrick T.↗
NASA NTRS1978

Comparison of surface and satellite gravity data

Satellite derived potential coefficients (GEM 9) are compared to terrestrial gravity data by degree in terms of coefficient differences and in terms of mean anomaly differences. The root mean square undulation difference (to degree 20) was 9 + or - m and the anomaly difference was + or - 7 mgals with GEM 9 commission errors of + or - 1.7 m and + or - 3.8 mgals. The standard deviations of the GEM 9 implied undulations increased from + or - 4 cm at degree 2 to + or - 53 cm at degree 20. The corresponding values implied by a recent (June 1978) terrestrial 5 deg field were + or - 2.53 m and + or - 0.38 m (at degree 20). Comparisons between Geos-3 altimeter derived anomalies and 1 deg X 1 Deg terrestrial data showed that + or - 6-8 mgals is a reasonable accuracy estimate for the altimeter derived anomalies. Anomalies derived from satellite to satellite tracking data indicate an accuracy of about + or - 6 mgals for the recovery of 5 deg equal area blocks.

Rapp, R. H.↗
NASA NTRS1979

Detailed gravity anomalies from Geos 3 satellite altimetry data

Detailed gravity anomalies are computed from a combination of Geos 3 satellite altimeter and terrestrial gravity data using least-squares principles. The mathematical model used is based on the Stokes' equation modified for a nonglobal solution. Using Geos 3 data in the calibration area, the effects of several anomaly parameter configurations and data densities/distributions on the anomalies and their accuracy estimates are studied. The accuracy estimates for 1 deg x 1 deg mean anomalies from low density altimetry data are of the order of 4 mgal. Comparison of these anomalies with the terrestrial data and also with Rapp's data derived using collocation techniques show rms differences of 7.2 and 4.9 mgal, respectively. Indications are that the anomaly accuracies can be improved to about 2 mgal with high density data. Estimation of 30 in. x 30 in. mean anomalies indicates accuracies of the order of 5 mgal. Proper verification of these results will be possible only when accurate ground truth data become available.

Gopalapillai, G. S.↗
NASA NTRS1989

Geopotential models in the Australian region

The ability of three high-order geopotential models (OSU81, GPM2 and OSU86E) to recover the gravity anomaly field (delta g) in the Australian region was tested. The region was divided into 2 x 2 deg blocks, and the mean and rms of the residual gravity (delta g measured - delta g modeled) was found to estimate the fit of the model to the point gravity data. The results showed that OSU81 and GPM2 performed similarly, recovering the delta g with a mean value of less than plus or minus 5 mGal in 63 and 70 percent of the blocks, respectively. However, both these models achieved a fit of worse that was plus or minus 13 mGal in 6 to 7 percent of cases. These were in areas either on or near the coast, or in the Central Australian region, inferring that for a precise geoid slope determination in these regions, a detailed analysis of delta g in region is needed. On the other hand, OSU86E produced a very good result, having a mean fit of less than plus or minus 5 mGal in 80 percent of the blocks, and worse than plus or minus 13 mGal in only 1 percent of cases. The rms values for this model were also improved over the other two models, indicating that for applications requiring highest precision, the preferred model is OSU86E.

Kearsley, A. H. W.↗
DOE OSTI2020

A Decade of Innovative Approaches to Treating and Dispositioning Radioactive Waste at the Savannah River Site - 20620

This year marks the 70. anniversary of the U.S. Department of Energy's (DOE) Savannah River Site (SRS), located near Aiken, South Carolina. SRS is a key industrial complex responsible for environmental stewardship, environmental cleanup, waste management, and disposition of nuclear materials. SRS also continues to have a role in critical defense-related activities and the reprocessing of used reactor fuel. The SRS encompasses 803 square kilometers (310 square miles) in parts of Aiken, Barnwell, and Allendale counties. The Liquid Waste Mission starts with the safe receipt and storage of radioactive liquid waste in the waste tanks, which principally includes Cold War legacy waste, but also waste from support of National Aeronautics Space Administration missions, medical isotope production, and research activities. This 133,000 cubic meters (m{sup 3}) (35 million gallons [Mgal]) of high-level radioactive waste (HLW) is currently held in 43 large underground waste tanks. The capacity of each of these tanks range from 2,800 m{sup 3} to 5,000 m{sup 3} (0.75 to 1.33 Mgal) and were placed in operation between 1954 and 1986. In July 2009, the DOE awarded a stand-alone contract to execute the Liquid Waste Mission at SRS. The Liquid Waste Contractor selected was Savannah River Remediation LLC1 (SRR), which is responsible for receipt, storage, retrieval and treatment of all HLW, disposal of the decontaminated low-activity waste fraction, as well as operationally closing cleaned HLW tanks. Since July 2009, SRR has successfully grouted and operationally closed six large underground tanks, poured 1,476 canisters of vitrified HLW (a stable glass waste form), treated approximately 34,200 m{sup 3} (9.0 Mgal) of HLW, and dispositioned over 41,200 m{sup 3} (10.9 Mgal) of decontaminated salt solution as low-level waste (LLW) into the Saltstone Disposal Units (SDUs) being constructed by SRR on site. The innovative work performed by SRR in the LLW portion of its mission has earned it the Richard S. Hodes Award. The work conducted by SRR is the same work championed by the late Richard S. Hodes, a respected physician, statesmen, and Chairman of the Southeast Compact Commission for Low-Level Radioactive Waste Management. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Understanding Oxide–Metal Interactions During Hot Isostatic Pressing to Diffusion Bond Aluminum Alloy 6061 Plates

The interaction between Mg, Si, and Al 2 O 3 during hot isostatic pressing diffusion bonding of aluminum alloy 6061 (AA6061) plates was investigated through thermodynamic calculations and experimental microstructural characterization. Thermodynamic calculations as functions of temperature, pressure, and composition revealed that the interaction among Mg, Si, and Al 2 O 3 yields Mg 2 Si and either MgO + Al or MgAl 2 O 4 + Al, facilitating the reduction of Al 2 O 3 and allowing Al/Al metallic bonds to form. Total pressure variation had a negligible influence on the oxygen partial pressure, and consequently, the reaction product formation. Oxygen partial pressure variation as a function of temperature and initial amount of Al 2 O 3 determined the formation of either MgO or MgAl 2 O 4 . Experimental Hot Isostatic Pressure (HIP) bonding at 723 K and 833 K under a constant pressure of 1017 atm documented the cooling rate-dependent formation of β–Mg 2 Si precipitates. High-resolution transmission electron microscopy imaging and selected area electron diffraction patterns verified the formation of β–Mg 2 Si and MgO at the interface but did not detect MgAl 2 O 4 . In conclusion, findings from this study clarify the role of thermochemical interactions in oxide disruption and bonding mechanisms during HIP diffusion bonding of AA6061 and provide guidance for optimizing joining processes for monolithic nuclear fuel assemblies.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Materials Data on Mg2Al3(SiO3)6 by Materials Project

(MgAl(SiO3)3)2Al crystallizes in the orthorhombic Cccm space group. The structure is three-dimensional and consists of four aluminum molecules and one MgAl(SiO3)3 framework. In the MgAl(SiO3)3 framework, Mg is bonded to six O atoms to form distorted MgO6 pentagonal pyramids that share corners with four SiO4 tetrahedra and faces with two equivalent AlO6 pentagonal pyramids. There are two shorter (1.89 Å) and four longer (2.13 Å) Mg–O bond lengths. Al is bonded to six O atoms to form distorted AlO6 pentagonal pyramids that share corners with four SiO4 tetrahedra and faces with two equivalent MgO6 pentagonal pyramids. There are a spread of Al–O bond distances ranging from 1.91–2.01 Å. There are three inequivalent Si sites. In the first Si site, Si is bonded to four O atoms to form SiO4 tetrahedra that share corners with two equivalent MgO6 pentagonal pyramids, corners with two equivalent AlO6 pentagonal pyramids, and a cornercorner with one SiO4 tetrahedra. There is three shorter (1.64 Å) and one longer (1.78 Å) Si–O bond length. In the second Si site, Si is bonded in a water-like geometry to two O atoms. Both Si–O bond lengths are 1.64 Å. In the third Si site, Si is bonded to four O atoms to form SiO4 tetrahedra that share corners with two equivalent MgO6 pentagonal pyramids, corners with two equivalent AlO6 pentagonal pyramids, and a cornercorner with one SiO4 tetrahedra. There are a spread of Si–O bond distances ranging from 1.64–1.77 Å. There are six inequivalent O sites. In the first O site, O is bonded in a 3-coordinate geometry to one Mg, one Al, and one Si atom. In the second O site, O is bonded in a distorted linear geometry to two Si atoms. In the third O site, O is bonded in a 2-coordinate geometry to one Mg and one Al atom. In the fourth O site, O is bonded in a bent 150 degrees geometry to two Si atoms. In the fifth O site, O is bonded in a bent 150 degrees geometry to two Si atoms. In the sixth O site, O is bonded in a distorted trigonal planar geometry to one Mg, one Al, and one Si atom.

36 MATERIALS SCIENCE↗
DOE OSTI2022

94ND10 Intergranular Phase Analysis and Fabrication

The composition and phase fraction of the intergranular phase of 94ND10 ceramic is determined and fabricated ex situ. The fraction of each phase is 85.96 vol% Al 2 O 3 bulk phase, 9.46 vol% Mg-rich intergranular phase, 4.36 vol% Ca/Si-rich intergranular phase, and 0.22 vol% voids. The Ca/Si-rich phase consists of 0.628 at% Mg, 12.59 at% Si, 10.24 at% Ca, 17.23 at% Al, and balance O. The Mgrich phase consists of 14.17 at% Mg, 0.066 at% Si, 0.047 at% Ca, 28.69 at% Al, and balance O. XRD of the ex situ intergranular material made by mixed oxides consisting of the above phase and element fractions yielded 92 vol% MgAl 2 O 4 phase and 8 vol% CaAl 2 Si 2 O 8 phase. The formation of MgAl 2 O 4 phase is consistent with prior XRD of 94ND10, while the CaAl 2 Si 2 O 8 phase may exist in 94ND10 but at a concentration not readily detected with XRD. The MgAl 2 O 4 and CaAl 2 Si 2 O 8 phases determined from XRD are expected to have the elemental compositions for the Mg-rich and Ca/Si-rich phases above by cation substitutions (e.g., some Mg substituted for by Ca in the Mg-rich phase) and impurity phases not detectable with XRD.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Simulation of a lunar gradiometer mission

A lunar gradiometer mission involves the mounting of a gradiometer on a satellite which is in a low, polar, and circular lunar orbit. The results of a numerical simulation of the mission is presented. It is shown that if the satellite is in a 50 km orbit, 1 deg and 2 deg gravity anomalies may be estimated with accuracies of 12 mgal and 1 mgal respectively. At a 100 km altitude, 2 deg gravity anomalies can be estimated with an accuracy of 12 mgal. These results assume a rotating type gradiometer with a .1E accuracy. The results can be readily scaled to reflect another level.

Argentiero, P. D.↗
NASA NTRS1980

Comparison of undulation difference accuracies using gravity anomalies and gravity disturbances

Errors in the outer zone contribution to oceanic undulation differences computed from a finite set of potential coefficients based on satellite measurements of gravity anomalies and gravity disturbances are analyzed. Equations are derived for the truncation errors resulting from the lack of high-degree coefficients and the commission errors arising from errors in the available lower-degree coefficients, and it is assumed that the inner zone (spherical cap) is sufficiently covered by surface gravity measurements in conjunction with altimetry or by gravity anomaly data. Numerical computations of error for various observational conditions reveal undulation difference errors ranging from 13 to 15 cm and from 6 to 36 cm in the cases of gravity anomaly and gravity disturbance data, respectively for a cap radius of 10 deg and mean anomalies accurate to 10 mgal, with a reduction of errors in both cases to less than 10 cm as mean anomaly accuracy is increased to 1 mgal. In the absence of a spherical cap, both cases yield error estimates of 68 cm for an accuracy of 1 mgal and between 93 and 160 cm for the lesser accuracy, which can be reduced to about 110 cm by the introduction of a perfect 30-deg reference field.

Jekeli, C.↗
NASA NTRS1982

Signal analysis and error analysis studies for a Geopotential Research Mission (GRM)

The signal characteristics and the geopotential parameter recovery capability of the SST Doppler sensor flown on the geopotential research mission (GRM) are discussed. Simulation studies of the velocity profiles resulting from the perturbation produced by a 1 deg/w/1 deg, 1 mgal anomaly as sensed by two GRM spacecraft orbiting altitudes of 160 km and 200 km respectively are described. It was found that the amplitude of the gravity signal drops off by a factor of 1.5 when going from an altitude of 160 km to 200 km. By extrapolation the signal amplitude is further decreased by a factor of 3 when the orbital altitude is increased to 250 km. Thus the amplitude of the measurement drops off as the altitude is increased to the point where it is insignificant at the 1 mgal level for altitudes above 200 km. Spectral analysis results show that for a GRM mission altitude of 160 km and a system precision of 1 micrometer/sec, gravity field information can be sensed up to 230 cycles per orbital revolution - beyond that frequency the gravity signal is characterized by white noise. It follows that at the GRM mission altitude of 160 km and a satellite to satellite Doppler system precision of 1 micrometer per second, 1/1 deg gravity and geoid anomalies can be determined to an accuracy of 3.4 mgals and 8.6 cm respectively.

Kahn, W. D.↗
NASA NTRS1989

The combination of satellite and topographic/isostatic potential models for mean anomaly determinations

A method is presented for the estimation of a global gravity anomaly field using the combination of satellite-derived potential coefficient models and the coefficients implied by the Airy-Heiskanen topographic/isostatic potential (Rummel et al., 1988) from topographic models with a 30-km depth of compensation. Gravity anomalies calculated with this method are compared with a terrestrial 1 x 1 degree anomaly file where the anomaly standard deviations were less than 10 mgals. Using the GEM T1 model (Marsh et al., 1988) to degree 36, the rms anomaly discrepency was + or - 19 mgals, while the rms values for the terrestrial anomalies was + or - 28 mgals.

Rapp, Richard H.↗
NASA NTRS1993

Comparison of marine gravity from shipboard and high-density satellite altimetry along the Mid-Atlantic Ridge, 30.5-35.5 deg S

We compare new marine gravity fields derived from satellite altimetry with shipboard measurements over a region of more than 120,000 sq km in the central South Atlantic. Newly declassified satellite data were employed to construct free-air anomaly maps on 0.05 degree grids. An extensive gravity and bathymetry data set from four cruises along the Mid-Atlantic Ridge from 30.5-35.5 deg S provides a benchmark for testing the 2D resolution and accuracy of the satellite measurements where their crosstrack spacing is near their widest. The satellite gravity signal is coherent with bathymetry in this region down to wavelengths of 26 km, compared to 12.5 km for shipboard gravity. Residuals between the shipboard and satellite data sets have a roughly normal distribution. The standard deviation of satellite gravity with respect to shipboard measurements is nearly 7 mGal in a region of 140 mGal total variation, whereas the internal standard deviation at crossovers for GPS-navigated shipboard data is 1.8 mGal. The differences between shipboard and satellite data are too large to use satellite gravity to determine crustal thickness variations within a typical ridge segment.

Neumann, Gregory A.↗