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DOE OSTI2023

Responses of the AC/DC Global Electric Circuit to Volcanic Electrical Activity in the Hunga Tonga-Hunga Ha'apai Eruption on 15 January 2022

Responses of the AC and DC global electric circuits (GECs) to the large eruption of the Hunga Tonga-Hunga Ha'apai (HT-HH) volcano on 15 January 2022 are discussed. The AC-related investigation is based on Schumann resonance (SR) measurements from six stations on four continents. The DC-related investigation utilizes atmospheric electric field (potential gradient, PG) measurements from six recording stations in Europe and the USA. According to data from the GLD360 and WWLLN lightning detection networks, the peak lightning stroke rate, 83/s, was dominated by negative polarity lightning, but the distributions of positive and negative lightning discharges in latitude and longitude around the volcano differed. A global intensification of SR is apparent in connection with the enhanced lightning activity caused by the eruption. SR data-based results confirm that the lightning activity in the eruption dominated the naturally occurring global activity for a period of about 1 hr. The highly localized increase in lightning activity over HT-HH was a unique point source of SR excitation. PG measurements suggest that impulse-like charging of the DC GEC, by ~15%, via negative cloud-to-ground lightning strokes took place twice during the eruption. A time constant of 7 or 8 min has been inferred for near-surface PG changes due to these enhancements. This could be the first direct measurement of the time constant of the GEC near the Earth's surface, as well as the first observation of the direct charging of the DC GEC by a unique atmospheric electrified source.

58 GEOSCIENCES↗

NASA NTRS2011

Measuring Moisture Levels in Graphite Epoxy Composite Sandwich Structures

Graphite epoxy composite (GEC) materials are used in the construction of rocket fairings, nose cones, interstage adapters, and heat shields due to their high strength and light weight. However, they absorb moisture depending on the environmental conditions they are exposed to prior to launch. Too much moisture absorption can become a problem when temperature and pressure changes experienced during launch cause the water to vaporize. The rapid state change of the water can result in structural failure of the material. In addition, heat and moisture combine to weaken GEC structures. Diffusion models that predict the total accumulated moisture content based on the environmental conditions are one accepted method of determining if the material strength has been reduced to an unacceptable level. However, there currently doesn t exist any field measurement technique to estimate the actual moisture content of a composite structure. A multi-layer diffusion model was constructed with Mathematica to predict moisture absorption and desorption from the GEC sandwich structure. This model is used in conjunction with relative humidity/temperature sensors both on the inside and outside of the material to determine the moisture levels in the structure. Because the core materials have much higher diffusivity than the face sheets, a single relative humidity measurement will accurately reflect the moisture levels in the core. When combined with an external relative humidity measurement, the model can be used to determine the moisture levels in the face sheets. Since diffusion is temperaturedependent, the temperature measurements are used to determine the diffusivity of the face sheets for the model computations.

Nurge, Mark↗

DOE OSTI2021

Atmospheric Electric Field-Mill Sensor Field Campaign Report

The foundation stone of atmospheric electricity is the existence of a Global Electric Circuit (GEC) influencing all of the planet. In fact, global thunderstorm activity acts as a voltage source that imposes a potential difference between the ionosphere (positively charged) and the Earth’s surface (negatively charged) of about ~300 kV. Such potential difference is discharged through the poorly conducting atmosphere in fair-weather regions, with atmospheric electric fields of ~100 V/m. First evidence of the GEC was gathered by scientists involved on the Carnegie vessel expeditions (early 20th Century), in which they describe a similar daily variation of the atmospheric electric field in different parts of the Pacific Ocean. Such variation become known as the Carnegie Curve (CC).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2026

Multi-Year Electric Field Study at the North Slope of Alaska (OYESNSA) Field Campaign Report

The Global Electric Circuit (GEC) of the atmosphere provides a unique perspective on Earth’s changing climate. Monitoring this global electrical signature provides details of the global nature of electrified clouds and thunderstorms. The North Slope of Alaska (NSA) is a unique location for collecting these electric field measurements. Besides being at the opposite pole from many previous electric field measurements taken at Russia’s Vostok station in Antarctica, this site provides a rare opportunity to use other instruments at the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility’s NSA observatory at Utqiaġvik (formerly known as Barrow), such as the Ka-band ARM Zenith Radar (KAZR), upward-facing micropulse lidar (MPL), vertical profile of meteorological measures, and other aerosol measurements. Since 2017, Texas A&M University at Corpus Christi (TAMUCC) has established an observational instrument package, including CS110 electric fields and anemometer, at ARM’s NSA observatory at Utqiaġvik. This enabled the unique opportunity to not only provide information about the global signature of the GEC, but also the physical inputs to the local electric field, by analyzing the physical properties of the simultaneous cloud, wind, and aerosol properties occurring with the vertical electric field.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2026

Multi-Year Electric Field Study at the North Slope of Alaska (OYESNSA) Field Campaign Report

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1984

Ccds: Their Cause and Cure

Charge coupled devices (CCDs) have opened new horizons in the optical astronomy. Most of the presently existing astronomical CCD systems are oriented and designed primarily for work on faint objects. The use of CCDs for high precision work on bright objects remains to be explored. Issues and problems specific to (CCDs) are covered in detail. The important structural characteristics of CCDs are that they are integrating, self scanned, photon counting (one selection for each detected photon), solid state devices. The typical physical sizes are of the order of 1 - 3 cm, and typical raster formats of 500x500 pixels (TI), 320x512 (RCA), 385x576 (GEC), 800x800 (TI), and 1500x1500 (GEC) should be available soon. Typical (and optimal) operating temperatures are around -100 C, with liquid N2 as the most common coolant. Some CCDs are physically warped. This causes focus variations across the surface, which amount to a spatially variable PSF. Other relevant properties of CCDs as detectors and a comparison with some other astronomical detectors are given.

Djorgovski, S.↗

NASA NTRS1987

High repetition rate sealed CO2 TEA lasers using heterogeneous catalysts

The significant operational advantages offered by CO2 lasers, operating in the 10.6 micron region of the spectrum, over current solid state lasers, emitting in the near IR region, have prompted increased interest in the development of compact, reliable, rugged CO2 laser sources. Perhaps the most critical aspect associated with achieving a laser compatible with military use is the development of lasers which require no gas replenishment. Sealed, single shot, CO2 TEA lasers have been available for a number of years. Stark et al were first to demonstrate reliable sealed operation in single shot CO2 TEA lasers in 1975 using gas catalysis. GEC Avionics reported the compact, environmentally qualified, MKIII CO2 TEA laser with a pulse life of greater than 10 to the 6th power pulses in 1980. A sealed laser lifetime of greater than 10 to the 6th power pulses is acceptable for single shot cases, such as direct detection rangefinders for tank laser sights. However, in many other applications, such as tracking of fast moving targets, it is essential that a repetition rate of typically 30Hz to 100Hz is employed. In such cases, a pulse lifetime of 10 to the 6th power pulses is no longer sufficient and a minimum pulse lifetime 10 to the 7th power pulses is essential to ensure a useful service life. In 1983 Stark el al described a sealed, 100Hz CO2 TEA laser, with a life of greater than 2.6 x 10 to the 6th power, which employed heterogeneous catalysis. Following this pioneering work, GEC Avionics has been engaged in the development of sealed high repetition rate lasers with a pulse lifetime of 20 million pulses.

Price, H. T.↗

NASA NTRS1992

Diterpanes, triterpanes, steranes, and aromatic hydrocarbons in natural bitumens and pyrolysates from different humic coals

Data are presented on the distribution of diterpanes, triterpanes, steranes, and aromatic hydrocarbons in the natural bitumens extracted from unheated coals identified as Rocky Mountain coal (RMC), Australian Gippsland Latrobe Eocene coal (GEC), Australian Gippsland Latrobe Cretaceous coal (GCC), and Texas Wilcox lignite (WL), as well as from pyrolysates obtained from heating of these coals. It was found that pentacyclic triterpanes are dominant in GEC, GCC, and WL, whereas diterpanes strongly predominate in the bitumen of RMC, indicating that resin is a more important constituent of RMC than of the other coals and that it releases the diterpenoids at an early stage of diagenesis. It was also found that the composition of diterpanes is different among these coals and that the distributions of sterane and triterpane in the natural bitumen of coals are very different from those of pyrolysates.

Lu, Shan-Tan↗

NASA NTRS1999

Diagnostic for Plasma Enhanced Chemical Vapor Deposition and Etch Systems

In order to meet NASA's requirements for the rapid development and validation of future generation electronic devices as well as associated materials and processes, enabling technologies ion the processing of semiconductor materials arising from understanding etch chemistries are being developed through a research collaboration between Stanford University and NASA-Ames Research Center, Although a great deal of laboratory-scale research has been performed on many of materials processing plasmas, little is known about the gas-phase and surface chemical reactions that are critical in many etch and deposition processes, and how these reactions are influenced by the variation in operating conditions. In addition, many plasma-based processes suffer from stability and reliability problems leading to a compromise in performance and a potentially increased cost for the semiconductor manufacturing industry. Such a lack of understanding has hindered the development of process models that can aid in the scaling and improvement of plasma etch and deposition systems. The research described involves the study of plasmas used in semiconductor processes. An inductively coupled plasma (ICP) source in place of the standard upper electrode assembly of the Gaseous Electronics Conference (GEC) radio-frequency (RF) Reference Cell is used to investigate the discharge characteristics and chemistries. This ICP source generates plasmas with higher electron densities (approximately 10(exp 12)/cu cm) and lower operating pressures (approximately 7 mTorr) than obtainable with the original parallel-plate version of the GEC Cell. This expanded operating regime is more relevant to new generations of industrial plasma systems being used by the microelectronics industry. The motivation for this study is to develop an understanding of the physical phenomena involved in plasma processing and to measure much needed fundamental parameters, such as gas-phase and surface reaction rates. species concentration, temperature, ion energy distribution, and electron number density. A wide variety of diagnostic techniques are under development through this consortium grant to measure these parameters. including molecular beam mass spectrometry (MBMS). Fourier transform infrared (FTIR) spectroscopy, broadband ultraviolet (UV) absorption spectroscopy, a compensated Langmuir probe. Additional diagnostics. Such as microwave interferometry and microwave absorption for measurements of plasma density and radical concentrations are also planned.

Cappelli, Mark A.↗

NASA NTRS2000

Research Activities at Plasma Research Laboratory at NASA Ames Research Center

In order to meet NASA's requirements for the rapid development and validation of future generation electronic devices as well as associated materials and processes, enabling technologies are being developed at NASA-Ames Research Center using a multi-discipline approach. The first step is to understand the basic physics of the chemical reactions in the area of plasma reactors and processes. Low pressure glow discharges are indispensable in the fabrication of microelectronic circuits. These plasmas are used to deposit materials and also etch fine features in device fabrication. However, many plasma-based processes suffer from stability and reliability problems leading to a compromise in performance and a potentially increased cost for the semiconductor manufacturing industry. Although a great deal of laboratory-scale research has been performed on many of these processing plasmas, little is known about the gas-phase and surface chemical reactions that are critical in many etch and deposition processes, and how these reactions are influenced by the variation in operating conditions. Such a lack of understanding has hindered the development of process models that can aid in the scaling and improvement of plasma etch and deposition systems. Our present research involves the study of such plasmas. An inductively-coupled plasma (ICP) source in place of the standard upper electrode assembly of the Gaseous Electronics Conference (GEC) radio-frequency (RF) Reference Cell is used to investigate the discharge characteristics. This ICP source generates plasmas with higher electron densities and lower operating pressures than obtainable with the original parallel-plate version of the GEC Cell. This expanded operating regime is more relevant to new generations of industrial plasma systems being used by the microelectronics industry. The research goal is to develop an understanding of the physical phenomena involved in plasma processing and to measure much needed fundamental parameters, such as gas phase and surface reaction rates, species concentration, temperature, ion energy distribution, and electron number density.

Sharma, S. P.↗

NASA NTRS2001

The Importance of Optical Pathlength Control for Plasma Absorption Measurements

An inductively coupled GEC Cell with modified viewing ports has been used to measure in-situ absorption in CF4 plasmas via Fourier Transform Infrared Spectroscopy, and the results compared to those obtained in a standard viewport configuration. The viewing ports were modified so that the window boundary is inside, rather than outside, of the GEC cell. Because the absorption obtained is a spatially integrated absorption, measurements made represent an averaging of absorbing species inside and outside of the plasma. This modification is made to reduce this spatial averaging and thus allow a more accurate estimation of neutral species concentrations and temperatures within the plasmas. By reducing this pathlength, we find that the apparent CF4 consumption increases from 65% to 95% and the apparent vibrational temperature of CF4 rises by 50-75 K. The apparent fraction of etch product SiF4 decreases from 4% to 2%. The data suggests that these density changes may be due to significant temperature gradients between the plasma and chamber viewports.

Cruden, Brett A.↗

NASA NTRS1998

In situ CF3 Detection in Low Pressure Inductive Discharges by Fourier Transform Infrared Spectroscopy

The detection of CF(x) (x=1-3) radicals in low pressure discharges using source gases such as CF4 and CHF3 is of importance to the understanding of their chemical structure and relevance in plasma based etching processes. These radicals are known to contribute to the formation of fluorocarbon polymer films, which affect the selectivity and anisotropy of etching. In this study, we present preliminary results of the quantitative measurement of trifluoromethyl radicals, CF3, in low pressure discharges. The discharge studied here is an inductively (transformer) coupled plasma (ICP) source in the GEC reference cell, operating on pure CF4 at pressures ranging from 10 - 100 mTorr, This plasma source generates higher electron number densities at lower operating pressures than obtainable with the parallel-plate capacitively coupled version of the GEC reference cell. Also, this expanded operating regime is more relevant to new generations of industrial plasma reactors being used by the microelectronics industry. Fourier transform infrared (FTIR) spectroscopy is employed to observe the absorption band of CF3 radicals in the electronic ground state X2Al in the region of 1233-1270/cm. The spectrometer is equipped with a high sensitivity HgCdTe (MCT) detector and has a fixed resolution of 0.125/cm. The CF3 concentrations are measured for a range of operating pressures and discharge power levels.

Kim, J. S.↗

NASA NTRS2014

On the Variability of Wilson Currents by Storm Type and Phase

Storm total conduction currents from electrified clouds are thought to play a major role in maintaining the potential difference between the earth's surface and the upper atmosphere within the Global Electric Circuit (GEC). However, it is not entirely known how the contributions of these currents vary by cloud type and phase of the clouds life cycle. Estimates of storm total conduction currents were obtained from data collected over two decades during multiple field campaigns involving the NASA ER-2 aircraft. In this study the variability of these currents by cloud type and lifecycle is investigated. We also compared radar derived microphysical storm properties with total storm currents to investigate whether these storm properties can be used to describe the current variability of different electrified clouds. The ultimate goal is to help improve modeling of the GEC via quantification and improved parameterization of the conduction current contribution of different cloud types.

Deierling, Wiebke↗

DOE OSTI2020

Continued Validation Studies using the MOOSE Framework for Plasma Simulation with Electromagnetics

Resources and tools for the modeling and simulation of low-temperature plasma (LTP) discharges are increasingly vital to progress in the field in order to properly characterize and study complex source designs and plasma chemistries beyond the scope of traditional diagnostics. Open-source software provides powerful platforms for this work and can enable community-driven LTP R&D. Within the Multiphysics Object-Oriented Simulation Environment (MOOSE) open-source framework [1], capabilities have been demonstrated in the areas of plasma fluids (Zapdos [2]), plasma chemistry (CRANE [3]), and general electromagnetic wave theory (Electromagnetic Library for Kinetics & fluids [ELK] [4]). ELK has since been coupled to Zapdos/CRANE to enable fully coupled electromagnetic plasma simulations. This talk will detail the continued validation efforts and discuss Zapdos-ELK-CRANE code coupling with various-low temperature plasma sources. The impact of fully coupled electromagnetics on process parameters (e.g., temperature and electron/ion energy) versus an electrostatic description will also be discussed. [1] Permann et al., SoftwareX, 11 (2020) 100430. [2] Lindsay et al., J. Phys. D: Appl. Phys. 49 (2016) 235204. [3] Keniley et al., Talk, GEC Session DT3.00002 (2019). [4] Icenhour et al., Talk, GEC Session RR1.00006 (2019). Acknowledgements: INL Graduate Fellowship Program, NSF SI2 Grant 1740300, U.S. Dept. of Energy Office of Science Graduate Student Research Program

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2020

Materials Data on CsGe by Materials Project

GeCs crystallizes in the cubic P-43n space group. The structure is three-dimensional. there are two inequivalent Cs sites. In the first Cs site, Cs is bonded in a 6-coordinate geometry to six Ge atoms. There are three shorter (3.77 Å) and three longer (4.03 Å) Cs–Ge bond lengths. In the second Cs site, Cs is bonded in a 6-coordinate geometry to six Ge atoms. There are a spread of Cs–Ge bond distances ranging from 3.64–4.04 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 9-coordinate geometry to six Cs and three equivalent Ge atoms. All Ge–Ge bond lengths are 2.61 Å. In the second Ge site, Ge is bonded in a 9-coordinate geometry to six Cs and three equivalent Ge atoms. There are two shorter (2.60 Å) and one longer (2.63 Å) Ge–Ge bond lengths.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on CsGe by Materials Project

GeCs crystallizes in the tetragonal I4_1/acd space group. The structure is three-dimensional. there are two inequivalent Cs sites. In the first Cs site, Cs is bonded in a 12-coordinate geometry to eight equivalent Ge atoms. There are a spread of Cs–Ge bond distances ranging from 3.88–4.08 Å. In the second Cs site, Cs is bonded in a 6-coordinate geometry to six equivalent Ge atoms. There are four shorter (3.91 Å) and two longer (4.02 Å) Cs–Ge bond lengths. Ge is bonded in a distorted q6 geometry to seven Cs and three equivalent Ge atoms. All Ge–Ge bond lengths are 2.63 Å.

36 MATERIALS SCIENCE↗

NASA NTRS1986

Translucent molecular clouds: Theory and observations

Few suitable stars behind molecular clouds have been identified. A limited survey was performed of interstellar lines toward highly reddened stars in the southern sky, using the ESO 1.4 m CAT telescope with a Reticon detector, and the Cerro Tololo 4 m telescope equipped with a GEC charge coupled device (CCD) detector. Because of the reduced extinction at longer wavelengths, molecules were searched for with transitions in the red part of the spectrum such as C2 and CN. For some lines-of-sight for which C2 was detected, the 4300 A line of CH was also observed. Absorption lines of interstellar C2 around 8750 A were detected in the spectra of about 1/4 of the 36 observed stars. The inferred C2 column densities range between 10 to the 13th power and 10 to the 14th power sq. cm., and are up to an order of magnitude larger than those found for diffuse clouds. The observed column densities of CH correlate very well with those of C2 over this range. In contrast, the measured column densities of CN vary by orders of magnitude between the various regions, and they do not correlate with those of C2 and CH. The observed rotational population distribution of C2 also provides information about the physical conditions in the clouds. Models of translucent molecular clouds have been constructed along the lines described by van Dishoeck and Black (1986) for diffuse clouds. The models compute accurately the fractions of atomic and molecular hydrogen as functions of depth into the clouds, as well as the excitation of H2 by ultraviolet pumping. They also incorporate a detailed treatment of the photodissociation processes of the molecules (cf. van Dishoeck 1986), which play an important role in the chemistry up to depths of about 3 mag.

Vandishoeck, E. F.↗

NASA NTRS1990

Unexpected effects of a trap in CCD echelle spectra of B-type stars

Because of the nature of echelle spectra, cosmetic defects such as traps may mimic real spectral features. An example from spectra taken at CTIO with a GEC CCD is presented, and it is shown how the affected pixels can be eliminated from the reduced spectrum, at a slight cost in signal-to-noise ratio.

Morrison, Nancy D.↗