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At least 19 records

Visualization of Space-Time Ambiguities to be Explored by NASA GEC Mission with a Critique of Synthesized Measurements for Different GEC Mission Scenarios

The Grant supported research addressing the question of how the NASA Solar Terrestrial Probes (STP) Mission called Geospace electrodynamics Connections (GEC) will resolve space-time structures as well as collect sufficient information to solve the coupled thermosphere-ionosphere- magnetosphere dynamics and electrodynamics. The approach adopted was to develop a high resolution in both space and time model of the ionosphere-thermosphere (I-T) over altitudes relevant to GEC, especially the deep-dipping phase. This I-T model was driven by a high- resolution model of magnetospheric-ionospheric (M-I) coupling electrodynamics. Such a model contains all the key parameters to be measured by GEC instrumentation, which in turn are the required parameters to resolve present-day problems in describing the energy and momentum coupling between the ionosphere-magnetosphere and ionosphere-thermosphere. This model database has been successfully created for one geophysical condition; winter, solar maximum with disturbed geophysical conditions, specifically a substorm. Using this data set, visualizations (movies) were created to contrast dynamics of the different measurable parameters. Specifically, the rapidly varying magnetospheric E and auroral electron precipitation versus the slower varying ionospheric F-region electron density, but rapidly responding E-region density.

Sojka, Jan J.↗

Visualization of Space-Time Ambiguities to be Explored by the NASA GEC Mission with a Critique of Synthesized Measurements for Different GEC Mission Scenarios

The objective of this grant was to study how a multi-satellite mission configuration can be optimized for maximum exploratory scientific return. NASA's Solar Terrestrial Probe (STP) concept mission Geospace Electrodynamic Connections (GEC) was the target mission for this pilot study. GEC prime mission characteristics were two fold: (i) a series of three satellites in the same orbit plane with differential spacing, and (ii) a deep-dipping phase in which these satellites could dip to altitudes as low as 130 km to explore the lower ionosphere and thermosphere. Each satellite would carry a full suite of plasma and neutral in-situ sensors and have the same dipping capability. This latter aspect would be envisaged as a series, up to 10, of deep-dipping campaigns, each lasting 10 days during which the perigee would be lowered to the desired probing depth. The challenge in optimization is to establish the scientific problems that can best be addressed by varying or selecting satellite spacing during a two-year mission while also interspersing, in this two year time frame, the deep-dipping campaigns. Although this sounds like a straightforward trade-off situation, it is complicated by the orbit precession in local time, the location of perigee, and that even the dipping campaigns will have preferred satellite spacing requirements.

Sojka, Jan J.↗

Thermodynamics and kinetics of 2D g-GeC monolayer as an anode materials for Li/Na-ion batteries

Development of high capacity anode materials is one of the essential strategies for next-generation high-performance Li/Na-ion batteries. Rational design, using density functional theory, can expedite the discovery of these anode materials. Here, we propose a new anode material, germanium carbide, g-GeC, for Li/Na-ion batteries. Our results show that g-GeC possesses both benefits of the high stability of graphene and the strong interaction between Li/Na and germanene. The single-layer germanium carbide, g-GeC, can be lithiated/sodiated on both sides yielding Li 2 GeC and Na 2 GeC with a storage capacity as high as 633 mA h/g. Besides germagraphene’s 2D honeycomb structure, fast charge transfer, and high (Li/Na)-ion diffusion and negligible volume change further enhance the anode performance. These findings provide valuable insights into the electronic characteristics of newly predicted 2D g-GeC nanomaterial as a promising anode for (Li/Na)-ion batteries.

25 ENERGY STORAGE↗

Orbit Optimization for the Geospace Electrodynamics Connections (GEC) Mission

The Geospace Electrodynamics Connections (GEC) mission plan is to launch multiple spacecraft to perform in-situ atmospheric science in the lower ionosphere. There is limited experience in this low altitude region with the Atmospheric Explorer-C (AE-C) being the last spacecraft to explore this region in 1973. AE-C flew an eccentric orbit using maneuvers to lower its perigee to near 130 km at various times during its mission. GEC will advance the science performed by AE-C by performing multiple low-perigee, atmospheric dipping campaigns for extended durations. AE-C kept its perigee near 130 km for only a total of roughly 1 day. Furthermore, GEC plans to carry a more diverse suite of instruments and will be able to capture different temporal and spatial phenomena through the use of multiple spacecraft flying in a string of pearls formation. The mission analysis for GEC has been broken into two parts: the analysis of the parking orbit with the dipping campaigns and the examination of the multi-satellite dynamics of the GEC constellation. The analysis described in this paper examines the capability to meet the requirements necessary to support the 10 dipping campaigns using a single spacecraft as a representative of all three in the constellation. Further analysis is being performed to analyze the multi-satellite nature of the GEC mission.

Mesarch, Michael A.↗

Understanding Plasma Interactions with the Atmosphere: The Geospace Electrodynamic Connections (GEC) Mission

The Geospace Electrodynamic Connections (GEC) mission is a multispacecraft Solar-Terrestrial Probe that has been specifically designed to advance the level of physical insight of our understanding of the coupling among the ionosphere, thermosphere, and magnetosphere. GEC is NASA's fifth Solar-Terrestrial Probe. Through multipoint measurements in the Earth's ionosphere-thermosphere (I-T) system, GEC will (i) discover the spatial and temporal scales on which magnetospheric energy input into the I-T region occurs, (ii) determine the spatial and temporal scales for the response of the I-T system to this input of energy, and (iii) quantify the altitude dependence of the response.

Source record↗

Relationships among diurnal variations of polar night cloud, precipitation, surface temperatures, and the fair-weather return current of the global electric circuit (GEC)

Over the past five years (June 2017-current), the vertical electric field (E z ) as well as numerous cloud, precipitation and radiation properties have been monitored at the Department of Energy-Atmospheric Radiation Measurement (DOE ARM) North Slope of Alaska (NSA) field site. Comparisons between the composite diurnal averaged fair-weather E z , and composite ceilometer derived cloud base height during the polar night, reveal a significant correlation between the parameters (r = 0.62), supporting previous studies that there is high correlation between local electric field and cloud properties. With the use of extensive instrumentation at the site, such as the Micro Pulse Lidar (MPL), Ka-band Zenith Radar (KAZR), ceilometer, SKYRAD, Precipitation Imaging Package (PIP), among others, this study provides a more comprehensive examination of the diurnal cycle of cloud and precipitation properties along with the localized fair-weather return current of the larger Global Electric Circuit (GEC) system. Comparisons between the composite diurnal averaged fair-weather E z , and cloud thickness, maximum column backscatter, and precipitation particle counts all show similar diurnal variability during the polar night, indicating that during the largest magnitude fair weather E z time periods, clouds bases tend to be higher, clouds are thicker, have a larger column backscatter, and display more precipitating particles. Furthermore, a slight diurnal variability in the polar night surface temperature was found to be highly correlated (r = 0.87) to the longwave downwelling irradiance measured by SKYRAD, indicating that the variations in the physical properties of local clouds could modulate the diurnal polar night surface temperature variability on the order of 0.5 °C/day. In conclusion, these findings emphasize the importance and global nature of the GEC system, with the global aggregate of thunderstorms and electrified clouds potentially influencing polar night cloud properties as well as diurnal wintertime polar surface temperature variation.

54 ENVIRONMENTAL SCIENCES↗

Materials Data on GeC by Materials Project

GeC is Zincblende, Sphalerite structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Ge4+ is bonded to four equivalent C4- atoms to form corner-sharing GeC4 tetrahedra. All Ge–C bond lengths are 1.99 Å. C4- is bonded to four equivalent Ge4+ atoms to form corner-sharing CGe4 tetrahedra.

36 MATERIALS SCIENCE↗

Materials Data on GeC by Materials Project

GeC is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ge4+ is bonded to six equivalent C4- atoms to form a mixture of edge and corner-sharing GeC6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ge–C bond lengths are 2.19 Å. C4- is bonded to six equivalent Ge4+ atoms to form a mixture of edge and corner-sharing CGe6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗

Enhancement of X-ray performance with new GEC charged coupled devices (CCD)

Samples of two GEC charge coupled devices with enhanced X-ray performance have been tested. The P8607, fabricated with reduced linear dimensions, gives the lowest detector noise reported for Fe-55 with a CCD. The deep depletion device P8600-HR gives the best combination of energy resolution and quantum efficiency at 6 keV. The energy resolution vs quantum efficiency trade-off curve are discussed.

Schwartz, D. A.↗

Fourier Transform Infrared Spectroscopy of CF4 on the GEC Reference Cell

Fourier Transform Infrared Spectroscopy (FTIR) has been used to characterize inductively coupled CF4 plasmas in a GEC Reference Cell in-situ In examining these FTIR spectra, several assumptions and approximations of FTIR analysis are addressed. This includes the density dependence of cross-sections, non-linear effects in the addition of overlapping bands and the effect of spatial variations in density and temperature, This analysis demonstrates that temperatures extracted from MR spectra may provide a poor estimate of the true neutral plasma temperature. The FTIR spectra are dominated by unreacted CF, accounting for 40-60% of the gas products. The amount of CF4 consumption is found to have a marked dependence on power, and is nearly independent of pressure in the range of 10-50 mtorr. Small amounts of C2F6 are observed at low power. Also observed are etching products from the quartz window SiF4 COF2 and CO which occur in approximately equal ratios and together account for less than 10% of the gas. The concentrations of these species are nearly independent of pressure. CFx radicals are below the detection limit of this apparatus (approx. 1012/cc).

Rao, M. V. V. S.↗

Langmuir Probe Measurements in an Inductively Coupled GEC Reference Cell Plasma

Measurements of electron number density, electron temperature, and electron energy distribution function (EEDF) using a compensated Langmuir probe have been performed on an inductively (transformer ) coupled Gaseous Electronics Conference (GEC) reference cell plasma. The plasma source is operated with CH4, CF4, or their mixtures with argon. The effect of independently driving the electrode supporting the wafer on the probe data is studied. In particular, we find that the plasma structure depends on the phase in addition to the magnitude of the power coupled to the electrode relative to that of the transformer coil. The Langmuir probe is translated in a plane parallel to the electrode to investigate the spatial structure of the plasma. The probe data is also compared with fluid model predictions.

Ji, J. S.↗

Orbit Optimization For The Geospace Electrodynamics Connections (GEC) Mission

Part of NASA's Solar Terrestrial Probe line of missions, the Geospace Electrodynamics Connections (GEC) mission will deploy a formation of three spacecraft to perform in-situ atmospheric research in the low Ionosphere-Thermosphere region. These spacecraft will fly together in a %tring-of-pearls formation with variable spacings ranging from 10 seconds to one-quarter of an orbit at perigee. Over the course of its two-year mission, the three spacecraft will perform ten, 1-week dipping campaigns whereby they maneuver to lower their perigee to near 134 km. Using available launch vehicle performance data, an optimal parking orbit of 222 x 1525 km was found to maximize the dry mass available while providing enough propellant to perform the ten deep-dipping campaigns over its two-year mission. The results were used to create multi-variable contour plots containing the orbit perigee, the orbit apogee, spacecraft dry mass, propellant mass, and T500 (a science data collection figure of merit that tabulates the cumulative time spent below 500 km). These plots illustrate how the mission can trade off science return relative to the cost in dry mass and propellant. Other optimal solutions such as minimum propellant or maximum T500 were found to either limit the science data collection or to be dry mass limiting, respectively. Sensitivity analyses were performed to find new optimal (maximum dry mass) solutions if the number of campaigns changed, if the coefficient of drag (CD) were different, and if the propellant specific impulse were increased. A surprising result showed that the dry mass and T500 were both increased if the number of campaigns decreased. Changes in CD provided the expected results - raising CD lowered both the dry mass and T500 while lowering CD raised both the dry mass and T500. Increases in the propellant specific impulse had the expected outcome of raising the dry mass and lowering the propellant load but there was no change in the T500 figure of merit. The orbit optimization was performed parametrically using a Matlab(TradeMark) script and validated using FreeFlyer(TradeMark), a commercial orbit analysis tool. ,

Mesarch, Michael A.↗

Salvage Mastectomy Versus Second Conservative Treatment for Second Ipsilateral Breast Tumor Event: A Propensity Score-Matched Cohort Analysis of the GEC-ESTRO Breast Cancer Working Group Database

Second conservative treatment has emerged as an option for patients with a second ipsilateral breast tumor event after conserving surgery and breast irradiation. We aimed to address the lack of evidence regarding second breast event treatment by comparing oncologic outcomes after conservative treatment or mastectomy.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

GEC Ferranti piezo vibratory gyroscope

Prototypes of a piezo-electric vibratory angular rate transducer (gyroscope) (PVG) have been constructed and evaluated. The construction is on the lines suggested by Burdess. The sensitive element is a cylinder of radially poled piezo-electric ceramic. The cylinder is metallized inside and out, and the outer metallization is divided into eight electrodes. The metallization on the inside is earthed. A phase locked loop, using pairs of the electrodes, causes the cylinder to vibrate in one of its two fundamental, degenerate modes. In the presence of rotation, some of the vibration is coupled into the outer mode. This can be detected, or suppressed with a closed-up technique and provides a measure of rotation rate. The gyroscope provides a number of advantages over rotating mass and optical instruments: low size and mass, lower power consumption, potentially high reliability, potentially good dormancy, low cost and high maximum rate.

Nuttall, J. D.↗

Detection of Chamber Conditioning by CF4 in the GEC Cell

During oxide etch processes, buildup of fluorocarbon residues on reactor sidewalks can cause to drift and will necessitate time for conditioning and cleaning of the reactor. Various measurements in CF4 and Ar plasmas are made in an attempt to identify a metric able to indicate the chamber condition. Mass spectrometry and a Langmuir probe shows that the buildup of fluorocarbon films on the reactor surface causes a decrease in plasma floating potential, plasma potential, and ion energy in argon plasmas. This change in floating potential is also observed in CF4 plasma operation, and occurs primarily during the first hour and a half of plasma operation. A slight rise in electron density is also observed in the argon plasmas. Because the change is seen in an argon plasma, it is indicative of altered physical, not chemical, plasma-surface interactions. Specifically, the insulating films deposited on metal surfaces alter the electromagnetic fields seen by the plasma, affecting various parameters including the floating potential and electron density. An impedance probe placed on the inductive coil shows a slight reduction in plasma impedance due to this rising electron density. The optical emission of several species, including CF, C2, atomic Si and atomic C, is also monitored for changes in density resulting from the buildup of film on the chamber wall. Changes in the optical emission spectrum are comparable to the noise levels in their measurement.

Cruden, Brett A.↗

Ion Energy and Ion Flux Distributions of CF4/Ar/O2 Inductively Coupled Plasmas in a GEC Cell

Knowledge of ion kinetics in plasma processing gas mixtures, such as CF4:Ar:O2, is important for understanding plasma assisted etching and deposition of materials. Ion energies and ion fluxes were measured in this mixture for 80:10:10, 60:20:20, and 40:30:30 mixture ratios in the pressure range of 10-50 mTorr, and at 200 and 300 W of RF power. Ions from plasma, sampled through a 10 micron orifice in the center of the lower plane electrode, were energy and mass analyzed by a combination of electrostatic energy and quadrupole mass filters. CFx(+) (x = 1 - 3), F2(+), F(+), C(+) from CF4, Ar(+) from Ar, and O2(+) and O(+) from O2, and by-product ions SiFx(+)(x = 1 - 3) from etching of quartz coupling window, COFx(+)(x = 1 - 3), CO(+), CO2(+), and OF(+) were detected. In all conditions ion flux decreases with increase of pressure but increase with increase of RF power. Ar(+) signal decreases with increase of pressure while CF3(+), which is the dominant ion at all conditions, increases with increase in pressure. The loss mechanism for Ar(+) and increase of CF3(+) is due to large cross section for Ar(+) + CF4 yields Ar + CF3(+) + F. Ion energies, which range from 15-25 eV depending on plasma operating conditions, are nearly Gaussian. By-product ion signals are higher at lower pressures indicating stronger plasma interaction with quartz window.

Rao, M. V. V. S.↗

Responses of the AC/DC Global Electric Circuit to Volcanic Electrical Activity in the Hunga Tonga-Hunga Ha'apai Eruption on 15 January 2022

Responses of the AC and DC global electric circuits (GECs) to the large eruption of the Hunga Tonga-Hunga Ha'apai (HT-HH) volcano on 15 January 2022 are discussed. The AC-related investigation is based on Schumann resonance (SR) measurements from six stations on four continents. The DC-related investigation utilizes atmospheric electric field (potential gradient, PG) measurements from six recording stations in Europe and the USA. According to data from the GLD360 and WWLLN lightning detection networks, the peak lightning stroke rate, 83/s, was dominated by negative polarity lightning, but the distributions of positive and negative lightning discharges in latitude and longitude around the volcano differed. A global intensification of SR is apparent in connection with the enhanced lightning activity caused by the eruption. SR data-based results confirm that the lightning activity in the eruption dominated the naturally occurring global activity for a period of about 1 hr. The highly localized increase in lightning activity over HT-HH was a unique point source of SR excitation. PG measurements suggest that impulse-like charging of the DC GEC, by ~15%, via negative cloud-to-ground lightning strokes took place twice during the eruption. A time constant of 7 or 8 min has been inferred for near-surface PG changes due to these enhancements. This could be the first direct measurement of the time constant of the GEC near the Earth's surface, as well as the first observation of the direct charging of the DC GEC by a unique atmospheric electrified source.

58 GEOSCIENCES↗