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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Electrostriction of a Near-Critical Fluid in Microgravity

We used interferometry to measure the electrostrictive increase of the density of sulfur hexaflouride (SF6) near its critical point. The results at three temperatures (T(sub c) + 5.0 mK, T(sub c) + 10.0 mK, T(sub c) + 30.0 mK with T(sub c) = 319 K) agree with a calculation based on the Clausius-Mossotti relation and the restricted cubic model equation of state. To measure electrostriction, an inhomogeneous electric field (less than or equal to 26 kV/cm) was applied to the SF6 sample by charging a fine wire that passed through it. These measurements were performed in microgravity so that the small electrostrictive density changes (less than or equal to 3.5 % in this work) would not be masked by the larger stratification of the fluid's density induced by the Earth's gravity. The predicted shifts of the critical temperature and density resulting from the electric field were too small to detect.

Zimmerli, Gregory A.↗
NASA NTRS1996

A Brief Survey of the Equilibrium and Transport Properties of Critical Fluids and the Degree to Which Microgravity is Required for Their Experimental Investigation

The modern theory of second order phase transitions is very successful in calculating the critical exponents as an asymptotic expansion in powers of epsilon = 4 - D, the deviation of D = 3, the spatial dimension of the actual physical system from that of the abstract four-dimensional reference model. This remarkable mathematical 'tour de force' leaves unanswered, however, many fundamental questions concerning the exact nature of how the fluctuations interact. I discuss here some experiments which would help to further our understanding of the equilibrium critical properties. Especially promising would be a measurement of the temperature dependence of the turbidity very close to the critical point. This has the promise of determining the small and elusive but fundamentally important anomalous dimension exponent eta. I also review various ways of measuring the critical transport coefficients and point out some cases where ground based experiments may usefully supplement flight experiments.

Ferrell, Richard A.↗
NASA NTRS1985

Interfacial tension of fluids near critical points and two-scale-factor universality

Measurements of interfacial tension in the critical region of a wide variety of fluids are reviewed. The data are analyzed using theoretical values of the critical exponents to obtain amplitude ratios. Many of the data are consistent within a few percent of sigma(0). Comparison of these amplitude ratios with ratios from a field-theory calculation and from a simulation suggests that the theoretical values are about half the experimental ones. Systematic errors which are the source of this discrepancy are discussed. The data sources and processing procedures of this study are also discussed, pointing out that for liquid-vapor systems the capillary length often has a remarkably simple temperature dependence.

Moldover, M. R.↗
NASA NTRS1992

Study of density distribution in a near-critical simple fluid (19-IML-1)

This experiment uses visual observation, interferometry, and light scattering techniques to observe and analyze the density distribution in SF6 above and below the critical temperature. Below the critical temperature, the fluid system is split up into two coexisting phases, liquid and vapor. The spatial separation of these phases on earth, liquid below and vapor above, is not an intrinsic property of the fluid system; it is merely an effect of the action of the gravity field. At a fixed temperature, the density of each of the coexisting phases is in principle fixed. However, near T sub c where the fluid is strongly compressible, gravity induced hydrostatic forces will result in a gradual decrease in density with increasing height in the sample container. This hydrostatic density profile is even more pronounced in the one phase fluid at temperatures slightly above T sub c. The experiment is set up to study the intrinsic density distributions and equilibration rates of a critical sample in a small container. Interferometry will be used to determine local density and thickness of surface and interface layers. The light scattering data will reveal the size of the density fluctuations on a microscopic scale.

Michels, Teun↗
NASA NTRS1981

Dynamic behavior of continuous cantilevered pipes conveying fluid near critical velocities

The plane motion of a cantilevered pipe conveying fluid is examined when the flow velocity is in the neighborhood of that generating flutter. In contrast to previous studies, the flow velocity is not prescribed as a constant, but is determined from the laws of motion. A system of two nonlinear partial differential equations which are coupled through the nonlinear terms is thereby obtained. The solution is found by the use of the Krylov-Bogoliubov averaging method and the results are discussed indicating the effect of nonlinearities.

Rousselet, J.↗
NASA NTRS1994

Fluids flight hardware

The following are discussed in this viewgraph presentation: Glovebox-2 investigations, study of oscillatory thermocapillary flows and validate physical models on the second U.S. Microgravity Laboratory Mission (USML-2), pool boiling experiment, critical fluid viscosity measurement experiment, Hitchhiker-G typical structural configuration, ZENO-critical fluid light scattering experiment, isothermal dendritic growth experiment, microgravity acceleration environment support, and the space acceleration measurement system (SAMS).

Shaw, Nancy↗
NASA NTRS2003

A 2-D Piston Effect Solution for the Relaxation in the MISTE Cell

When a large density stratification is no longer a problem in a microgravity environment, one would like to increase the sample size in order to increase the signal-to-noise ratio for a specific heat measurement. To reduce the equilibration time associated with the large sample size, we designed a cylindrical cell containing a stack of plates that separate the bulk fluid into 60 equally thin layers. To understand the thermal behavior of the whole cell, we analyzed the thermal behavior of a 2-D composite system of a cylindrical near-critical fluid layer in contact with a cylindrical copper plate. In this 2-D analysis, the circumference boundary of the two cylindrical layers is subjected to a step temperature change. The solution of this 2-D composite system includes the piston effect that speeds up the equilibration in the near-critical fluid layer and the pure diffusion in the copper plate. The results of this analysis indicate that the characteristic length for the equilibration of the stacked cell is determined by an effective thickness of a single fluid layer instead of the total height of the cylindrical cell.

Weilert, Mark↗
NASA NTRS1975

Langevin equation with stochastic damping - Possible application to critical binary fluid

We solve the familiar Langevin equation with stochastic damping to represent the motion of a Brownian particle in a fluctuating medium. A connection between the damping and the random driving forces is proposed which preserves quite generally the Einstein relation between the diffusion and mobility coefficients. We present an application to the case of a Brownian particle in a critical binary mixture.

Jasnow, D.↗
NASA NTRS1976

Spacelab experiment definition study on phase transition and critical phenomena in fluids: Interim report on experimental justification

Pure fluids and fluid mixtures near critical points are identified and are related to the progress of several disciplines. Consideration is given to thermodynamic properties, transport properties, and the complex nonlinear phenomena which occur when fluids undergo phase transitions in the critical region. The distinction is made between practical limits which may be extended by advances in technology and intrinsic ones which arise from the modification of fluid properties by the earth's gravitational field. The kinds of experiments near critical points which could best exploit the low gravity environment of an orbiting laboratory are identified. These include studies of the index of refraction, constant volume specific heat, and phase separation.

Moldover, M. R.↗
NASA NTRS2007

Critical Phenomena in Microgravity: Past, Present, and Future

This review provides an overview of the progress in using the low-gravity environment of space to explore critical phenomena and test modern theoretical predictions. Gravity-induced variations in the hydrostatic pressure and the resulting density gradients adversely affect ground-based measurements near fluid critical points. Performing measurements in a low-gravity environment can significantly reduce these difficulties. A number of significant experiments have been performed in low-Earth orbit. Experiments near the lambda transition in liquid helium explored the regime of large correlation lengths and tested the theoretical predictions to a level of precision that could not be obtained on Earth. Other studies have validated theoretical predictions for the divergence in the viscosity as well as the unexpected critical speeding up of the thermal equilibrium process in pure fluids near the liquid-gas critical point. We describe the scientific content of previously flown low-gravity investigations of critical phenomena as well as those in the development stage, and associated ground-based work.

renormalization-group theory↗
NASA NTRS1977

Concepts and methods for describing critical phenomena in fluids

The predictions of theoretical models for a critical-point phase transistion in fluids, namely the classical equation with third-degree critical isotherm, that with fifth-degree critical isotherm, and the lattice gas, are reviewed. The renormalization group theory of critical phenomena and the hypothesis of universality of critical behavior supported by this theory are discussed as well as the nature of gravity effects and how they affect cricital-region experimentation in fluids. The behavior of the thermodynamic properties and the correlation function is formulated in terms of scaling laws. The predictions of these scaling laws and of the hypothesis of universality of critical behavior are compared with experimental data for one-component fluids and it is indicated how the methods can be extended to describe critical phenomena in fluid mixtures.

Sengers, J. V.↗
NASA NTRS2003

Measurement of Critical Adsorption of Nitrogen near Its Liquid-vapor Critical Point

The density profile of a critical fluid near a solid surface is expected to show an universal shape. This is known as critical adsorption. The measurement of this effect, especially close to the critical point, is often obscured by gravity. We were able to separate the gravitational effect from critical adsorption by using two capacitors, one with a large gap and one with a small gap of approximately 2 m. Within the uncertainty in the measurement, our data, which ranges between 10(exp -3) to 2 x 10(exp -6) in reduced temperatures, is consistent with the predicted power law dependence. This work is carried out in collaboration with Rafael Garcia, Sarah Scheidemantel and Klaus Knorr. It is funded by NASA's office of Biological and Physical Researchunder.

Chan, Moses↗