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Results for “surface oxidation”
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Effects of high CO2 levels on surface temperature and atmospheric oxidation state of the early earth
One-dimensional radiative and photochemical models are used to determine how much CO2 must have been present to maintain a temperate early climate and to examine the consequences that are implied for the controls on atmospheric oxidation state. It is shown that CO2 concentrations of the order of 1000 PAL are required to keep the average surface temperature close to the present value, if albedo changes and heating by reduced greenhouse gases were relatively unimportant. The oxidation state of such a high-CO2, prebiotic atmosphere should have been largely determined by the balance between the H2O2 rainout rate and the rate at which hydrogen escaped to space, with only a weak dependence on the volcanic outgassing rate or on other speculative sources of H2. The implied upper limit on the ground-level O2 mixing ratio is approximately 10 to the -11th and is subject to less uncertainty than the results of previous models.
Oxidation and low cycle fatigue life prediction
When a metallic material is exposed to a high temperature in an ambient atmosphere, oxidation takes place on the metallic surface. The formed oxides (both surface and grain boundary oxides) are mechanically brittle so that if the stress is high enough the oxides will be cracked. The grain boundary oxide formation in TAZ-8A nickel-base superalloy was studied. The effect of oxide crack nucleus on low cycle fatigue life will be analyzed. The TAZ-8A was subjected to high temperature oxidation tests in air under the stress-free condition. The oxidation temperatures were 600, 800, and 1000 C. The oxidation time varies from 10 to 1000 hours.
Oxidized basalts on the surface of Venus: Compositional implications of measured spectral properties
Venera Lander reflectance data are compared with high temperature spectra of the same basaltic materials. The dark, flat unoxidized basalts are still inconsistent with the Venera data in the near-infrared. Basaltic material with a ferric component, however, would satisfy both the increase in reflectance beyond 0.7 microns as well as the dark, relatively colorless character in the visible. Therefore, it is concluded that besaltic surfaces of Venus represented by these measurements either contain minerals with uncommon characteristics, or, more likely, are relatively oxidized.
Oxygen-induced Al surface segregation in Al(x)Ga(1-x)As and the effect of Y overlayers on the oxidation of the Y/Al(x)Ga(1-x)As interface
The oxidation of Al(x)Ga(1-x)As (x = 0.15, AlGaAs) was studied by AES and XPS at 350 C and different oxygen exposures (up to 5 x 10 exp 4 L). Also studied were the effects of yttrium overlayers (theta = 3 ML) on the oxidation of the AlGaAs surface. Substantial oxygen-induced Al surface segregation has been observed for both yttriated and nonyttriated AlGaAs surfaces which increased with increasing oxygen exposure. Also observed is a significant Y-enhanced oxidation of the AlGaAs surface. Oxidation of the yttriated AlGaAs surface was found to be a factor of 4 greater than that of the nonyttriated surface. Also, while oxidation of the nonyttriated AlGaAs yielded mainly Al2O(x) (x less than 3) and only little Ga2O3, the yttriated AlGaAs surface oxide layer was principally Ga2O3 and stoichiometric Al2O3. However, both the yttriated and nonyttriated surfaces were found to contain metallic As within the oxide layer.
Friction at High Sliding Velocities of Oxide Films on Steel Surfaces Boundary-lubricated with Stearic-acid Solutions
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Combustion interaction with radiation-cooled chambers
Over 15 hours of thruster operation at temperatures between 1916 and 2246 C without failure or erosion has been demonstrated using iridium-coated rhenium chamber materials with nitrogen tetroxide/monomethylhydrazine propellants operating over a mixture ratio range of 1.60-2.05. Research is now under way to provide a basic understanding of the mechanisms which make high-temperature operation possible and to extend the capability to a wider range of conditions, including other propellant combinations and chamber materials. Techniques have been demonstrated for studying surface fracture phenomena. These include surface Raman and Auger for study of oxide formation, surface Raman and X-ray diffraction to determine the oxide phase, Auger to study oxide stoichiometry, and sputter Auger to study interdiffusion of alloy species.
Reduction of bacterial dissemination. germicidal activity of ethylene oxide. reduction of bacterial contamination on surfaces third quarterly summary report of progress
Bacteria dissemination reduction, ethylene oxide germicidal activity, and bacteria contamination reduction on surfaces
Oxidation of the Si(100) surface promoted by Sr overlayer - An X-ray photoemission study
The interaction of strontium films with the underlaying Si (100) surface and the Sr-promoted low-temperature oxidation of Si were investigated, using XPS, at three different Sr coverages (theta): theta = 0.55 monolayer (ML), theta = 1 ML, and theta = 1.85 ML. Oxygen adsorption was studied both at room temperature and at 500 C, and at oxygen exposures up to 2 x 10 to the 6th L (1 L = 10 to the -6th torr) and 2 x 10 to the 5th L, respectively. The XPS spectra of the Si2p, O1s, and Sr3d core levels were measured for the atomically clean Si, the Sr-covered Si, and for the Sr-covered Si after each oxygen exposure. Results indicate that Sr interacts with the Si(100) surface forming a strong ionic bond, and that Sr promotes the oxidation of the Si (100) surface.
Surface activation of air oxidation of hydrazine on kaolinite. 2. Consideration of oxidizing/reducing entities in relationship to other compositional, structural, and energetic factors
The rates (previously reported) for the air oxidation of hydrazine on kaolinite and substituent oxides of kaolinite showed a complex dependence on the relative amounts of several structural oxidizing/reducing entities within the reaction-promoting solids. The rates indicated an important role of the clay but no dominant role of any one of the oxidizing/reducing entities. In this paper we review (a) the reaction-promoting activity of these centers as studied in other systems, (b) various spectroscopic results showing interaction between these entities in clays, and (c) reported spectroscopic studies of the complexation between hydrazine and aluminosilicate surfaces as a whole, in an effort to propose a mechanism for the reaction. Whereas some uncertainties remain, the present synthesis concludes that a mechanism operating through single electron/hole transfers and hydrogen atom transfers by discrete centers is adequate to explain the observed rate behaviors including the observed second order dependence of the oxidation rate on catalyst amount. The effects of these operations on the catalyst can result in no alteration of, or complete or partial electronic relaxation of its contingent of trapped separated charge pairs. The degree to which surface complexation as a whole, intercalation, or luminescent processes may also be associated with the reaction cannot be adequately assessed with the information in hand.
Oxidation and emittance of superalloys in heat shield applications
Recently developed superalloys that form alumina coatings have a high potential for heat shield applications for advanced aerospace vehicles at temperatures above 1095C. Both INCOLOY alloy MA 956 (of the Inco Alloys International, Inc.), an iron-base oxide-dispersion-strengthened alloy, and CABOT alloy No. 214 (of the Cabot Corporation), an alumina-forming nickel-chromium alloy, have good oxidation resistance and good elevated temperature strength. The oxidation resistance of both alloys has been attributed to the formation of a thin alumina layer (alpha-Al2O3) at the surface. Emittance and oxidation data were obtained for simulated Space Shuttle reentry conditions using a hypersonic arc-heated wind tunnel. The surface oxides and substrate alloys were characterized using X-ray diffraction and scanning and transmission electron microscopy with an energy-dispersive X-ray analysis unit. The mass loss and emittance characteristics of the two alloys are discussed.
Moderate temperature detector development
P-side backside reflecting constant, photodiode characterization, and photodiode diffusion and G-R currents were investigated in an effort to develop an 8 m to 12 m infrared quantum detector using mercury cadmium telluride. Anodization, phosphorus implantation, and the graded band gap concept were approaches considered for backside formation. Variable thickness diodes were fabricated with a back surface anodic oxide to investigate the effect of this surface preparation on the diffusion limited zero bias impedance. A modeling technique was refined to thoroughly model diode characteristics. Values for the surface recombination velocity in the depletion region were obtained. These values were improved by implementing better surface damage removal techniques.
Build Surface Roughness and Internal Oxide Concentration for Laser Powder Bed Fusion of IN718
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Oxidation of the Martian surface - Constraints due to chemical processes in the atmosphere
Dissociation of water in the Martian atmosphere may supply oxygen to the surface and may result in the formation of minerals such as goethite, as proposed by Huguenin. The supply rate is limited by chemical processes in the atmosphere which regulate the abundance of O2. The net surface sink for atmospheric oxygen can be as large as 33 million atoms per sq cm per sec which compares to the escape rate of 60 million atoms per sq cm per sec.
The production of glow precursors by oxidative erosion of spacecraft surfaces
Erosion rates of organic materials are measured during a recent flight of the shuttle (STS-8). Several forms of carbon and a variety of thermosetting and thermoplastic polymers are exposed to the ram beam of atomic oxygen. Arrhenius energies of about 1000 to 2000 cal/mole were measured from the rate dependencies on temperature. If some simple assumptions are made about the chemical nature of the desorbed species, the data can be used to estimate production rates at surfaces in orbit under different conditions of temperature, oxygen atom flux, and material surface conditions.
A Theoretical and Experimental Study of Boric Oxide Deposition on a Surface Immersed in an Exhaust Gas Stream from a Jet-engine Combustor, Including a Method of Calculating Deposition Rates on Surfaces
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X-Ray Absorption Spectroscopy in High Temperature Oxidation of Metals and Alloys
An experimental technique is described that allows for the joint study of the kinetics and of the oxide structure during the high temperature oxidation of metal surfaces. Oxygen is supplied at the metal through an electrochemical oxygen pump and the oxygen pressure, at the metal surface, is measured during oxidation by a YSZ (yttria stabilized zirconia) oxygen sensor. XAS (x-ray absorption spectroscopy) is performed in fluorescence mode at the cation K edge and after each oxidation step. An appropriate analysis of the XAS spectra could provide information on both the oxidation kinetics and oxide structure. Experimental data on the high temperature oxidation of nickel, cobalt, and Fe(64%)Ni(36%) alloy, at low oxygen pressure, are reported and analyzed according to the proposed data reduction. These results indicate the presented technique to be particularly suitable for studying the hot corrosion of oxide film too thick for common surface spectroscopy (AUGER, ESCA) and too thin for conventional thermogravimetric technique.
Atomic Oxygen Durability Evaluation of a UV Curable Ceramer Protective Coating
The exposure of most silicones to atomic oxygen in low Earth orbit (LEO) results in the oxidative loss of methyl groups with a gradual conversion to oxides of silicon. Typically there is surface shrinkage of oxidized silicone protective coatings which leads to cracking of the partially oxidized brittle surface. Such cracks widen and branch crack with continued atomic oxygen exposure ultimately allowing atomic oxygen to reach any hydrocarbon polymers under the silicone coating. A need exists for a paintable silicone coating that is free from such surface cracking and can be effectively used for protection of polymers and composites in LEO. A new type of silicone based protective coating holding such potential was evaluated for atomic oxygen durability in an RF atomic oxygen plasma exposure facility. The coating consisted of a UV curable inorganic/organic hybrid coating, known as a ceramer, which was fabricated using a methyl substituted polysiloxane binder and nanophase silicon-oxo-clusters derived from sol-gel precursors. The polysiloxane was functionalized with a cycloaliphatic epoxide in order to be cured at ambient temperature via a cationic UV induced curing mechanism. Alkoxy silane groups were also grafted onto the polysiloxane chain, through hydrosilation, in order to form a network with the incorporated silicon-oxo-clusters. The prepared polymer was characterized by H-1 and Si-29 NMR, FT-IR, and electrospray ionization mass spectroscopy. The paper will present the results of atomic oxygen protection ability of thin ceramer coatings on Kapton H as evaluated over a range of atomic oxygen fluence levels.