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At least 235 records · Page 13

Narrowing down sources of high-frequency gravitational waves

Detecting gravitational waves above 100 kHz would constitute a major discovery, as any observable signal would have to arise from new physics within the late universe. Although many technologies have been identified to explore this high-frequency regime, the known landscape of promising sources remains extremely sparse. In this work, we aim to rectify this issue by providing model-independent arguments that highlight the most interesting parts of theory space, while remaining agnostic of the specific signal mechanism. For example, energy-conservation implies that gravitational waves detectable by future experiments well above a MHz would most likely have to originate from within the Solar System. Based on these arguments, we also constrain the physical properties of such sources.

Berlin, Asher [Fermilab] (ORCID:0000000211561482)↗

Marine renewable energy for Arctic observations

Arctic observations are becoming increasingly valuable as researchers investigate climate change and its associated concerns, such as decreasing sea ice and increasing ship traffic. Networks of sensors with frequent sampling capabilities are needed to run forecast models, improve navigation, and inform climate research. Sampling frequency and deployment duration are currently constrained by battery power limitations. In-situ power generation using marine renewable energy sources such as waves and currents can be used to circumvent this constraint. Wave and current resources vary spatially and temporally in the Arctic, with some locations and seasons being better suited for marine renewable energy power generation. Locations and seasons with small resources may still be able to use marine renewable energy because of the low power requirements of the instruments. In this study, we describe the wave and current resources in the Arctic, outline the electricity generation developments that are needed to utilize the resources, and suggest use cases. Wave and current energy converters developed to power observations in the Arctic could also be used to power observations at lower latitudes. Marine renewable energy has the potential to decrease dependence on batteries and improve data collection capabilities in the Arctic; however, this would require the development of new low power technologies that can operate in extreme Arctic environments.

16 TIDAL AND WAVE POWER↗

Reference Site Conditions for Floating Wind Arrays in the United States

Floating offshore wind farm design is highly site-specific, requiring detailed information about the specific conditions of a project area for realistic design studies. Unfortunately, publicly available site condition data for potential floating offshore wind project sites in the United States is scarce. To support U.S. offshore wind research, we developed reference site condition datasets, including metocean and seabed information, for four potential floating wind project areas in the U.S.: Humboldt Bay, Morro Bay, the Gulf of Maine, and the Gulf of Mexico. These datasets were compiled using publicly available data. Our metocean analysis, covering wind, waves, and surface currents, utilized measurement data from 2000 to 2020. Sources included the National Renewable Energy Laboratory’s National Offshore Wind Dataset for wind data, National Data Buoy Center buoys for wave data, and the High Frequency Radar Network for surface currents. These data were integrated into hourly time series used to compute extreme return periods up to 500 years, monthly statistics, and joint probability clusters for fatigue analysis. Soil conditions were evaluated using the usSEABED database and bathymetry grids were interpolated from the NCEI Digital Elevation Model Global Mosaic. In addition to providing curated reference site condition datasets for four U.S. areas, our assessment highlights the need for more publicly available metocean and soil condition data.

17 WIND ENERGY↗

The Remarkable 2024 North Atlantic Mid‐Season Hurricane Lull

Abstract The 2024 North Atlantic (hereafter Atlantic) hurricane season started quickly, with the earliest Category 5 on record (Beryl) and three hurricanes forming through 14 August. Following Ernesto's dissipation on 20 August, the Atlantic hurricane season became extremely quiet during the climatological peak of hurricane season, with only one Category 2 hurricane (Francine) and one tropical storm through 23 September. Several environmental factors likely contributed to this unexpected, prolonged lull. During mid‐to‐late August, subseasonal conditions were broadly favorable for Atlantic hurricanes, but a northward shift in African easterly wave emergence latitude yielded fewer tropical cyclone seed disturbances that also traversed unfavorably cool ocean water. During early‐to‐mid September, subseasonal variability driven by the Madden‐Julian oscillation was less conducive to hurricane activity, with several bouts of increased vertical wind shear across the central Atlantic. Throughout most of the lull, the tropical Atlantic was anomalously dry and subsident, suppressing hurricane formation chances. Plain Language Summary The 2024 North Atlantic (hereafter Atlantic) hurricane season was anticipated to be extremely active, with seasonal forecasts calling for a potentially historic season. Following a busy start including the earliest Category 5 Atlantic hurricane on record (Beryl), the season became very quiet between 20 August–23 September, with only one Category 2 hurricane (Francine) and one tropical storm forming. Following the lull, the Atlantic became extremely busy again, with seven hurricanes forming from 25 September through the end of the season–the most on record for this period. This paper focuses on the surprising lull and attributes it to several different factors, including a late‐August northward shift in African easterly wave tracks (organized thunderstorm complexes spanning thousands of kilometers that often serve as Atlantic hurricane seeds). This northward shift brought these systems out over colder water and into a drier airmass, suppressing their hurricane formation chances. During the first 3 weeks of September, a large‐scale tropical phenomenon known as the Madden‐Julian oscillation, resulted in increased sinking motion, drier mid‐levels and increased vertical wind shear–all of which typically reduce Atlantic hurricane activity. Overall, the lull demonstrates how seed disturbances and other environmental factors can strongly modulate aggregate seasonal tropical cyclone activity. Key Points Following an active start, the 2024 Atlantic hurricane was quiet during the climatological peak with only 1 tropical storm and 1 hurricane The lull was not anticipated by seasonal forecasting agencies, which called for an extremely active 2024 Atlantic hurricane season Factors reducing storm count included a northward shift in African easterly waves, broad‐scale subsidence, and reduced mid‐level moisture

Klotzbach, P J↗

A description of structured waves in shock compressed particulate composites

Dynamic compression of composite materials is of scientific interest because the mechanical mismatch between internal phases challenges continuum theories. Typical assumptions about steady wave propagation and quasi-instantaneous state changes require reexamination along with the need for time-dependent models. To that end, data and models are presented here for the shock compression of an idealized particulate composite. To serve as a generic representative of this material class, a polymer matrix was filled with tungsten particles, ranging from 1 to 50 vol. %. This creates a simple microstructure containing randomly scattered particles with an extreme impedance mismatch to the binding matrix. These materials were parallel plate impact loaded by Al flyers traveling at 1.8–5.0 km/s. Velocimetry provided records of the equilibrium state and the compression wave structure for each case with trends quantified by an empirical fit. The same quantities were also studied as a function of the wave's propagation distance. A homogenized viscoelastic model then made it possible to progress from cataloging trends to making predictions. Starting from a Mie–Gruneisen equation of state, additional time varying terms were added to capture the transient response. After calibration, accurate predictions of the steady wave structure were possible.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Oceanic fronts shape hemispheric contrasts in polar stratospheric extremes

Sudden Stratospheric Warmings (SSWs) and Polar Stratospheric Clouds (PSCs) exhibit striking inter-hemispheric asymmetries: SSWs are frequent in the Arctic but rare in the Antarctic, while PSCs are more persistent in the Antarctic. Although land–sea thermal contrast and orography (LSCO) have been traditionally invoked to explain these asymmetries, here we show using semi-idealized model experiments that even though LSCO strongly impacts the mean state of SSWs and PSCs, it alone cannot fully account for the observed differences. Using model experiments, we reveal that midlatitude oceanic sea surface temperature (SST) fronts represent a crucial supporting additional driver of the hemispheric stratospheric differences. Like LSCO, SST fronts enhance stratospheric convergence of resolved waves, strengthening the Brewer–Dobson Circulation and inducing high-latitude adiabatic warming. This warming significantly enhances Arctic SSW frequency and strongly suppresses PSC formation. Sub-grid-scale non–resolved wave forcing modulates the stratospheric resolved waves effect. The oceanic impact is dominated by North Pacific SST fronts. Our results highlight the indispensable role of SST fronts in shaping Arctic–Antarctic asymmetries in stratospheric dynamics and associated extremes.

Omrani, Nour-Eddine [Univ. of Bergen (Norway)] (OR↗

Effects of Autoionizing Resonances on Wave-Packet Dynamics Studied by Time-Resolved Photoelectron Spectroscopy

Here, we report a combined experimental and theoretical study on the effect of autoionizing resonances in time-resolved photoelectron spectroscopy. The coherent excitation of N 2 by ~14.15 eV extreme-ultraviolet photons prepares a superposition of three dominant adjacent vibrational levels (v'=14–16) in the valence b' 1 $Σ^+_u$ state, which are probed by the absorption of two or three near-infrared photons (800 nm). The superposition manifests itself as coherent oscillations in the measured photoelectron spectra. A quantum-mechanical simulation confirms that two autoionizing Rydberg states converging to the excited A 2 Π u and B 2 $Σ^+_u$ $N^+_2$ cores are accessed by the resonant absorption of near-infrared photons. We show that these resonances apply different filters to the observation of the vibrational wave packet, which results in different phases and amplitudes of the oscillating photoelectron signal depending on the nature of the autoionizing resonance. This work clarifies the importance of resonances in time-resolved photoelectron spectroscopy and particularly reveals the phase of vibrational quantum beats as a powerful observable for characterizing the properties of such resonances.

74 ATOMIC AND MOLECULAR PHYSICS↗

Gravitational Waves from Black Holes in Merging Ultra-Dwarf Galaxies

The origin of the black-hole:black-hole mergers discovered through gravitational waves with for example the LIGO/Virgo collaboration are a mystery. We investigate the idea that some of these black holes originate from the centers of extremely low-mass ultra-dwarf galaxies that have merged together in the distant past at $z>1$. Extrapolating the central black hole to stellar mass ratio suggests that the black holes in these mergers could arise from galaxies of masses $\sim 10^{5} - 10^{6}$ M$_{\odot}\,$. We investigate whether these galaxies merge enough, or too much, to be consistent with the observed GW rate of $\sim 9.7-101$ Gpc$^{-3}$ yr$^{-1}$ using the latest LIGO/Virgo results. We show that in the nearby universe the merger rate and number densities of ultra-dwarf galaxies are too low, by an order or magnitude, to produce these black hole mergers. However, by considering that the merger fraction, merger-time scales, and the number densities of low-mass galaxies all conspire at $z>1-1.5$ to increase the merger rate for these galaxies at higher redshifts we argue that it is possible that some of the observed GW events arise from BHs in the centers of low-mass galaxies. The major uncertainty in this calculation is the dynamical time-scales for black holes in low-mass galaxies. Our results however suggest a very long BH merger time-scale of 4-7 Gyr, consistent with an extended black hole merger history. Further simulations are needed to verify this possibility, however our theory can be tested by searching for host galaxies of gravitational wave events. Results from these searches would will put limits on dwarf galaxy mergers and/or the presence and formation mechanisms of black holes through PopIII stars in the lowest mass galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Climate Dynamics Preceding Summer Forest Fires in California and the Extreme Case of 2018

Recent record-breaking wildfire seasons in California prompt an investigation into the climate patterns that typically precede anomalous summer burned forest area. Using burned-area data from the U.S. Forest Service’s Monitoring Trends in Burn Severity (MTBS) product and climate data from the fifth major global reanalysis produced by the European Centre for Medium-Range Weather Forecasts (ERA5) over 1984–2018, relationships between the interannual variability of antecedent climate anomalies and July California burned area are spatially and temporally characterized. Lag correlations show that antecedent high vapor pressure deficit (VPD), high temperatures, frequent extreme high temperature days, low precipitation, high subsidence, high geopotential height, low soil moisture, and low snowpack and snowmelt anomalies all correlate significantly with July California burned area as far back as the January before the fire season. Seasonal regression maps indicate that a global midlatitude atmospheric wave train in late winter is associated with anomalous July California burned area. July 2018, a year with especially high burned area, was to some extent consistent with the general patterns revealed by the regressions: low winter precipitation and high spring VPD preceded the extreme burned area. However, geopotential height anomaly patterns were distinct from those in the regressions. Extreme July heat likely contributed to the extent of the fires ignited that month, even though extreme July temperatures do not historically significantly correlate with July burned area. While the 2018 antecedent climate conditions were typical of a high-burned-area year, they were not extreme, demonstrating the likely limits of statistical prediction of extreme fire seasons and the need for individual case studies of extreme years.

54 ENVIRONMENTAL SCIENCES↗

Microseismicity Modulation Due To Changes in Geothermal Production at San Emidio, Nevada, USA

Brief cessations of geothermal production can induce seismicity, a phenomenon that has drawn increasing attention in recent years. Such observations are rare, and the underlying mechanism requires careful analysis. In April 2022, a dense seismic and hydrologic monitoring system was deployed at the San Emidio geothermal field, Nevada, to accompany a planned power plant shutdown. Using the dense seismic array data, we detected and located ∼1,800 microseismic events (MSEs) and developed a high-resolution tomographic P-wave velocity model. We observed substantially increased microseismicity during shutdown. Most MSEs occurred on pre-existing normal faults, which are contained within extremely low-velocity zones that are likely damaged, fluid-filled, and hydraulically connected to nearby production wells. Hydrologic data show rapid fluid pressure increases of <60 kPa following the shutdown. We suggest that the cessation of production rapidly increased fluid pressures along pre-existing fault zones, activating critically stressed fault patches and fractures and producing microseismicity.

Guo, Hao [University of Wisconsin-Madison, WI (Uni↗

Extreme Heating of Minor Ions in Imbalanced Solar-wind Turbulence

Minor ions in the solar corona are heated to extreme temperatures, far in excess of those of the electrons and protons that comprise the bulk of the plasma. These highly nonthermal distributions make minor ions sensitive probes of the collisionless processes that heat the corona and power the solar wind. The recent discovery of the "helicity barrier" offers a mechanism in which imbalanced Alfvénic turbulence in low-β plasmas preferentially heats protons over electrons, generating high-frequency, proton-cyclotron-resonant fluctuations. We use the hybrid-kinetic particle-in-cell code Pegasus++ to drive imbalanced Alfvénic turbulence in a 3D low-β plasma with additional passive ion species, He 2+ and O 5+ . A helicity barrier naturally develops, followed by clear phase-space signatures of oblique proton-cyclotron-wave heating and Landau-resonant heating from the imbalanced Alfvénic fluctuations. The former results in characteristically arced ion velocity distribution functions, whose non-bi-Maxwellian features are shown by linear ALPS calculations to be critical to the heating process. Additional features include a steep transition-range electromagnetic spectrum, proton-cyclotron waves propagating in the direction of the imbalance, significantly enhanced proton-to-electron heating ratios, ion temperatures that are considerably more perpendicular with respect to magnetic field, and extreme heating of heavier species in a manner consistent with mass scalings inferred from spacecraft measurements. None of these features are realized in an otherwise equivalent simulation of balanced turbulence. If seen simultaneously in the fast solar wind, these signatures of the helicity barrier would testify to the necessity of incorporating turbulence imbalance in a complete theory for the evolution of the solar wind.

79 ASTRONOMY AND ASTROPHYSICS↗

Dynamic Mooring Field Experiment and Design of a Wave Energy Converter Platform Test System

Abstract This study evaluated a multi-catenary spread mooring system design of a mobile ocean test berth for wave energy converters (WECs), the Ocean Sentinel (OS) instrumentation buoy, through dynamic simulation, numerical analysis, and comparison with measured field motion data of the OS off the OR coast. First, the accuracy of the numerical employed model based on a fully-coupled method of the OS and its mooring lines was validated by comparing predicted mooring tensions to the field measurements. Then, the anchor movability, fatigue damage, and extreme mooring tension of the OS mooring system were analyzed to assess survivability. Field test results show that the numerical model provided accurate predictions of mooring tensions even under environmental conditions of strong wind, current, and waves. Factors affecting the accuracy are discussed. One mooring anchor was shown to have moved significantly during the ocean field test. Mooring fatigue damage was calculated for different levels of sea states. Design strengths of the mooring lines were calculated and analyzed.

Engineering↗

Underground hydrogen storage leakage detection and characterization based on machine learning of sparse seismic data

Underground hydrogen storage (UHS) is considered as a scalable approach for massive storage and seasonal extraction of hydrogen (H 2 ). Although conventional leakage detection and characterization methods based on time-lapse seismic imaging and inversion generally apply to H 2 leakage detection problem, a high-fidelity yet cost effective geophysics approach is still missing to reliably inform leakage location and properties based on very sparse data. In response, we develop a novel supervised machine learning method to detect and characterize H 2 leakage from UHS. The input to our neural network are sparse time-lapse seismic waveforms, while the output from the neural network includes the spatial location and physical properties of a H 2 leakage. Here, we generate high-quality time-lapse waveforms using the elastic-wave equations to train the neural network. We train and validate our machine learning model and find that it attains high accuracy in using extremely sparse time-lapse seismic data to detect and characterize H 2 leakage. Our investigation is the first systematic study that focuses on applying machine learning to subsurface H 2 leakage detection and characterization and could potentially serve as a cost-effective geophysical tool for underground hydrogen leakage detection and characterization with high fidelity.

08 HYDROGEN↗

A Fast Algorithm for Scanning Transmission Electron Microscopy Imaging and 4D-STEM Diffraction Simulations

Scanning transmission electron microscopy (STEM) is an extremely versatile method for studying materials on the atomic scale. Many STEM experiments are supported or validated with electron scattering simulations. However, using the conventional multislice algorithm to perform these simulations can require extremely large calculation times, particularly for experiments with millions of probe positions as each probe position must be simulated independently. Recently, the plane-wave reciprocal-space interpolated scattering matrix (PRISM) algorithm was developed to reduce calculation times for large STEM simulations. Here, we introduce a new method for STEM simulation: partitioning of the STEM probe into “beamlets,” given by a natural neighbor interpolation of the parent beams. This idea is compatible with PRISM simulations and can lead to even larger improvements in simulation time, as well requiring significantly less computer random access memory (RAM). We have performed various simulations to demonstrate the advantages and disadvantages of partitioned PRISM STEM simulations. We find that this new algorithm is particularly useful for 4D-STEM simulations of large fields of view. We also provide a reference implementation of the multislice, PRISM, and partitioned PRISM algorithms.

97 MATHEMATICS AND COMPUTING↗

Radiation by a laser-driven flying-focus electron wave packet

An exact solution of the Dirac equation in the presence of an arbitrary electromagnetic plane wave is found, which corresponds to a focused electron wave packet, with the focus of the wave packet moving at the speed of light in the opposite direction of the average momentum of the electron wave packet (unless the plane wave is so intense to reflect the electron). The photon spectrum emitted by such an electron wave packet in the presence of a linearly polarized plane wave is studied both analytically and numerically. The spectrum is also compared with the one emitted by a single-momentum, plane-wave electron in the case of the electron being initially counterpropagating (on average for the flying-focus case) with the plane wave and within the locally constant field approximation. It is found that if the electron flying-focus wave packet is focused beyond a Compton wavelength, the angular distribution of the emitted radiation along the magnetic field of the electromagnetic plane wave is broader than for an electron with definite momentum. Corresponding the maximum value of the photon yield on the transverse plane is smaller in the flying-focus electron case. This could represent an experimental signature of a laser-driven flying-focus electron wave packet.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Determining the Effects of Neutron Irradiation on the Structural Integrity of Additively Manufactured Heat Exchangers for Very Small Modular Reactor Applications, DOE Final Report (Project # 19-16980)

Auburn University (AU) teamed with the University of Missouri Research Reactor (MURR) and Kansas State University (KSU) to determine how to best use laser-powder bed fusion (L-PBF) additive manufacturing (AM) methods for generating radiation resistant nickel-based superalloys, Inconel alloy 625 and 718, for special purpose reactor (SPR) or very small modular reactor (vSMR) heat-exchangers (HeXs). Compact, conformal, and durable HeXs that are tolerant of extreme environments are needed for supporting the technical maturity of next-generation, portable compact reactors. AM is an enabler for realizing this new wave of HeXs – providing a means to make customizable hot and cold stream architectures with novel flow path geometries (e.g., tortuous channels with non-uniform, asymmetric cross-sections) and reduced layer-to-layer contact resistance (i.e., no separate bonding procedure required). AM further enables a more time/cost efficient means for fabricating SPRs by reducing the number of suppliers required for HeX assembly and allowing for on-site HeX fabrication. The project aim has been to better understand how neutron irradiation affects the microstructure and properties of additively manufactured nickel-based superalloys, to accelerate their safe, reliable use in the modular reactor industry. The major objective was to qualify/quantify the microstructure and microhardness of nickel-based superalloys (including Inconel 718 and 625) additively manufactured via the L-PBF process in the neutron-dosed (irradiated) and non-irradiated states over a course of 3 years. Effects of build orientation during L-PBF and post-AM heat treatments on neutron resistance, microstructure and mechanical properties were also investigated. Neutron damage mechanisms via hardening were characterized. This project combined subject-matter experts in AM, mechanical/microstructure metallic part characterization, and neutron irradiation, as well as unique assets and capabilities at AU and MURR at MU, to ensure project results translated to effectively addressing known gaps in nuclear science and engineering. Parts were fabricated using L-PBF systems readily available at AU. Specimens were then irradiated using MURR facilities; a manipulator equipped hot cell was also used to measure material hardness after dosing. MURR, a 10 MW, light-water nuclear reactor, is the largest, highest powered, highest-flux university owned research reactor in the U.S. The major findings in this project provide evidence that AM can serve as an alternative way to build structural components for future advanced small modular reactors using advanced materials like Inconel 625 (IN625) or Inconel 718 (IN718). After full spectrum neutron irradiation, vertically as-built AM IN625 samples were observed to display better resistance towards radiation-induced-hardening defects relative to traditionally machined metals. A Vickers microhardness tester, using settings of 1 kgf and dwell time of 15 seconds per indentation, was used to measure hardness in this study. The as-built, vertically printed samples experienced 1.2% of radiation hardening vs. 5.25% radiation hardening observed in wrought IN625. Another set of IN625 and IN718 samples were exposed to fast neutron irradiation. It was observed that IN718 showed more resistance towards radiation hardening compared to IN625 samples indicating IN718 had a better performance. Results showed that the IN718 samples experienced less change (-2.5 to 3.24 %) in microhardness. On the other hand, IN625 samples underwent more (0.9 to 7.21%) change in microhardness after fast neutron irradiation. AM IN625 samples were irradiated using an ion (proton) beam in cyclotron. The mechanical properties of AM samples post irradiation were compared with wrought samples. The irradiated region on the samples were tested using nano-hardness indention. It was observed that the beam current and time used in this study generated an annealing effect and thus reduced the hardness of the samples. The sum of the project results provide precious insight into how one may minimize radiation hardening in AM materials while maintaining material property constraints. Results should assist engineers in selecting an appropriate heat treatment for AM nickel-based superalloys for increased radiation resistance. Results should increase confidence levels for adopting AM for building nuclear reactor components which perform the same or better than conventionally manufactured components. Fast neutron irradiation testing provided an accelerated means of obtaining radiation effects without making materials radioactive and difficult to handle.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Statistical imprints of wave-like dark matter on multiply-imaged galaxies in strong cluster lenses from JWST

Wave-like dark matter ($ψ$DM) is an elusive dark matter (DM) candidate. The model, often also called fuzzy or ultralight DM, proposes that DM is an extremely light ($m\sim10^{-22}$ eV) boson and thereby has a kpc-scale de Broglie wavelength. Hence, interference of DM gives rise to sub-galactic density fluctuations that can be studied with strong gravitational lensing. In this paper, we use the residual power spectrum, $\mathrm{P}_δ(k)$, as a probe of $ψ$DM, which quantifies deviations from smooth lensing predictions, measured from multiply-imaged galaxies in strong cluster lenses. The key idea is that imprinted in these deviations are lensing distortions from DM substructure, which can be harnessed statistically to distinguish among DM theories. We simulate JWST-quality mock observations of strong gravitational lensing in galaxy clusters, modeling line-of-sight DM substructure within $ψ$DM and the standard cold dark matter (CDM) paradigms. Using mock deep observations ($\sim$ 20 hours), we find that $\mathrm{P}_δ(k)$ is sensitive to both $ψ$DM particle mass and fluctuation amplitude, and can distinguish $ψ$DM fluctuations from CDM subhalos. We demonstrate that $\mathrm{P}_δ(k)$ can be measured directly from data by modeling the smooth lensing with a local Curved Arc Basis formalism. With realistic modeling systematics, we find a statistically significant separation between $ψ$DM and CDM across $1 \lesssim k \lesssim 11\,\mathrm{kpc}^{-1}$ -- offering an independent probe of the wave-like nature of DM complementary to existing constraints.

Cosmology and Nongalactic Astrophysics (astro-ph.C↗

Direct observation of diamond formation in a shock-compressed high explosive

Understanding the formation timescale and structure of carbonaceous reaction products is critical for modeling the high-pressure equation-of-state of organic materials. We use the National Ignition Facility to shock-compress polycrystalline TATB (C 6 H 6 N 6 O 6 ) samples to ~70–130 GPa and ~4000–5500 K, employing in situ nanosecond X-ray diffraction to probe reaction products and velocimetry to measure transmitted compression wave profiles. Our diffraction data is consistent with the formation of diamond over timescales less than ~60 ns. This represents carbon condensation from a molecular explosive on timescales three times faster than previously reported and the earliest observation of diamond produced from reacting TATB. Reactive flow simulations with explicit chemistry reproduce the observed temporal structure within wave profiles to inform the distribution of P-T states. These findings provide direct evidence of ultrafast diamond formation in a reactive system at extreme conditions and provide new constraints for models of shock and detonation chemistry.

Clarke, Samantha M. [Lawrence Livermore National L↗