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At least 217 records · Page 12

Influence of Surfactants on Noble Metal Liquid-Gas Interface Mass Transfer in Molten Salt Reactors

Noble metals, a group of insoluble fission products (FPs), can accumulate in molten salt reactors (MSRs) and influence system performance and safety through deposition. Upon generation in fission, noble metals are transported by circulating salt and may either deposit on structural surfaces or enter the circulating gas bubble interfaces. While sparging was primarily designed for xenon and krypton removal, the mass transfer of noble metals into bubble interfaces highlights a potential pathway for their transport and partial extraction. The properties of the liquid-gas interface therefore play an important role in noble metal deposition and removal behaviors. Observations from earlier studies suggest that noble metals accumulated at the bubble interface can act as surfactants, making the bubble interface partially immobile. This behavior reduces the mass transfer capacity of circulating bubbles and affects both the overall distribution of noble metals in the loop and their removal efficiency. To investigate the influence of surfactants on noble metal transport, deposition, and extraction behaviors in MSRs, a previously developed and validated species transport model incorporating noble metal interphase mass transfer was used to simulate these behaviors. Two designed cases were studied to predict the distribution of 132Te along the Molten Salt Reactor Experiment (MSRE) loop under different bubble interface conditions. The results show that the mass transfer coefficients at the liquid-gas interface, determined by bubble interface characteristics, significantly influence noble metal distribution within the reactor loop. These findings emphasize the importance of continuously introducing fresh circulating bubbles into the molten salt to improve the removal efficiency of insoluble FPs from the MSR primary loop.

MSR↗

Printed Strain Gauges for High Temperature Applications (>300°C)

The real-time understanding of strain and deformation of materials provides prognostic health monitoring of components of current operational reactors and valuable data that shortens the timeline for the development of new nuclear-relevant materials in test reactor experiments. This report discusses the current development and testing of additively manufactured strain gauges. This has potential to improve the sensor design and manufacturing techniques to meet the requirements of the current and advanced nuclear reactors (i.e., in terms of environment conditions, sample geometry, and materials compatibility). The developmental additively manufactured strain gauges are exposed to separate effects testing (i.e., mechanical strain, high temperature) to determine environmental factors that affect the strain gauge. In addition, sensor qualification methodologies are further developed for determining the reliability and robustness at the interface of the AM strain gauge materials.

36 MATERIALS SCIENCE↗

Initial calculations for source term of Molten Salt Reactors

This paper provides an overview of the current MSR design space and lists unique features of the various designs under consideration. Some general considerations for source terms calculation for Molten Salt Reactors (MSRs) are explained. Applicability and limitations of terminology currently defined for legacy light water reactor (LWR) systems are discussed in the view of MSRs and the need for updated terminology is discussed. Calculations carried out for the Molten Salt Reactor Experiment (MSRE) are discussed with a qualitative comparison to the designs presented. The nature of the fission products (FPs) and actinides for Low enriched uranium, thorium and fast U/Pu fuel cycles employed in representative molten salt reactor systems are discussed. Computational results are obtained from a code (Serpent 2) with online reprocessing. Divergence in source terms when fission product bubbling is demonstrated. The source release for each molten salt reactor during postulated accidents is also presented.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Measure Effects of Molten Halide Salt on Creep Rupture Lifetime for 316H, 709 and 617

Ongoing commercialization of different molten salt reactor concepts can considerably benefit from quantitative information on the impact of molten halide salts on the engineering properties such as creep and fatigue strength of materials of interest. Limited legacy data from the molten salt reactor experiment (MSRE) program showed a significant reduction in creep rupture strength of a Ni-base alloy in molten fluoride salt. This task evaluated the creep behavior of candidate structural materials 316H, 709 and 617 for advanced nuclear reactors under molten halide salt environments at 650, 700 and 750°C respectively. Creep tests were conducted in air, Ar, fluoride (FLiNaK) and chloride (NaCl-MgCl 2 ) salts. The molten salt environment caused a 50% reduction in creep rupture lifetime for 316H in FLiNaK and an 80% reduction in creep rupture lifetime in NaCl-MgCl 2 compared to air exposures. The molten fluoride salt environment resulted in almost a 90% and 50% reduction in creep rupture time for 709 and 617 irrespective of the cover gas environment (air and Ar). Significant differences in the compositional changes between the salt- and air-facing surfaces were observed in the alloy subsurface which might have potentially lead to formation of phases detrimental to the creep behavior.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Validation of Printed Strain Gauges at Moderate Temperatures (up to 300°C)

Strain gauges in material test reactors serve to generate critical mechanical property data for qualifying the performance of reactor components. Resistance based strain gauge technologies are both well established and commercially available; however, they present limitations in terms of reactor experiment conditions, especially in areas where physical space is a challenge. In this work, an additively manufactured capacitance-based strain gauge was printed on a stainless-steel specimen and tested at up to the prototypic pressurized-water reactor operating temperature of 300°C. In addition, a high-temperature resistive strain gauge (RSG) was used to better understand how the RSGs operate, and to provide baseline measurements for comparison against the printed strain gauges. Future development of printed strain gauges will focus on expanding their temperature limits to 500°C and enabling applications currently beyond the capabilities of commercial RSGs.

36 MATERIALS SCIENCE↗

Potential Challenges of HyBlend Storage in a Methane Reservoir Located in Southwestern United States

Hydrogen has been identified as a flexible energy carrier with zero or negative emissions across multiple energy systems. It is possible to utilize hydrogen by storing Hyblend, or hydrogen gas blended with methane, in existing natural gas infrastructure. However, the compatibility of adapting the current CH4 storage strategies to include H2 injection has not been fully demonstrated. It is essential that we understand the impact of H2 gas on the naturally occurring microbial community of subsurface storage reservoirs before deploying large-scale H2-CH4 storage. We designed a series of experiments that allowed us to identify potential geochemical and microbial challenges of HyBlend Storage in existing methane reservoirs. First, we collected and characterized field fluid samples from a methane reservoir located in southwestern United States. Next, we used these field fluid samples to complete a series of short-term reactor experiments at reservoir conditions (80 °C and ~1,000 psi) for a natural gas (100% CH4) and HyBlend(80% CH4/20% H2) storage environment to measure the transformation of gas content. We conducted both biotic and abiotic (sterilized) measurements to accurately understand and decouple abiotic and microbially driven processes. Overall, we found that our field sample was characterized by a diverse microbial community with the metabolic capacity for sulfur reduction, iron reduction, and acetogenesis. Across our reactors, there was minimal change in geochemistry.

hydrogen storage↗

Why matter effects matter for JUNO

In this paper we focus on the Earth matter effects for the solar parameter determination by a medium baseline reactor experiment such as JUNO. We derive perturbative expansions for the mixing angles θ 12 and θ 13 as well as the Δm$^{2}_{21}$ and Δm$^{2}_{31}$ in terms of the matter potential relevant for JUNO. These expansions, up to second order in the matter potential, while simple, allow one to calculate the electron antineutrino survival probability to a precision much better than needed for the JUNO experiment. We use these perturbative expansions to semi-analytically explain and confirm the shift caused by the matter effects on the solar neutrino mixing parameters θ 12 and Δm$^{2}_{21}$ which were previously obtained by a purely numerical χ 2 analysis. Since these shifts do not satisfy the naive expectations and are significant given the precision that can be achieved by the JUNO experiment, a totally independent cross check using a completely different method is of particular importance. We find that these matter effect shifts do not depend on any of the details of the detector characteristics apart from the baseline and earth mass density between reactor(s) and detector, but do depend on the normalized product of reactor neutrino spectrum times the inverse-beta decay cross-section. The results of this manuscript suggests an alternative analysis method for measuring sin 2 θ 12 and Δm$^{2}_{21}$ in JUNO which would be a useful cross check of the standard analysis and for the understanding of the Wolfenstein matter effect. The explanation of these shifts together with a quantitative understanding, using a semi-analytical method, is the principal purpose of this paper.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Extension of Virtual Test Bed Advanced Modeling and Simulation Capabilities for Fusion Energy

The National Reactor Innovation Center (NRIC) was established to accelerate the deployment of novel reactor concepts. This is achieved by providing physical and virtual spaces for building and testing reactor experiments. The Virtual Test Bed (VTB) represents the virtual counterpart to the physical test beds. It is a collaboration with the Department of Energy’s (DOE) Nuclear Energy Advanced Modeling and Simulation (NEAMS) program with the mission to accelerate the deployment of advanced reactors by facilitating the adoption of advanced modeling and simulation (M&S) tools developed by the DOE. This mission has been carried out by the VTB since 2020 by hosting and featuring dozens of advanced fission nuclear reactor models developed by national laboratories and academia. The charter of the NRIC’s definition of advanced reactors also includes fusion nuclear reactors. As the tools developed by the NEAMS program are increasingly used for modeling fusion energy devices, there is an increasing need to host fusion reactor models on the VTB repository. The VTB will be extended in 2024 to support fusion energy modeling and simulation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Potential Risks Associated with Short-Term Hydrogen Storage in Methane Reservoirs

Hydrogen (H2) has been identified as a flexible energy carrier with zero emissions. It is possible to utilize H2 by storing Hyblend, or H2 blended with CH4, in existing natural gas infrastructure. However, the compatibility of adapting the current CH4 storage strategies to include H2 injection has not been fully demonstrated. It is essential that we understand the impact of H2 gas on the naturally occurring microbial community of subsurface storage reservoirs before deploying large-scale H2-CH4 storage. We designed a series of experiments that allowed us to identify potential challenges of HyBlend Storage in existing methane reservoirs (Figure 1). First, we characterized two field fluid samples from a methane reservoir located in Western United States. Next, we used these samples to complete a series of short-term reactor experiments at reservoir conditions for a natural gas (100% CH4) and HyBlend (80% CH4/20% H2) storage environment.

geomicrobiology↗

Thermocouple Testing in Support of the AGR-5/6/7 Experiment

This report documents thermocouple testing performed in IRC Lab C-15 over a period of seven years. This testing supported selection and characterization of the thermocouple set used in the AGR-5/6/7 experiment. The following summary was taken directly from the report. Temperature measurement is a challenging aspect of very high temperature irradiation experiments because commonly used high-temperature commercial thermocouples such as platinum-rhodium (Types S, R, and B) and tungsten-rhenium (Type C), suffer dramatic drift because of neutron-induced transmutation. As a result, these types of thermocouples, which are used routinely for industrial temperature measurements outside of reactors, are used only in very special circumstances for reactor experiments. Conversely, because of their low neutron cross-sections, Type N thermocouples are affected to only a limited extent by neutron irradiation. However, the use of these nickel-based thermocouples is limited when the temperature exceeds 1050°C due to drift arising from minor alloying elements migrating from the thermocouple's metal sheath to the thermoelements. This change in the composition of the thermo-elements results in significant decalibration of the signal. The issues described above were recognized during the early planning stages of the final AGR experiment (designated AGR-5/6/7), and a thermocouple furnace testing program was performed over a seven-year period (2014-2019, 2021) to first select and then characterize the best thermocouple set for the high temperature regions of the AGR-5/6/7 irradiation experiment. The calculated temperature range of the AGR-5/6/7 experiment was 600–1500°C. For temperatures below 1000°C standard Type N thermocouples were deemed adequate. The furnace testing campaign identified two thermocouple types suitable for measuring temperatures above 1000°C, a Mo/Nb thermocouple developed at INL called HTIR-TC, and a Type N thermocouple developed by Cambridge University (called herein Cambridge Type N), which featured a custom high nickel alloy sheath. One of the original goals of the furnace testing program was to identify a thermocouple capable of low drift operation near the peak temperature expected in AGR-5/6/7, i.e., about 1400°C. The HTIR-TC design appeared promising in this regard, however a manufacturing difficulty proved to be a barrier and instead the furnace testing focused on drift performance at 1250°C. The manufacturing difficulty was that the Nb sheaths of the HTIR-TCs experienced extreme embrittlement when heat treated at 1600°C or greater. Heat treatment is needed to stabilize the emf output of this TC type, and the higher the heat treatment temperature the higher the peak temperature of stable operation. Because of the sheath embrittlement the heat treatment temperature had to be lowered to 1450°C resulting in a stable operating temperature of about 1250°C. One of the successes of the furnace testing program was identification of a shortcoming in the heat treatment procedure that had been traditionally used in the production of HTIR-TCs. The shortcoming was that the entire heated length of the HTIR-TC sensor was not being heat treated, but rather only the part of the sensor expected to experience temperatures above 1000°C. The problem manifested itself when the thermocouples were removed from the heat treat furnace and placed in another furnace with a different geometry, their indicated temperatures would be widely scattered, but mostly in the negative direction. The solution was to heat treat the entire heated length of the sensor. Since the deepest immersion depth in the AGR-5/6/7 experiment was about 40 inches, a heat treatment length of 48 inches was used. After this change was implemented, thermocouples which were moved into a new environment with a different temperature profile (i.e., a different furnace), produced accurate temperature measurements. Although assembly of the AGR-5/6/7 experiment was completed in September of 2017 (and irradiation begun in 2018), furnace testing of thermocouples continued in 2018 and 2019. The main purpose of this testing was to establish very long-term drift characteristics of the HTIR and Cambridge Type N thermocouples installed in the experiment. Representative thermocouples from the same lots as those installed in the AGR-5/6/7 experiment were used. Additionally, thermocouples of different designs, (particularly variations on the HTIR-TC design) were "piggy-backed" on this testing program to provide insights for instrumenting future very high temperature irradiation experiments. This two-year testing program demonstrated that HTIR-TCs and Cambridge Type N TCs could operate at 1250°C for up to 10,000 hrs (and in some cases longer) while experiencing negative drifts on the order of 2-4°C/1000 hrs. This performance was considered acceptable given the extreme operating environment the sensors faced.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Chlorine Nuclear Data Evaluation Aided Through New LANSCE Measurements

The collaboration between the Los Alamos National Laboratory Neutron Science Center (LANSCE) and TerraPower LLC enables the enhanced understanding of fast spectrum critical systems consisting of chlorine. Specifically, TerraPower is interested in updating the nuclear data for the stable isotopes of chlorine, 35 Cl and 37 Cl, because these nuclides are the primary constituents of the chloride fuel salt in the Molten Chloride Reactor Experiment (MCRE), for which TerraPower is leading the design. The Cooperative Research and Development Agreement (CRADA) between the parties is funded by DOE’s Office of Nuclear Energy’s Gateway for Accelerated Innovation in Nuclear (GAIN) initiative to provide the nuclear community with access to the technical, regulatory, and financial support necessary to motivate innovative nuclear reactor technologies toward commercialization. New measurements of 35 Cl(n,p total ) and 35 Cl(n,α total ) were completed at LANSCE to constrain the reaction theory models that are used to generate the updated evaluations. The updated evaluations were then tested across the sensitivities of the MCRE by TerraPower to provide direct feedback to the evaluation for application specific sensitivities.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Nuclear Fusion Space Propulsion Research, Experimentation, Theory Development, and Systems Analysis Efforts Led by the NASA Glenn Research Center (1994-2004)

This review paper summarizes work performed from 1994 to 2004 by a several interrelated government, academic, and industry teams led by the NASA Glenn Research Center. The nuclear fusion space propulsion system concept was predicated on a spherical torus reactor, which enabled manned missions to the outer planets in less than one year. Moderate thrust levels (1,000’s lbf)from direct nuclear fusion exhaust plasma via a magnetic nozzle enabled high thrust-to-weight. An entire vehicle conceptual design, including an artificial gravity crew habitat, was created by the NASA Glenn Research Center. The proof of concept experiment test article and facility upgrade was performed at the Ohio State University which also included staff from the Ohio Aerospace Institute and Science Applications International Corporation.The governing equations for the plasma physics theory of magnetic nozzle operation were derived by the Los Alamos National Laboratory. A preliminary investigation of a proof of concept test utilizing Coaxial Helicity Ejection as a means to supply plasma for propulsion at the National Spherical Torus Experiment reactor was outlined by the Princeton Plasma Physics Laboratory. An industry standard on nuclear fusion propulsion conceptual design was created by two AIAA teams. Despite extremely modest funding levels, significant progress was made advancing the state of the art.The result was a coordinated conceptual, theoretical, and experimental design effort to guide fusion space propulsion development.

Nuclear fusion↗

Development of a Computational Framework for Multiphysics Multiphase Species Tracking using NEAMS Tools

This report implements a high-fidelity multiphysics modeling framework using the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program tools to track isotopic species in Molten Salt Reactors (MSRs), with a specific focus on the 91-depletion chain within the Molten Salt Reactor Experiment (MSRE). The model integrates neutronics, thermal-hydraulics, depletion, and thermochemistry to simulate the production, transport, and phase transitions of isotopes under steady-state and transient conditions. The main findings reveal that isotopes such as bromine-91 largely remain in the liquid phase, while others, including krypton-91and yttrium-91, transition to the gas phase, significantly influencing the reactor’s radiological source term. The study also shows that during transients, like a reactivity insertion transient, rapid void formation and the expansion of the liquid-gas interface led to substantial transfers of dissolved isotopes into the gas phase, altering isotope distribution and largely increasing the source term in the off-gas system. Additionally, the research highlights that short-lived isotopes dominate the initial off-gas response during transients, while longer-lived isotopes determine the equilibrium state, underscoring the necessity of dynamic simulations for accurate species tracking and reactor safety analysis. The developed methodology will be applied in the future to the tracking of a larger number of species and introduce other species tracking mechanisms, such as deposition and plating.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Signature Analysis Utilizing a Dynamic Molten Salt Reactor Model for MC&A

Moving from traditional fixed fuel nuclear reactor systems to a mobile, dynamic fuel system that has dissolved special nuclear material in a molten salt is a paradigm shift in several respects. One major consideration is how to develop effective nuclear material controls and accounting for these novel reactor systems. The Molten Salt Reactor Experiment is one example of a critical molten salt system and provided a significant reference library based on the documented effort. But it was low thermal power that was not intended to reflect a commercial scale electricity production design. Therefore, to facilitate and assist vendors with domestic licensing considerations, research is underway to identify methods that could be used for domestic safeguards approaches for these novel reactor systems. This research presents the results of a signature analysis of data generated from three simulated scenarios using the molten salt demonstration reactor model defined in the Transient Simulation Framework of Reconfigurable Modules. Each scenario provides 1 hour isotope inventories over a 180 day period. The scenarios investigated provide test cases to examine if direct gamma-ray spectroscopy of the fuel can be used to identify changes comparing a base case (no reactivity control and fixed fission contribution) to an insertion of reactivity (10 pcm no change in fission composition) and a change in fission composition. The analysis demonstrates that monitoring the total count rate in a highly collimated high-resolution photon energy spectrum is sensitive to perturbations imposed into the reactor model. The total photon count rate changes ≈2% for the fission composition change and ≈4.5% for the reactivity insertion compared to the base case. However, both scenarios show an increase in the total photon count rate. The total photon count rate can be used to identify changes due to power (number of fissions) but not due to a change in the material undergoing fission. To distinguish between the two cases of increased power, the photon spectrum would require an intensive analysis technique. A photon peak count rate ratio analysis could be used to identify changes in the fissile material fission generation in the core through identification of a static peak that shows little variation to the source of fission and a highly varying peak. The photon peak strength will ultimately be determined by the isotope’s fission yield. A preliminary analysis investigating the coupling of the isotope’s fission yield and its concentration in the fuel salt derived from the modeling has been performed. A ratio analysis of the photon peak count rates of 140 La to 99 Mo demonstrated that the reactivity insertion creates a distinct difference in the ratio compared to the fission composition change scenario.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Modeling Molten Salt Reactor Fission Product Removal with SCALE

Liquid-fuel Molten Salt Reactors (MSRs) allow for continuous online fuel treatment and processing using a variety of subsystems. Among these subsystems, the off-gas system (OGS) continuously removes fission products from the primary fuel salt through a helium sparging process. Accurately modeling fission product behavior is paramount for the development of MSRs; while there are a variety of depletion modeling and simulation tools that allow for removal of material from a defined system, most of them work in a semicontinuous, batch-wise manner. The new tools implemented into TRITON, in the SCALE suite for reactor analysis and design, aim to address this issue by implementing truly continuous material feeds and removals. In addition, material accountancy is enhanced in these tools, which enable tracking of removed material in user-specified mixtures. These continuous depletion tools provide a way to model material transport throughout systems more efficiently and accurately. This report validates the new SCALE MSR modeling capabilities using data from the Molten Salt Reactor Experiment (MSRE). After a framework was established for deriving realistic removal rates based on design specifications, these rates were used by TRITON to continuously remove specific elements while performing burnup calculations. Results were compared to those obtained in MSRE, with a focus on the 135 Xe poison fraction. After these capabilities were validated, the learned concepts and best practices were applied to model the Molten Salt Breeder Reactor (MSBR) and the Molten Salt Demonstration Reactor (MSDR) to study the effects of continuous fission product removal in fuel salt reactivity, as well as the lifetime effects.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗