Electrochemical behavior of the boron anode in aqueous solutions
Electrochemical oxidation of p-type boron anode in aqueous solutions
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Electrochemical oxidation of p-type boron anode in aqueous solutions
DC electric arc with superimposed axial subsonic gas flow breakdown voltage and anode heat transfer using high speed photography
Fatigue effects of incident illumination on area sensitivity, dynode gain stability and anode output for end-on photomultipliers
Surface parameters influence on energy transfer to arc jet anode, discussing work function, accommodation coefficient and diffuse reflection coefficient of electrons
Electrochemical oxidation of p-type boron anode in aqueous solutions, using galvanostatic technique
Pinch and parallel-plate discharges, and analysis of anode region of quasi-steady MPD arc
Instructions for use of anodic oxidation apparatus in conjunction with computer program to obtain electrically active concentration profiles of doped silicon wafers
Quasi-steady MPD accelerators current conduction and power loss mechanism investigation through local anode fall voltage and current density measurements at different arc current levels
Plasma anode tube in metal-ceramic envelope with improved capabilities for electron emission studies, considering movable Langmuir probe
The electrochemical oxidation of p-type boron in 0.2 N NaNO3 solutions of pH 0.4 to 13.1 was studied by galvanostatic techniques. The capacitance of the electrode, Tafel slopes, and a limited analysis of reaction mechanisms are reported. The anodic dissolution in acid solution is a charge-transfer-limited one-electron reaction to form a monovalent species in the over-potential region of 0.25 to 0.70 V. The dissolution in basic solution is most probably a one-electron charge-transfer reaction from a monovalent to divalent species involving three hydroxyl ions. Open circuit potentials were mixed potentials, probably due to hydrogen formation at open circuit but not contributing to the electrochemical reaction at the applied overpotential. Exchange current, estimated by extrapolation of the Tafel line to the standard oxidation potential for the boron reaction, were of the order of 10 to the minus 6th power A/cm2 in acid solution and 10 to the minus 12th power A/cm2 in basic solution. The reaction order of the rate determining acidic and basic reactions was determined with regard to (H+) and (OH-). The level of illumination had no effect on the electrochemical behavior of the electrode.
A scheme which permits the ends (near the anode seals) as well as the bottom and sides of an X-ray astronomy proportional counter to be protected by anticoincidence guard counters is described. A rocket-borne test showed that the non-X-ray background is reduced by an additional factor of about 30 when the end guard counter feature is added.
We have devised, constructed, and tested in flight a scheme which permits the ends (near the anode seals) as well as the bottom and sides of an X-ray astronomy proportional counter to be protected by anticoincidence guard counters. A rocket-borne test has shown that the non-X-ray background is reduced by an additional factor of about 30 when the end guard counter feature is added.
A versatile photon and charged particle imaging system is described. The Ranicon employs a microchannel electron multiplier plate to convert each detected event into a charge signal. This charge pulse is proximity-focused onto a large-area resistive anode plate equipped with pickup electrodes on its edges. Each event is located electronically by the ratios of the charges collected at the edges or by the differences of the signals' risetimes. One- or two-dimensional pictures are built up by storing events digitally (e.g., a core memory) or in analog form (e.g., a storage oscilloscope). Compact laboratory models have been constructed and tested. Operating characteristics, applications, limitations, and advantages of the Ranicon are discussed.
Anodization technique produces GaAs pn-junction solar cells exhibiting improved response to high energy photons and higher open circuit voltages through reduction of reflection loss.
A high-intensity xenon arc lamp having a plurality of separate anodes axially disposed in a symmetrical pattern which spaced a discharge gap from a common cathode is presented.
The Multi-Anode Microchannel Arrays (MAMA's) are a family of photoelectric, photon-counting array detectors being developed for use in instruments on both ground-based and space-borne telescopes. These detectors combine high sensitivity and photometric stability with a high-resolution imaging capability. MAMA detectors can be operated in a windowless configuration at extreme-ultraviolet and soft X-ray wavelengths or in a sealed configuration at ultraviolet and visible wavelengths. Prototype MAMA detectors with up to 512 x 512 pixels are now being tested in the laboratory and telescope operation of a simple (10 x 10)-pixel visible-light detector has been initiated. The construction and modes-of-operation of the MAMA detectors are briefly described and performance data are presented.
A method to achieve high spatial resolution readout of individual photoelectron events using microchannel plates and a resistive anode is presented. A clamped pair of microchannel plates is used, followed by a gap and a clamped triplet of microchannel plates in cascade to achieve a high stable electron gain of 3 x 10 to the 7th. The gain allows the position determination of each photoelectron event with a very high signal-to-noise ratio. A model consisting of a windowless vacuum-ultraviolet image sensor is presented to demonstrate 500 x 500 pixel images of 50 micron FWHM over a 25-mm circular field of view. The detector offers sufficient speed, sensitivity and resolution for a variety of applications, and the mount design is compatible with planar, remotely-processed, proximity-focused photocathodes.
The construction and modes of operation of Multi-Anode Microchannel Arrays (MAMA's) are briefly reviewed. The MAMA detectors, which are a family of photoelectric, photon-counting array detectors being developed specifically for use in instruments on ground-based and space-borne telescopes, combine the high sensitivity and photometric stability of a conventional channel electron multiplier with a high-resolution imaging capability. The MAMA detectors feature low applied potential (less than 3 kV), high gain (greater than 10 to the 6th electrons/pulse), an absolute event timing accuracy of 100 ns or better, a very long count lifetime (greater than 2.5 x 10 to the 11th counts/sq mm), and a power consumption of less than 30 W for a complete system