Development of battery separator composites

Abstract

Improved inorganic-organic separators developed by NASA were commercially prepared. A single-ply asbestos substrate was developed, as well as alternative substrates based on cellulose and on polypropylene fibers. The single-ply asbestos was bound with butyl rubber and was functionally superior to the formerly used polyphenylene oxide saturated sheet. Commercially prepared separators exhibited better measured separator properties than the NASA standard. Cycle life in Ni/Zn and Ag/Zn cells was related to substrate, decreasing in the order; asbestos cellulose paper nonwoven polypropylene. The cycle life of solvent-coated separators was better than aqueous in Ni/Zn cells, while aqueous coatings were better in Ag/Zn cells.