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Yung, Y. L.

Publications and source records attributed to Yung, Y. L..

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

CO2 on Titan

A sharp stratospheric emission feature at 667/cm in the Voyager infrared spectra of Titan is associated with the nu2 Q branch of CO2. A coupling of photochemical and radiative-transfer theory yields an average mole fraction above the 110 mbar level of (1.5 + 1.5 or - 0.8) x 10 to the -9th, with most of the uncertainty being due to imprecise knowledge of the vertical distribution. CO2 is found to be in a steady state, with its abundance being regulated principally by the 72 K cold trap near the tropopause and secondarily by the rate at which water-bearing meteoritic material enters the top of the atmosphere. An influx of water about 0.4 times that at the top of the terrestrial atmosphere is consistent with a combination of the observed CO2 abundance and a steady-state CO mole fraction of 0.00011; the thoeretical value for CO is close to the value observed by Lutz et al. (1983), although there are large margins for error in both numbers. If steady-state conditions for CO prevail, little information is available regarding the evolution of Titan's atmosphere.

Samuelson, R. E.↗
NASA NTRS1983

A two-stage mechanism for escape of Na and K from Io

A two-stage process is presented to identify Io as the source of Na and K ions in the Io plasma torus. The Voyager I IRIS experiment recorded an SO2 abundance of 0.2 cm atm in the Io subsolar region, and further calculations determined that the S(+) and O(+) would have sufficient energy to penetrate the Io atmosphere and produce sputtering of surface atoms at a rate of 800 million/sq cm per sec. If K, Na, and S are present on the surface in cosmic proportions, then an evenly applied sputter distribution would produce the same abundances of sputtered Na and K as observed in the Na and K clouds around Io. Sputtered into the atmosphere, the ions undergo thermal Jean's escape and attain velocities of at least 2.6 km/sec. The sputtering ions are a factor of two greater on the Jupiter side than on the solar side, in agreement with asymmetries measured by the Voyager.

Summers, M. E.↗
NASA NTRS1983

A general circulation model study of atmospheric carbon monoxide

The carbon monoxide cycle is studied by incorporating the known and hypothetical sources and sinks in a tracer model that uses the winds generated by a general circulation model. Photochemical production and loss terms, which depend on OH radical concentrations, are calculated in an interactive fashion. The computed global distribution and seasonal variations of CO are compared with observations to obtain constraints on the distribution and magnitude of the sources and sinks of CO, and on the tropospheric abundance of OH. The simplest model that accounts for available observations requires a low latitude plant source of about 1.3 x 10 to the 15th g/yr, in addition to sources from incomplete combustion of fossil fuels and oxidation of methane. The globally averaged OH concentration calculated in the model is 750,000/cu cm. Models that calculate globally averaged OH concentrations much lower than this nominal value are not consistent with the observed variability of CO. Such models are also inconsistent with measurements of CO isotopic abundances, which imply the existence of plant sources.

Pinto, J. P.↗
NASA NTRS1983

An analysis of the reflection spectrum of Jupiter from 1500 A to 1740 A

The Jovian reflection spectrum was modeled to determine the mixing ratios of C2H2, the upper limits to mixing ratios of C2H4, C4H2, and NH3, to detect the amount of dust in the stratosphere, and to measure the intensity of the H2 Lyman band dayglow emission. Data were gathered by the IUE spacecraft in the wavelength regions 1500 A to 1740 A, concentrating in the 10 mbar pressure region. Detailed Jupiter model parameters are provided. The mixing ratios of C2H2, C2H6, and C4H2 were found to be near 10 to the -7th, 6.6 x 10 to the -6th, and 2.9 x 10 to the -10th, respectively. Comparisons made with the Voyager 1 and 2 data indicated that the scale height of C2H2 in the 150-10 mbar region is double that of the bulk atmosphere. The data are significant for photochemical modeling of the upper Jovian atmosphere.

Gladstone, G. R.↗
NASA NTRS1982

Catalytic processes in the atmospheres of earth and Venus

Photochemical processes in planetary atmospheres are strongly influenced by catalytic effects of minor constituents. Catalytic cycles in the atmospheres of Earth and Venus are closely related. For example, chlorine oxides (ClOx) act as catalysts in the two atmospheres. On earth, they serve to convert odd oxygen (atomic oxygen and ozone) to molecular oxygen. On Venus they have a similar effect, but in addition they accelerate the reactions of atomic and molecular oxygen with carbon monoxide. The latter process occurs by a unique combination of ClOx catalysis and sulful dioxide photosensitization. The mechanism provides an explanation for the very low extent of carbon dioxide decomposition by sunlight in the Venus atmosphere.

Demore, W. B.↗
NASA NTRS1982

Radiation and chemistry in the stratosphere - Sensitivity to O2 absorption cross sections in the Herzberg continuum

It is suggested that the discrepancies between observed and modeled vertical profiles of such halocarbons as CFCl3, as well as the problem of simultaneously fitting N2O, CH4, CF2Cl2 and CFCl3 profiles with a single eddy diffusion model, are due to an overestimation of the molecular oxygen absorption cross sections in the 200-220 nm spectral region. The replacement of current O2 cross sections in this range with values that are in better agreement with results for the compounds cited leads to N2O, CF2Cl2 and CFCl3 concentration reductions of factors 0.70, 0.62 and 0.19, respectively. Profiles of CH4, H2 and CO remain unchanged, and the predicted concentration of HNO3 above 30 km is reduced by about 50% for yet another improved fit with observations. It is noted that the correction proposed produces a 30% ozone increase near the 20-25 km peak.

Froidevaux, L.↗
NASA NTRS1982

Photochemistry of the stratosphere of Venus - Implications for atmospheric evolution

The photochemistry of the Venus stratosphere is modeled using an updated and expanded chemical scheme along with the results of recent observations and laboratory studies. Three models, with H2 mixing ratio equal to 2 x 10 to the -5th, 5 x 10 to the -7th, and 1 x 10 to the -13th, respectively, are examined. All three models are found to satisfactorily account for the observations of CO, O2, O2(1Delta), and SO2 in the stratosphere, but only the last one may be able to account for the diurnal behavior of mesospheric CO and the UV albedo. Oxygen, derived from CO2 photolysis, is mainly consumed by CO2 recombination and oxidation of SO2 to H2SO4. The photolysis of HCl in the upper stratosphere provides a major source of odd hydrogen and free chlorine radicals, essential for the catalytic oxidation of CO. Oxidation of SO2 by O occurs in the lower stratosphere. The modeling reveals a number of interesting similarities, previously unsuspected between the chemistry of the stratosphere of Venus and that of the earth; photochemistry may have played a major role in the evolution of the atmosphere.

Yung, Y. L.↗
NASA NTRS1982

Laboratory studies of UV emissions of H2 by electron impact - The Werner- and Lyman-band systems

The vacuum ultraviolet electron-impact-induced fluorescence emissions of H2 were studied for the Lyman and Werner band systems in the range of 120-170 nm, using an optical system containing a photomultiplier and a spectrometer, over an energy range from threshold to 400 eV. The emission cross sections for the Lyman and Werner transitions at 100 eV are determined. The cross-section ratio is in excellent agreement with theoretical calculations and experimental data for the optical oscillator strengths. The cross-section for cascading to the B state is stated as a percentage of the total emission cross section at both 100 and 300 eV, increasing substantially at 20 eV. The vibrational population distribution of the B state is found to be a function of electron-impact energy as the importance of cascading relative to direct excitation changes with electron-impact energy.

Ajello, J. M.↗
NASA NTRS1982

Transient species on Mars and Venus

The similarities between the atmospheres of Earth, Venus, and Mars are discussed. The following species are highlighted: NOx, HOx, and COx. The concentrations of the species were examined for all three planets.

Yung, Y. L.↗
NASA NTRS1982

Research in atmospheric chemistry and transport

The carbon monoxide cycle was studied by incorporating the known CO sources and sinks in a tracer model which used the winds generated by a general circulation model. The photochemical production and loss terms, which depended on OH radical concentrations, were calculated in an interactive fashion. Comparison of the computed global distribution and seasonal variations of CO with observations was used to yield constraints on the distribution and magnitude of the sources and sinks of CO, and the abundance of OH radicals in the troposphere.

Yung, Y. L.↗
NASA NTRS1981

Sputter ejection of matter from Io

Direct collisional interaction of magnetospheric particles, particularly 520-eV S ions, with Io, cause sputter removal of matter. It is estimated that direct sputtering of a full-disk S-containing atmosphere with an exobase at a few hundred km, can provide up to 5 x 10 to the tenth S atoms per sq cm-s. Supplies of S and O required to stabilize the torus are estimated to be from 10 to the 10th to 10 to the 12th per sq cm-s. Sputtering rates are calculated for an atmosphere containing a one percent concentration of Na and K, and are found to be large enough to supply the fluxes required to maintain the Na and K clouds. Sputtering is found to remove heavy molecules from the atmosphere, and the rate of direct sputtering of unprotected surfaces is calculated for ejections of S and Na. Atomic species on the surface are ejected at a rate proportional to the surface abundance; and plume sputtering, avalanche cascading, and ionic saltation which lead to spatial and temporal variations in the number of ejected particles are observed.

Haff, P. K.↗
NASA NTRS1981

Evolution of the atmosphere of Venus

The photochemistry of the stratosphere of Venus was modeled using an updated and expanded chemical scheme, and the results of recent laboratory studies. The model satisfactorily accounts for the observations of CO, O2, (1) and SO2 in the stratosphere. Oxygen, derived from CO2 photolysis, is primarily consumed by CO2 recombination and oxidation of SO2 to H2SO4. Photolysis of HCl in the upper stratosphere provides a major source of odd hydrogen radicals essential for the catalytic oxidation of CO. Oxidation of SO2 by O occurs in the lower stratosphere, with the O-O bond broken by S + O2 and SO + HO2. The sensitivity of stratospheric chemistry to ambient H2 abundance was studied and the model prefers the high value (1 10 ppm) recently inferred from the Pioneer Venus ionospheric measurements. The importance of the photochemical production of S2O, (SO)2, S2, H2S2O2 and H2S2O3 is speculated. A number of previously unsuspected similarities between the chemistry of the stratospheres of Venus and the Earth, presented and discussed.

Yung, Y. L.↗
NASA NTRS1981

Vertical transport and photochemistry in the terrestrial mesosphere and lower thermosphere /50-120 km/

A study is conducted of the coupled effects of kinetics, solar cycle flux variations, and vertical transport on the distribution of long-lived hydrogen-carbon-oxygen compounds in the terrestrial mesosphere and lower thermosphere, using a one-dimensional aeronomy model. The calculations account for the important chemical reactions and use rocket measurements of the solar flux at solar minimum and maximum. Photodissociation rates appropriate for the mesosphere are determined with a spherical shell atmosphere formalism. Detailed corrections for the O2 Schumann-Runge bands and the temperature dependence of the CO2 cross sections are used. An eddy diffusion profile is derived which is in agreement with the Aladdin 74 mass spectral measurements of atomic O, O2, CO2, and Ar in the lower thermosphere and observations of the O3 minimum at about 80 km.

Allen, M.↗
NASA NTRS1980

Titan - Aerosol photochemistry and variations related to the sunspot cycle

A photochemical theory is proposed for producing complex polymers in a methane atmosphere. It is argued that the polyacetylenes (C2nH2) are the most likely precursor molecules for the formation of the stratospheric haze layer on Titan. The production of polyacetylenes involves a strong positive feedback, leading to more production of polyacetylenes. The thermosphere of Titan may undergo substantial expansion and contraction over a solar cycle, with important consequences for the chemistry of the upper atmosphere.

Allen, M.↗
NASA NTRS1980

Photochemical production of formaldehyde in earth's primitive atmosphere

Formaldehyde could have been produced by photochemical reactions in the earth's primitive atmosphere, at a time when it consisted mainly of molecular nitrogen, water vapor, carbon dioxide, and trace amounts of molecular hydrogen and carbon monoxide. Removal of formaldehyde from the atmosphere by precipitation can provide a source of organic carbon to the oceans at the rate of 100 billion moles per year. Subsequent reactions of formaldehyde in primeval aquatic environments would have implications for the abiotic synthesis of complex organic molecules and the origin of life.

Pinto, J. P.↗
NASA NTRS1980

On the relationship between secular brightness changes of Titan and solar variability

Titan's geometric albedo varied noticeably from 1972 to 1978, in phase with variations in solar activity (Lockwood and Thompson, 1979). A series of radiative transfer and aerosol formation calculations were made to demonstrate the feasibility of the following scenario for these secular brightness changes. Solar activity changes, especially in the UV output of the sun, result in alterations to the mass production rate of aerosols in Titan's atmosphere, which lead to modifications of their microphysical properties. The latter, in turn, cause the albedo to vary. Current estimates of the change in the solar UV radiation below the dissociation limit of methane imply alterations to the mean radius of the aerosols over an 11-yr solar cycle that are consistent in sign and magnitude with those required to explain the observed secular brightness changes.

Pollack, J. B.↗