Engineering topics

Yung, Y. L.

Publications and source records attributed to Yung, Y. L..

At least 55 records · Page 3

NASA NTRS1993

The young Sun and photochemistry of the primitive Martian atmosphere

We will investigate the climatology of an atmosphere where CO2 is a minor constituent but still the key radiative species. The thermal structure of the dust-free atmosphere is estimated by employing a simple radiative-convective model similar to that used by Gierasch and Goody. Radiative heating rates are computed using the Caltech/JPL one-dimensional photochemical model. Thermal cooling rates for a Martian atmosphere containing O2, O3, H2O, N2O, CO, and CO2 are calculated using FASCODE and k-distribution methods. The effects due to pressure broadening of the infrared absorption lines of CO2 by CO and O2, as well as the radiative effects of increased ozone densities in the atmosphere, will be examined.

Nair, H.↗

NASA NTRS1992

The impact of temperature dependent CO2 cross section measurements: A role for heterogeneous chemistry in the atmosphere of Mars?

Carbon dioxide comprises over 95 percent of the Mars atmosphere, despite continuous photolysis of CO2 by solar ultraviolet (UV) radiation. Since the direct recombination of CO and O is spinforbidden, the chemical stability of CO2 in the Martian atmosphere is thought to be the result of a HO(x)-catalyzed recombination scheme. Thus the rate of CO oxidation is sensitive to the abundance and altitude distribution of OH, H, and HO2. Most Martian atmospheric models assume that HO(x) abundances are governed purely by gas phase chemistry. However, it is well established that reactive HO(x) radical are adsorbed by a wide variety of surfaces. The authors have combined laboratory studies of H, OH, and HO2 adsorption on inorganic surfaces, observational data of aerosol distributions, and an updated photochemical model to demonstrate that adsorption on either dust or ice aerosols is capable of reducing HO(x) abundances significantly, thereby retarding the rate of CO oxidation.

Anbar, A. D.↗

NASA NTRS1991

Kinetic conversion of CO to CH4 in the Solar System

Some of the most interesting chemistry in the Solar System involves changes in the oxidation state of the simple carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4, is, however, poorly understood. This is surprising in view of the importance of the reduction process in the chemistry of the Solar System. Recently we investigated the chemical kinetics of a hitherto unsuspected reaction. It is argued that the formation of the methoxy radical (CH3O) from H+H2CO may play an essential role in the reduction of CO to CH4. The rate coefficient for this reaction has been estimated using the approximate theory of J. Troe and transition state theory. We will discuss the implications of this reaction for the chemistry of CO on Jupiter, in the solar nebula, for interpreting the laboratory experiments of A. Bar-Nun and A. Shaviv and A. Bar-Nun and S. Chang, and for organic synthesis in the prebiotic terrestrial atmosphere. The possible relation of CO reduction in the solar nebula and polyoxymethylene observed in comet Halley will be discussed.

Yung, Y. L.↗

NASA NTRS1990

Triton - Topside ionosphere and nitrogen escape

The principal ion in the ionosphere of Triton is N(+). Energetic electrons of magnetospheric origin are the primary source of ionization, with a smaller contribution due to photoionization. To explain the topside plasma scale height, it is postulated that N(+) ions escape from Triton. The loss rate is 3.4 x 10 to the 7th/sq cm per sec or 7.9 x 10 to the 24th ions/sec. Dissociative recombination of N2(+) produces neutral exothermic fragments that can escape from Triton. The rate is estimated to be 8.6 x 10 to the 6th N/sq cm per sec or 2.0 x 10 to the 24th atoms/sec. Implications for the magnetosphere of Neptune and Triton's evolution are discussed.

Yung, Y. L.↗

NASA NTRS1989

The structure of Io's thermal corona and implications for atmospheric escape

A steady-state model of Io's exospheric corona and its interaction with the Io plasma torus is used to study the escape of species from Io's atmosphere. It is found that atmospheric sputtering is the major escape mechanism for models in which the plasma flow reaches the critical level, and that such models produce total mass-loading rates an order of magnitude larger than values inferred from observations. The results suggest the presence of an extended Na coronal component in the thermal exosphere, and are consistent with an O-dominated corona, an exospheric temperature of about 1000 K, an Na critical level mixing ratio of 0.001, and a critical level radius of about 1.5 Io radii.

Summers, M. E.↗

NASA NTRS1987

Determination of O2(a1 delta g) and O2(b1 sigma+ g) yields in the reaction O + ClO --> Cl + O2: implications for photochemistry in the atmosphere of Venus

A discharge flow apparatus with chemiluminescence detector has been used to study the reaction O + ClO --> Cl + O2, where O2 = O2(a1 delta g) or O2(b1 sigma+ g). The measured quantum yields for producing O2(a1 delta g) and O2(b1 sigma+ g) in the above reaction are less than 2.5 x 10(-2) and equal to (4.4 +/- 1.1) x 10(-4), respectively. The observed O2(a1 delta g) airglow of Venus cannot be explained in the context of standard photochemistry using our experimental results and those reported in recent literature. The possibility of an alternative source of O atoms derived from SO2 photolysis in the mesosphere of Venus is suggested.

Non-NASA Center↗

NASA NTRS1986

An updated hydrocarbon photochemical model for the Jovian atmosphere from the troposphere through the homopause: A prelude to Galileo

A photochemical model for the atmosphere of Jupiter, including 1-D vertical eddy diffusive transport, was developed. It extends from the upper troposphere through the homopause. The hydrocarbon chemistry involves species containing up to four carbon atoms (and polyynes through C8H2). The calculations show that a large fraction of photochemical carbon may be contained in molecules with more than two carbon atoms. At the tropopause, C2H6 is the major photochemical species and C2H2, C3H8, and C4H10 are of comparable abundance and down from C2H6 by a factor of ten. These species may be detectable with the mass spectrometer of the Galileo Probe. The vertical distributions of the photochemical species are sensitive to the magnitude of eddy diffusive mixing in the troposphere and stratosphere and the details of the interface region.

Allen, M.↗

NASA NTRS1986

The D to H ratio on Titan and the planets: Implications for origin and evolution of planetary atmospheres

Measurements of deuterated methane show that Titan's atmosphere is enriched by at least several times in deuterium compared to the major planets. Potential causative factors for this enrichment are condensation to form tropospheric methane clouds, fractionation occuring over a hypothetical CH4-C2H2 ocean and between the ocean and the clathrate crust beneath, fractionation which occurred during the formation of Titan and fractionation occuring as a result of the evolution of Titan's atmosphere. The greater part of the observed fractionation is probably derived from the formation of Titan and the subsequent evolution of Titan atmosphere driven by photochemistry. The latter process is developed here for the first time. The D/H ratio in a planetary atmosphere is one readily available measure of the origin and evolution of the hydrogen bearing volatiles on the planet. Comparison between D/H ratio in the inner solar system and the outer solar system may pose important constraints on current theories.

Pinto, J. P.↗

NASA NTRS1986

Radiative transfer in a sphere illuminated by a parallel beam - An integral equation approach

The problem of multiple scattering of nonpolarized light in a planetary body of arbitrary shape illuminated by a parallel beam is formulated using the integral equation approach. There exists a simple functional whose stationarity condition is equivalent to solving the equation of radiative transfer and whose value at the stationary point is proportional to the differential cross section. The analysis reveals a direct relation between the microscopic symmetry of the phase function for each scattering event and the macroscopic symmetry of the differential cross section for the entire planetary body, and the interconnection of these symmetry relations and the variational principle. The case of a homogeneous sphere containing isotropic scatterers is investigated in detail. It is shown that the solution can be expanded in a multipole series such that the general spherical problem is reduced to solving a set of decoupled integral equations in one dimension. Computations have been performed for a range of parameters of interest, and illustrative examples of applications to planetary problems as provided.

Shia, R.-L.↗

NASA NTRS1986

D to H ratio and the origin and evolution of Titan's atmosphere

Potential causative factors for the unusually large ratio of CH3D to CH4 reported in the stratosphere of Titan (6 x 10 to the -4th) compared to that of Saturn (8.7 x 10 to the -5th) or Jupiter (6.7 x 10 to the -5th) are examined. With uncertainty in the observations and data reduction taken into account, an atmospheric enrichment factor of three or more is calculated for Titan relative to the planets. This enrichment factor is seen to be accounted for by condensation to form tropospheric methane clouds, fractionation occurring over a hypothetical CH4-C2H6 ocean and between the ocean and the clathrate crust beneath, fractionation which occurred during the formation of Titan, and fractionation as a result of the evolution of Titan's atmosphere. It is concluded that the greater part of the observed fractionation is probably derived from the last two of these mechanisms. The mechanisms studied do not account for the observed CH3D/CH4 value of 1.7 x 10 to the -3rd obtained by Kim and Caldwell (1982).

Pinto, J. P.↗

NASA NTRS1985

A critical analysis of CLO and O3 in the mid-latitude stratosphere

The Caltech one-dimensional photochemical model is used to analyze important questions concerning the upper stratospheric O3 and the key HO(x), NO(x), and ClO(x) free radicals. The model is described and first order effects of the inclusion of diffuse radiation in a spherical rather than plane parallel atmosphere at solar zenith angles close to 90 deg are assessed. A comparison is made between photochemical theory and observations for upper stratospheric O3, where local photochemistry rather than dynamics should control the O3 abundance. The photochemical equilibrium relation for odd oxygen is studied, including the important radicals involves. It is concluded that a significant model ozone deficit exists in the upper stratosphere. Possible causes for such a discrepancy are investigated in light of current model and experimental uncertainties. In particular, the observational ratio of atomic oxygen to zone appears to disagree with the model results.

Froidevaux, L.↗

NASA NTRS1985

Laboratory studies on the reactions between chlorine, sulfur dioxide, and oxygen - Implications for the Venus stratosphere

Fourier transform IR spectrophotometry is used to monitor the reactants and products in a Venus stratosphere simulation study involving the photolysis of mixtures of Cl2 and SO2, with and without O2 present in an atmosphere of N2. When several speculative reactions inferred from these experiments are incorporated by the Yung and DeMore (1982) model of Venus stratospheric chemistry, it emerges that SO2Cl2 is a key reservoir species for chlorine, and that the reaction between Cl and SO2 furnishes an important cycle for the destruction of O2 and the conversion of SO2 to H2SO4, thereby providing a possible solution to the photochemistry of the Venus stratosphere.

Demore, W. B.↗

NASA NTRS1984

A note on the variational method of Stokes and DeMarcus for radiative transfer in planetary atmospheres

A generalization of the variational principle of Stokes and DeMarcus (1971) by the construction of two bifunctionals is proposed. The equation of radiative transfer is obtained by imposing the stationary condition on such functionals, and the reflectivity and transmissivity at arbitrary angle are given by their extremum values. Further simplification is possible when trail functions are used that are linear in the variational parameters, in which case the source function derived from the method of Stokes and DeMarcus can give the reflectivity at arbitrary emergent angle to second order. The usefulness and limitations of these variational priinciples are explored with extensive numerical results.

Chow, K. S. K.↗

NASA NTRS1984

Photochemistry of the atmosphere of Titan - Comparison between model and observations

Updated chemical schemes and estimates of key rate coefficients are used in the present investigation of the photochemistry of Titan atmosphere C- H- and O-atom containing simple molecules, according to a model incorporating exospheric boundary conditions, vertical transport, and condensation processes at the tropopause. It is suggested that the composition, climatology, and evolution of the Titan atmosphere are controlled by five major processes: CH4 photolysis and photosensitized dissociation, H-to-H2 conversion and hydrogen escape, higher hydrocarbon synthesis, nitrogen and hydrocarbon coupling, and oxygen and hydrocarbon coupling. The model accounts for the minor species concentrations observed by Voyager instruments. Implications of abiotic organic synthesis on Titan for the origin of life on earth are briefly discussed.

Yung, Y. L.↗

NASA NTRS1984

The vertical distribution of ozone in the mesosphere and lower thermosphere

An assessment is made of the ability of current theory to explain the phenomenology of upper atmospheric ozone as revealed by the sizeable body of measurements presently available. The chemical processes affecting the vertical distribution of ozone are reviewed, and simple analytical expressions for the ozone concentrations at different altitudes are derived which approximate the key elements of the ozone chemistry. These equations provide simple explanations of the sensitivity of model computations to the choice of rate constants and climatological patterns. Model calculations are compared with a detailed measurement of an ozone profile, and the model is modified to assess the variation in ozone expected to result from perturbations in key climatological processes. These predictions are then compared with the variability observed in midlatitude measurements in order to verify the model description of ozone processes in the upper atmosphere.

Allen, M.↗

NASA NTRS1984

Studies of extreme-ultraviolet emission from Rydberg series of H2 by electron impact

Calibrated laboratory measurements of H2 bands in the 70-170-nm region using crossed neutral and electron beams have allowed the estimation of the cross sections for H2 bands which account for virtually all of the H2 EUV band emission. It is found, in general, that the internal population structure of the directly excited EUV band systems, B-X, B'-X, C-X, D-X, and D'-X, is modeled accurately by theoretical collision strengths. Moreover, the analysis of the measurements indicates that the same constant factor at a given electron energy at or above 100 eV, relates the theoretical oscillator strengths of the systems to the cross sections to within about 15 percent. The higher-Rydberg series band systems measured have been found to be a significant factor in the analysis of EUV planetary spectra. The prominence of the E,F-B contribution at low electron impact energies is also of astrophysical importance and further work is recommended to better define the excitation parameters of the E,F system.

Ajello, J. M.↗

NASA NTRS1984

The thermosphere of Titan

The vertical structure of Titan's thermosphere is calculated down to the mesopause as a function of local time based on Voyager 1 occultation data. The thermal time scales that characterize the diurnal behavior of the thermosphere are discussed, the input model atmosphere used to calculate the temperature profile is presented, and the dominant heating and cooling mechanisms in the thermosphere are examined. The temperature profiles obtained by integrating the heat transfer equation with and without electron heating are presented and discussed. The implications that derived exospheric temperatures have for the neutral hydrogen torus are investigated. The diurnal exospheric temperature is unlikely to exceed 225 K, averages between 187 and 197 K, and has a variational amplitude of 28 K or less. The vertical extent of the hydrogen cloud is too large to be explained in terms of simple thermal escape of hydrogen from the exosphere.

Friedson, A. J.↗

NASA NTRS1983

Computations and estimates of rate coefficients for hydrocarbon reactions of interest to the atmospheres of outer solar system

The rate coefficients, including Arrhenius parameters, have been computed for a number of chemical reactions involving hydrocarbon species for which experimental data are not available and which are important in planetary atmospheric models. The techniques used to calculate the kinetic parameters include the Troe and semiempirical bond energy-bond order (BEBO) or bond strength-bond length (BSBL) methods.

Laufer, A. H.↗