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Whitten, R. C.

Publications and source records attributed to Whitten, R. C..

At least 109 records · Page 6

Seasonal variations of NO and O3 at altitudes of 18.3 and 21.3 km

Nitric oxide and ozone concentrations have been measured in situ from a high-altitude research aircraft. Data which show the variations of NO and O3 with the time of year are presented for altitudes of 18.3 and 21.3 km. The extreme values of the observed NO concentrations at 21.3 km are 1.2 billion per cu cm in summer and 0.2 billion per cu cm in winter. At 18.3 km the extreme values are 1.6 billion per cu cm in summer and 0.1 billion per cu cm in winter. The smoothed NO seasonal data show a variation of about a factor of 2.5 at 21.3 km and a factor of 4 at 18.3 km. The ozone data show the generally expected magnitude and seasonal variation. We have used a photochemical model employing the measured ozone concentrations, the mean solar zenith angle, and seasonal HNO3 data reported by others to predict the seasonal NO variation at 20 km. The result is a summer-to-winter NO ratio of 2.5 which is in fair agreement with the observed ratios.

Loewenstein, M.↗

Possible ozone depletions following nuclear explosions

The degree of depletion of the ozone layer ensuing after delivery of strategic nuclear warheads (5000 and 10,000 Mton) due to production of nitrogen oxides is theoretically assessed. Strong depletions are calculated for 16-km and 26-km altitudes, peaking 1-2 months after detonation and lasting for three years, while a significant depletion at 36 km would peak after one year. Assuming the explosions occur between 30 and 70 deg N, these effects should be much more pronounced in this region than over the Northern Hemisphere as a whole. It is concluded that Hampson's concern on this matter (1974) is well-founded.-

Whitten, R. C.↗

Elementary introduction to the Green's function

A technique, using the method of variation of parameters for solving differential equations, is developed for introducing Green's functions early in an undergraduate curriculum. Various examples are presented.

Whitten, R. C.↗

Ionospheric effects of X-ray source Scorpius XR-1

A simple two-ion model was employed to evaluate the ionospheric effects of various nocturnal ionization sources. The model was used to calculate the decay of the electron number density at 90 km with and without illumination by Scorpius XR-1 X rays. Reflection parameters for the determination of the effect of cosmic x-ray sources on radio wave propagation were also obtained. The results obtained in the investigation do not support the proposal made by Anathakrishnan and Ramanathan (1969) that the X-ray source in Scorpius XR-1 affects the nighttime lower ionosphere of the earth.

Poppoff, I. G.↗

Preliminary assessment of the potential impact of solid-fueled rocket engines in the stratosphere

Free chlorine atoms produced from HCl deposited by solid-fueled rocket engines react to destroy odd oxygen in the stratosphere. Using a one-dimensional photochemical model, we have computed the reduction of ozone likely to be caused by long-term operation of such vehicles powered by large solid-fueled rocket engines. It is likely that ozone reduction will not be greater than a few tenths of a per cent, although the value is dependent upon ambient NO(x) concentrations.

Whitten, R. C.↗

The ionosphere and atmosphere of Io

A neon atmosphere and ionosphere is proposed for Io, based on Pioneer 10 observations of the peak electron number density, height of the peak above the surface, and the topside plasma scale height. Calculations of mass, momentum and energy equations for a neon atmosphere yield results that are in reasonable agreement with the observations. A nitrogen atmosphere and a neon-argon-helium atmosphere are also considered. Calculations of the electron number density of a neon ionosphere also yield reasonable agreement with observations. It is noted that Io has about the same mass and radius as the moon, and that Apollo mass spectrometer measurements indicated an abundance of neon in the lunar atmosphere. The presence of other elements, such as hydrogen, helium, and sodium, in Io's atmosphere is also discussed.

Whitten, R. C.↗

Chlorofluoromethanes in the stratosphere and some possible consequences for ozone

Inert chlorofluoromethanes are used by man as refrigerants and aerosol propellants. These substances eventually escape and diffuse upward into the stratosphere. At great enough heights, UV sunlight can photodissociate these chlorofluorocarbons into chlorine atoms which will catalytically destroy ozone molecules. Chlorofluoromethane production has been increasing steadily in recent years to its present level of about a megaton per year, and chlorofluorocarbon usage will probably continue to grow in the future. Calculations with a one-dimensional time-dependent atmospheric model suggests that, if projected increases in chlorofluoromethane use materialize and there is no tropospheric destruction mechanism for these gases, the total global abundance of ozone may be reduced by more than 20 per cent over the next 50 years. If the residence times for these fluorocarbons in the troposphere are in the range of 10-30 years, however, predicted ozone depletions would be significantly smaller.

Turco, R. P.↗

The Ames two-dimensional stratosphere-mesospheric model

A two-dimensional model of the stratosphere and mesosphere has recently been developed at Ames Research Center. The model contains chemistry based on 18 species that are solved for at each step and a seasonally-varying transport model based on both winds and eddy transport. The model is described and a preliminary assessment of the impact of supersonic aircraft flights on the ozone layer is given.

Whitten, R. C.↗

A comparison of several computational techniques for solving some common aeronomic problems

Several numerical integration techniques for solving common aeronomic problems involving species rate equations are compared for speed and accuracy. A newer technique that defines families of species that are nearly conserved is found to be superior to an iterative technique when both methods are applied to simple test problems. The 'conservation' technique is also found to be more economical than the more complex Gear (1969) integration scheme for comparable accuracy.

Turco, R. P.↗

The ionospheres of Mars and Venus

Observations made by spacecraft in the Mariner and Venera series have provided considerable knowledge of the structure of the ionospheres and atmospheres of Mars and Venus. This paper begins with brief but complete discussions of these measurements and their interpretations. The principles for constructing models of ionospheres are presented from the standpoint of mass, momentum, and energy conservation. The relevant ion chemistry is presented, and the meaning and use of plasma scale heights are discussed. The models discussed are the model of Cloutier and co-workers; the models of Banks and Axford, of Whitten, and of Herman and co-workers; the model developed by McElroy and Strobel to account for the nighttime ionosphere of Venus; and the models developed by a number of investigators for the thermal structure of the Martian and Venusian ionospheres.

Whitten, R. C.↗

The lower ionosphere of Venus

Galactic cosmic ray bombardment provides a permanent background ionosphere in planetary atmospheres. A transport technique is used to compute the cosmic ray ionization rate profile in a model of the Venusian atmosphere at altitudes between 55 and 100 km. These ionization rates are then applied to a model of ion chemistry to predict equilibrium electron and ion density profiles. Ionization rates for typical solar flare proton events are available from earlier calculations and have been included.

Dubach, J.↗

Three-body Coulomb systems using generalized angular-momentum S states

An expansion of the three-body Coulomb potential in generalized angular-momentum eigenfunctions developed earlier by one of the authors is used to compute energy eigenvalues and eigenfunctions of bound S states of three-body Coulomb systems. The results for He, H(-), e(-)e(+)e(-), and pmu(-)p are compared with the results of other computational approaches.

Whitten, R. C.↗

Diurnal variations of HOx and NOx in the stratosphere

The diurnal variations of odd hydrogen (OH, HO2, H2O2) and odd nitrogen compounds (NO, NO2, HNO3) are investigated by using a one-dimensional time-dependent model containing both chemistry and eddy transport. These variations are discussed in terms of relevant processes.-

Whitten, R. C.↗

An assessment of the potential impact of solid-fueled rocket engines in the stratosphere

The effects of shuttle-emitted HCl on stratospheric ozone are reported. A one-dimensional model of the distribution of trace constituents in the stratosphere and mesosphere is described, and chemical reactions and photodissociation rates in the chlorine chemistry are listed. Analysis of mathematical models is presented, and the results show ozone depletion when emissions are considered to be spread uniformly in the horizontal over a hemisphere and an increase in ozone when emissions are considered in a zone 1000 km wide centered at Cape Kennedy. Sensitivity studies to determine the effects of some assumptions in the model and comparisons with nitric oxide reactions are described. The importance of a two-dimensional model for a proper long term study is noted. Lists of reaction rate coefficients and photodissociation rates for the O-H-N system are included.

Whitten, R. C.↗

The effect of SST emissions on the earth's ozone layer

The work presented here is directed toward assessment of environmental effects of the supersonic transport (SST). The model used for the purpose includes vertical eddy transport and the photochemistry of the O-H-N system. It is found that the flight altitude has a pronounced effect on ozone depletion. The largest ozone reduction occurs for NO deposition above an altitude of 20 km.

Whitten, R. C.↗

Which electromagnetic equations apply in rotating coordinates

It was discovered some years ago by Schiff that two equations for fields in vacuum do not carry over without change from an inertial frame to a frame with rotating axes of space coordinates, even for a region with all velocities much lower than the speed of light. However, the belief that all four of the field equations are invariant under such conditions is still prevalent and causes misconceptions in physical applications, including astrophysical and geophysical ones. The purpose of the present paper is therefore to call attention to Schiff's discovery, discussing its basis and its extension to fields in material media, and to interpret the additional terms that must be added to the equations in order to obtain valid transformations to rotating axes of coordinates.

Webster, D. L.↗

A model of carbon compounds in the stratosphere and mesosphere.

A photochemical model with vertical transport is employed to compute profiles of CO, CH4, CH3, CH2, CHO, CH2O, CH3O, CH3O2, and CH4O2 from 10- to 90-km altitude. The upper boundary condition is taken as diffusive equilibrium at 120 km, and the lower boundary condition as chemical equilibrium or a flux condition at 10 km. The results are in reasonable agreement with observations and with the results of other model studies.

Whitten, R. C.↗

The photolytic stability of the Martian atmosphere.

Several recent suggestions for stabilizing the Martian atmosphere against photolysis have proved untenable. However, downward convective transport as well as a low altitude (0-35 km) aerosol, which catalyzes two-body molecular recombination reactions, can bring about such stability. The 'effective' convection velocity and 'average' two-body reaction rate coefficients required by observed abundances are evaluated. The computed profiles of CO and O at high altitude are shown to agree well with observations.

Whitten, R. C.↗