Engineering topics

Whitten, R. C.

Publications and source records attributed to Whitten, R. C..

At least 91 records · Page 5

NASA NTRS1978

Reservoirs of atmospheric chlorine - Prospects for HOCl revisited

Possible effects of HOCl aeronomy in the terrestrial stratosphere are reexamined. Chemical kinetics data for HOCl are analyzed which are required in aeronomical studies, and the possible role of HOCl as a reservoir of atmospheric chlorine is evaluated. Chemical production and loss of HOCl in the stratosphere is considered, along with photolysis of HOCl and prospects for HOCl as an inert chlorine reservoir. It is shown that a recent theoretical calculation of the HOCl photodissociation cross section suggests this species as a possible significant reservoir of atmospheric chlorine, but that the theoretical calculations are in sharp disagreement with some experimental measurements. Laboratory and atmospheric experiments to clarify the uncertainties of HOCl aeronomy are proposed.

Prasad, S. S.↗

NASA NTRS1978

Effect of the reaction HO2 + O3 yields OH + 2O2 on stratospheric ozone

It is noted that recent measurements of large values of the rate coefficient for the reaction NO + HO2 yields NO2 + OH lead to model predictions of excessive amounts of stratospheric ozone. This letter shows that a recent measurement of the rate coefficient (k2) for the reaction HO2 + O3 yields OH + 2O2 largely resolves these problems of excessive stratospheric ozone in models. A two-dimensional model of stratospheric trace constituents is used to calculate the concentrations of 35 constituents; the results are compared with experimental measurements of ozone column densities. It is found that the model predictions of excess ozone abundances diminish significantly when the measured value of k2 is employed.

Whitten, R. C.↗

NASA NTRS1978

An assessment of the effect of supersonic aircraft operations on the stratospheric ozone content

An assessment of the potential effect on stratospheric ozone of an advanced supersonic transport operations is presented. This assessment, which was undertaken because of NASA's desire for an up-to-date evaluation to guide programs for the development of supersonic technology and improved aircraft engine designs, uses the most recent chemical reaction rate data. From the results of the present assessment it would appear that realistic fleet sizes should not cause concern with regard to the depletion of the total ozone overburden. For example, the NOx emission of one type designed to cruise at 20 km altitude will cause the ozone overburden to increase by 0.03% to 0.12%, depending upon which vertical transport is used. These ozone changes can be compared with the predictions of a 1.74% ozone decrease (for 100 Large SST's flying at 20 km) made in 1974 by the FAA's Climatic Impact Assessment Program.

Poppoff, I. G.↗

NASA NTRS1978

Geographical variations of NO and O3 in the lower stratosphere

Nitric oxide and ozone concentrations in the lower stratosphere have been measured from a high-altitude research aircraft using in situ measuring techniques. Results of several geographical surveys are presented along with predictions of two two-dimensional stratospheric models. Meridional and zonal data were obtained in June 1974 and in June, July, and August 1975. At longitudes 122-158 deg W the meridional data taken between 5 and 80 deg N latitude show an increasing NO concentration with latitude, by a factor of 4 at 21-km altitude and a less marked increase at 18 km. The minimum NO concentration at 21 km is observed at 5 deg N latitude and is about 6 x 10 to the 8th power/cu cm. Zonal data at latitudes 22-38 deg N taken from 55 to 176 deg N longitude show little variation of the NO and O3 concentrations with longitude.

Loewenstein, M.↗

NASA NTRS1978

A note on the diurnal averaging of aeronomical models

An approximate technique for diurnally time-averaging atmospheric photochemical-dynamical models which eliminates the need for a detailed numerical resolution of sunrise and sunset transitions is developed. The scheme is equivalent to scaling certain chemical rate constants and photodissociation coefficients by appropriate aeronomical factors. To calculate the scaling factors, diurnal variations are parameterized with a step-function behavior, assuming that each species has a constant day-time and night-time concentration whose ratio can be determined by analyzing the chemical interactions occurring after sunset. The solution accounts for the effects of night-time reactions on the 24 h average values of species abundances, and on the average daily rates of the catalytic processes consuming ozone in the stratosphere. The accuracy of the technique is demonstrated by comparing its predictions to those of a full diurnal simulation; typically, the precision is better than 10%. By contrast, it is shown that the use of some other well-known computational schemes can result in significantly larger predictive errors.

Turco, R. P.↗

NASA NTRS1978

Properties of the stratospheric aerosol layer studied with a one-dimensional computer model

Aerosol particle effects are often neglected in theoretical studies of stratospheric phenomena. In reality, the particulate matter normally found above the tropopause may influence the terrestrial radiation balance, catalyze heterogeneous chemical interactions, and serve as a tracer of atmospheric motions. The paper proposes a one-dimensional model of the stratospheric aerosol layer, and it is used to compare aerosol theory with observational data. The model considers gaseous sulfur photochemistry and the physical aerosol processes of nucleation, coagulation, sedimentation, and diffusion. Calculations of the effects on the aerosol layer of stratospheric injections of aluminum oxide particles by Space Shuttle engines and of sulfur dioxide molecules by volcanic activity are performed. The relation between measured aerosol variability and changes in stratospheric air temperatures and vertical transport rates are discussed.

Turco, R. P.↗

NASA NTRS1977

The NASA Ames Research Center one- and two-dimensional stratospheric models. Part 1: The one-dimensional model

A one-dimensional model of stratospheric trace constituents is described in detail. Specifically, the numerical solution of the species continuity equations, including a technique for treating the stiff differential equations representing the chemical kinetic terms, and an appropriate method for simulating the diurnal variations of the species concentrations, are discussed. A specialized treatment of atmospheric photodissociation rates is outlined in the text. The choice of a vertical eddy diffusivity profile and its success in predicting the vertical tracer distributions (carbon 14, methane, and nitrous oxide) are also discussed.

Turco, R. P.↗

NASA NTRS1977

The NASA Ames Research Center one- and two-dimensional stratospheric models. Part 2: The two-dimensional model

The two-dimensional model of stratospheric constituents is presented in detail. The derivation of pertinent transport parameters and the numerical solution of the species continuity equations, including a technique for treating the stiff differential equations that represent the chemical kinetic terms, and appropriate methods for simulating the diurnal variations of the solar zenith angle and species concentrations are discussed. Predicted distributions of tracer constituents (ozone, carbon 14, nitric acid) are compared with observed distributions.

Whitten, R. C.↗

NASA NTRS1977

The ionospheres of Saturn, Uranus, and Neptune

Models of the ionospheres of Saturn, Uranus, and Neptune are presented. It is postulated that galactic cosmic-ray ionization is an important component of these ionospheres. For example, in the case of Neptune, the level of ionization caused by cosmic rays is comparable with that due to solar extreme-ultraviolet (EUV) radiation. The existence of cosmic-ray, as well as solar EUV-produced ionization, could be a valuable diagnostic tool for investigating the atmospheric thermal structure of those planets.

Capone, L. A.↗

NASA NTRS1977

The upper ionosphere of Titan

Photoionization of the upper atmosphere of Titan by sunlight is expected to produce a substantial ionospheric layer. One-dimensional forms of the mass, momentum, and energy conservation equations for ions and electrons have been solved along with electron number densities of about 1000/cu cm, using various model atmospheres. The significant ions in a CH4-H2 atmosphere are H(+), H3(+), CH5(+), CH3(+), and C2H5(+). Electron temperatures may be as high as 1000 K, depending on the abundance of hydrogen in the high atmosphere. Interaction of the solar wind with the ionosphere is also discussed.

Whitten, R. C.↗

NASA NTRS1976

Model predictions of latitude-dependent ozone depletion due to supersonic transport operations

Results are presented from a two-dimensional model of the stratosphere that simulates the seasonal movement of ozone by both wind and eddy transport, and contains all the chemistry known to be important. The calculated reductions in ozone due to NO2 injection from a fleet of supersonic transports are compared with the zonally averaged results of a three-dimensional model for a similar episode of injection. The agreement is good in the northern hemisphere, but is not as good in the southern hemisphere. Both sets of calculations show a strong corridor effect in that the predicted ozone depletions are largest to the north of the flight corridor for aircraft operating in the northern hemisphere.

Borucki, W. J.↗

NASA NTRS1976

On the energy deposition of photoelectrons in the atmosphere of Venus

Vertical components of photoelectron fluxes in the atmosphere of Venus are computed by solving an appropriate form of the Boltzmann equation in the cases where there is no flux of either photoelectrons or solar-wind particles across the ionopause and where photoelectrons are free to escape from the atmosphere. It is assumed that Venus has no magnetic field and that the atmosphere is composed of carbon dioxide, atomic oxygen, and helium. The results are plotted as a function of altitude for several energies in the range from 100 eV to a cutoff of the order of 1 eV. Heating rates for the two upper boundary conditions and the case of no spatial transport are determined which show that transport effects dominate at altitudes greater than about 200 km. Electron temperatures are calculated for the adopted model atmosphere and ionosphere by solving the pertinent conservation equation, and excitation rates are computed for the CO Cameron band as well as the CO2(+) A and B bands.

Mccormick, P. T.↗

NASA NTRS1976

Effect of nearby supernova explosions on atmospheric ozone

An investigation has been conducted of the probable effects of a nearby supernova event on the ozone layer of the earth. It is found that the ozone depletion, although smaller than that estimated by Ruderman (1974), is still significant, and could, as a result of cosmic rays, extend over periods of time from 1000 to 10,000 years. However, the probability of the occurrence of such an event within the past 100 million years appears to be low. The calculated ozone depletion seems to be the major effect of a supernova on a earth-like planet at a distance in the range from 5 to 10 pc.

Whitten, R. C.↗

NASA NTRS1976

The lower ionosphere of Titan

Ionization of the atmosphere of Titan by galactic cosmic rays is a very significant process throughout the altitude range from 100 to 400 km. An approximate form of the Boltzmann equation for cosmic-ray transport has been used to obtain local ionization rates. Models of both ion and neutral chemistry have been employed to compute electron and ion density profiles for three different values of the H2/CH4 abundance ratio. The peak electron density is of the order of 1000 per cu cm. The most abundant positive ions are C2/H9(+) and C3H9(+), while the predicted densities of the negative ions H(-) and CH3(-) are very small (less than one ten-thousandth that of the positive ions). It is suggested that inclusion of the ion chemistry is important in the computation of the H and CH3 density profiles in the lower ionosphere.

Capone, L. A.↗

NASA NTRS1976

A comparison of one-dimensional theoretical models of stratospheric minor constituents

The density profiles of stratospheric minor constituents are compiled from several one-dimensional theoretical models that have appeared in the literature. The models are compared with each other and also with observations if data are available. The similarity and disparity of the models are clarified and discussed. If a large difference exists among the models, attempts are made to interpret it as much as possible in terms of the physical and chemical data employed in each model. The inadequacy of one-dimensional models in calculating the realistic ozone density distributions and the problems related to it are briefly discussed.

Shimazaki, T.↗

NASA NTRS1976

Model predictions of latitude-dependent ozone depletion due to aerospace vehicle operations

Borucki, W. J.↗

NASA NTRS1976

The mesosphere

The mesosphere is an atmospheric region characterized by a negative gradient of solar energy absorption and temperature. Although the distribution of most minor constituents is dominated by photochemistry, vertical transport does have a pronounced effect on many of them. The basic dynamic principles are discussed along with their application to the important mesospheric motions: acoustic-gravity waves, tides, planetary-scale waves, and eddy motions. Oxides of nitrogen and hydrogen are also examined which strongly influence the balance of odd oxygen (O and O3). Brief discussions of the chemistry of carbon compounds and of excited species are also included. The chemistry of ionic species in the mesosphere is very important because it strongly influences the propagation and absorption of radio waves. Because of ion clustering and negative-ion formation, such chemistry is extremely complex. The current state of knowledge is discussed in some detail. The principles involved in constructing models for predicting the distribution of minor constituents, both neutral and ionic, are presented.

Poppoff, I. G.↗

NASA NTRS1975

The lower ionosphere of Mars

Recently reported (Savich et al. 1975) results of dual frequency (0.94 and 3.75 GHz) radio occultation experiments indicated the existence of a nocturnal ionospheric layer between the Martian surface and 80 km altitude. It is suggested that the observed ionosphere is due to ionization by galactic cosmic rays. The observed nocturnal electron density profile is compared with that of the negative ion model assumed by Whitten et al. (1971). The profiles are similar below 50 km if the negative ion concentration is reduced by a factor of 10.

Whitten, R. C.↗