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Whitten, R. C.

Publications and source records attributed to Whitten, R. C..

At least 37 records · Page 2
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NASA NTRS1984

Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 x 10 to the -6th W/sq m can be expected. This value is much lower than that for earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C2N2 produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 0.01, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.

Borucki, W. J.↗
NASA NTRS1984

Dynamics of the Venus ionosphere - A two-dimensional model study

A two-dimensional model of the ionosphere of Venus which simulates ionospheric dynamics by self-consistently solving the plasma equations of motion, including the inertial term, in finite difference form has been constructed. The model, which is applied over the solar zenith angle range extending from 60 to 140 deg and the altitude range 100 to 480 km, simulates the measured horizontal velocity field quite satisfactorily. The ion density field is somewhat overestimated on the dayside, because of the choice model neutral atmosphere, and underestimated on the nightside, because of setting the ionopause height at too low an altitude. It is concluded that solar photoionization on the dayside and ion recombination on the nightside are the processes mainly responsible for accelerating the plasma to the observed velocities. The plasma flow appears to be sufficient to maintain the nightside ionosphere at or near the observed median level of ion densities.

Whitten, R. C.↗
NASA NTRS1984

Terrestrial nitrous oxide cycles and atmospheric effects

The basic processes that cause N2O emission from soils are briefly discussed, and the rate of the processes is shown to vary widely in space and time, depending on soil, climate, and agrotechnical conditions. Although significant amounts of N2O are indeed emitted from the land, the complexity of the soil processes involved and the wide variation of measured rates still prevents the quantitative evaluation, global budgeting, and reliable prediction of atmospheric N2O. Increased atmospheric N2O abundance increases the levels of odd-nitrogen in the stratosphere, which, in turn, decreases the stratospheric ozone density via a catalytic cycle. Using appropriate atmospheric models and current chemical kinetic data, it has been found that the dependence of ozone reduction on N2O increase is nearly linear; a simulated doubling of N2O leads to a predicted decrease of about 14 percent in total ozone column density. A 10 percent increase in N2O yields a predicted increase in nonmelanoma skin cancer of several percent, and a possible raising of surface temperature of 0.03 K.

Whitten, R. C.↗
NASA NTRS1984

Global N2O cycles - Terrestrial emissions, atmospheric accumulation and biospheric effects

Recent findings concerning the budget and cycles of nitrous oxide on earth are summarized, and the sources and sinks for N2O on land, in the ocean, and in the atmosphere are examined in view of the N2O concentration increase of 0.2-0.4 percent per year, observed over the period of 1975-1982. Possible atmospheric and biospheric consequences of the N2O concentration increase are evaluated. N2O emission values are given for several major ecosystem types, such as forest, desert, cultivated land; values from different sources are compared and discussed. Analysis shows an excess of documented sources over sinks by 0-51 Tg N2O-N/yr.

Banin, A.↗
NASA NTRS1983

A two-dimensional model simulation of the EL Chichon volcanic eruption cloud

Using a two-dimensional model of sulfate photochemistry, transport, and aerosol microphysics, a 2-year period following the eruptions of El Chichon have been simulated. Present calculations suggest that the residence time of the cloud in the stratosphere exceeds 2 years. The model reproduces the observed optical depth, lidar backscatter, and infrared extinction coefficients, if about 10 megatonnes of SO2 are injected. The major deficiency of the model is a somewhat too rapid transport.

Capone, L. A.↗
NASA NTRS1983

Galactic cosmic rays and N2 dissociation on Titan

The electromagnetic and particle cascade resulting from the absorption of galactic cosmic rays in the atmosphere of Titan is shown to be an important mechanism for driving the photochemistry at pressures of 1 to 50 mbar in the atmosphere. In particular, the cosmic ray cascade dissociates N2, a process necessary for the synthesis of nitrogen organics such as HCN. The important interactions of the cosmic ray cascade with the atmosphere are discussed. The N2 excitation and dissociation rates and the ionization rates of the principal atmospheric consituents are computed for a Titan model atmosphere that is consistent with Voyager 1 observations. It is suggested that HCN may be formed efficiently in the lower atmosphere through the photodissociation of methylamine. It is also argued that models of nitrogen and hydrocarbon photochemistry in the lower atmosphere of Titan should include the absorption of galactic cosmic rays as an important energy source.

Capone, L. A.↗
NASA NTRS1983

The 1980 eruptions of Mount St. Helens - Physical and chemical processes in the stratospheric clouds

The large and diverse set of observational data collected in the high-altitude plumes of the May 18, May 25, and June 13, 1980 eruptions is organized and analyzed with a view to discerning the processes at work. The data serve to guide and constrain detailed model simulations of the volcanic clouds. For this purpose, use is made of a comprehensive one-dimensional model of stratospheric sulfate aerosols, sulfur precursor gases, and volcanic ash and dust. The model takes into account gas-phase and condensed-phase (heterogeneous) chemistry in the clouds, aerosol nucleation and growth, and cloud expansion. Computational results are presented for the time histories of the gaseous species concentrations, aerosol size distributions, and ash burdens of the eruption clouds. Also investigated are the long-term buildup of stratospheric aerosols in the Northern Hemisphere and the persistent effects of injected chlorine and water vapor on stratospheric ozone. It is concluded that SO2, water vapor, and ash were probably the most important substances injected into the stratosphere by the Mount St. Helens volcano, both with respect to their widespread effects on composition and their effect on climate.

Turco, R. P.↗
NASA NTRS1983

A simple example of a classical gauge transformation

Attention is given to the manner in which the interaction of a gravitational field with a diffusing gas is induced by a gauge transformation. Since the gas can be thought of as a field, the diffusion process may be represented by a Lagrangian density with the symmetry property of invariance under translation. While this property is lost when the field interacts with a static gravitational field, it is formally restored when an appropriate gauge transformation is performed. This ascription of field properties to a gas offers an illuminating illustration of the coupling of matter to a gauge field within the context of classical mechanics.

Whitten, R. C.↗
NASA NTRS1983

Venus -Mesospheric hazes of ice, dust, and acid aerosols

Four distinct types of particles are suggested to be present in the upper atmosphere of Venus. The lowest and densest haze may consist of a submicron sulfuric acid aerosol which extends above the cloud tops, up to about 80 km, representing an extension of the upper cloud deck. Temperature structure measurements in the 70-120 km altitude range indicate the occasional appearance of two independent water ice layers, of which the lower may form between 80 and 100 km and is probably the detached haze layer noted in high contrast limb photography. A nucleation of this ice layer on sulfuric acid aerosols is hypothesized. Temperatures of the Venus mesopause, near 120 km altitude, are frequently cold enough to allow ice nucleation on meteoric dust or ambient ions, yielding a haze (analogous to noctilucent clouds on earth) which is expected to be tenuous to the point of optical invisibility.

Turco, R. P.↗
NASA NTRS1982

Noctilucent clouds - Simulation studies of their genesis, properties and global influences

A numerical model is presented for testing theories of the physical mechanisms of noctiluminescent clouds. The time-dependent, one-dimensional model describes the formation, evolution, and properties of the clouds as interactive ice crystals, meteoric dust, water vapor, and ionized air. Mesopause temperatures below 140 K are found to be necessary for the formation of the clouds, conditions existing only at high latitudes in the summer. No predominant nucleation particle could be identified for the formation of the clouds, although a time period of up to a day was determined as necessary for materialization, which lasts several days. Several atmospheric and environmental conditions were characterized which enhance the appearance of the noctiluminescent clouds. One conclusion reached is that the numerous launches necessary to build a solar power satellite system would not significantly exacerbate noctiluminescent cloud formation.

Turco, R. P.↗
NASA NTRS1982

Space Shuttle ice nuclei

Estimates are made showing that, as a consequence of rocket activity in the earth's upper atmosphere in the Shuttle era, average ice nuclei concentrations in the upper atmosphere could increase by a factor of two, and that an aluminum dust layer weighing up to 1000 tons might eventually form in the lower atmosphere. The concentrations of Space Shuttle ice nuclei (SSIN) in the upper troposphere and lower stratosphere were estimated by taking into account the composition of the particles, the extent of surface poisoning, and the size of the particles. Calculated stratospheric size distributions at 20 km with Space Shuttle particulate injection, calculated SSIN concentrations at 10 and 20 km altitude corresponding to different water vapor/ice supersaturations, and predicted SSIN concentrations in the lower stratosphere and upper troposphere are shown.

Turco, R. P.↗
NASA NTRS1982

The Venus ionosphere at grazing incidence of solar radiation - Transport of plasma to the night ionosphere

A quasi-two-dimensional model of the Venusian ionosphere is used to calculate the ion number densities and horizontal ion bulk velocities expected for a range of solar zenith angles near the terminator (80-100 deg). These results are compared with data from the Pioneer Venus Orbiter retarding potential analyzer. It is shown that antisunward horizontal plasma fluxes produced by solar EUV-induced pressure gradients are sufficient to maintain the nighttime ionosphere. While photoionization is the dominant source of ionospheric plasma for solar zenith angles less than 92 deg, plasma transport from the dayside is the dominant plasma source for solar zenith angles greater than 95 deg. It is also shown that the main nightside plasma peak at a height of 140 km is of the F2 type; its height and shape are therefore quite insensitive to the height of the ion source.

Whitten, R. C.↗
NASA NTRS1982

Predicted electrical conductivity between 0 and 80 km in the Venusian atmosphere

Calculations of the space charge, ion density, and conductivity in the Venus atmosphere were made. The presence of the cloud particles on Venus causes a profund reduction in the calculated values of the ion density and conductivity compared to the values that are obtained without consideration of the cloud particles. When the cloud particles are included in the calculations, the results for the ion density and conductivity are approximately the same as those of the terrestrial atmosphere at the same pressure-altitude. Because the particles span such a large range of sizes and are abundant over a substantial range of pressure, the space charge varies strongly with altitude and particle size. Differential settling of the particles is expected to produce weak electric fields in the clouds.

Borucki, W. J.↗
NASA NTRS1982

Stratospheric aerosols - Observation and theory

Important chemical and physical roles of aerosols are discussed, and properties of stratospheric aerosols as revealed by experimental data are described. In situ measurements obtained by mechanical collection and scattered-light detection yield the overall size distribution of the aerosols, and analyses of preserved aerosol precursor gases by wet chemical, cryogenic and spectroscopic techniques indicate the photochemical sources of particle mass. Aerosol chemical reactions including those of gaseous precursors, those in aqueous solution, and those on particle surfaces are discussed, in addition to aerosol microphysical processes such as nucleation, condensation/evaporation, coagulation and sedimentation. Models of aerosols incorporating such chemical and physical processes are presented, and simulations are shown to agree with measurements. Estimates are presented for the potential aerosol changes due to emission of particles and gases by aerospace operations and industrial consumption of fossil fuels, and it is demonstrated that although the climatic effects of existing levels of stratospheric aerosol pollution are negligible, potential increases in those levels might pose a future threat.

Turco, R. P.↗
NASA NTRS1982

An analysis of the physical, chemical, optical, and historical impacts of the 1908 Tunguska meteor fall

An analysis is presented of the physical characteristics and photochemical aftereffects of the 1908 Tunguska explosive cometary meteor, whose physical manifestations are consistent with a five million ton object's entry into the earth's atmosphere at 40 km/sec. Aerodynamic calculations indicate that the shock waves emanating from the falling meteor could have generated up to 30 million tons of nitric oxide in the stratosphere and mesosphere. A fully interactive one-dimensional chemical-kinetics model of atmospheric trace constituents is used to estimate the photochemical consequences of such a large NO injection. The 35-45% hemispherical ozone depletion predicted by the model is in keeping with the 30 + or - 15% ozone variation reported for the first year after the Tunguska fall. Attention is also given to the optical anomalies which followed the event for indications of NO(x)-O(x) chemiluminescent emissions, NO2 solar absorption, and meteoric dust turbidity, along with possible climate changes due to the nearly one million tons of pulverized dust deposited in the mesosphere and stratosphere by the meteor.

Turco, R. P.↗
NASA NTRS1982

The satellite power system - Assessment of the environmental impact on middle atmosphere composition and on climate

Numerical models were developed to calculate the total deposition of watervapor, hydrogen, CO2, CO, SO2, and NO in the middle atmosphere from operation of heavy lift launch vehicles (HLLV) used to build a satellite solar power system (SPS). The effects of the contaminants were examined for their effects on the upper atmosphere. One- and two-dimensional models were formulated for the photochemistry of the upper atmosphere and for rocket plumes and reentry. An SPS scenario of 400 launches per year for 10 yr was considered. The build-up of the contaminants in the atmosphere was projected to have no significant effects, even at the launch latitude. Neither would there by any dangerous ozone depletion. It was found that H, OH, and HO2 species would double in the thermosphere. No measurable changes in climate were foreseen.

Whitten, R. C.↗
NASA NTRS1982

A study of mesospheric rocket contrails and clouds produced by liquid-fueled rockets

Changes in the atmospheric composition, particularly through the condensation of rocket vehicle exhaust, caused by the flights of 400 heavy lift launch vehicles (HLLV) to carry crews and materials into space to build a satellite solar power system (SPS) were examined. Attention was given to the formation of mesospheric contrails and clouds. A one-dimensional model was used to formulate the photochemistry and vertical transport of water vapor, its nucleation into an ice cloud, and the microphysical development of the cloud. Considering one HLLV launch per day for a decade, it is projected that the upper atmosphere water vapor concentration would be increased by 10-20%, thereby augmenting the size and opacity of natural noctilucent clouds by 50%. No climatological consequences are foreseen from the clouds, although spectacular noctiluminescent cloud displays are thought to be possible.

Turco, R. P.↗