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Wasson, J. T.

Publications and source records attributed to Wasson, J. T..

At least 91 records · Page 5

Trace element evidence regarding a chondritic component in howardite meteorites

The concentrations of siderophiles Ni, Ge, Ru, Ir, and Au and volatiles Zn, Ga, Cd, and In in howardite meteorites were determined and are discussed along with similar data for eucrites and diogenites. The concentrations of the chondritic component in howardites are remarkably high. The concentrations in four high-siderophile howardites are comparable to those found in mature soils from the lunar highlands. The amounts of excess volatiles are roughly consistent with those expected if the chondritic component resemble CI, CM, or E4 chondrites. Evidence indicates that the howardite parent body had a radius of several hundred kilometers, and the most probable formation location was 1-2 AU from the sun.

Chou, C.-L.↗

Siderophiles and volatiles in Apollo-16 rocks and soils

The duplicate and mean concentrations of eight trace elements (Ni, Zn, Ga, Ge, Cd, In, Ir, Au) in eight Apollo-16 soils, five rocks, and a metallic spherule were determined by radiochemical neutron-activation analysis (RNAA) following radiochemical separation. Data are presented and compared with analyses of Apollo-14 samples. The concentration of extralunar components in mature Apollo-16 soils is about 3.8%, and the samples contain a large amount of pre-Imbrium regolith. Volatiles, siderophiles, and cosmogenic isotopes are intercorrelated, largely as a result of mixing of North Ray crater ejecta having low concentrations with mature soils containing high concentrations. Light soils have higher concentrations of Zn, Ga, and Cd than dark mature and submature soils, which contain comparatively higher concentration of Sc and Fe. Volatility largely controls the distributions of Zn, Cd, and In in soils and soil breccias and probably affects the Ga distribution.

Wasson, J. T.↗

Classification and properties of iron meteorites

The paper describes the general requirements for a genetically significant scheme for classifying iron meteorites. Some of the properties which may be used to classify iron meteorites are reviewed, and a classification scheme based on Ga-Ni and Ge-Ni plots, taxonomic properties, and chemical properties is proposed. It is found that 95% of the irons can be assigned to a genetic group or an anomalous class.

Scott, E. R. D.↗

Compositional evidence regarding the influx of interplanetary materials onto the lunar surface

Siderophilic element/Ir ratios are higher in mature lunar soils from highlands sites than in those from mare sites. It is suggested that the population of materials responsible for the early intense bombardment of the moon had high ratios and that the population responsible for the essentially constant flux has low ratios. Arguments are summarized against the viewpoint that the siderophiles in most highlands breccias originated in basin-forming projectiles. Differences in mature soil siderophile concentrations at the Apollo 14 and 16 sites indicate a substantially greater concentration at the latter site immediately following the Imbrium event. Siderophile concentrations are used to estimate mean regolith depths at the landing sites. The long-lived flux is calculated to be 2.9 g per cm per aeon averaged over the past 3.7 aeons. Consideration of the relationship between mass fluence and time indicates that the mass flux decreased with a half-life of about 40 million years immediately following the Imbrium event.

Wasson, J. T.↗

Volatiles on the surface of Apollo 15 green glass and trace-element distributions among Apollo 15 soils

Zn, Ge, Cd, In, and Au have been detected in surficial deposits on Apollo 15 green-glass spherules, and it is suggested that these deposits are condensates from the magmatic gas phase which was responsible for the pneumatic expulsion of the green glass from the lunar interior. Thermodynamic data indicate that chlorides and fluorides were the dominant forms of the volatile metals. The Ar-40x content of a nongreen-glass soil fraction is greater than that found in green-glass. Mare and low-K Fra Mauro basalts seem to be the most prominent components of Apollo 15 soil. The correlation of Zn with Ar-40x and with Pb-204 is studied, and the distribution of quartz-normative and olivine-normative basalts is considered.

Chou, C.-L.↗

Fractionation of moderately volatile elements in ordinary chondrites

The CI chondrites are the most volatile-rich meteorites. Relative to the CI chondrites, the ordinary chondrites have lower abundances of refractory and volatile elements. Four types of fractionations are summarized in a table. Ordinary-chondrite/CI abundance ratios for moderately volatile elements in H- and L-group chondrites are presented in a graph. Possible explanations for the observed relations are considered, giving attention to several processes which could result in the separation of nebular solids and gases.

Wasson, J. T.↗

Mesosiderites. I - Compositions of their metallic portions and possible relationship to other metal-rich meteorite groups

The metal from 17 mesosiderites has been analyzed for Ni, Ga, Ge, and Ir by the techniques of atomic-absorption spectrometry and neutron activation. Most mesosiderite metal samples fall in a narrow compositional range: Ni, 7.0-9.0%; Ga, 13-16 ppm; Ge, 47-58 ppm; and Ir, 2.4-4.4 ppm. Most of those falling outside these ranges belong to Powell's (1971) least-metamorphosed type. Mesosiderite metal falls in the same general composition range as IIIAB irons, IIIE irons, pallasites and H-group chondrite metal. There are distinct differences in detail, however, and firm evidence for a close genetic relationship between any of these groups and the mesosiderites is lacking.

Wasson, J. T.↗

Volatile and siderophilic trace elements in the soils and rocks of Taurus-Littrow

Data are reported on 22 elements determined on 11 soils, one soil breccia, and two crystalline rocks from the Apollo 17 Taurus-Littrow landing site. The elements determined include the siderophilic elements Ni, Ge, Ir, and Au. The volatile elements considered include Na, Zn, Cd, and In. Attention is given to the extralunar component in soils and breccias, the orange-glass component in soils and breccias, and the labile elements in lunar soils.

Baedecker, P. A.↗

Volatile-element systematics and green glass in Apollo 15 lunar soils

A number of volatiles in Apollo 15 soils correlate with each other and with decreasing distance from the Apennine Front. These correlations can be understood in terms of a deposition of green glass and cogenetic volatiles on the flanks of the Front followed by addition of secondary magmatic volatiles including excess Ar-40. Mixing of these materials with mare-type regolith resulted in the observed volatile-element patterns. The absence of an increase in siderophilic element content with decreasing distance from the Front probably resulted from the failure of the steeply sloping front to develop a highlands-type mature regolith. Breccia 15015 has a siderophilic element signature typical of a mature Apollo 15 soil, which tends to rule out its transport to the site as part of an Autolycus or Aristillus ray.

Chou, C.-L.↗

Extralunar materials in cone-crater soil 14141.

Radiochemical neutron activation analysis has been used to determine Ni, Zn, Ga, Ge, Cd, In, Ir, and Au in duplicate samples of lunar soil 14141 and in one additional replicate each of soils 14163 and 14259. The concentrations of extralunar trace elements Ni, Ge, Ir, and Au in 14141 and 14163 are, respectively, about 69 and 82% as high as those in 14259. Although most of the mass of 14141 appears to be ejecta from Cone Crater, a sizable contamination by mature Fra Mauro soil such as 14259 is also present. The siderophilic-element concentrations of the subregolith Fra Mauro materials are estimated to be 25 plus or minus 25% of those observed in 14259.

Wasson, J. T.↗

Atmophilic elements in lunar soils

Ten volatile elements are more abundant in soil 14163 than in 14259 by factors of 1.4 or greater, too high to be explained by the 15% higher KREEP content of 14163. The enrichments suggest that these elements are easily volatilized by energetic events generated by solar particles or micrometeorites and as a result move from site to site through the lunar atmosphere. The elements Zn, C, and Cd are correlated with excess Ar-40 in Apollo 15 soils. Since concentrations also increase in the direction of the Apennine Front, the correlation chiefly indicates that the Front regolith is enriched in these elements relative to the Apollo 15 regolith away from the Front. The absence of known lunar rock types showing Zn and Cd concentrations as high as those in the Apollo 15 Front regolith or the Apollo 14 or 16 highlands regoliths and the relatively uniform concentrations of both elements in these soils despite differences in major element composition suggest that large amounts of these elements were released as volatiles during early lunar magmatic activity.

Chou, C.-L.↗

Formation of ordinary chondrites.

Most of the chemical and mineralogical properties of the ordinary chondrites were established by processes that occurred in the solar nebula during a short time span near the time of formation of the solar system. Four separate and distinct fractionation events appear to have been involved in their formation from more primitive material of mean solar-system composition. In order of occurrence these were a refractory-element fractionation, a siderophilic-element fractionation, a fractionation of slightly volatile elements, and a fractionation of highly volatile elements. In each of the four cases the most plausible fractionation mechanism involves a separation of gases from solids. The ambient temperature in the planetary portion of the solar nebula during the formation of these chondrites appears to have been characterized by two maximums.

Wasson, J. T.↗