Engineering Papers⌕ Search

Engineering topics

Wasson, J. T.

Publications and source records attributed to Wasson, J. T..

At least 73 records · Page 4

Mesosiderites and howardites - Igneous formation and possible genetic relationships

Neutron activation data are presented for major, minor, and trace elements in whole rock howardites and silicates from mesosiderites. Compositions of howardites and mesosiderites are similar and intermediate between those of eucrites and diogenites. It is indicated that mesosiderites have a higher normative silica component than howardites. It appears that this results partly from a higher content of a highly evolved igneous component and partly from in situ reduction of FeO to Fe followed by magnetic separation of metal prior to analysis. It is shown that light rare earth elements are enriched in some mesosiderites.

Mittlefehldt, D. W.↗

The compositional-petrographic search for pristine nonmare rocks - Third foray

In the present paper, eleven nonmare samples are characterized petrographically and by composition, including numerous key trace elements (siderophiles and incompatibles). At least eight of the samples were identified as positively pristine, which means that they preserve faithfully the compositional variety of the original lunar crust. Anorthosites, troctolites, and norites appear to be the major 'primary' constituents of the crust.

Warren, P. H.↗

Cooling rates of group IVA iron meteorites

Cooling rates of six group IVA iron meteorites were estimated by a taenite central Ni concentration-taenite half-width method. Calculated cooling rates range from 13 to 25 C/Myr, with an average of 20 C/Myr. No correlation between cooling rate and bulk Ni content is observed, and the data appear to be consistent with a uniform cooling rate as expected from an igneous core origin. This result differs from previous studies reporting a wide range in cooling rates that were strongly correlated with bulk Ni content. The differences result mainly from differences in the phase diagram and the selected diffusion coefficients. Cooling rates inferred from taenite Ni concentrations at the interface with kamacite are consistent with those based on taenite central Ni content.

Willis, J.↗

A core origin for group IVA iron meteorites - A reply to Moren and Goldstein

Because uncertainties in experimental data are large, one has considerable latitude in choosing the input parameters needed to calculate iron meteorite cooling rates. The best way to test input parameters is by examining their ability to yield the observed properties of the meteorites. Our phase diagram yields fits to kamacite profiles that are superior to those based on the Moren-Goldstein phase diagram. Our method of allowing for the effect of P on the Ni diffusion coefficient takes into account the enhancement in this effect with decreasing temperature; Moren and Goldstein use a relationship derived for a temperature of 1100 C, well outside the 700-350 C range where kamacite growth occurs. Use of our input parameters yields cooling rates in IVA irons that are independent of composition, consistent with a core origin. Since the fractionation of siderophiles in group IVA also indicates a core origin, we conclude that this is the correct model for this group.

Willis, J.↗

Maximum temperatures during the formation of the solar nebula

Most numerical models of cloud collapse yield the result that temperatures were never above 1000 K at distances not less than 1 AU from the axis of the forming solar system. In contrast, most meteorite researchers hold that higher temperatures are necessary to account for a variety of elemental fractionations found between groups of meteorites, between members of a single group, and between components of a single meteorite. A summary of the researchers' viewpoint is presented. An investigation is conducted of the evidence which indicates that chondrites were formed in the solar nebula. Attention is also given to the maximum nebular temperatures during the formation of chondrites.

Wasson, J. T.↗

Compositional-petrographic investigation of pristine nonmare rocks

Twenty-six highlands rocks and clasts are characterized petrographically and by determinations of major and trace elements, including key incompatibles and siderophiles. Most samples were selected in the hope that they would prove to be pristine, i.e., unremelted, monomict products of endogenous lunar magmatism. About 3/5 are almost certainly pristine, while about 1/4 are definitely non-pristine, and the remainder await further study before pristinity may be either proven or disproven. All of the major conclusions of Warren and Wasson (1977) about the significance of pristine nonmare rocks and the nature of the lunar crust still appear correct. Probably none, or virtually none, of the samples possessing the attributes by which 'pristinity' is judged formed as 'secondary differentiates' in giant impact melt pools, as Delano and Ringwood (1978) propose. Those which possess markedly plutonic textures (e.g., 62236) almost certainly did not.

Warren, P. H.↗

Four new iron meteorite finds

Four new iron meteorites are described: Buenaventura (IIIB) from Chihuahua, Mexico: mass 114 kg; Denver City (anomalous) from Texas, USA: mass 26.1 kg; Kinsella (IIIB) from Alberta, Canada: mass 3.7 kg; and Tacoma (IA) from Washington, USA: mass 17 g. Denver City is unique - i.e., not related to any other known iron. Tacoma is the smallest iron meteorite recorded. The meteorites were initially discovered in 1969, 1975, 1946, and between 1925 and 1932, respectively.

Scott, E. R. D.↗

Distribution of 28 elements in size fractions of lunar mare and highlands soils

Four volatile, six siderophile and 18 generally lithophile elements were determined in six sieve fractions of mare soil 15100 (moderately mature) and seven sieve fractions of highlands soil 66080 (highly mature). Previous work (Boynton et al., 1976) showed that the volatile elements in lunar soils were enriched in the finest size fraction relative to the coarsest factors by up to about 20. The present investigation tests Boynton's interpretation that the distribution pattern of the volatiles indicates the presence of two components: a volume-correlated component having volatile concentrations independent of grain size and a surface-correlated component with concentration increasing with decreasing grain size.

Boynton, W. V.↗

Nebular condensation of moderately volatile elements and their abundances in ordinary chondrites

Two models accounting for the concentrations of moderately volatile elements in ordinary chondrites are discussed. The first relies on an apparent correlation between ordinary chondrite/type-I carbonaceous chondrite abundance ratios and ideal solution-condensation temperatures of such elements as Sn, Cu, Li, Na, and Mn to construct a model in which volatiles are lost as gases before nebular condensation or as finely-divided solids that are incompletely agglomerated, and the condensation/agglomeration efficiency declines as a function of time. The second theory largely discounts this gas-dust diffraction effect and instead proposed condensation on matrix and volatization from chondules and coarse metal grains as mechanisms explaining the apparent existence of three distinct classes of volatile-element abundance in ordinary chondrites.

Wai, C. M.↗

Pristine nonmare rocks and the nature of the lunar crust

It is shown that the interdisciplinary study of the nonmare lunar rocks based on trace element, major element, and isotopic data plus petrographic evidence can succeed in amassing a large suite of demonstrably pristine rocks, and that the relative numbers of these rocks are not in accord with statistics amassed on soil fragments and glasses. The term 'pristine' is taken to mean rocks with primary compositions (albeit not necessarily textures) produced by lunar endogenous igneous processes. Melt rocks and crystalline matrix breccias produced by impact processes are excluded. A petrographic synonym for pristine would be 'unremelted, monomict'. It is found that anorthositic norites and noritic anorthosites were rare as primary nonmare rocks. Mechanical mixing appears to have been the dominant petrogenetic process on the highlands.

Warren, P. H.↗

SCCRV, a major component of highlands rocks

An investigation was conducted of the composition of lunar highlands samples rich in mafics. Most of the samples were Apollo 16 rocks. The compositional data for 13 lunar rocks are listed in a table. The nonpristine rocks 64815 and 77545 having essentially identical KREEP contents of about 32% have very similar, high contents of the mafic component SCCRV. The same amounts of rather similar ingredients were mixed at locations 1000 km apart. The composition of SCCRV is discussed. According to the three most plausible hypotheses for the origin of SCCRV which are proposed the SCCRV is primordial material, SCCRV consists entirely or mainly of a single type of lunar rock, or SCCRV resulted from the mixing of two or more lunar materials.

Wasson, J. T.↗

Explanation for the very low Ga and Ge concentrations in some iron meteorite groups

Parallels between the abundance patterns of moderately volatile elements in iron meteorites and ordinary chondrites are pointed out and discussed in relation to condensation processes in the solar nebula. The discussion is centered around a graph in which As, Cu, Ga, Ge to Ni ratios, normalized to CI chondrites, are compared for IVB, IVA, IVB, and IIIAB irons and H-group ordinary chondrites. The patterns suggest that the same volatile loss mechanism was at work for both IVB irons and ordinary chondrites, but was more efficient in the IVB process. A picture for the process at the IVB location is proposed, according to which condensation occurred when temperature decreased rapidly and trace metals condensed as a fine aerosol that was later blown away by a T-Tauri solar storm. Condensation at the H-group location was more complete because of a less rapid temperature decrease, allowing trace metals to diffuse deeper into Fe-Ni grains. Possible ways in which IVA conditions may have differed from IIIAB or H conditions are also proposed and discussed.

Wasson, J. T.↗

Chemical classification of iron meteorites. VIII - Groups IC, IIE, IIIF and 97 other irons

Results are reported for determinations of Ni, Ga, Ge, and Ir concentrations in 106 iron meteorites. Three new groups are defined (IC, IIE, and IIIF) which contain 10, 12, and 5 irons, respectively. It is noted that group IC is a cohenite-rich group distantly related to IA, group IIE consists of those irons previously designated as Weekeroo Station type together with five others having similar compositions but diverse structures, and group IIIF is a well-defined group of low-Ni and low-Ge irons. Several anomalous irons are discussed, including a cluster of five plessitic octahedrites and ataxites with Ge/Ga atomic ratios ranging from 10 to 16 and a meteorite that has the second highest Ni content of any iron. It is shown that the IIE irons are compositionally similar to the mesosiderites and pallasites, and it is suggested that the three groups probably formed at approximately the same heliocentric distance.

Scott, E. R. D.↗

Volatile compounds released during lunar lava fountaining

A modified radiochemical neutron activation analysis was used to determine 24 elements in three sieve separates and in HCl leach, HF etch, and residue fractions of the 500-62 micron separate of orange glass fines 74220. Six elements - In, Cd, Zn, Ga, Ge, and Au - were strongly concentrated in the leach, indicating that they were present as a surface deposit, probably a sublimate resulting from condensation of lava-fountain volatiles which expelled the orange glass onto the lunar surface.

Wasson, J. T.↗