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Trajmar, S.

Publications and source records attributed to Trajmar, S..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Cross Sections for Electron Scattering by Ground State Ba; Elastic Scattering and Excitation of the ...6s6p (sup 1)P(sub 1) Level

Differential cross sections for elastic and inelastic (6s6p (sup 1)P(sub 1)) electron scattering from ground state Ba atom have been measured at 5eV, 10eV, 15eV, and 20eV impact energies in the angular range from 0(sup 0) to 130(sup 0). Extrapolation to the larger angles have been performed using theoretical calculations as a guide, and integral and momentum transfer cross sections were derived. Theoretical calculations based on two channel clos coupling and relativistic and non-relativistic distorted wave methods have been compared with the present results. Good agreement between experiment and various theoretical results is found at small scattering angles but significant deviations exist at larger scattering angles.

electon scattering extrapolation scattering angles↗
NASA NTRS1991

Electron impact excitation and dissociation of N2 via the b 1Pi(u) state

Electron impact excitation of the b 1Pi(u) state in N2 plays a prominent role in the dissociation of the molecule and thus in the production of atomic nitrogen in planetary atmospheres. Electron impact excitation cross sections combined with electron-impact-induced fluorescence measurements can yield the corresponding dissociation cross sections. Serious discrepancies exist among excitation cross sections reported in the literature. To clarify the situation, these cross sections were measured at two impact energies using electron energy loss spectroscopy. The new results are in agreement with recent values deduced from optical measurements and fall midway between previous results which are too high or low by factors of 2.

Ratliff, J. M.↗
NASA NTRS1990

Electron impact excitation of coronene

A preliminary study of the electron-impact excitation of thermally evaporated coronene at 550 C was carried out using electron-energy-loss spectroscopy. Measurements of the energy-loss spectra of coronene at high (100 eV) and low (5-20 eV) impact energies are presented. One of the high-energy spectra was converted to an apparent generalized oscillator strength spectrum and compared to the photoabsorption spectrum of coronene. Observations concerning vibrational excitation of coronene by electron impact are also presented and discussed.

Khakoo, M. A.↗
NASA NTRS1990

Influence of a finite scattering volume on the determination of electron-impact coherence parameters

Superelastic electron scattering from laser-excited Ba-138 ...6s6p (1)P is investigated both theoretically and experimentally. The theoretical framework is developed and incorporated into a model of a realistic scattering geometry of finite spatial extent. Model calculations predict that the dependence of the superelastic scattering intensity on the linear polarization direction of the laser beam can be severely distorted due to the existence of a finite scattering volume. Measurements obtained confirm the presence of this distortion and are well described by the model calculations. Conclusions are drawn concerning the influence of this effect on the extraction of electron-impact coherence parameters.

Zetner, P. W.↗
NASA NTRS1990

Electron-impact spectroscopy

The methods of electron impact spectroscopy and cross section measurements are discussed and compared to optical spectroscopy. A brief summary of the status of this field and the available data is given.

Trajmar, S.↗
NASA NTRS1989

Principles and procedures for determining absolute differential electron-molecule (atom) scattering cross sections

Procedures and calibration techniques for measuring the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples. The elastic DCS for the molecule under study is first determined by calibration against helium using the relative flow technique. The second step involves the production of energy-loss spectra for the instrument response function, the unfolding of overlapping inelastic structures and the normalization of inelastic intensities to the elastic cross sections. It is concluded that this method of determining absolute differential electron-molecule (atom) scattering cross sections is generally applicable and provides reliable results.

Nickel, J. C.↗
NASA NTRS1989

Problems associated with the measurement of coherence parameters - Superelastic electron scattering by laser-excited Ba-138(...6s6p1P1) atoms

Measurements of superelastic scattering of electrons by laser-excited Ba-138(...6s6p1P1) atoms were carried out. An asymmetry observed has been explained using a model of scattering from a target with finite dimensions. This model employed coherence parameters which were calculated in the distorted-wave approximation. The results indicated that the interpretation of coherence experiments in terms of scattering from a pointlike target can lead to serious errors in the deduction of coherence parameters at low scattering angles.

Zetner, P. W.↗
NASA NTRS1987

Electron-impact excitation cross sections for the b 3Sigma(+)nu state of H2

Differential and integral cross sections for electron-impact excitation of the b 3Sigma(+)nu state of H2 have been determined in the 20-100-eV impact energy region. The calibration of the cross sections was achieved through the H2 elastic scattering cross sections, which in turn were normalized to absolute He elastic scattering cross sections. Comparison is made with available experimental data and with theoretical results applying Born-Ochkur-Rudge, distorted-wave, and close-coupling approximations.

Khakoo, M. A.↗
NASA NTRS1986

Electron-impact ionization of laser-excited Ba-138 (... 5p6 6s 6p) and Ba-138 (... 5p6 6s 5d) atoms

Electron-impact ionization cross sections for laser-excited Ba-138 (... 5p6 6s 6p; 1P1, M = - 1) and cascade-populated Ba-138 (... 5p6 6s 5d; 1D + 3D) atoms were measured in the threshold to 10 eV energy range. The peak cross sections for the excited species are about a factor of 2 larger than that for ground-state Ba. In addition, it was demonstrated that ionization from individual magnetic substates of various hyperfine levels can be studied. The ionization cross sections in the case of Ba-138 (1P1) were found to be equal for the M = 0 and for the M = + or - 1 sublevels within the experimental error limit.

Trajmar, S.↗
NASA NTRS1986

A polarisation correlation study of the excitation of the H2 d3Piu (v1 = 0, N1 = 1) level by electron impact

Full details are given of an experiment in which the three normalized Stokes' parameters characterizing the decay of the electron impact excited d3Piu (v1 = 0, N1 = 1) rotational level of H2 were determined in an electron-photon coincidence experiment at 25 eV impact energy and over the angular range of 20-60 deg. An analysis shows how these parameters are related to the state multipoles characterizing the excited state. The rather low degree of coherence which was observed is consistent with various depolarizing effects, namely the averaging over magnetic sublevels which occurred in both the excitation and decay channels and also the perturbations due to fine and hyperfine structure relaxations.

Mcconkey, J. W.↗
NASA NTRS1986

Elastic electron scattering cross sections for molecular hydrogen

Using an electron-beam - molecular-beam apparatus and employing the relative flow technique, ratios of the differential elastic scattering cross sections (DCSs of H2 to He were measured at incident electron energies of 15-100 eV and over the angular range of 10-125 degrees. From these ratios, the absolute elastic DCSs for H2 were determined by normalization to accurate, available elastic DCSs of He. Since pure rotational structure was not resolved in this work, the DCSs reported are the sum of elastic and rotational excitations of H2 at room temperature. The reliability of the relative flow normalization to He was checked at each energy and angle by performing similar elastic DCS measurements on Ne (for which the cross sections are known). The resulting absolute Ne DCSs were found to be in good agreement (within 10 percent with the Ne elastic DCSs measured previously (Register and Trajmar, 1984). From the DCSs, integral and momentumtransfer cross sections were calculated. The present results are compared with other recent measurements.

Khakoo, M. A.↗
NASA NTRS1986

Electron-impact excitation of the a3Sigma(+)g, B1Sigma(+)u, c3Pi u, and C1Pi u states of H2

Normilized differential and integral cross sections for electron-impact excitation of the dipole-allowed B1Sigma(+)u, C1Pi u and dipole-forbidden a3Sigma(+)g, c3Pi u states of molecular hydrogen have been determined by analysis of energy-loss spectra obtained with a crossed-beam apparatus at electron-impact energies of 20, 30, 40 and 60 eV and scattering angles ranging from 10 to 120 degrees. Normalization of the data was achieved by utilizing elastic differential cross sections measured previously by (Khakoo and Trajmar, 1986). The cross sections are compared with other available theoretical and experimental data.

Khakoo, M. A.↗
NASA NTRS1985

Rotationally resolved electron-photon coincidence study of H2(d 3 Pi u) excitation

The three normalized Stokes' parameters characterizing the decay of the electron impact excited d 3 Pi u (V1=O, N1=1) rotational level of H2 were determined in an electron-photon coincidence experiment at 25 eV impact energy and 60 deg scattering angle. The low degree of polarization (coherence) which was observed could be caused by both the averaging over the magnetic sublevels of the ground state of the target and the fine and hyperfine relaxation process. The average angular momentum transfer perpendicular to the scattering plane from the electrons to the molecules was found to be near zero in this excitation process.

Mcconkey, J. W.↗
NASA NTRS1985

Total electron scattering cross sections. I - He, Ne, Ar, Xe

The apparatus and experimental procedures used to obtain total electron scattering cross sections are described, and results are presented for He, Ne, Ar and Xe in the 4-300 eV incident energy range, together with statistical errors. The results are generally found to be in good agreement with previous data except at low impact energies. Serious discrepancies remain in Xe below 20 eV impact energy.

Nickel, J. C.↗
NASA NTRS1984

Differential, integral, and momentum-transfer cross sections for elastic electron scattering by neon - 5 to 100 eV

Relative elastic-scattering differential cross sections were measured in the 5-100-eV impact energy and 10-145 deg angular ranges. Normalization of these cross sections was achieved by utilizing accurate total electron-scattering cross sections. A phase-shift analysis of the angular distributions in terms of real phase shifts has been carried out. From the differential cross sections, momentum-transfer cross sections were obtained and the values of the critical energy and angle were established (associated with the lowest value of the differential cross section) as 62.5 + or - 2.5 eV and 101.7 deg + or - 1.5 deg, respectively. The present phase shifts, the critical parameters, and differential, integral, and momentum-transfer cross sections are compared to previous experimental and theoretical results. The error associated with the present data is about 10 percent.

Register, D. F.↗
NASA NTRS1984

Electron-impact-excitation cross sections for electronic levels in neon for incident energies between 25 and 100 eV

Absolute differential cross sections (DCS's) for electron-impact excitation of the lowest forty electronic levels in atomic neon have been determined for incident electron energies of 30 and 50 eV, for the four lowest levels at 25 eV, and two levels at 100 eV. The cross sections for these forty electronic levels are grouped into fifteen features, six of which represent excitation to resolved single electronic levels and the remaining nine which contain the unresolved contributions from two or more electronic levels. These DCS's were extrapolated to 0 deg and 180 deg and integrated to yield absolute integral cross sections as a function of incident electron energy. The results are compared to other experimental and theoretical results.

Register, D. F.↗
NASA NTRS1984

Electron impact spectroscopy of high temperature species

The application of the methods of electron impact spectroscopy to the study of high temperature species is discussed. Electron scattering by metal vapors (Ba, Bi, Cu, Mn, Tl, Zn), alkali halide molecules, and KOH are described as demonstrative examples.

Trajmar, S.↗