Engineering topics

Toon, O. B.

Publications and source records attributed to Toon, O. B..

At least 91 records · Page 5

NASA NTRS1982

Noctilucent clouds - Simulation studies of their genesis, properties and global influences

A numerical model is presented for testing theories of the physical mechanisms of noctiluminescent clouds. The time-dependent, one-dimensional model describes the formation, evolution, and properties of the clouds as interactive ice crystals, meteoric dust, water vapor, and ionized air. Mesopause temperatures below 140 K are found to be necessary for the formation of the clouds, conditions existing only at high latitudes in the summer. No predominant nucleation particle could be identified for the formation of the clouds, although a time period of up to a day was determined as necessary for materialization, which lasts several days. Several atmospheric and environmental conditions were characterized which enhance the appearance of the noctiluminescent clouds. One conclusion reached is that the numerous launches necessary to build a solar power satellite system would not significantly exacerbate noctiluminescent cloud formation.

Turco, R. P.↗

NASA NTRS1982

Volcanoes and climate

The evidence that volcanic eruptions affect climate is reviewed. Single explosive volcanic eruptions cool the surface by about 0.3 C and warm the stratosphere by several degrees. Although these changes are of small magnitude, there have been several years in which these hemispheric average temperature changes were accompanied by severely abnormal weather. An example is 1816, the "year without summer" which followed the 1815 eruption of Tambora. In addition to statistical correlations between volcanoes and climate, a good theoretical understanding exists. The magnitude of the climatic changes anticipated following volcanic explosions agrees well with the observations. Volcanoes affect climate because volcanic particles in the atmosphere upset the balance between solar energy absorbed by the Earth and infrared energy emitted by the Earth. These interactions can be observed. The most important ejecta from volcanoes is not volcanic ash but sulfur dioxide which converts into sulfuric acid droplets in the stratosphere. For an eruption with its explosive magnitude, Mount St. Helens injected surprisingly little sulfur into the stratosphere. The amount of sulfuric acid formed is much smaller than that observed following significant eruptions and is too small to create major climatic shifts. However, the Mount St. Helens eruption has provided an opportunity to measure many properties of volcanic debris not previously measured and has therefore been of significant value in improving our knowledge of the relations between volcanic activity and climate.

Toon, O. B.↗

NASA NTRS1982

Simulation studies of the physical and chemical processes occurring in the stratospheric clouds of the Mount St. Helens eruptions of May and June 1980

The large and diverse set of observational data collected in the high-altitude clouds of May 18, May 25, and June 13, 1980 was organized and analyzed for trends which reveal the processes at work. The data were used to guide and constrain model simulations of the volcanic eruptions. A comprehensive one-dimensional model of stratospheric sulfate aerosols, sulfur precursor gases, and volcanic ash and dust particles is utilized which accounts for homogeneous and heterogeneous chemistry in the clouds, aerosol nucleation and growth, and cloud expansion. Computational results are given for the time histories of the gaseous species concentrations, sulfate aerosol size dispersions, and ash burdens in the eruption clouds. The long-term buildup of stratospheric aerosols in the Northern Hemisphere and the persistent effects of injected chlorine and water vapor on ozone are discussed. It is concluded that SO2, water vapor, and ash are the most important substances injected by the volcano into the stratosphere, with respect to both the widespread effects on composition and the impact on climate. It is found that the volcano probably had little influence on the climate ( 0.05 K global surface cooling) or on stratospheric ozone ( 0.2 percent maximum hemispherical reduction).

Turco, R. P.↗

NASA NTRS1982

Space Shuttle ice nuclei

Estimates are made showing that, as a consequence of rocket activity in the earth's upper atmosphere in the Shuttle era, average ice nuclei concentrations in the upper atmosphere could increase by a factor of two, and that an aluminum dust layer weighing up to 1000 tons might eventually form in the lower atmosphere. The concentrations of Space Shuttle ice nuclei (SSIN) in the upper troposphere and lower stratosphere were estimated by taking into account the composition of the particles, the extent of surface poisoning, and the size of the particles. Calculated stratospheric size distributions at 20 km with Space Shuttle particulate injection, calculated SSIN concentrations at 10 and 20 km altitude corresponding to different water vapor/ice supersaturations, and predicted SSIN concentrations in the lower stratosphere and upper troposphere are shown.

Turco, R. P.↗

NASA NTRS1982

Predicted electrical conductivity between 0 and 80 km in the Venusian atmosphere

Calculations of the space charge, ion density, and conductivity in the Venus atmosphere were made. The presence of the cloud particles on Venus causes a profund reduction in the calculated values of the ion density and conductivity compared to the values that are obtained without consideration of the cloud particles. When the cloud particles are included in the calculations, the results for the ion density and conductivity are approximately the same as those of the terrestrial atmosphere at the same pressure-altitude. Because the particles span such a large range of sizes and are abundant over a substantial range of pressure, the space charge varies strongly with altitude and particle size. Differential settling of the particles is expected to produce weak electric fields in the clouds.

Borucki, W. J.↗

NASA NTRS1982

The ultraviolet absorber on Venus - Amorphous sulfur

It is pointed out that the identity of the chemical species responsible for the yellow coloration of the clouds of Venus and for the dark features which dapple the planet at ultraviolet wavelengths has long been a mystery. Independent pieces of evidence, discovered recently, suggest now that amorphous sulfur is the so-called UV absorber. A review of earlier ideas and controversies is presented, and attention is given to a new physical-chemical model of the Venus clouds which shows that sulfur should form there. A description is provided of physical characteristics of the cloud particles that, in comparison with model predictions, indicate the presence of sulfur. Optical data suggesting that elemental sulfur occurs in the clouds is discussed, and cloud morphological evidence for sulfur is considered.

Toon, O. B.↗

NASA NTRS1982

Quasi-periodic climate changes on Mars - A review

The current understanding of the manner in which astronomical variations modulate the Martian climate and thereby lead to the occurrence of laminated polar terrain is considered. The seasonal cycles of dust, carbon dioxide and water, and their responses to astronomical variations, are studied. After an assessment of the way in which these cycles presently operate, for which pertinent spacecraft and ground-based observations are extant, attempts to predict how these cycles may differ under conditions of high and low obliquity and eccentricity are discussed. Attention is given not only to those areas in which there is broad agreement, but also to the controversial and speculative. Key questions include the proportion of dust and water ice in the laminae and its variations within individual layers, the relative importance of older laminae and lower-latitude material as sources of new laminae, and the factors responsible for the youth of the laminated terrain.

Pollack, J. B.↗

NASA NTRS1982

Stratospheric aerosols - Observation and theory

Important chemical and physical roles of aerosols are discussed, and properties of stratospheric aerosols as revealed by experimental data are described. In situ measurements obtained by mechanical collection and scattered-light detection yield the overall size distribution of the aerosols, and analyses of preserved aerosol precursor gases by wet chemical, cryogenic and spectroscopic techniques indicate the photochemical sources of particle mass. Aerosol chemical reactions including those of gaseous precursors, those in aqueous solution, and those on particle surfaces are discussed, in addition to aerosol microphysical processes such as nucleation, condensation/evaporation, coagulation and sedimentation. Models of aerosols incorporating such chemical and physical processes are presented, and simulations are shown to agree with measurements. Estimates are presented for the potential aerosol changes due to emission of particles and gases by aerospace operations and industrial consumption of fossil fuels, and it is demonstrated that although the climatic effects of existing levels of stratospheric aerosol pollution are negligible, potential increases in those levels might pose a future threat.

Turco, R. P.↗

NASA NTRS1982

An analysis of the physical, chemical, optical, and historical impacts of the 1908 Tunguska meteor fall

An analysis is presented of the physical characteristics and photochemical aftereffects of the 1908 Tunguska explosive cometary meteor, whose physical manifestations are consistent with a five million ton object's entry into the earth's atmosphere at 40 km/sec. Aerodynamic calculations indicate that the shock waves emanating from the falling meteor could have generated up to 30 million tons of nitric oxide in the stratosphere and mesosphere. A fully interactive one-dimensional chemical-kinetics model of atmospheric trace constituents is used to estimate the photochemical consequences of such a large NO injection. The 35-45% hemispherical ozone depletion predicted by the model is in keeping with the 30 + or - 15% ozone variation reported for the first year after the Tunguska fall. Attention is also given to the optical anomalies which followed the event for indications of NO(x)-O(x) chemiluminescent emissions, NO2 solar absorption, and meteoric dust turbidity, along with possible climate changes due to the nearly one million tons of pulverized dust deposited in the mesosphere and stratosphere by the meteor.

Turco, R. P.↗

NASA NTRS1982

A study of mesospheric rocket contrails and clouds produced by liquid-fueled rockets

Changes in the atmospheric composition, particularly through the condensation of rocket vehicle exhaust, caused by the flights of 400 heavy lift launch vehicles (HLLV) to carry crews and materials into space to build a satellite solar power system (SPS) were examined. Attention was given to the formation of mesospheric contrails and clouds. A one-dimensional model was used to formulate the photochemistry and vertical transport of water vapor, its nucleation into an ice cloud, and the microphysical development of the cloud. Considering one HLLV launch per day for a decade, it is projected that the upper atmosphere water vapor concentration would be increased by 10-20%, thereby augmenting the size and opacity of natural noctilucent clouds by 50%. No climatological consequences are foreseen from the clouds, although spectacular noctiluminescent cloud displays are thought to be possible.

Turco, R. P.↗

NASA NTRS1982

Importance of heterogeneous processes to tropospheric chemistry - Studies with a one-dimensional model

A one-dimensional, time-dependent model of tropospheric air composition is developed which incorporates several heterogeneous physical and chemical processes. The model includes the interaction of gases, aerosols, and hydrometeors through the physical mechanisms of nucleation, condensation, evaporation, coagulation, coalescence, and deliquescence. Precipitation, sedimentation, and dry deposition act to remove material from the atmosphere, while chemical transformations occur both in the vapor and the condensed phases. The model also incorporates the sources and vertical diffusion of gases and particles, as well as changes in the solar intensity caused by light-scattering from aerosols and clouds. Preliminary simulations made using this model indicate that rainout and washout processes strongly influence the distributions of tropospheric gases and aerosols under certain conditions.

Turco, R. P.↗

NASA NTRS1982

Evolution of an impact-generated dust cloud and its effects on the atmosphere

A simulation is carried out of the evolution of an optically thick dust cloud in the earth's atmosphere, and calculations are made of the effects that such a dust cloud would have on the amount of visible light reaching the surface and the temperature at the earth's surface. It is found that large quantities of dust remain in the atmosphere for periods of only three to six months. This duration is fixed by the physical processes of coagulation; these cause the rapid formation of micron-sized particles and sedimentation that quickly removes the particles from the atmosphere. The duration of the event is found to be nearly independent of the initial altitude, initial particle size, initial mass, atmospheric vertical diffusive mixing rate, and rainout rate. It depends to a slight extent on the particle density and the probability that colliding particles stick together to form a larger particle. In addition, the duration is limited by the rate at which the debris spreads from the initial impact site. A doubling code is used to calculate the visible radiative transfer in the dust clouds. It is found that light levels are too low for vision for one to six months and too low for photosynthesis for two months to one year.

Toon, O. B.↗

NASA NTRS1981

Quasi-periodic climatic changes on Mars and earth

Evidence of climatic changes on Mars and the earth due to geologic and astronomical variations is discussed. Finely striped ice-free bands in the Martian polar caps have been taken to indicate that long term variations in the orbit and axial tilt of Mars have precipitated these features at the rate of a mm/yr. Photogrammetric and photometric methods have contributed to measurements of the composition and depth of the Martian caps (14-46 m), and observations of higher solar energy absorption in the northern ice cap implies greater dust deposition in that region than on the south cap; however, the transport mechanisms are not well understood. Comparisons of earth and Martian climatic variations data are made, noting a lack of information on the age intervals of marine and nonmarine sediments on the earth. The possibilities of using quantitative data other than layer thickness to constrain climate models are discussed, and the slope or albedo of layers, or the spacing of polar undulations are suggested.

Cutts, J. A.↗

NASA NTRS1981

Absorption of visible radiation in atmosphere containing mixtures of absorbing and nonabsorbing particles

The presence of a strongly absorbing material, tentatively identified as graphitic carbon, or 'soot', is indicated by measurements of single-scattering albedo of tropospheric aerosols. Although theoretical calculations based on models of the ways in which soot may mix with other aerosol materials yield the single-scattering albedo values of 0.6, accounted for by a minimum 20% soot by volume, in urban regions and 0.8, yielded by 1-5% soot by volume, in rural settings, it is found that these same values can be produced by similar amounts of the iron oxide magnetite. Magnetite is shown to be indistinguishable from soot by optical measurements performed on bulk samples, and calculation of various mixtures of soot indicate the difficulty of determining aerosol composition by optical scattering techniques.

Ackerman, T. P.↗

NASA NTRS1981

Algorithms for the calculation of scattering by stratified spheres

Efficient, numerically stable, methods for the calculation of light-scattering intensity functions for concentrically coated spheres are discussed. Earlier forms of these equations are subject to various numerical difficulties which give rise to significant errors, especially for thin absorbing shells. The present equations are accurate for all refractive indices, for large and small particles, and for cores with any relative size.

Toon, O. B.↗

NASA NTRS1981

Tunguska meteor fall of 1908 - Effects on stratospheric ozone

The Tunguska meteor, whose disintegration over Siberia in 1908 may have generated as much as 30 million metric tons of nitric oxide (NO) in the stratosphere and mesosphere, is discussed. The photochemical aftereffects of the event are simulated using a comprehensive model of atmospheric trace composition. Calculations are made which indicate that up to 45% of the ozone in the Northern Hemisphere may have been depleted by the meteor's nitric oxide cloud early in 1909 and that large ozone reductions may have persisted until 1912. Measurements of atmospheric transparency by the Smithsonian Astrophysical Observatory for the years 1909-1911 reveal evidence of a steady ozone recovery from unusually low levels in early 1909, implying a total ozone deficit of 30 + or - 15%. The coincidence in time between the observed ozone recovery and the Tunguska meteor fall suggests that the event may provide a test of current ozone depletion theories.

Turco, R. P.↗

NASA NTRS1981

Effects of meteoric debris on stratospheric aerosols and gases

Characterizations of meteoric dust height and size distributions are obtained using Hunten's calculations of meteor ablation and recondensation rates. The contribution of meteor residues to aerosol composition, the role of meteoric dust as condensation nuclei, and the effects of meteor debris on aerosol size distributions are quantified, and particle surface areas are estimated. The potential importance of heterogeneous chemistry for stratospheric trace gases is discussed. The interaction between H2SO4 vapor and meteor metal vapors is investigated. It is concluded that meteoric particles may dominate the natural stratospheric aerosols at small (less than .01 micron radius) and large (greater than 1 micron radius) sizes under normal conditions.

Turco, R. P.↗

NASA NTRS1981

Stratospheric hydroxyl radical concentrations - New limitations suggested by observations of gaseous and particulate sulfur

A one-dimensional aerosol model is employed in investigating the sensitivity of the stratospheric distributions of gaseous sulfur compounds and sulfate aerosol particles to changes in OH and CS2 concentrations, in eddy diffusion coefficients, and in important chemical rate constants. By comparing model predictions with recent observational data for SO2, OCS, and particulates, it is found that, with regard to atmospheric sulfur, CS2 is only a secondary source of sulfur for the stratosphere relative to OCS and that background tropospheric CS2 concentrations by volume are likely to be less than 70 parts per trillion. It is also established that under stratospheric conditions the rate coefficients for the reactions of OH with OCS and CS2 may be substantially smaller than the room temperature laboratory values of Kurylo (1978).

Turco, R. P.↗