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Pickett, H. M.

Publications and source records attributed to Pickett, H. M..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Validation of the Aura Microwave Limb Sounder middle atmosphere water vapor and nitrous oxide measurements

The quality of the version 2.2 (v2.2) middle atmosphere water vapor and nitrous oxide measurements from the Microwave Limb Sounder (MLS) on the Earth Observing System (EOS) Aura satellite is assessed. The impacts of the various sources of systematic error are estimated by a comprehensive set of retrieval simulations. Comparisons with correlative data sets from ground-based, balloon and satellite platforms operating in the UV/visible, infrared and microwave regions of the spectrum are performed. Precision estimates are also validated, and recommendations are given on the data usage. The v2.2 H2O data have been improved over v1.5 by providing higher vertical resolution in the lower stratosphere and better precision above the stratopause. The single-profile precision is ~0.2–0.3 ppmv (4–9%), and the vertical resolution is ~3–4 km in the stratosphere. The precision and vertical resolution become worse with increasing height above the stratopause. Over the pressure range 0.1–0.01 hPa the precision degrades from 0.4 to 1.1 ppmv (6–34%), and the vertical resolution degrades to ~12–16 km. The accuracy is estimated to be 0.2–0.5 ppmv (4–11%) for the pressure range 68–0.01 hPa. The scientifically useful range of the H2O data is from 316 to 0.002 hPa, although only the 82–0.002 hPa pressure range is validated here. Substantial improvement has been achieved in the v2.2 N2O data over v1.5 by reducing a significant low bias in the stratosphere and eliminating unrealistically high biased mixing ratios in the polar regions. The single-profile precision is ~13–25 ppbv (7–38%), the vertical resolution is ~4–6 km and the accuracy is estimated to be 3–70 ppbv (9–25%) for the pressure range 100–4.6 hPa. The scientifically useful range of the N2O data is from 100 to 1 hPa.

Atlas, E.↗
NASA NTRS2007

Observed and Modeled HOCl Profiles in the Midlatitude Stratosphere: Implication for Ozone Loss

Vertical profiles of stratospheric HOCl calculated with a diurnal steady-state photochemical model that uses currently recommended reaction rates and photolysis cross sections underestimate observed profiles of HOCl obtained by two balloon-borne instruments, FIRS-2 (a far-infrared emission spectrometer) and MkIV (a mid-infrared, solar absorption spectrometer). Considerable uncertainty (a factor of two) persists in laboratory measurements of the rate constant (k(sub 1)) for the reaction ClO + HO2 yields HOCl + O2. Agreement between modeled and measured HOCl can be attained using a value of k(sub 1) from Stimpfle et al. (1979) that is about a factor-of-two faster than the currently recommended rate constant. Comparison of modeled and measured HOCl suggests that models using the currently recommended value for k(sub 1) may underestimate the role of the HOCl catalytic cycle for ozone depletion, important in the midlatitude lower stratosphere.

temperature dependence↗
NASA NTRS2006

Observation of Night OH in the Mesosphere

Satellite measurements from the Aura MLS instrument show a layer of OH near 82 km in the night. This layer confirms earlier measurements by ground-based LIDAR. The MLS and LIDAR observations measure OH in the lowest vibrational state and are distinct, but related chemically, from vibrationally-excited emission from the OH Meinel bands in the near infrared. The Caltech 1-D model has been extended to include vibrational dependence of OH reactions and shows good agreement with MLS OH data and with observations of the Meinel bands. The model shows a chemical lifetime of HO(x) that increases from less than a day at 80 km to over a month at 87 km. Above this altitude transport processes become an important part of HOx chemistry. The model predicts that ground state OH represents 99% of the total OH up to 84 km.

hydroxyl↗
NASA NTRS2002

Microwave, Millimeter, Submillimeter, and Far Infrared Spectral Databases

The spectrum of most known astrophysical molecules is derived from transitions between a few hundred to a few hundred thousand energy levels populated at room temperature. In the microwave and millimeter wave regions. spectroscopy is almost always performed with traditional microwave techniques. In the submillimeter and far infrared microwave technique becomes progressively more technologically challenging and infrared techniques become more widely employed as the wavelength gets shorter. Infrared techniques are typically one to two orders of magnitude less precise but they do generate all the strong features in the spectrum. With microwave technique, it is generally impossible and rarely necessary to measure every single transition of a molecular species, so careful fitting of quantum mechanical Hamiltonians to the transitions measured are required to produce the complete spectral picture of the molecule required by astronomers. The fitting process produces the most precise data possible and is required in the interpret heterodyne observations. The drawback of traditional microwave technique is that precise knowledge of the band origins of low lying excited states is rarely gained. The fitting of data interpolates well for the range of quantum numbers where there is laboratory data, but extrapolation is almost never precise. The majority of high resolution spectroscopic data is millimeter or longer in wavelength and a very limited number of molecules have ever been studied with microwave techniques at wavelengths shorter than 0.3 millimeters. The situation with infrared technique is similarly dire in the submillimeter and far infrared because the black body sources used are competing with a very significant thermal background making the signal to noise poor. Regardless of the technique used the data must be archived in a way useful for the interpretation of observations.

Pearson, J. C.↗
NASA NTRS1999

Performance of a 2.5 THz Receiver Front-End for Spaceborne Applications

The OH radical plays a significant role in a great many of the known ozone destruction cycles, and has become the focus of an important radiometer development effort for NASA's Earth Observing System Chem I satellite, which will monitor and study many tropospheric and stratospheric gases and is scheduled for launch in 2002. Here we describe the design, fabrication, and testing of a receiver front end used to detect the OH signals at 2.5 THz. This is to be the first Terahertz heterodyne receiver to be flown in space. The challenges of producing the necessary high-performance mixers are numerous, but for this application, there is the added challenge of designing a robust receiver which can withstand the environmental extremes of a rocket launch and five years in space. The receiver front-end consists of the following components: a four-port dual-polarization diplexer, off-axis elliptical feed mirrors, mixers for horizontal and vertical polarization, support structures allowing simple and rugged alignment, low noise IF amplification from 7.7 to 21.1 GHz, and mixer DC bias circuitry. The front-end design, alignment, and operation will be covered in depth, followed by a discussion of the most recent results in receiver noise and dual-mode horn beam patterns. JPL MOMED mixers are employed, and have resulted in receiver noise temperatures of 14,500 K, DSB with LO frequency 2.522 GHz and IF of 12.8 GHz. Horn beam patterns correspond well with theory, with no significant sidelobes above the -25 dB level. Considering the high-quality beam of this receiver, these results are competitive with the best reported in the literature.

Gaidis, Michael C.↗
NASA NTRS1998

A2.5 THz Receiver Front-End for Spaceborne Application

The OH radical is an important player in known ozone depletion cycles; however, due to its location in the atmosphere, it must be studied from either a balloon or spaceborne platform.

receiver ozone destruction Earth Observing System ↗
NASA NTRS1998

Simultaneous amplification of terahertz difference frequencies by an injection-seeded semiconductor laser amplifier at 850 nm

Two-frequency operation of an 850 nm semiconductor optical amplifier was achieved by simultaneously injection seeding it with two diode lasers. The two frequencies could be independently amplified without strong interference when they were separated by more than 10 GHz, and the spectral purity was preserved by the amplification process. At frequency differences below 10 GHz, unbalanced two-frequency output was observed, which can be explained by a two-mode interaction driven by the refractive index modulation at the beat frequency. The laser system is suitable for the difference-frequency generation of coherent terahertz radiation in ultra-fast photoconductors or nonlinear optical media.

NASA Discipline Exobiology↗
NASA NTRS1997

Submillimeter, Millimeter, and Microwave Spectral Catalog

This paper describes a computer-accessible catalog of submillimeter, millimeter, and microwave spectral lines in the frequency range between 0 and 10,000 GHz (i.e., wavelengths longer than 30um).

submillimeter millimeter microwave spectral lines↗