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Kunde, V. G.

Publications and source records attributed to Kunde, V. G..

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Stratospheric sounding by infrared heterodyne spectroscopy

Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution (approximately 5 MHz = 0.000167 kaysers at 10 microns). The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described, and applications to synthetic lines of O3, CO2, CH4, and N2O are given. Some recent heterodyne measurements of CO2 and O3 absorption lines are analytically inverted, and the vertical distributions of the two gases are determined.

Abbas, M. M.↗
NASA NTRS1978

Stratospheric ozone measurement with an infrared heterodyne spectrometer

Measurements of a stratospheric ozone concentration profile are made by detecting infrared absorption lines with a heterodyne spectrometer. The infrared spectrometer is based on a line-by-line tunable CO2 lasers, a liquid-nitrogen cooled HgCdTe photomixer, and a 64-channel spectral line receiver. The infrared radiation from the source is mixed with local-oscillator radiation. The difference frequency signal in a bandwidth above and below the local-oscillator frequency is detected. The intensity in each sideband is found by subtracting sideband contributions. It is found that absolute total column density is 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio at about 24 km. The (7,1,6)-(7,1,7) O3 line center frequency is identified as 1043.1772/cm. Future work will involve a number of ozone absorption lines and measurements of diurnal variation. Completely resolved stratospheric lines may be inverted to yield concentration profiles of trace constituents and stratospheric gases.

Abbas, M. M.↗
NASA NTRS1978

Stratospheric ozone measurement with an infrared heterodyne spectrometer

A stratospheric ozone absorption line in the 10 microns band was measured and resolved completely, using an infrared heterodyne spectrometer with spectral resolution of 5 MHz (0.000167 cm to -1 power). The vertical concentration profile of stratospheric ozone was obtained through an analytical inversion of the measured spectral line profile. The absolute total column density was 0.34 cm atm with a peak mixing ratio occurring at approximately 24 km. The (7,1,6) to (7,1,7) O3 line center frequency was found to be 1043.1775 + or - 0.00033 cm to toe -1 power, or 430 + or - 10 MHz higher than the P(24) CO2 laser line frequency.

Abbas, M. M.↗
NASA NTRS1978

Stratospheric sounding by infrared heterodyne spectroscopy

Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution. The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes, and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described and applications to synthetic lines of O3, CO2, CH4 and N2O are given.

Abbas, M. M.↗
NASA NTRS1978

Stratospheric ozone measurement with an infrared heterodyne spectrometer

A stratospheric ozone absorption line in the 10 micron band was measured and resolved completely, using an infrared heterodyne spectrometer with a spectral resolution of 5 MHz. The vertical concentration profile of stratospheric ozone was obtained through an analytical inversion of the measured spectra line profile. The absolute total column density was 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio occurring at approximately 24 km. The (7,1,6) - (7,1,7) O3 line center frequency was found to be 1043.1772 plus or minus 0.00033 cm/1 or 420 plus or minus 10 MHz higher than the P(24) CO2 laser line frequency.

Abbas, M. M.↗
NASA NTRS1977

High spectral resolution ground-based observations of Venus in the 450- to 1250 kayser region

Ground-based observations of Venus were made with a 5-cm drive Michelson interferometer during December 1970 and December 1973. The thermal emission spectrum of the central portion of the apparent disk was recorded from 450-1250 kaysers with an apodized spectral resolution of 0.25 kaysers. All statistically significant sharp line-absorption features in the spectrum have been identified with gaseous CO2. Comparison between the observed spectrum and a synthetic spectrum computed from a model atmosphere, assuming gaseous CO2 and a sulfuric acid haze as opacity sources, indicates good agreement. A broad diffuse absorption feature associated with the sulfuric acid haze is evident in the 870- to 930 kayser region. With the exception of the rotational lines of the 927 kayser CO2 band, the above feature appears as a continuum down to 0.25 kayser resolution. In the 750- to 1250 kayser range, the spectrum exhibits moderate thermal contrast with maximum brightness temperatures of 234-238 K occurring near 825 kaysers. These temperatures are in general agreement with previous measurements.

Kunde, V. G.↗
NASA NTRS1977

Detection of upper atmospheric constituents using submillimeter wave /SMMW/ heterodyne radiometry

Submillimeter wave heterodyne radiometry has been applied to the detection and sounding of upper atmospheric constituents. The use of room-temperature Schottky-diode mixers for the receivers has yielded measurements of 70,000 K noise temperature. Coupling losses into the diode and matching of the IF output limit are observed to limit noise temperature. The technique is evaluated by calculating spectra with assumed temperature and constituent profiles. Vertical integrations are made with a multilayer atmosphere and the direct summation of absorption coefficients for the individual spectral lines is used. Results are presented for tangent path parameters for a mid-latitude summer model and the fractional parts of upper atmospheric constituents as a function of altitude.

Mcavoy, N.↗
NASA NTRS1976

High spectral resolution ground-based observations of Venus in the 450-1250 cm sup-1 region

The thermal emission of Venus was recorded during the winter of 1970-1971, and in 1973 using the 2.7m telescope at McDonald Observatory. The double beam Michelson interferometer installed at the Coude focus was used. The spectrum was recorded between 400/cm and 1,400/cm. For the 1970 observations, the spectral resolution was 0.25/cm and the linear spatial resolution was 3/4 of the disk of Venus. In 1973 the spectral resolution was 0.20/cm with a spatial resolution 1/3 of the planetary disk. In addition to Venus, the moon, the sky adjacent to each object, and the zenith sky were recorded to help eliminate the absorption and emission effects of the earth's atmosphere.

Kunde, V. G.↗
NASA NTRS1975

Fourier spectroscopy in planetary research

The application of Fourier Transform Spectroscopy (FTS) to planetary research is reviewed. The survey includes FTS observations of the sun, all the planets except Uranus and Pluto, The Galilean satellites and Saturn's rings. Instrumentation and scientific results are considered. The prospects and limitations of FTS for planetary research in the forthcoming years are discussed.

Hanel, R. A.↗
NASA NTRS1975

Venus cloud properties - Infrared opacity and mass mixing ratio

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is inferred from the infrared spectrum of the planet between 450 and 1250 per cm. Volume extinction coefficients varying from 0.000005 to 0.000015 per cm, depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 0.000005 and a particle concentration of about 900 particles per cu cm at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.

Samuelson, R. E.↗
NASA NTRS1974

Estimation of sea surface temperature from remote sensing in the 11to 13-micron window region

The Nimbus 3 and 4 Iris spectral data in the 11- to 13-micron water vapor window region are analyzed to determine the sea surface temperature (SST). The high spectral resolution data of Iris are averaged over approximately 1-micron-wide intervals to simulate channels of a radiometer to measure the SST. In the present exploratory study, three such channels in the 775- to 960-per cm (12.9-10.5 micron) region are utilized to measure the SST over cloud-free oceans. However, two of these channels are sufficient in routine SST determination. The differential absorption properties of water vapor in the two channels make it possible to determine the water vapor absorption correction without detailed knowledge of the vertical profiles of temperature and water vapor. The feasibility of determining the SST is demonstrated globally with Nimbus 3 data, where cloud-free areas can be selected with the help of albedo data from the medium-resolution infrared radiometer experiment on board the same satellite. The SST derived from this technique agrees with the measurements made by ships to about 1 C.-

Prabhakara, C.↗
NASA NTRS1974

Fourier spectroscopy and planetary research

The application of Fourier Transform Spectroscopy (FTS) to planetary research is reviewed. The survey includes FTS observations of the sun, all the planets except Uranus and Pluto, the Galilean satellites and Saturn's rings. Instrumentation and scientific results are considered and the prospects and limitations of FTS for planetary research in the forthcoming years are discussed.

Hanel, R. A.↗
NASA NTRS1974

Direct integration transmittance model

A transmittance model has been developed for interpretation of high spectral resolution measurements of laboratory absorption and of planetary thermal emission. The high spectral resolution requires transmittances to be computed monochromatically by summing the contribution of individual molecular absorption lines. A magnetic tape atlas of H2O, O3, and CO2 molecular line parameters serves as input to the transmittance model with simple empirical representations used for continuum regions wherever suitable laboratory data exist. The theoretical formulation of the transmittance model and the computational procedures used for the evaluation of the transmittances are discussed, and application of the model to several homogeneous-path laboratory absorption examples is demonstrated.

Kunde, V. G.↗
NASA NTRS1974

Venus cloud properties: Infrared opacity and mass mixing ratio

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is inferred from the infrared spectrum of the planet between 450 and 1250/cm. Justification for applying the homogeneous cloud model is found in the fact that numerous polarization and infrared data are mutually consistent within the framework of such a model; on the other hand, dense cloud models are not satisfactory. Volume extinction coefficients varying from 0.000005 to 0.000015/cm depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 0.000005 and a particle concentration of about 900 particles per cu cm at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.

Samuelson, R. E.↗
NASA NTRS1974

Nimbus 4 IRIS spectra in the 750-1250 wavelengths/cm atmospheric window region

Present operational schemes for infrared remote sounding measurements of surface temperature use the 899 wavelengths/cm atmospheric window region. Spectra from the Nimbus 4 IRIS in the 750 to 1250 wavelengths/cm region are analyzed. Comparison of the actual surface temperature and the observed brightness temperature at 10 wavelengths/cm resolution shows that the clearest windows were at 936 and 960 wavelengths/cm. Although there is a small amount of CO2 absorption in these regions, this is compensated for by a decrease in water vapor continuum absorption. Atmospheric absorption was 0.5 K less than experienced by the 899 wavelengths/cm window.

Kunde, V. G.↗
NASA NTRS1974

The Nimbus 4 infrared spectroscopy experiment. II - Comparison of observed and theoretical radiances from 425-1450 wavelengths/cm

The Nimbus 4 infrared interferometer spectrometer (IRIS) measured the thermal emission of the earth's atmosphere and surface from 400-1600 wavelengths/cm with an apodized spectral resolution of 2.8 wavelengths/cm. A comparison of theoretical radiances, computed from in situ measurements and using a direct integration slant path atmospheric transmittance model, with the observed IRIS radiances has been made to verify the radiometric and spectral performance of the instrument and to assess the accuracy of the atmospheric transmittances. The radiance comparison has indicated a relatively constant difference of less than 5% in the water vapor continuum in the 425 to 550 wavelengths/cm and 750 to 1200 wavelengths/cm atmospheric 'window' regions, whereas in the 667 wavelengths/cm CO2 band the difference was 5-10%.

Kunde, V. G.↗