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Kunde, V. G.

Publications and source records attributed to Kunde, V. G..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Atmospheric infrared emission of ClONO2 observed by a balloon-borne Fourier spectrometer

ClONO2 was observed in high-resolution infrared emission spectra obtained on Nov. 6, 1984, by a balloon-borne Fourier spectrometer. The observations took place near 0300 LT at a latitude of 35 N. Spectral simulations are used to determine the mixing ratios of ClONO2. This analysis incorporates line by line calculations and new ClONO2 cross sections measured in the laboratory at 223 K. The inferred mixing ratios of ClONO2 are 1.3 + or - 0.45 ppb and 0.98 + or - 0.35 ppb at 14 and 34 mbar. One-dimensional photochemical model predictions are compared to the observations. The ClONO2 mixing ratio at 34 mbar appears to be larger than theory, while there is agreement at 14 mbar.

Massie, S. T.↗
NASA NTRS1987

Simultaneous measurement of stratospheric O3, H2O, CH4, and N2O profiles from infrared limb thermal emissions

Thermal emission measurements of the earth's stratospheric limb were made with a cryogenically cooled high-resolution Michelson interferometer on a balloon flight launched from Palestine, TX, on Nov. 6, 1984. Infrared spectra for complete limb sequences were obtained over portions of the 700-1940/cm range with an unapodized spectral resolution of 0.03/cm for tangent heights varying from 13 to 39 km. The observed data from 1125 to 1425/cm have been analyzed for simultaneous measurement of O3, H2O, CH4, and N2O profiles. The analysis employs line-by-line and layer-by-layer radiative-transfer calculations, including curvature and refraction effects. The optimum use of geometric and spectral effects is made to obtain sharply peaked weighting functions. Contributions from stratospheric aerosol are included by measuring the light extinction within the window regions of the observed spectra. The retrieved constituent profiles are compared with measurements made with a variety of techniques by other groups. The comparison shows good agreement with the published data for all gases, indicating the capability of retrieving trace gas profiles from high-resolution thermal emission limb measurements.

Abbas, M. M.↗
NASA NTRS1986

Water vapor in Jupiter's atmosphere

High spectral resolution observations of Jupiter at 2.7 and 5 microns acquired from the Kuiper Airborne Observatory were used to infer the vertical distribution of H2O between 0.7 and 6 bars. The H2O mole fraction, qH2O, is saturated for P<2 bars, qH2O = 4x.000001 in the 2 to 4 bar range and it increases to 3x.00001 at 6 bars where T = 288 K. The base of the 5 micron line formation region is determined by pressure-induced H2 opacity. At this deepest accessible level, the O/H ratio in Jupiter is depleted by a factor of 50 with respect to the solar atmosphere. High spatial resolution Voyager IRIS spectra of Jupiter's North Tropical Zone, Equatorial Zone, and Hot Spots in the North and South Equatorial Belt were analyzed to determine the spatial variation of H2O across the planet. The column abundance of H2O above the 4 bar level is the same in the zones as in the SEB Hot Spots, about 20 cm-amgt. A cloud model for Jupiter's belts and zones was developed in order to fit the IRIS 5 micron spectra. An absorbing cloud located at 2 bars whose 5 micron optical thickness varies between 1 in the Hot Spots and 4 in the coldest zones satisfactorily matches the IRIS data.

Bjoraker, G. L.↗
NASA NTRS1986

Planetary infrared astronomy using a cryogenic postdisperser on Fourier transform spectrometers

High resolution infrared spectra of planets from ground-based observatories were analyzed and instrumentation to improve sensitivity was developed. A cryogenic postdisperser (a narrow bandpass spectral filter) for use with Fourier transform spectrometers (FTS's) at facility observatories was constructed. This instrument has improved the sensitivity of FTS observations at 8 to 20 microns by about an order of magnitude. Spectra of Jupiter, Saturn and Comet Halley were obtained using the postdisperser with FTS facilities at the Kitt Peak 4-meter and McMath telescopes. Spectral resolution as high as 0.01/cm was achieved.

Jennings, D. E.↗
NASA NTRS1986

The gas composition of Jupiter derived from 5 micron airborne spectroscopic observations

It is pointed out that Jupiter's 5-micron spectrum is a very diagnostic observational tool to probe the troposphere of this giant planet. A report is presented of abundance analyses of NH3, PH3, CH4, CH3D, CO, and GeH4 in the 1- to 6-bar pressure range in Jupiter's troposphere. All the considered molecules have been previously detected in ground-based, airborne, and spacecraft observations of Jupiter. The contribution made by the present study is related to a self-consistent simultaneous determination of the abundances of all of these molecules at the same physical level in Jupiter's atmosphere using one high spectral resolution dataset and a radiative transfer model. It is found that most abundances deviate significantly from expectations based upon an atmospheric model assuming solar composition and chemical equilibrium. The D/H ratio in Jupiter is comparable to that measured in the interstellar medium.

Bjoraker, G. L.↗
NASA NTRS1986

Balloon-borne cryogenic spectrometer for measurement of lower stratospheric trace constituents

A liquid-nitrogen cooled, multidetector Fourier transform spectrometer has been constructed to measure minor stratospheric constituents via high resolution, earth-limb emission spectroscopy from a balloon-borne platform. Cryogenic cooling, combined with the use of extrinsic silicon photoconductor detectors cooled to liquid-helium temperature, allows the detection of weak emission features of gaseous species. The spectrometer has two basic scan modes: the first mode records the continuous spectrum from 650-2100/cm with 0.2/cm resolution; the second simultaneously records four preselected narrow intervals (about 175/cm bandpass each) with 0.02/cm resolution, unapodized. Filtering of the interferogram signal is done by real-time, digital signal processing. The most important feature of this flat mirror Michelson system, with respect to remote balloon-borne operation, is the dynamic alignment system which maintains the relative parallelism of the two flat reflectors of the interferometer. Species identified to date in data obtained during a Nov. 6, 1984, flight include: CO2, O3, H2O, CH4, HNO3, N2O, NO2, NO, CCl3F (Freon-11) and CF2Cl2 (Freon-12).

Brasunas, J. C.↗
NASA NTRS1985

Finite field of view effects on inversion of limb thermal emission observations

It is pointed out that the technique of thermal emission spectroscopy provides an effective means for remote sounding of stratospheric temperature structure and constituent distributions. One procedure for measuring the stratospheric infrared spectrum involves the conduction of observations along ray paths tangent to the stratospheric limb. Thermal emission limb tangent observations have certain advantages compared to other types of observations. The techniques for determining temperature and trace gas distributions from limb thermal emission radiances are based on the assumption that the bulk of opacity lies near the tangent point. Ideally, the field of view (FOV) of the observing instrument should be very small. The effect of a finite FOV is to reduce the spatial resolution of the retrieved temperature and constituent profiles. The present investigation is concerned with the effects of the FOV on the inversion of infrared thermal emission measurements for balloon platforms. Attention is given to a convenient method for determining the weighting functions.

Abbas, M. M.↗
NASA NTRS1984

Measurements of H2O in Jupiter's Atmosphere from 5 Microns Airborne Observations

Measurement of the abundance and vertical distribution of H2O in Jupiter's atmosphere is discussed. Water was first detected using the Kuiper airborne observatory (KAO) and has also been observed at 5 micrometers by the Voyager infrared spectrometer, IRIS. Studies of H2O in the atmospheres of other planets require special high altitude facilities to reduce the interference of telluric H2O. Jovian H2O absorption lines are overwhelmed by terrestrial H2O at ground-based observatories but they are readily apparent in airborne spectra. Typical column abundances of H2O above ground-based telescopes are about 3000 precipitable micrometers versus only 10 pr micrometers above the KAO at the 12.5 km level. For comparison, there is about 150 pr micrometers H2O above the 3 bar level on Jupiter. Airborne observations also take advantage of cryogenic detectors which have not been used thus far on deep space probes.

Bjoraker, G. L.↗
NASA NTRS1984

Method for correction of errors in observation angles for limb thermal emission measurements

Thermal emission measurements of the earth's stratospheric limb from space platforms require an accurate knowledge of the observation angles for retrieval of temperature and constituent distributions. Without the use of expensive stabilizing systems, however, most observational instruments do not meet the required pointing accuracies, thus leading to large errors in the retrieval of atmospheric data. This paper describes a self-constituent method of correcting errors in pointing angles by using information contained in the observed spectrum. Numerical results based on temperature inversions of synthetic thermal emission spectra with assumed random errors in pointing angles are presented.

Abbas, M. M.↗
NASA NTRS1983

CO2 on Titan

A sharp stratospheric emission feature at 667/cm in the Voyager infrared spectra of Titan is associated with the nu2 Q branch of CO2. A coupling of photochemical and radiative-transfer theory yields an average mole fraction above the 110 mbar level of (1.5 + 1.5 or - 0.8) x 10 to the -9th, with most of the uncertainty being due to imprecise knowledge of the vertical distribution. CO2 is found to be in a steady state, with its abundance being regulated principally by the 72 K cold trap near the tropopause and secondarily by the rate at which water-bearing meteoritic material enters the top of the atmosphere. An influx of water about 0.4 times that at the top of the terrestrial atmosphere is consistent with a combination of the observed CO2 abundance and a steady-state CO mole fraction of 0.00011; the thoeretical value for CO is close to the value observed by Lutz et al. (1983), although there are large margins for error in both numbers. If steady-state conditions for CO prevail, little information is available regarding the evolution of Titan's atmosphere.

Samuelson, R. E.↗
NASA NTRS1981

Albedo, internal heat, and energy balance of Jupiter - Preliminary results of the Voyager infrared investigation

Full disk measurements recorded by the 0.4-1.7 micron radiometer on Voyager 1 indicate a geometric albedo of 0.274 + or - 0.013. This measurement and the Pioneer-based phase integral of 1.25 yield a Jovian Bond albedo of 0.343 + or - 0.032. Infrared spectra yield a thermal emission of 1.359 + or - 0.014 x .001 W/sq cm, which corresponds to an equivalent blackbody temperature of 124.4 + or - 0.3 K. In addition, the internal heat flux of Jupiter is estimated to be 5.444 + or - 0.425 x .0001 W/sq cm, and the energy balance defined as the ratio of emitted thermal to absorbed solar energy is 1.668 + or - 0.085.

Hanel, R. A.↗
NASA NTRS1981

C3H8 and C3H4 in Titan's atmosphere

Four bands of propane C3H8 and two of methyl acetylene C3H4 have been identified in the Voyager IR spectrum of Titan. Stratospheric abundances of 2 x 10 to the -5 for C3H8 and 3 x 10 to the -8 for C3H4 have been determined for the mid-latitude region. A feature at 1,154/cm, previously assigned solely to CH3D, is now identified at least in part due to C3H8.

Maguire, W. C.↗
NASA NTRS1981

C4H2, HC3N and C2N2 in Titan's atmosphere

Voyager 1 took IR measurements of the atmosphere of Titan, and obtained an average of 346 spectra, mostly from the center of the disk. The compounds C4H2, HC3N, and C2N2 were detected in the atmosphere of Titan. The identification of two compounds containing nitrogen, in addition to HCN, provides further evidence for the abundance of free N2 on Titan. The organic compounds observed in the atmosphere of Titan are summarized in a table, which also indicates the approximate mole fraction for each compound identified previously. The observed compounds originate by reactions of methane and nitrogen radicals in a predominantly nitrogen atmosphere.

Kunde, V. G.↗
NASA NTRS1981

Mean molecular weight and hydrogen abundance of Titan's atmosphere

The 200-600/cm continuum opacity in the troposphere and lower stratosphere of Titan is inferred from thermal emission spectra from the Voyager 1 IR spectrometer (IRIS). The surface temperature and mean molecular weight are between 94 and 97 K and between 28.3 and 29.2 AMU, respectively. The mole fraction of molecular hydrogen is 0.002 + or - 0.001, which is equivalent to an abundance of approximately 0.2 + or - 0.1 km amagat.

Samuelson, R. E.↗
NASA NTRS1980

The helium abundance of Jupiter from Voyager

Full disk measurements recorded 31 days before the Voyager 1 encounter with Jupiter by the radiometer of the infrared instrument, IRIS, indicate a geometric albedo of 0.274 + or - 0.013. Combining this measurement with the Pioneer derived phase integral of 1.25 and our error estimate of 0.1 yields a Jovian Bond albedo of 0.343 + or - 0.032. Infrared spectra recorded at the same time by the Michelson interferometer, along with a model extrapolation to low wave numbers not covered by the instrument, yield a thermal emission of (1.359 + or - 0.014) .001 W cm to the (-2) power. As in the case of the albedo measurement, the quoted errors in the emission measurement reflect estimates of systematic effects and are uncertain while the random component is negligible. From these measurements the internal heat flux of Jupiter is estimated to be (5.444 + or - 0.425) .0001 W cm to the (-2) power, and the energy balance defined as the ratio of emitted thermal to absorbed solar energy is 1.668 + or - 0.085.

Gautier, D.↗