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Knacke, R. F.

Publications and source records attributed to Knacke, R. F..

At least 37 records · Page 2
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NASA NTRS1988

The ice band in IRAS 09371 + 1212

Spectra from 2 to 4 microns of the unusual IRAS source 09371 + 1212, a bipolar nebula, reveal a deep H2O ice absorption band near 3.1 microns. No long-wavelength wing is present, implying that the absorbing grain mantles are of high purity. The structure of the absorption feature is reasonably well modeled by a mixture of amorphous and crystalline H2O ice mantles on silicate grains, but discrepancies remain that could indicate other absorbers also.

Geballe, T. R.↗
NASA NTRS1988

The origin and vertical distribution of carbon monoxide in Jupiter

Six clearly-resolved lines of the CO 1-0 vibration-rotation band near 4.7 microns have been observed in Jupiter at a resolution of 0.07/cm. CO is not found to be concentrated in the stratosphere, but is shown to be present in the troposphere at a mole fraction of 1.6 + or - 0.3 x 10 to the -9th, suggesting that rapid vertical mixing is the source of CO. Results indicate that the global oxygen abundance in Jupiter's gaseous envelope below the cloud-forming regions must be near the solar value, and that intervening clouds with an optical depth of 0.5-4 are present above the line-forming region.

Noll, Keith S.↗
NASA NTRS1987

Spectroscopy of the Kleinmann-Low nebula - Scattering in a solid absorption band

Spectroscopic observations (2.4-3.6 microns) of BN, IRc 2, 3, and 4, and three scattering locations in the KL reflection nebula are reported. A previous report (Knacke et al., 1982) of a 2.97-micron spectral feature in the BN object is not confirmed in the new data. The 2.97-micron feature is observed in sources in the KL nebula, and the spectrum is distorted by a nearby hydrogen line. All the spectra are dominated by absorption along the radiation path, making scattering effects difficult to separate. Scattering could broaden the 3.1-micron interstellar-ice feature, but the effects appear to be small. Except for a long-wavelength wing, the spectra can be modeled reasonably well with core-mantle, silicate-water-ice grains. The wing position and intensity indicate bands of C-H groups of ammonia-ice mixtures.

Knacke, R. F.↗
NASA NTRS1986

Ground-based detection of water in Comet Halley

Gaseous water was detected in the coma of comet Halley. Emission was observed in the upsilon 1 + upsilon 3 band at 1.4 microns, and the upsilon 2 + upsilon 3 band at 1.9 microns. Based on the upsilon 1 + upsilon 3 band intensity, the mass loss rate is 2 times 10 to the 29th power molecules/sec (with an uncertainty of a factor of 2) on 29 Oct. 1985, marginally consistent with other detections. The method is applicable to observations of H2O in other fast-moving comets.

Knacke, R. F.↗
NASA NTRS1986

Detection of carbon monoxide in Saturn

The detection of CO in the atmosphere of Saturn is reported. Six spectral regions containing lines of the CO 1-0 vibration-rotation band near 4.7 microns are studied; three of the lines are free of blending and in effect attest to the presence of this molecule in Saturn's atmosphere. Consideration is given to the following CO sources: (1) rapid convection from the hot interior, and (2) the infall of oxygen-bearing material from outside.

Noll, Keith S.↗
NASA NTRS1986

The abundances of ethane to acetylene in the atmospheres of Jupiter and Saturn

The present determination of the stratospheric abundances of ethane and acetylene on Jupiter and Saturn on the basis of IR spectra near 780/cm uses atmospheric models whose thermal and density profiles have constant mixing ratios. The ratio of ethane to acetylene is noted to be insensitive to model atmosphere assumptions; it is 55 + or - 31 for Jupiter and 23 + or - 12 where model mixing ratios are uniform. Atmospheric model density profiles adapted from theoretical photochemical models are noted to also yield a higher ethane/acetylene ratios for Jupiter.

Noll, K. S.↗
NASA NTRS1986

Infrared spectroscopy of Jupiter and Saturn

The origin of carbon monoxide has been a puzzle for some time, and it has become apparent that CO serves as a tracer of disequilibrium processes in the Jovian atmosphere. High resolution spectra with a Fabry-Perot spectrometer was obtained. From a detailed synthetic spectral analysis of the CO line profiles, it was established that the CO is located in the troposphere of Jupiter. It must therefore be a product of convection upward from hotter levels in the deep atmosphere, and is not a product of infall of material from above the stratosphere. Six lines of CO in Saturn was detected, a surprising result because disequilibrium models predicted that the CO mixing ratio would be too low to be observable if upward convection is the dominant mechanism. Therefore several possibilities for the origin of the CO now exist, none completely satisfactory at this time.

Knacke, R. F.↗
NASA NTRS1986

The abundances of ethane and acetylene in the atmospheres of Jupiter and Saturn

The present determination of the stratospheric abundances of ethane and acetylene on Jupiter and Saturn on the basis of IR spectra near 780/cm uses atmospheric models whose thermal and density profiles have constant mixing ratios. The ratio of ethane to acetylene is noted to be insensitive to model atmosphere assumptions; it is 55 + or - 31 for Jupiter and 23 + or - 12 where model mixing ratios are uniform. Atmospheric model density profiles adapted from theoretical photochemical models are noted to also yield a higher ethane/acetylene ratios for Jupiter.

Noll, K. S.↗
NASA NTRS1985

Interstellar dust spectra between 2.5 and 3.3 microns - A search for hydrated silicates

Spectra in the 2.5-3.3 micron wavelength region of VI Cyg 12, AFGL 2205, and AFGL 2885 were obtained in a search for bound water, hydroxyl groups, and hydrated minerals in interstellar dust. No new absorption bands were found. Comparison of expected strengths of bands of serpentine and chlorite-like minerals with the data suggests that less than 25 percent and 50 percent, respectively, of the silicate in the grains is composed of these materials.

Knacke, R. F.↗
NASA NTRS1982

The abundances of CH4, CH3D, NH3, and PH3 in the troposphere of Jupiter derived from high-resolution 1100-1200/cm spectra

High-resolution spectra of the 1100-1200/cm region of the central part of Jupiter obtained in March 1980 and April 1981 are analyzed. The best fit NH3 distribution curve reveals a higher than solar mixing ratio, the abundance of NH3 to that of H2 being (3.3 + or - 1.7) x 10 to the -4th, below the 147 K layer (greater than 0.6 atmosphere). If NH3 ice particles are introduced as an opacity source, the NH3 mixing ratio below the 147 K layer can be lowered, but the fit is worse than that given by the model that excludes NH3 ice particles. The best fit PH3 distribution curve exhibits a PH3/H2 mixing ratio of (8.3 + or - 2.0) x 10 to the -7th in the troposphere. In addition, a CH4/H2 mixing ratio of (2.5 + or - 0.4) x 10 to the -3rd is found in the troposphere.

Knacke, R. F.↗
NASA NTRS1982

Observation of interstellar ammonia ice

An absorption band probably due to solid ammonia on interstellar grains has been detected in the infrared spectrum at 2.97 microns of the Becklin-Neugebauer object and probably in NGC 2264-IR. An ammonia-water amorphous ice mixture can explain the structure of the new band and of the 3.07 microns interstellar absorption. Laboratory data suggest that a long wavelength wind extending to 3.5 microns in interstellar dust spectra may be absorption by NH3-H2O complexes in the ices. In the molecular cloud obscuring the BN object, about 20 times as much NH3 is frozen in grains as exists in the gas phase, suggesting the gas-grain interactions may be important in the ammonia chemistry of molecular clouds. Arguments are given that interstellar features at 6.0 and 6.8 microns are also ammonia-related absorptions.

Knacke, R. F.↗
NASA NTRS1980

High spatial and spectral resolution 10-micron observations of Jupiter

Ten-micrometer spectra of the North Tropical Zone, North Equatorial Belt, and Great Red Spot at a spectral resolution of 1.1/cm are compared to synthetic spectra. These ground-based spectra were obtained simultaneously with the Voyager 1 encounter with Jupiter in March, 1979. The NH3 vertical distribution is found to decrease with altitude significantly faster than the saturated vapor pressure curve and is different for the three observed regions. Spatial variability in the NH3 mixing ratio could be caused by changes in the amount of NH3 condensation or in the degree of the NH3 photolysis. The C2H6 emission at 12 microns has approximately the same strength at the North Tropical Zone and North Equatorial Belt, but it is 30% weaker at the Great Red Spot. A cooler temperature inversion or a smaller abundance of C2H6 could explain the lower C2H6 emission over the Great Red Spot.

Tokunaga, A. T.↗
NASA NTRS1979

High-resolution spectra of Jupiter in the 744-980 inverse centimeter spectral range

Spectra of the central 5 in region of Jupiter in the 744 to 980 kayser spectral range are presented at 0.05 and 0.28 kayser resolution. The gases (N-14)H3, (N-15)H3, and PH3 are observed in absorption, and C2H2 and C2H6 observed in emission. A synthetic spectrum which included the opacity from the H2, (N-14)H3, (N-15)H3, and PH3 is compared with observations. It is concluded that: (1) the (N-14)H3 line profiles are best fitted with a NH3 density in the troposphere which is 0.5 times the saturated vapor pressure density and an opaque cloud at the 0.56 bar pressure level, (2) the best fit (N-15)H3/(N-14)H3 ratio is 0.006, (3) the PH3/H2 abundance ratios of NH3 and PH3 must be highly subsaturated above the tropopause or the temperature inversion is cooler than model predictions.

Tokunaga, A. T.↗
NASA NTRS1978

Signal-to-noise ratios of multiplexing spectrometers in high backgrounds

Signal-to-noise ratios and the amount of multiplexing gain achieved with a Michelson spectrometer during detector and background noise are studied. Noise caused by the warm background is found in 10 and 20-micron atmospheric windows in high resolution Fourier spectroscopy. An equation is derived for the signal-to-noise ratio based on the number of channels, total time to obtain the complete spectrum, the signal power in one spectral element, and the detector noise equivalent power in the presence of negligible background. Similar expressions are derived for backgrounds yielding a noise equivalent power to a spectral element, and backgrounds having flat spectra in the frequency range under investigation.

Knacke, R. F.↗
NASA NTRS1977

17-25 micrometer spectra of Jupiter and Saturn

Ground-based spectra of Jupiter and Saturn in the region from 17 to 25 microns are compared with intensities computed from current thermal-structure models. Good agreement with the continuum of Jupiter is obtained for models which incorporate a temperature inversion, but published models give disagreement with the continuum of Saturn. Upper-limit abundances for sulfur and phosphorus in the Jovian atmosphere, as thermodynamically stable species S8 and P4, are found to be 0.04 and 2.1 times the solar abundance, respectively.

Tokunaga, A.↗
NASA NTRS1976

Ethane and acetylene abundances in the Jovian atmosphere

The paper reports spectra of Jupiter in the spectral region from 755 to 850 kaysers, which covers the nu-9 fundamental of ethane and contains lines from the R branch of the nu-5 fundamental of acetylene. The monochromatic absorption coefficient of the central Q branch of the nu-9 fundamental of ethane, which was determined in the laboratory, is applied in a radiative-transfer calculation to evaluate the ethane mixing ratio in the Jovian atmosphere; the present data are also used to place an upper limit on the acetylene mixing ratio. For the radiative-transfer calculation, emission intensity is computed for the region above the 0.02-atm level assuming both an isothermal inversion layer and a previously reported temperature profile. The resulting maximum mixing ratios consistent with the observations are 0.00003 for ethane and 7.5 by 10 to the -8th power for acetylene.

Tokunaga, A.↗