Comment on Carbon Monoxide in Jupiter After Comet SL-9
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Carbon Monoxide Jupiter Comet↗
Engineering topics
Knacke, R. F.
Publications and source records attributed to Knacke, R. F..
Titan's 5 micrometers spectral window: carbon monoxide and the albedo of the surface
We have measured the spectrum of Titan near 5 micrometers and have found it to be dominated by absorption from the carbon monoxide 1-0 vibration-rotation band. The position of the band edge allows us to constrain the abundance of CO in the atmosphere and/or the location of the reflecting layer in the atmosphere. In the most likely case, 5 micrometers radiation is reflected from the surface and the mole fraction of CO in the atmosphere is qCO=10(+10/-5) ppm, significantly lower than previous estimates for tropospheric CO. The albedo of the reflecting layer is approximately 0.07(+0.02/-0.01) in the 5 micrometers continuum outside the CO band. The 5 micrometers albedo is consistent with a surface of mixed ice and silicates similar to the icy Galilean satellites. Organic solids formed in simulated Titan conditions can also produce similar albedos at 5 micrometers.
Saturn↗
An estimate of the comet Shoemaker-Levy 9 fragment sizes from the debris field
The impacts of Comet Shoemaker-Levy 9 left spots on Jupiter with diameters on the order of tens of thousands of kilometers, which have the appearance of debris fields strewn upon the Jovian cloud tops. In this note we employ a measurement of the optical depth of the debris at the impact site of fragment G to estimate mass in the debris field and lower limits to the G fragment mass of 4 x 10(exp12) - 4 x 10(exp 13) g and diameter of 0.1 - 0.3 km.
Knacke, R. F.↗
The Spectrum of Titan near 3.4 Micron: Comparison of Spectral Features to Organic Molecules
In August 1993 we observed the spectrum of Titan from 2.9 to 4.1 micrometers at a resolving power of R=500-1000 (dw approx. 2-4 per cm). The spectrum shows, as expected, a strong absorption throughout this region from three strong bands Of CH4. However, comparison of the spectrum to simple radiative transfer models and to the spectrum of Jupiter reveal some interesting differences. A broad emission feature that we attribute to CH4 is centered at 3.3 micrometers. At 3.45 micrometers we see a distinct narrow absorption feature that is present in both the Jupiter and laboratory spectrum, but only when other features, absent in the Titan spectrum, are also present. In our attempt to understand the origin of this spectral feature we have compared the spectrum to CH4 and other organic molecules. Interesting similarities appear between the aliphatic hydrocarbons (CH2 and CH3 groups) seen in laboratory organics and the Titan spectrum, but only if we assume that the shorter wavelength feature (CH3) is masked by the broad CH4 emission. A second problem with the explanation is that like column abundance of organic haze (Toon et al. 1991) is insufficient to provide the required number of molecules to create a spectral feature with tau approx. 1. Laboratory organics produced through a variety of processes have been compared to the Titan spectrum and the results arc presented.
Pendleton, Yvonne↗
Edison - The next generation infrared space observatory
Edison, a large-aperture, radiatively-cooled telescope, is proposed as the major international mission to follow the current generation of cryogenically-cooled infrared space telescopes. It is being studied at present as a 2.5-3.5 m mixed radiatively- and mechanically-cooled facility optimized to investigate the wavelength range 3-100+ microns. This paper outlines the status of the project, discusses some aspects of a smaller-aperture 'precursor' mission, and describes a portion of the baseline science mission.
Thronson, H. A., Jr.↗
Titan's mid-IR albedo: New observations from 3 to 5 microns
Photometric and spectrophotometric observations of Titan in the wavelength interval from 3 to 5 micrometers which were made in Jun. 1990 and Jun. 1991 are reported and analyzed. The broadband flux measured at 4.8 micrometers in both years and on two different telescopes is more than a factor of three lower than measurements made by two independent groups in 1971 and 1973. No other measurements were made in the 17 intervening years. It was concluded that either the original measurements were contaminated by long wavelength leaks or that Titan's albedo at 4.8 micrometers has decreased. The low resolution spectrum obtained near 4.8 micrometers is crudely consistent with the presence of CO at 60 ppm in the lower troposphere and a reflecting layer located between 100 mbar and the surface at 1500 mbar. The spectrum from 3.1 to 4.0 micrometers is relatively featureless at low spectral resolution but has some hints of structure that may yield information at higher resolution and signal to noise.
Noll, K. S.↗
Detection of silicates in the Beta Pictoris disk
A broad 10-micron emission feature has been detected within 3 arcsec of the star Beta Pic which is known to have a circumstellar, possibly protoplanetary, disk. The observations were made using four narrow-band filters in the MSFC bolometer array at the IRTF. The emission feature closely resembles silicate features observed in Comets Halley and Kohoutek and in a variety of Galactic sources. The feature is strong, with the total flux density emitted by dust at 10.3 microns being at least twice the estimated continuum at that wavelength, and must be emitted by particles with characteristic radii less than 10 microns.
Telesco, C. M.↗
Water vapor in the Orion Molecular Cloud
Infrared observations of interstellar gas-phase H2O in the spectrum of the BN object in Orion are reported. There are absorptions (S/N = 2-5) at the positions of four of the strong lines in the 000-001 nu3 vibration-rotation band. With an estimated excitation temperature of 150 K, the column density of gaseous H2O toward BN in the OMC-1 cloud is (2 + or - 1) x 10 to the 17th/sq cm. The intensities of the lines imply an ortho/para ratio of 1 + or - 0.5 indicating recent sublimation of H2O from low-temperature grains. The results give gas-phase abundance ratios of H2O/CO roughly 0.03 + or - 0.02 and HDO/H2O = 0.001-0.0001 toward BN. The velocities of the H2O absorptions agree with those of the ridge source and CO outflow, but the position along the line of sight is not well constrained. The gas/solid ratio is H2O(gas)/H20(ice) = 0.05 or less. Less than 1 percent of the oxygen is in H2O gas (assuming total cosmic abundance). Most of the H2O in the line of sight to BN, and by inference in quiescent regions of molecular clouds generally, is frozen on grains.
Knacke, R. F.↗
Detection of the 3.4 micron emission feature in Comets P/Brorsen-Metcalf and Okazaki-Levy-Rudenko (1989r) and an observational summary
The 3.4 micron emission feature due to cometary organics was detected in Comets P/Brorsen-Metcalf and Okazaki-Levy-Rudenko (1989r). Features-to-continuum ratios in these two comets were higher than those expected from the trend seen in other comets to date. Three micron spectra of eight comets are reviewed. The 3.4 micron band flux is better correlated with the water production rate than with the dust production rate in this sample of comets. High feature-to-continuum ratios in P/Brorsen-Metcalf and Okazaki-Levy-Rudenko can be explained by the low dust-to-gas ratios of these two comets. The observations to date are consistent with cometary organics being present in all comets (even those for which no 3.4 micron feature was evident) at comparable abundances with respect to water. The emission mechanism and absolute abundance of the organics are not well determined; either gas-phase fluorescence or thermal emission from hot grains is consistent with the heliocentric distance dependence of the 3.4 micron band flux. There is an overall similarity in the spectral profiles of the 3.4 micron feature in comets; however, there are some potentially significant differences in the details of the spectra.
Brooke, T. Y.↗
Search for interstellar methane
Researchers searched for interstellar methane in the spectra of infrared sources embedded in molecular clouds. New observations of several lines of the P and R branches of the nu 3 band of CH4 near 3.3 microns give column densities in the range N less than 1(-2) times 10 to the minus 16th power cm(-2). Resulting abundance ratios are (CH4)/(CO) less than 3.3 times 10 to the minus 2nd power toward GL961 in NGC 2244 and less than 2.4 times 10 to the minus 3rd power toward GL989 in the NGC 2264 molecular cloud. The limits, and those determined in earlier observations of BN in Orion and GL490, suggest that there is little methane in molecular clouds. The result agrees with predictions of chemical models. Exceptions could occur in clouds where oxygen may be depleted, for example by H2O freezing on grains. The present observations probably did not sample such regions.
Knacke, R. F.↗
Detection of the 3.4- and 2.8-micron emission features in Comet Bradfield (1987s)
Comet Bradfield's 3.4-micron C-H emission feature at 3.4 microns, as well as the emission feature near 2.8 microns, exhibit spectral shapes similar to those noted in Comets Halley and Wilson; the derived abundances of the C-H bonds in all three comets are also comparable (within water production rate uncertainties). These data support the hypothesis that the species responsible for the 3.4- and 2.8-micron features may be common to all comets. Beyond this, the widely differing ages of the three comets suggest that the 3.4-micron feature-emitting organics are not the product of surface irradiation processes after the comets' formation.
Brooke, T. Y.↗
Detection of the 3.4 micron emission feature in comets P/Brorsen-Metcalf and Okazaki-Levy-Rudenko (1989r) and an observational summary
A survey was performed of the 3 micron spectral region of comets, including the broad 3.4 micron emission feature due to C-N bonds in organic molecules. One goal is to determine how the strength of the emission band varies with heliocentric distance r in comets. This depends on both the production rate of the organic molecules and the emission mechanism, neither of which is well determined at present. The observations to date are consistent with cometary organics being present in all comets at comparable abundances relative to water. Loss of contrast in the 3.4 micron feature as comets get closer to the sun is then easily explained by dilution by thermal emission from the continuum grains, whose flux rises more steeply with heliocentric distance than that of organics.
Brooke, T. Y.↗
An upper limit to the acetylene abundance toward BN in the orion molecular cloud
A search for the acetylene (C2H2) nu3 infrared vibration-rotation absorption near 3 microns toward the Becklin-Neugebauer source in the Orion molecular cloud is reported. The relative abundance of C2H2/CO in the quiescent gas is less than 0.003.
Knacke, R. F.↗
Arsine in Saturn and Jupiter
New spectra of Saturn and Jupiter are reported that show a prominent, heretofore unidentified absorption near 2126/cm. The observation is interpreted as unambiguous evidence for the presence of arsine, AsH3. The abundance of AsH3 appears to be almost a factor of two higher in Saturn than in Jupiter. The observed enrichments are consistent with the core instability model for the formation of giant planets. Models of arsenic chemistry that predict strong depletions of AsH3 at temperatures below 370 K are not consistent with the observations, suggesting that vertical convection or perhaps some other mechanism inhibits depletion. Arsenic is the first new element identified in a planetary atmosphere since germanium was found in Jupiter a decade ago.
Noll, Keith S.↗
Evidence for interstellar H2O in the Orion molecular cloud
A search for interstellar gas phase H2O in the infrared spectrum of the BN object in Orion is reported. There is absorption (S/N = 2-4) at the position of the nu3 1(01)-2(02) line of H2O at 3801.42/cm, the strongest expected H2O line. Statistical analysis of the spectrum provides corroborating evidence for other H2O lines. With an assumed H2O excitation temperature of 150 K, N(H2O) of 2.3 x 10 to the 17th/sq cm or less toward the BN object is derived. The H2O column density implies abundance ratios of (H2O)/(CO) = 0.01-0.08 or less and (HDO)/(H2O) = 0.8-3.0 x 10 to the -3rd or more. The gas-to-ice ratio is (H2O gas)/(H2O ice) = 0.06 with an estimated uncertainty of a factor of 5.
Knacke, R. F.↗
Evidence for germane in Saturn
Observations in Saturn have prompted the development of an 0.4 + or - 0.2 ppb mole fraction for germane (GeH4) on the basis of the P- and R-branch lines' spectra. The presence of germane in Saturn implies a disequilibrium of the upper atmosphere by rapid vertical convection. It is suggested that future, more realistic radiative transfer models that include the effects of scattering within a cloud layer will probably only reduce the mole fraction presently derived for germane, by increasing the effective path length in a given atmospheric layer.
Noll, Keith S.↗
The 3.4 micrometer emission feature in Comet Halley
Several teams of ground based observers reported observations of the emission feature centered at 3.36 micrometers in comet Halley following its discovery by the Vega 1 spacecraft. The position and shape of the band indicate a superposition of emissions by C-H groups. But the mechanism for the excitation of these C-H3 groups is still not agreed upon. Three possibilities are summarized. Elucidation of the emission mechanism is needed to determine whether the source is predominately solid or gas. In addition, is it shown that the derived carbon abundance in Halley depends strongly on the assumed mechanism.
Brooke, Timothy Y.↗
The near-infrared polarization and color of Comet Halley: What can we learn about the grains
The near infrared polarization and JHK colors of light scattered by dust grains in comet Halley were measured over a wide range in phase angle and heliocentric distance. Colors were redder than solar with no statistically significant variation with phase angle, heliocentric distance, or pre- and post-perihelion. This suggests that the grain population did not change drastically over time and that the data may be combined and modeled. However, short term variations in visible polarization and dust albedo were seen in Halley. Also, near infrared colors became systematically bluer after the observations were completed. The near infrared colors of Halley fall in the range of those of other comets. The near infrared polarization is similar to the visible polarization of Halley and other comets in showing a negative branch at small phase angles and an approximately linear rise toward positive values at larger phase angles. Mie theory calculations and a size distribution based on spacecraft data were used to model the near infrared polarization and color of comet Halley. Numerous lines of evidence point to the presence of dark, absorbing, probably carbonaceous materials in comets.
Brooke, Timothy Y.↗