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Irvine, W. M.

Publications and source records attributed to Irvine, W. M..

At least 91 records · Page 5
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NASA NTRS1985

Astronomical identification of the C3H radical

The C3H radical has been identified in the millimeter-wave spectra of IRC +10216 and TMC-1. In IRC +10216, four rotational transitions have been observed, three in the lower fine-structure ladder (2Pi1/2) and one in the upper (2Pi3/2), each a resolved or partially resolved lambda-doublet. In TMC-1, both lambda components of the lowest lying 3/2-1/2 transition of the 2Pi1/2 ladder have been observed, each with well-resolved hfs. In IRC +10216, the excitation of C3H is similar to that of SiCC: the rotational temperature Trot within the 2Pi1/2 ladder is low (8.5 K), because of rapid radiative decay, while Trot across the ladders is high (about 52 K), because interconnecting far-IR radiative transitions are only weakly permitted. The column density of C3H in IRC +10216 averaged over the estimated source diameter of 84 arcsec is 2.8 x 10 to the 13th/sq cm, an order of magnitude less than that of C2H and C4H.

Thaddeus, P.↗
NASA NTRS1985

The spectra of Orion A and IRC + 10216 between 72.2 and 91.1 GHz

Spectral scans of Orion A and the envelope of IRC + 10216, obtained with resolution 1 MHz over the complete range from 72.2 to 91.1 GHz using the radome-enclosed 20-m mm-wave telescope at Onsala Space Observatory during 1979-1982, are presented graphically (as main-beam brightness temperature in 500-MHz bands), providing the data basis is for the discussion of Johansson et al. (1984). Observing parameters include main-beam efficiency 0.58, aperture efficiency 0.44, FHPBW 47 arcsec, and total-system noise temperature 300-500 K.

Johansson, L. E. B.↗
NASA NTRS1985

The detection of acetaldehyde in cold dust clouds

Observations of the 1(01)-0(00) rotational transitions of A and E state acetaldehyde are reported. The transitions were detected, for the first time in interstellar space, in the cold dust clouds TMC-1 and L134N, and in Sgr B2. This is also the first time acetaldehyde has been found in a dust cloud and is the most complex oxygen-bearing molecule yet known in this environment. A column density of 6 x 10 to the 12th/sq cm in TMC-1, comparable to many other species detected there, and an approximately equal column density in L134N are formed. In the direction of Sgr B2, the CH3CHO profile appears to consist of broad emission features from the hot molecular cloud core, together with absorption features resulting from intervening colder material. The possible detection of HC9N toward IRC + 10 deg 216 through its J = 33-32 transition is also reported. Implications for cold dust cloud chemistry and excitation are discussed.

Matthews, H. E.↗
NASA NTRS1985

The chemical state of dense interstellar clouds - An overview

The currently known interstellar molecules and isotopes are listed, procedures for determining relative chemical abundances in molecular clouds are discussed, and current best estimates for such abundances in regions of differing physical properties are presented. Among the results are a general chemical similarity across a range of density and temperature for quiescent clouds, and some striking differences among regions which are not easily related to such physical parameters and may instead reflect cloud history and evolution. The possibility of constraining chemical models via measurements of relative abundances for the isomeric pairs HNC/HCN, CH3NC/CH3CN, and HOC(+)/HCO(+) is discussed in detail.

Irvine, W. M.↗
NASA NTRS1984

Hydrogen cyanide in comets - Excitation conditions and radio observations of comet IRAS-Araki-Alcock 1983d

The HCN emission of the pure rotation and rotation/vibration lines in comet IRAS-Araki-Alcock 1983d is examined. The prevailing excitation mechanism for the emissions was the excitation of the nu-2, 2 nu-2, and nu-3 vibrational bands by the solar infrared field. For the description of inner coma, a dynamical excitation model is presented which includes collisions. It is predicted on the basis of the model that HCN molecules in rotation and rotation vibration lines of IRAS-Araki-Alcock 1983d would be detectable with a large-millimeter wave telescope, and that the strongest infrared lines would be observable from space observatories. Subsequent searches for the J = 1-0 HCN radio lines in comet 1983d with the Five College Radio Astronomy Observatory (FCRAO) proved unsuccessful. An extremely low upper limit was found for HCN production which suggests that HCN might not be the only parent of planetary cometary CN.

Bockelee-Morvan, D.↗
NASA NTRS1984

Studies of radiative transfer in planetary atmospheres

Progress is reported in modeling cometary emission in the 18-cm OH transition with specific application and predictions for Comet Halley. Radiative transfer is also being studied in rough and porous media. The kinematics of the cold, dark interstellar cloud Li34N were examined, and CO monitoring of Venus and Mars continues. Analysis of 3.4 mm maps of the lunar surface shows thermal anomalies associated with such surface features as the Crater Copernicus, Mare Imbrium, Mare Nubium, Mare Serenitatis, and Mare Tranquillatis.

Irvine, W. M.↗
NASA NTRS1984

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)

Continuum and spectral-line radio observations of the comets IRAS-Araki-Alcock and Sugano-Saigusa-Fujikawa obtained at a number of observatories during May and June, 1983, are compiled in tables and briefly characterized. The species NH3, H2O, CO, and HCN are considered in detail; visible-range observations of CN are compared; and the implications of the results and the experience gained in performing and coordinating the observations for the detection of important species in other comets, especially Halley's Comet, are explored.

Irvine, W. M.↗
NASA NTRS1984

Cyanide and isocyanide abundances in the cold, dark cloud TMC-1

Cold, dark molecular clouds are particularly useful for the study of interstellar chemistry because their physical parameters are better understood than those of heterogeneous, complex giant molecular clouds. Another advantage is their relatively small distance from the solar system. The present investigaation has the objective to provide accurate abundance ratios for several cyanides and isocyanides in order to constrain models of dark cloud chemistry. The relative abundances of such related species can be particularly useful for the study of chemical processes. The cloud TMC-1 considered in the current study has a remarkably high abundance of acetylene and polyacetylene derivatives. Data at 3 mm, corresponding to the J = 1 to 0 transitions of HCN, H(C-13)N, HN(C-13), HC(N-15), and H(N-15)C were obtained.

Irvine, W. M.↗
NASA NTRS1984

A new interstellar molecule - Tricarbon monoxide

The C3O molecule, whose pure rotational spectrum has only recently been studied in the laboratory, has been detected in the cold, dark interstellar Taurus Molecular Cloud 1. Since C3O is the first interstelar carbon chain molecule to contain oxygen, its existence places an important new constraint on chemical schemes for cold interstellar clouds. The abundance of C3O can be understood in terms of purely gas-phase ion-molecule chemistry.

Matthews, H. E.↗
NASA NTRS1984

The detection of interstellar methylcyanoacetylene

A new interstellar molecule, methylcyanoacetylene (CH3C3N), has been detected in the molecular cloud TMC-1. The J = 8 to 7, J = 7 to 6, J = 6 to 5, and J = 5 to 4 transitions have been observed. For the first three of these, both the K = 0 and K = 1 components are present, while for J = 5 to 4, only the K = 0 line has been detected. The observed frequencies were calculated by assuming a value of radial velocity V(LSR) = 5.8 km/s for TMC-1, typical of other molecules in the cloud. All observed frequencies are within 10 kHz of the calculated frequencies, which are based on the 1982 laboratory constants of Moises et al. (1982), so the identification is secure. The lines are broadened by hyperfine splitting, and the J = 5 to 4, K = 0 transition shows incipient resolution into three hyperfine components. The rotational temperature determined from these observations is quite low, with T(rot) in the range from 2.7 to 4 K. The total column density is approximately 5 x 10 to the 12th per sq cm.

Broten, N. W.↗
NASA NTRS1984

Spectral scan of Orion A and IRC+10216 from 72 to 91 GHz

The spectra of the Orion KL molecular cloud and the envelope of the carbon star IRC+10216 are surveyed at 1 MHz resolution over the interval 72.2-91.1 GHz to a sensitivity usually better than 0.1 K. Multitransition analysis of several molecular species is presented which gives information on the physical conditions and chemical abundance in the Orion KL region. The excitation conditions and relative abundances in the IRC+10216 envelope are surveyed. It is stressed that the low detection rate of molecular lines in this object does not necessarily imply a poorer chemistry compared with that in interstellar clouds, but is partly a reflection of low abundances and unsatisfied excitation requirements.

Johansson, L. E. B.↗
NASA NTRS1984

The chemical composition of interstellar molecular clouds

Quantitative molecular abundances are becoming available for dense interstellar clouds and circumstellar envelopes, revealing both similarities across a wide range of source conditions and significant differences in the chemistries involved. As understanding concerning the processes that lead to particular compositions increases, it may become possible to relate these findings to the evolution of molecular clouds and hence to the chemistry of regions in which stellar and planetary formation is in progress. Attention is given to the results of a recently completed spectral scan of the Orion molecular cloud, as well as the envelope around the evolved star IRC + 10216, published by Johansson et al. (1983).

Irvine, W. M.↗
NASA NTRS1983

Observations of SO2 and HCS(+) in cold molecular clouds

The first instance of SO2 emission from a dark dust cloud (L183), and the first astronomical detections of the J = 1-0 rotational transition of the HCS(+) ion and the J = 16-15 transition of HC5N, both towards the cold cloud TMC-1, are reported. The HCS(+)/CS abundance ratio in TMC-1 is greater than about 0.1. Unlike HCS(+) and the cyanopolyynes, SO2 appears to be more abundant in L183 than in TMC-1. SO2 was also detected in the Orion ambient molecular cloud and in the Rho Oph cloud.

Irvine, W. M.↗
NASA NTRS1983

Theoretical interpretation of the ground-based photometry of Saturn's B ring

Small tilt angle photographic photometry obtained during 1979 and 1981 apparitions is combined with previous data to derive physical parameters for the Saturn B ring in red and blue colors. The value of the volume density is 0.020 + or - 0.004, with no indication of dependence on either the color or the tilt for values between 6 and 26 deg. For the geometric albedo of a single particle, the derived values of 0.61 + or - 0.04 in the red and 0.41 + or - 0.03 in the blue are superior to earlier estimates lacking the most recent data. The present results indicate that the ground-based photometry is fully consistent with the classical, many-particle-thick ring model.

Lumme, K.↗
NASA NTRS1983

The chemical composition of the pre-solar nebula

The chemical composition of comets may reflect an origin in the molecular cloud which subsequently formed the solar nebula. The chemistry of different types of interstellar clouds is contrasted, including an inventory of molecular species detected in Orion and in TMC 1. The first astronomical detections of the J = (1-0) transition of HCS(+) and the J = (16-15) transition of HC5N and the first detection of SO2 in a cold dust cloud are reported.

Irvine, W. M.↗
NASA NTRS1983

Radio science and the International Halley Watch

The radio observations planned for the perihelion passage of Halley's comet in 1986 within the framework of the International Halley Watch (IHW) are reviewed. The roles of radar astronomy, continuum radio astronomy, and spectral-line radio astronomy in investigating the size and surface characteristics of the cometary nucleus, the nature and kinematics of the parent molecules sublimating into the coma, the properties of the coma particulate matter, and the cometary plasma are examined. Problems related to the inaccuracy of comet position data and lacks of background-source information, simultaneous submillimeter observations, and Southern-Hemisphere radio observing time are discussed; and the observatories participating in the IHW network are listed in tables with their instrument parameters.

Irvine, W. M.↗
NASA NTRS1982

Radiative transfer in the surfaces of atmosphereless bodies. III - Interpretation of lunar photometry

Narrowband and UBV photoelectric phase curves of the entire lunar disk and surface photometry of some craters have been interpreted using a newly developed generalized radiative transfer theory for planetary regoliths. The data are well fitted by the theory, yielding information on both macroscopic and microscopic lunar properties. Derived values for the integrated disk geometric albedo are considerably higher than quoted previously, because of the present inclusion of an accurately determined opposition effect. The mean surface roughness, defined as the ratio of the height to the radius of a typical irregularity, is found to be 0.9 + or - 0.1, or somewhat less than the mean value of 1.2 obtained for the asteroids. From the phase curves, wavelength-dependent values of the single scattering albedo and the Henyey-Greenstein asymmetry factor for the average surface particle are derived.

Lumme, K.↗