Engineering topics

Irvine, W. M.

Publications and source records attributed to Irvine, W. M..

At least 73 records · Page 4

NASA NTRS1988

Methanol in dark clouds

The first observation of methanol in cold dark clouds TMC 1, L 134 N, and B 335 is reported. In all three clouds, the relative abundance of methanol was found to be in the range of 10 to the -9th (i.e., almost an order of magnitude more abundant than acetaldehyde), with no observable variation between the clouds. Methanol emission showed a complex velocity structure; in TMC 1, clear indications of non-LTE were observed. Dimethyl ether was searched for in L 134 N; the upper limit of the column density of dimethyl ether in L 134 N was estimated to be 4 x 10 to the 12th/sq cm, assuming 5 K rotation temperature and LTE. This limit makes the abundance ratio (CH3)2O/CH3OH not higher than 1/5, indicating that dimethyl ether is not overabundant in this dark cloud.

Friberg, P.↗

NASA NTRS1987

Observations of HCN in comet P/Halley

This paper presents observations of the HCN J =1-0 rotational transition at 3.4 mm wavelength in Comet P/Halley, obtained during 56 individual observing sessions between November 1985 and May 1986 carried out at the Five College Radio Astronomy Observatory. A comparison of the HCN production with the total gas production of the comet indicates that HCN is a relatively minor constituent with 0.1 percent the abundance of H2O. A comparison of HCN and CN production suggests that HCN is a major parent molecule of CN, but probably not the sole parent. Evidence is presented of day-to-day time variability in the total HCN emission and in the hyperfine ratios. The time variation of the total emission is consistent with the known time variable behavior of the comet.

Schloerb, F. P.↗

NASA NTRS1987

Deuterium hyperfine structure in interstellar C3HD

The deuterium nuclear quadrupole hyperfine structure of the transition 1(10)-1(01) of the ring molecule cyclopropenylidene-d1 (C3HD) has been observed in emission from interstellar molecular clouds. The narrowest linewidths (approximately 7 kHz) so far observed are in the cloud L1498. The derived D coupling constants Xzz = 186.9(1.4) kHz, eta=0.063(18) agree well with correlations based on other molecules.

NASA Program Exobiology↗

NASA NTRS1987

The chemistry of cold, dark interstellar clouds

In recent years the nearby cold, dark clouds have been shown to possess a rich chemistry, with interesting differences with respect to warmer massive-star-forming regions and also among the cold clouds themselves. Thirty-nine molecular species are now known in these regions. Recent molecular detections and upper limits in dark clouds are discussed, with particular emphasis on the tricarbon species C3O, C3H, and C3H2.

Irvine, W. M.↗

NASA NTRS1987

Chemical abundances in molecular clouds

At present approximately 70 interstellar molecules are known. The paper discusses methods for determining chemical abundances in interstellar clouds and presents results for the best studied regions, which include the 'spiral arm' clouds seen towards distant continuum sources, quiescent dark and giant clouds, and the gas in regions of active star formation. For many simple molecules, abundances are rather uniform over a range of densities and temperatures in quiescent clouds, in accord with gas phase, ion-molecule chemical models. Some striking chemical differences do exist both within and among clouds, however, particularly in star-forming regions.

Irvine, W. M.↗

NASA NTRS1986

Multi-level study of C3H2: The first interstellar hydrocarbon ring

Cyclic species in the interstellar medium have been searched for almost since the first detection of interstellar polyatomic molecules. Eleven different C3H2 rotational transitions were detected; 9 of which were studied in TMC-1, a nearby dark dust cloud, are shown. The 1 sub 10 yields 1 sub 01 and 2 sub 20 yields 2 sub 11 transitions were observed with the 43 m NRAO telescope, while the remaining transitions were detected with the 14 m antenna of the Five College Radio Observatory (FCRAO). The lines detected in TMC-1 have energies above the ground state ranging from 0.9 to 17.1 K and consist of both ortho and para species. Limited maps were made along the ridge for several of the transitions. The HC3N J = 2 yields 1 transition were mapped simultaneously with the C3H2 1 sub 10 yields 1 sub 01 line and therefore can compare the distribution of this ring with a carbon chain in TMC-1. C3H2 is distributed along a narrow ridge with a SE - NW extension which is slightly more extended than the HC2N J = 2 yields 1. Gaussian fits gives a FWHP extension of 8'5 for C3H2 while HC3N has a FWHP of 7'. The data show variations of the two velocity components along the ridge as a function of transition. Most of the transitions show a peak at the position of strongest HC3N emission while the 2 sub 21 yields 2 sub 10 transition shows a peak at the NH3 position.

Madden, S. C.↗

NASA NTRS1986

Radiative transfer in planetary atmospheres

The research effort was concentrated toward comet P/Halley, although observations of other comets including Giacobini-Zinner, Hartley-Good and Thiele were made as opportunities arise. In preparing for the apparition of P/Halley, detailed predictions for the emission in the 18 cm OH transitions were made in order to assist observers and to indicate what type of data would be particularly valuable. Likewise, since occultations by the comet of background radio sources can provide unique types of information, the tracks of P/Halley and P/Giacobini-Zinner were surveyed with the NRAO Very Large Array, background sources were mapped, and a catalogue of occulted sources published. Beginning in September, 1985, regular observations of the 18 cm OH lines have been made for P/Halley using the 43 m antenna of the NRAO in Greenbank, West Virginia. These data promise to provide the most accurate time sequence for the OH emission for any comet ever obtained at radio wavelengths. From the linewidth and shape, information is obtained on the kinetics of the gas in the cometary coma. An extensive series of observations have been undertaken with 14 m antenna to study emission from the HCN molecule in P/Halley. These data provide the first definitive detection of this component of the cometary ices. Interesting variations in the production of HCN were observed with time scales less than a day. Likewise, there appeared to be variations in the ratio of the hyperfine components of the J = 1-0 transition.

Irvine, W. M.↗

NASA NTRS1986

International Halley Watch: Discipline specialists for radio science

Some 34 radio observatories in 18 countries are participating in the Radio Science Net of the International Halley Watch. Approximately 100 radio astronomers are contributing to this effort, which has included observations of comets P/Crommelin and P/Giacobini-Zinner as well as P/Halley. It is clear that the record of data for the 18 cm OH ground state lambda doublet, which provides fundamental information on the gas production rate, kinematics, and potentially the magnetic field in the coma, will be vastly more complete and of higher accuracy than has even been obtained on any previous comet. The coverage by a number of radio observatories will enable short period variations to be studied and correlated with simultaneous data obtained at other wavelengths. Likewise, the first definitive detection of the important parent molecule hydrogen cyanide in a comet was obtained and is being studied by groups in the United States, Sweden, and France. The first detection of the comet with the Very Large Array telescope operated by NRAO was achieved and has produced exciting results for the distribution of emission at high angular resolution from the OH radical. At this writing data are still being obtained and being processed, and there are still strong indications that exciting information will be obtained from radar studies of P/Halley and from searches for additional parent molecules.

Irvine, W. M.↗

NASA NTRS1986

The C3H2 2(20)-2(11) transition - Absorption in cold dark clouds

The first observations of the 2(20)-2(11) transition of cyclopropenylidene (C3H2) at 21.6 GHz are described. The most significant finding is that the 2(20)-2(11) transition line is always seen in absorption, in contrast to the 18.3-GHz 1(10)-1(01) resonance line of the ortho species which always appears in emission in cold dust clouds. Thus the former must have an excitation temperature less than the brightness temperature of the universal microwave background and becomes only the second molecule to exhibit such 'refrigeration' below this temperature in cold, dark dust clouds.

Matthews, H. E.↗

NASA NTRS1986

Studies of radiative transfer in planetary atmospheres

A set of high signal-to-noise spectra of the 18 cm OH emission from the comet P/Halley was obtained. During the course of the Halley OH campaign, high signal-to-noise spectra were also obtained on the comets P/Giacobini-Zinner, C/Thiele, and C/Hartley-Good. The HCN observations of Comet Halley were performed during a total of 56 individual observing sessions between 18 November 1985 and 11 May 1986. These observations represent the largest monitoring program of HCN emission from any comet, and moreover, represent the first time that a cometary parent molecule was so extensively observed. In addition to offering a direct means to monitor the production of a parent molecule from the nucleus, these data also provide fundamental information about the kinematics of parent molecules in the coma. Finally, in addition to monitoring HCN from the comet, attempts were also made to detect other molecues via millimeter-wave spectroscopy. Future plans are descussed.

Irvine, W. M.↗

NASA NTRS1986

Boundary conditions for the paleoenvironment: Chemical and Physical Processes in dense interstellar clouds

The present research includes searches for important new interstellar constituents; observations relevant to differentiating between different models for the chemical processes that are important in the interstellar environment; and coordinated studies of the chemistry, physics, and dynamics of molecular clouds which are the sites or possible future sites of star formation. Recent research has included the detection and study of four new interstellar molecules; searches which have placed upper limits on the abundance of several other potential constituents of interstellar clouds; quantitative studies of comparative molecular abundances in different types of interstellar clouds; investigation of reaction pathways for astrochemistry from a comparison of theory and the observed abundance of related species such as isomers and isotopic variants; studies of possible tracers of energenic events related to star formation, including silicon and sulfur containing molecules; and mapping of physical, chemical, and dynamical properties over extended regions of nearby cold molecular clouds.

Irvine, W. M.↗

NASA NTRS1986

Studies of radiative transfer in planetary atmospheres

The research emphasis during the period of this report has been on radio observations of comets, related to the International Halley Watch. Observations of the 18 cm lambda-doublet of OH have been carried out monthly. Both of the 1667 and 1665 MHz lines have been repeatedly detected for Comets Halley, Giacobini-Zinner, Thiele, and Hartley-Good. The first astronomical detection of the weak satellite line at 1720 MHz was made for P/Halley. These data promise to supply the highest signal-to-noise-ratio data over an extended period ever obtained for cometary radio observations. Analysis will provide gas production rates as a function of heliocentric distance and allow for detailed comparisons with the OH excitation model involving ultraviolet pumping. In the case of Halley, the lines appear quite symmetric, usually being centered within 0.1 km/s with respect to the nominal nuclear velocity. Line widths have been typically within 10% of 2 km/s. There is thus little evidence for asymmetric emission in the data obtained to date. It seems likely that non-steady-state models of the coma will be required to interpret the data. Evidence for significant departures from the LTE hyperfine ratios was found for Comet Giacobini-Zinner. Smaller, but nonetheless significant, deviations have been found for Comet Halley.

Irvine, W. M.↗

NASA NTRS1986

New interstellar masers in nonmetastable ammonia

The first astronomical detections of several ammonia inversion transitions involving nonmetastable levels with energies as high as 1090 K above the ground state are reported. The (J, K) = (9, 6) inversion transition shows maser-like emission in the directions of W51, NGC 7538, W49, and DR 21(OH). The NH3 (6, 3) line exhibits similar characteristics in W51 but is seen in absorption in NGC 7538. These are the first definite detections of ammonia masers in space. The intensities and narrow line widths (0.5-1.5 km/s) for the emission features are in contrast to the previously detected broad, weak, nonmetastable lines attributed to thermal emission in these sources. Temporal variability appears to be evident in the (9, 6) emission in W49 over a 4 month period. The highly excited (J, K) = (9, 6) and (6, 3) ammonia lines are found in regions containig compact H II regions and strongly infrared sources with associated H2O and OH masers; i.e., in regions of active star formation.

Madden, S. C.↗

NASA NTRS1986

Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula

The first interstellar hydrocarbon ring, cyclopropenylidene (C3H2) is being studied. Both a survey of galactic sources in several C3H2 transitions and a more detailed study of a subset of these sources are under way. In the latter category is a study of the nearby cold dark cloud TMC-1, which is a potential formation site for solar type stars. A spectra is shown of seven rotational transitions which have been observed at the Five College Radio Astronomy Observatory. Three of these were detected for the first time in any astronomical source: the 3 sub 30 to 2 sub 21 transition at 216 GHz, the 2 sub 21 to 1 sub 10 transition at 122 GHz, and the 1 sub 11 to 0 sub 00 transition at 52 GHz. From the data it is apparent that C3H2 is quite spacially extended in typical interstellar molecular clouds, and that at least in TMC-1 it is one of the most abundant organic molecules.

Irvine, W. M.↗

NASA NTRS1986

Studies of radiative transfer in planetary atmospheres

Schloerb and Claussen continued their analysis of the very high quality data set obtained on the 18 centimeter OH line from the Comet P/Halley with the NRAO 43 meter antenna. The high spectral resolution (0.22 km/sec) and high signal-to-noise of the OH spectra make them ideal for the study of kinematics in the coma. Synthetic profiles were initiated for comparison with the data. A vectorial model was developed using the Monte Carlo techniques originated by Combi and Delsemme. Analysis of the millimeter wavelength observations of HCN emission from P/Halley obtained throughout much of the recent apparition were continued using the University of Massachusetts 14 millimeter-wavelength (FCRAO) antenna. A detailed analysis of the HCN lineshpaes was performed over the last six months. The excitation of HCN in the coma was studied to obtain a detailed match to the observed spectra. The passive millimeter wave radiometer was used to probe the physical and chemical nature of comets from spacecraft. Work was continued on an improved theory of radiative transfer for rough and porous surfaces, such as the regoliths of satellites, asteroids, and comets.

Irvine, W. M.↗

NASA NTRS1986

Observational astrochemistry

Astronomers have identified some 70 molecular species in dense interstellar clouds and the envelopes expelled by evolved stars. Some 75 percent of these are organic, including molecules with up to 13 atoms and with weights up to 147 daltons. Elements found in interstellar compounds include H, C, N, O, S, Si, and probably Cl. A recent addition to the list of interstellar molecules is the first hydrocarbon ring, cyclopropenylidene (C3H2). Current research in astrochemistry is concentrating on the determination of accurate chemical abundances as a function of environment. Both basic similarities and intriguing differences among clouds are found, which may provide clues to processes associated with cloud evolution and star formation.

Irvine, W. M.↗

NASA NTRS1985

The hydrocarbon ring C3H2 is ubiquitous in the Galaxy

The discovery of a strong microwave (1.6 cm-wavelength) spectral line, the carrier of which is common and widespread throughout the Galaxy is reported. A survey of a large number of sources shows that the line appears in emission in cold dust clouds, in absorption in the direction of the Galactic center, and exhibits complex profiles toward H II regions. Toward Cas A and distant H II regions, intervening 'spiral arm' clouds produce absorption. For almost all cases, the absorption features show a striking 1:1 radial velocity correspondence with those seen, e.g., in H2CO spectra of the same objects. The data indicate that the line arises between low-lying energy states of a rather polar molecule. Recent work by Thaddeus, Vrtilek, and Gottlieb (1985) incorporating the present data, shows that the line in question is the 1(10)-1(01) transition of the small hydrocarbon ring C3H2.

Matthews, H. E.↗

NASA NTRS1985

Roughness of the lunar soil

Three stereoscopic close-up photographs taken of the lunar surface by Apollo 11 and 12 astronauts were analyzed to investigate the roughness of the lunar soil at millimeter resolution. Most existing measurements of regolith roughness were based on radar measurements at wavelengths of about 8.6 mm. Several statistical parameters were determined for they landing site. The surace roughness has been found to be nearly Gaussian. The rms slopes were obtained over scales between 0.5 mm and 5 cm. They steadily decrease with increasing scale length from 58 deg to 2 deg and are in reasonable agreement with radar-measured values. The autocorrelation coefficient of the height distribution has also been obtained; it has a scale length of 0.7 mm.

Lumme, K.↗