Effect of pyrolysis temperature and air flow on toxicity of gases from a polyethylene polymer
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Hilado, C. J.↗
Engineering topics
Hilado, C. J.
Publications and source records attributed to Hilado, C. J..
Effect of pyrolysis temperature and air flow on toxicity of gases from a polycarbonate polymer
A polycarbonate polymer was evaluated for toxicity of pyrolysis gases generated at various temperatures without forced air flow and with 1 L/min air flow, using the toxicity screening test method developed at the University of San Francisco. Time to various animal responses decreased with increasing pyrolysis temperature over the range from 500 C to 800 C. There appeared to be no significant toxic effects at 400 C and lower temperatures.
Hilado, C. J.↗
The effect of fire retardants on the fire response characteristics of cellulosic materials
The resistance to ignition of fire retardant-treated wood, cotton, and cellulose insulation was studied. The proprietary composition used to treat wood was found to increase resistance to ignition and to reduce smoke toxicity. Cotton treated with boric acid (added by padding on or by vapor phase process) was found to have increased resistance to ignition and decreased smoke toxicity. Boric acid increased the resistance of cellulose insulation to ignition but also slightly increased the smoke toxicity.
Hilado, C. J.↗
Smoke density studies with the Arapahoe and NBS chambers
Smoke density studies on twelve cellulosic and five synthetic materials using the Arapahoe and NBS smoke chambers show an empirical relationship between smoke weight as per cent of initial weight in the Arapahoe test and maximum specific optical density under piloted conditions in the NBS test. The NBS optical density data under piloted conditions exhibited sensitivity to test artifacts such as type of pilot burner.
Hilado, C. J.↗
Ignition characteristics of some aircraft interior fabrics
Six samples of aircraft interior fabrics were evaluated with regard to resistance to ignition by radiant heat. Five samples were aircraft seat upholstery fabrics and one sample was an aircraft curtain fabric. The aircraft seat fabrics were 100% wool (2 samples), 83% wool/17% nylon, 49% wool/51% polyvinyl chloride, and 100% rayon. The aircraft curtain fabric was 92% modacrylic/8% polyester. The five samples of aircraft seat upholstery fabrics were also evaluated with regard to resistance to ignition by a smoldering cigarette. The four samples of wool-containing aircraft seat fabrics appeared to be superior to the sample of rayon seat fabric in resistance to ignition, both by radiant heat and by a smoldering cigarette.
Hilado, C. J.↗
Char yield and flash-fire propensity of pyrolysis gases from materials
Comparison of the char yield after occurrence of a flash fire in the pyrolysis gases from various materials indicates that increased char yield appears to be associated with reduced flash-fire propensity for certain types of materials. For certain other materials, flash-fire propensity appears to be independent of char yield. The mechanisms of thermal decomposition and char formation may be more important factors in flash-fire propensity than the quantitative degree of char formation.
Hilado, C. J.↗
Statistical studies of animal response data from USF toxicity screening test method
Statistical examination of animal response data obtained using Procedure B of the USF toxicity screening test method indicates that the data deviate only slightly from a normal or Gaussian distribution. This slight departure from normality is not expected to invalidate conclusions based on theoretical statistics. Comparison of times to staggering, convulsions, collapse, and death as endpoints shows that time to death appears to be the most reliable endpoint because it offers the lowest probability of missed observations and premature judgements.
Hilado, C. J.↗
Two-week studies of survivors from exposures to pyrolysis gases
Swiss Webster male mice which had survived near-lethal concentrations of pyrolysis gases from a variety of polymeric materials were killed two weeks after exposure, and the lungs, heart, liver, kidney, and spleen were examined. Microscopic examination revealed no significant effects on the liver, kidney, and spleen, while the effect on lungs could not be determined because of the high level of pathology in both experimental and control animals. The polymeric materials which were pyrolyzed were polyethylene, ABS, polycarbonate, polyaryl sulfone, polyether sulfone, polyphenylene sulfide, modified polyphenylene oxide, chlorinated polyvinyl chloride, polyvinylidene fluoride, and fluorene polycarbonate. It is suggested that tissue specimens should be examined 24 or 48 hr after exposure rather than 2 wks after exposure, since the 2 wk period permits healing to occur.
Bucci, T. J.↗
Effect of pyrolysis temperature on toxicity of gases from a polyethylene polymer
A polyethylene polymer was evaluated for time of toxic effect to occur as the result of exposure to gases generated by pyrolysis at various temperatures, using the toxicity screening test method developed at the University of San Francisco. Times to various animal responses decreased with increasing pyrolysis temperature over the range from 400 C to 800 C. Responses at a pyrolysis temperature of 350 C were more rapid than would be expected from the other data, and may indicate the predominance of different pyrolysis reactions in this particular temperature region.
Hilado, C. J.↗
Screening materials for smoke evolution
The density of smoke produced by burning or smoldering materials is a factor that affects the ability of occupants to escape from a burning structure and the effectiveness of firefighters. Accordingly, considerable effort is being spent on developing materials that minimize the amount of smoke without impairing their performance characteristics. In the present paper, laboratory tests on such materials are described and evaluated. It is seen that the National Bureau of Standards smoke test and the Ohio State University release-rate test are the most promising for screening materials for smoke evolution. It is shown that, for plastics, smoke obscuration is a more realistic concern than smoke toxicity.
Hilado, C. J.↗
Relative toxicity of the pyrolysis products from some thermoplastic and thermoset polymers
Relative toxicity data on the pyrolysis products of a variety of thermoplastic and thermoset polymers are presented. The data are presented in terms of time to incapacitation and time to death with a fixed sample weight of 1.0 g, and in terms of the apparent lethal concentration required to produce 50 percent mortality within a fixed exposure period of 30 min.
Kourtides, D. A.↗
Toxicity of pyrolysis gases from some cellular polymers
Various samples of cellular polymers were evaluated for toxicity of pyrolysis gases, using the screening test method developed at the University of San Francisco. The cellular polymer samples included polyimide, polymethacrylimide, polybismaleimide, polyurethane, polyisocyanurate, polyethylene, polychloroprene, polyvinyl chloride, polystyrene, polysiloxane, and polyphosphazene. The cellular polymers exhibited varying levels of toxicity under these test conditions. Among the rigid cellular polymers, times to death were shortest with the imide type foams and longest with polyvinyl chloride and polystyrene. Among the flexible cellular polymers, times to death were shortest with polyimide and polyester, and longest with polychloroprene and polysiloxane. Increased char yield was not necessarily associated with reduced toxicity.
Hilado, C. J.↗
Concentration-response data on toxicity of pyrolysis gases from some natural and synthetic polymers
Concentration-response data are presented on the toxic effects of the pyrolysis gases from some natural and synthetic polymers, using the toxicity screening test method developed at the University of San Francisco. The pyrolysis gases from wool, red oak, Douglas fir, polycaprolactam, polyether sulfone, polyaryl sulfone, and polyphenylene sulfide appeared to exhibit the concentration-response relationships commonly encountered in toxicology. Carbon monoxide seemed to be an important toxicant in the pyrolysis gases from red oak, Douglas fir, and polycaprolactam, but did not appear to have been the principal toxicant in the pyrolysis gases from polyether sulfone and polyphenylene sulfide.
Hilado, C. J.↗
Effect of foam age on toxicity of pyrolysis gases from polyurethane flexible foams
The toxicity of the pyrolysis gases from some samples of polyurethane flexible foams appears to have decreased with age, while other samples seem to exhibit no significant change with age in this respect. The changes observed were greater than could be accounted for by variations in the material, or test variations or artifacts.
Hilado, C. J.↗
A simple laboratory method for determining ignitability of materials
A simple laboratory method for determining ignitability of materials is described. The apparatus consists of a Mellen high-flux heater capable of producing up to 13 W/sq cm heat flux, a Medtherm water-cooled radiometer for measuring heat flux, a mounting frame to hold all components in proper position, and specimen holders of the type used for the NBS smoke test. Time to ignition at different heat flux levels is recorded. Test results are presented for a variety of materials.
Hilado, C. J.↗
Fire response test methods for aerospace materials
Fire response methods which may be suitable for materials intended for aircraft and aerospace applications are presented. They address ignitability, smolder susceptibility, oxygen requirement, flash fire propensity, fire spread, heat release, fire containment, smoke evolution, and toxic gas evolution.
Hilado, C. J.↗
Ignitability of some insulation and building materials
A variety of insulation and building materials were evaluated for ignitability, using a screening test method developed at the University of San Francisco. Ignitability tended to be greater with the more efficient insulation materials because the insulating qualities resulted in a more rapid rise in temperature at the exposed surface. The use of a noncombustible facing material is recommended to provide protection from surface ignition.
Hilado, C. J.↗
Flash-fire propensity of rigid foam insulation
Twelve samples of rigid foam insulation were evaluated for flash-fire propensity, using the USF flash-fire screening test method. These materials exhibited little or no flash-fire propensity under these particular test conditions.
Hilado, C. J.↗