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Guillaume Gronoff

Publications and source records attributed to Guillaume Gronoff.

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2022

SO2 Plumes Observation with LMOL: Theory, Modeling, and Validation

LMOL, the NASA Langley Mobile Ozone Lidar, is locatednear NASA’s LaRC steam plant when not deployed in campaigns. Theplant produces steam through the incineration of local trash, and itsexhaust plume occasionally contains SO2.SO2is a known, regulated, pollutant that affects O3observations in theUV, as is the case with LMOL. In this work, we show how we modifiedLMOL to detect the plant SO2plumes and compute its density when theO3background is stable; we observed densities compatible with what isexpected from the typical plume exhaust. The selection of laser lines sothat an O3variation would not get confused with a SO2detection isexplained in details, and a model capable of simulating the Lidar signalwith (notably) O3and SO2absorption for the validation of the retrievalresolution and uncertainty is presented. Finally, the comparison betweenthe modeled and observed performances of the system is shown: themaximum altitude, resolution, and error in the modeled signal and theobserved signals are the same within reasonable margins.This work demonstrates that LMOL is fully capable of working withSO2. The next step being the addition of an additional laser channel,which is simplified by the tunable aspect of the LMOL laser, to addressO3and SO2simultaneously, allowing the assessment of SO2when O3has variations.

Guillaume Gronoff↗
NASA NTRS2021

Volatile chemical product emissions enhance ozone and modulate urban chemistry

Decades of air quality improvements have substantially reduced the motor vehicle emissions of volatile organic compounds (VOCs). Today, volatile chemical products (VCPs) are responsible for half of the petrochemical VOCs emitted in major urban areas. We show that VCP emissions are ubiquitous in US and European cities and scale with population density. We report significant VCP emissions for New York City (NYC), including a monoterpene flux of 14.7 to 24.4 kg ⋅ d−1 ⋅ km−2 from fragranced VCPs and other anthropogenic sources, which is comparable to that of a summertime forest. Photochemical modeling of an extreme heat event, with ozone well in excess of US standards, illustrates the significant impact of VCPs on air quality. In the most populated regions of NYC, ozone was sensitive to anthropogenic VOCs (AVOCs), even in the presence of biogenic sources. Within this VOC-sensitive regime, AVOCs contributed upwards of ∼20 ppb to maximum 8-h average ozone. VCPs accounted for more than 50% of this total AVOC contribution. Emissions from fragranced VCPs, including personal care and cleaning products, account for at least 50% of the ozone attributed to VCPs. We show that model simulations of ozone depend foremost on the magnitude of VCP emissions and that the addition of oxygenated VCP chemistry impacts simulations of key atmospheric oxidation products. NYC is a case study for developed megacities, and the impacts of VCPs on local ozone are likely similar for other major urban regions across North America or Europe.

Matthew M. Coggon↗
NASA NTRS2018

TPSAS-NF1676L-31421-DND

Sherpa aircraft spirals conducted over the Chesapeake Bay Bridge Tunnel (CBBT) and Hampton Roads region.

Megan Buzanowicz↗
NASA NTRSDate not supplied

TPSAS-NF1676L-33873-DND

NOAA's National Air Quality Forecasting Capability (NAQFC) model provides 48-hour forecast of surface ozone and other atmospheric constituents serving as the nation's key tool actively used by regulatory professionals in assessing air quality events and the issuance of public air quality alerts. NAQFC incorporates input meteorology from North American Mesoscale Model (NAM) at 12 km horizontal resolution that is coupled to the Community Multi-scale Air Quality Model (CMAQ) to predict emissions, tropospheric gas and aerosol chemistry, and related deposition and removal processes. The NAQFC forecast simulations contain 35 steps in altitude, with about one third of these in a typical afternoon daytime boundary layer (0-1.5 km). While several studies have been conducted comparing NAQFC predictions to surface observations, investigations comparing the vertical distribution to observations remain limited. Vertical comparisons are needed in order to fully assess forecast model behavior and atmospheric mixing conditions leading to the formation of ozone at the surface. The Tropospheric Ozone Lidar Network (TOLNet) instruments provide a unique observational capability in this regard, as ozone vertical measurements can be directly compared to models, such as NAQFC, and provide additional insight into atmospheric processes and enhance forecast capabilities. In this study, we utilize multiple TOLNet lidar observations obtained during the Ozone Water Land Environmental Transition Studies (OWLETS-2017 & OWLETS-2018) and the Long Island Sound Tropospheric Ozone Study (LISTOS-2018) to compare with NAQFC vertical predictions of ozone. These campaigns took place at different coastal locations along the US East coast with each campaign having multiple TOLNet lidars present, providing a unique opportunity to examine vertical structure of ozone in regions with complex water-land boundaries. Preliminary comparison results will be presented on ozone temporal and vertical differences between NAQFC and the TOLNet lidars along with example case studies to illustrate insights into boundary layer and surface processes of trace gases.

Timothy Berkoff↗
NASA NTRSDate not supplied

Synthesis Analysis of Mulit-Dimensional Ozone Lidar Measurements in Coastal Environments Toward Improving Ozone Simulation

Large surface ozone variations are frequently observed in coastal regions which makes the modeling of air quality in these regions challenging. The ability to properly model coastal regions relies heavily on the proper detailed observations. There have been three air quality studies (over Chesapeake Bay and the Long Island Sound) that focused on thorough measurements in these complex coastal regions; OWLETS 1 & 2 and LISTOS. Over the course of the campaigns, there were surface ozone observations taken from LIDAR (LIght Detection And Ranging) instruments for a total of 89 days at a high temporal rate. We developed a clustering method that characterizes the multiple timestamps of measurements into a range of ozone events that are specific to these coastal regions. We simulated coastal ozone for these cluster groups using WRF-GC and WRF-Chem to identify gaps within the model. Using the characterized ozone clusters, we were able to identify multiple coastal mechanisms that led to incorrect model simulations.

Claudia Bernier↗
NASA NTRSDate not supplied

Active Solar-Like Stars and the Production of Prebiotically Relevant Molecules in Young Earth Like Exoplanet

The magnetic activity of young G type stars produces elevated ionizing radiation fluxes for its planetary system. X-ray, Extreme UV, flare radiation and the associated precipitating energetic particles accelerated in coronal mass ejection driven shocks can drive complex chemistry in the exoplanetary atmosphere, and ignite the production of complex molecules (Airapetian et al., 2016; Hayworth et al. 2021). To address the efficiency of the production of prebiotic molecules in young Earth-like environments, we developed and coupled a set of atmospheric models that account for the determination of the flux of precipitating particle, its ionization/dissociation effects in the planetary atmosphere, and the subsequent chemistry that leads to the creation of prebiotic molecules and greenhouse gases. We show that the productions rates are high enough to provide critical input for the origin of prebiotic molecules on the early Earth. Overall, the impact of the space weather on the atmospheric photochemistry should not be neglected when assessing the factors of habitability of the environments of young rocky (exo)planets.

Guillaume Gronoff↗