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Grisaffe, S. J.

Publications and source records attributed to Grisaffe, S. J..

At least 19 records

JTEC panel report on advanced composites in Japan

The JTEC Panel on Advanced Composites visited Japan and surveyed the status and future directions of Japanese high performance ceramic and carbon fibers and their composites in metal, intermetallic, ceramic and carbon matrices. The panel's interests included not only what composite systems were chosen, but also how these systems were developed. A strong carbon and fiber industry makes Japan the leader in carbon fiber technology. Japan has initiated an oxidation resistant carbon/carbon composite program. The goals for this program are ambitious, and it is just starting, but its progress should be closely monitored in the United States.

Diefendorf, R. J.

Microgravity Materials Science Laboratory

A Microgravity Materials Science Laboratory (MMSL) has been planned, designed, and is being developed. This laboratory will support related efforts to define the requirements for the Microgravity and Materials Processing Laboratory (MMPF) and the MMPF Test Bed for the Space Station. The MMSL will serve as a check out and training facility for science mission specialists for STS, Spacelab and Space Station prior to the full operation of the MMPF Test Bed. The focus of the MMSL will be on experiments related to the understanding of metal/ceramic/glass solidification, high perfection crystal growth and fluid physics. This ground-based laboratory will be used by university/industry/government researchers to examine and become familiar with the potential of new microgravity materials science concepts and to conduct longer term studies aimed at fully developing a l-g understanding of materials and processing phenomena. Such research will help create new high quality concepts for space experiments and will provide the basis for modeling, theories, and hypotheses upon which key space experiments can be defined and developed.

Grisaffe, S. J.

Trends in high temperature gas turbine materials

High performance - high technology materials are among the technologies that are required to allow the fruition of such improvements. Materials trends in hot section components are reviewed, and materials for future use are identified. For combustors, airfoils, and disks, a common trend of using multiple material construction to permit advances in technology is identified.

Grisaffe, S. J.

Thermal Barrier Coatings

Thermal barrier coatings offer gas turbines one way to reach fuel flexibility and improved efficiency. Test/analytical results are encouraging for this young technology.

Grisaffe, S. J.

High temperature environmental effects on metals

The current status of knowledge and ability to predict high-temperature environmental attack of metals is reviewed with particular reference to the gas turbine engine. Environmental attack is caused by high temperatures, combustion products, and impurities. A schematic representation of life-limiting factors of turbine components shows that environmental attack can lead to very early failures. Attention is given to high-temperature oxidation with prevailing modes of oxidation attack, and to hot corrosion and other impurity effects. Erosion attack results from the direct mechanical removal of component material by impact of hard substances like ash, sand, or dirt. Solutions to hot-corrosion problems can be found semiempirically by using improved alloys or ceramics, protective surface coatings, additives to the engine environment, and air/fuel cleanup to eliminate detrimental impurities.

Grisaffe, S. J.

High temperature environmental effects on metals

The gas turbine engine was used as an example to predict high temperature environmental attack on metals. Environmental attack in a gas turbine engine derives from high temperature, combustion products of the air and fuel burned, and impurities. Of all the modes of attack associated with impurity effects, hot corrosion was the most complicated mechanistically. Solutions to the hot corrosion problem were sought semi-empirically in: (1) improved alloys or ceramics; (2) protective surface coating; (3) use of additives to the engine environment; and (4) air/fuel cleanup to eliminate harmful impurities.

Grisaffe, S. J.

Toward more environmentally resistant gas turbines - Progress in NASA-Lewis programs

The paper surveys programs for improving the environmental resistance of gas turbine and power system materials to oxidation and hot corrosion. A computer program Corest has been produced which provides an initial method for predicting long-time metal loss using short-time oxidation data. The role of the coefficient of thermal expansion mismatch on oxide spallation is being studied. A paralinear oxidation attack model in conjunction with regression analysis of weight change data has been applied to the study of oxidation and hot corrosion attack of some Ni-Cr-Al system alloys. Oxide-dispersion strengthened alloys based on the Ni-Cr-Al system are being developed. Sodium sulfate formation during turbine combustion is being investigated from a thermodynamic viewpoint.

Lowell, C. E.

Toward more environmentally resistant gas turbines: Progress in NASA-Lewis programs

A wide range of programs are being conducted for improving the environmental resistance to oxidation and hot corrosion of gas turbine and power system materials. They range from fundamental efforts to delineate attack mechanisms, allow attack modeling and permit life prediction, to more applied efforts to develop potentially more resistant alloys and coatings. Oxidation life prediction efforts have resulted in a computer program which provides an initial method for predicting long time metal loss using short time oxidation data by means of a paralinear attack model. Efforts in alloy development have centered on oxide-dispersion strengthened alloys based on the Ni-Cr-Al system. Compositions have been identified which are compromises between oxidation and thermal fatigue resistance. Fundamental studies of hot corrosion mechanisms include thermodynamic studies of sodium sulfate formation during turbine combustion. Information concerning species formed during the vaporization of Na2SO4 has been developed using high temperature mass spectrometry.

Lowell, C. E.

Duplex aluminized coatings

The surface of a metallic base system is initially coated with a metallic alloy layer that is ductile and oxidation resistant. An aluminide coating is then applied to the metallic alloy layer. The chemistry of the metallic alloy layer is such that the oxidation resistance of the subsequently aluminized outermost layer is not seriously degraded.

Gedwill, M. A.

Method of protecting the surface of a substrate

The surface of a metallic base system is initially coated with a metallic alloy layer that is ductile and oxidation resistant. An aluminide coating is then applied to the metallic alloy layer. The chemistry of the metallic alloy layer is such that the oxidation resistance of the subsequently aluminized outermost layer is not seriously degraded.

Gedwill, M. A.

Aluminized alloy boosts turbine blade life

Description of an aluminized alloy coating technique that involves first the application of a ductile, oxidation-resistant overlay, such as NiCrAl, which is then partially aluminized. The duplex protective system has performance advantages over conventional aluminide coatings in that it provides higher-temperature hot corrosion resistance over a longer service life.

Gedwill, M. A.

Advanced Rankine and Brayton cycle power systems - Materials needs and opportunities

Conceptual advanced potassium Rankine and closed Brayton power conversion cycles offer the potential for improved efficiency over steam systems through higher operating temperatures. However, for utility service of at least 100,000 hours, materials technology advances will be needed for such high temperature systems. Improved alloys and surface protection must be developed and demonstrated to resist coal combustion gases as well as potassium corrosion or helium surface degradation at high temperatures. Extensions in fabrication technology are necessary to produce large components of high temperature alloys. Long-time property data must be obtained under environments of interest to assure high component reliability.

Grisaffe, S. J.

Advanced Rankine and Brayton cycle power systems: Materials needs and opportunities

Conceptual advanced potassium Rankine and closed Brayton power conversion cycles offer the potential for improved efficiency over steam systems through higher operating temperatures. However, for utility service of at least 100,000 hours, materials technology advances will be needed for such high temperature systems. Improved alloys and surface protection must be developed and demonstrated to resist coal combustion gases as well as potassium corrosion or helium surface degradation at high temperatures. Extensions in fabrication technology are necessary to produce large components of high temperature alloys. Long time property data must be obtained under environments of interest to assure high component reliability.

Grisaffe, S. J.

Coated columbium thermal protection systems: An assessment of technological readiness

Evaluation and development to date show that of the coated columbium alloys FS-85 coated with R512E shows significant promise for a reusable thermal protection system (TPS) as judged by environmental resistance and the retention of mechanical properties and structural integrity of panels upon repeated reentry simulation. Production of the alloy, the coating, and full-sized TPS panels is well within current manufacturing technology. Small defects which arise from impact damage or from local coating breakdown do not appear to have serious immediate consequences in the use environment anticipated for the space shuttle orbiter TPS.

Levine, S. R.

Life prediction of turbine components: On-going studies at the NASA Lewis Research Center

An overview is presented of the many studies at NASA-Lewis that form the turbine component life prediction program. This program has three phases: (1) development of life prediction methods for major failure modes through materials studies, (2) evaluation and improvement of these methods through a variety of burner rig studies on simulated components in research engines and advanced rigs. These three phases form a cooperative, interdisciplinary program. A bibliography of Lewis publications on fatigue, oxidation and coatings, and turbine engine alloys is included.

Spera, D. A.

Oxidation resistant claddings for superalloys.

The oxidation protection afforded IN-100 and WI-52 superalloys by thin claddings of NiCrAlSi and FeCrAlY alloys was examined primarily at 1090 C. Comparisons were made with commercial aluminide coatings, using cyclic furnace and high-velocity burner rig tests. In furnace tests, NiCrAlSi on IN-100 and FeCrAlY on WI-52 performed as well as or better than two aluminide coatings. Burner rig performance of the FeCrAlY cladding was better than that of the NiCrAlSi cladding on IN-100 and the aluminide coating on WI-52, but less than the aluminide coating on IN-100. An aluminized NiCrAlSi cladding performed better than any coating or cladding.

Gedwill, M. A.