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Goldman, A.

Publications and source records attributed to Goldman, A..

150 records · Page 9

Detection of fluorocarbons in the stratosphere

Infrared absorption spectral measurements are applied to selected balloon flight data to detect CF2Cl2 and CFCl3 in the stratosphere. Identification of the fluorocarbons from absorption spectra is described, and the results are compared with previous models of fluorocarbon content at 21 km. A volume mixing ratio is derived for CF2Cl3 and a probable ratio is estimated for CFCl3. An upper limit for HF in the lower stratosphere up to 30 km is set based on data from a balloon flight.

Murcray, D. G.↗

Laboratory studies of infrared absorption by NO2 and HNO3

Data concerning the quantitative absorption in the 11 and 22 micron region by HNO3 were obtained. Results are presented indicating the temperature dependence of these bands of HNO3 vapor. The 21.8 micron absorption bands of HNO3 vapor at 40 C are discussed along with the integrated intensity and line parameters for the 6.2 micron band of NO2.

Murcray, D. G.↗

Absolute integrated intensity and individual line parameters for the 6.2-micron band of NO2

The absolute integrated intensity of the 6.2-micron band of NO2 at 40 C was determined from quantitative spectra at about 10 per cm resolution by the spectral band model technique. A value of 1430 plus or minus 300 per sq cm per atm was obtained. Individual line parameters, positions, intensities, and ground-state energies were derived, and line-by-line calculations were compared with the band model results and with the quantitative spectra obtained at about 0.5 per cm resolution.

Goldman, A.↗

Statistical-band-model analysis and integrated intensity for the 21.8 micrometer bands of HNO3 vapor

A large number of low-resolution quantitative spectra were obtained for a band-model analysis of 21.8-micrometer bands. The experimental investigations were conducted with pure nitric-acid vapor at 40 C, taking into account pressures in the range from a few torr to a pressure which is close to the saturation pressure. It is pointed out that the obtained data, in addition to those from the 11.3-micrometer band, can be used for an independent determination of the nitric acid vertical distribution in the stratosphere.

Goldman, A.↗

Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

Goldman, A.↗

Gage of 6.5 per cent Si-Fe sheet is chemically reduced

Chemical milling process aids the production of 6.5 percent silicon-iron soft magnetic-alloy sheets to very thin gages. Following conventional rolling to safe gage limits, the material is chemically reduced to the desired gage.

Goldman, A.↗