Engineering topics
Publications and source records attributed to Goldman, A..
Over 4500 absorption lines have been marked on the spectra and the corresponding line positions tabulated. The associated absorbing telluric or solar species for more than 90% of these lines have been identified and only a fraction of the unidentified lines have peak absorptions greater than a few percent. The high resolution and the low Sun spectra greatly enhance the sensitivity limits for identification of trace constituents.
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Individual spectral line parameters including line positions, strengths, and intensities were generated for the sq Alpha Sigma - sq Chi Pi (0,0) band of OH, applicable to atmospheric and high temperatures. Energy levels and transition frequencies are calculated by numerically diagonalizing the Hamiltonian. Line strengths are calculated using the dipole matrix and eigenvectors derived from energy matrix diagonalization. The line strengths are compared to those calculated from previously published algebraic line strength formulas. Tables of line parameters are presented for 240 K and 4600 K.
The role of various infrared techniques in measurements of trace gases in the stratosphere were surveyed. Particular emphasis was placed on the role of instruments exhibiting ultrahigh resolution (i.e., less than or equal to 0.00/cm) such as laser heterodyne spectrometers.
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A spectral feature, apparently an absorption line, has been observed at an energy of 20.1 + or - 0.5 keV in the pulsed flux of the 3.61-s X-ray pulsar 4U 0115+63 by using the UCSD/MIT instrument on HEAO 1. The line strength, expressed as equivalent width, is 3.1 + or - 0.5 keV. Although essentially unresolved, the feature has a depth more than 60% of the continuum flux. If the feature arises by cyclotron resonance absorption near the magnetic poles of the neutron star, it implies a magnetic field of between approximately 1.8 and 2.5 x 10 to the 12th G, depending on the gravitational redshift (no more than about 5-40%).
A new atlas of CH4 lines in the 1120-1800-per cm region has been generated, based on laboratory spectra taken with a Nicolet interferometer at 0.06-per cm resolution with 635-cm path length at pressures of 0.98 torr, 4.86 torr, and 19.97 torr. A compilation of line positions and line intensities includes 1339 CH4 lines, several hundred of which have not been previously observed.
Balloon-borne infrared solar spectra in the 1292/cm region, at 0.02/cm resolution, obtained during sunset, are used to derive a mixing ratio altitude profile of ClONO2. Portions of the spectra covering the 1292/cm region are shown together with a laboratory spectrum of ClONO2 and HNO3 taken with a flight interferometer. The agreement of the atmospheric absorption feature in shape and position with the ClONO2 spectrum, along with the fact that the feature is not due to other known atmospheric compounds, results in the identification of the atmospheric absorption as being due to ClONO2.
Infrared solar spectra in the 850 to 1350/cm region, at 0.02/cm resolution, were obtained during a balloon flight made on 27 October 1978 from Alamogordo, New Mexico. Analysis of the 1275-1290/cm region indicates that the atmospheric absorption lines of CH4, N2O, H2O, HNO3 and CO2 near 1283/cm are super-imposed on a broader absorption feature which we interpret as due to the V3 band of CF4. Fine structure of CF4 is also identified. Preliminary estimates from the sunset spectra show approximately 75 pptv CF4 near 25 km.
The Denver University Infrared Spectrometer (DUIRS) is a liquid-helium-cooled emission radiometer designed to study minor atmospheric constituents. DUIRS flew on 12 data flights during the 1977 Intertropical Convergence Zone experiment. No data were obtained on the flight from Wallops Island to Panama because of a power failure or on the return flight to Wallops Island because of a cryogen line freeze-up. The data coverage on the nine vertical profile flights that were flown before the freeze-up are shown. Typical spectra and variations as a function of U-2 (research aircraft) altitude are also shown. Radio metric data and rawinsonde temperature data were used to perform band model calculations to obtain molecular number densities in the column above the aircraft at each altitude.
The data compiled during the study allowed a detailed examination of the attenuation of the solar radiance by the combined effect of the atmospheric trace gases and the SAGE filters. The case of the 0.44 microns channel is presented. The amounts of NO2, NO2, O3 and the airmass were chosen to closely simulate a low sun spectral scan from a 9 February 1977 balloon flight. The solar radiance outside the earth's atmosphere was determined from the AFGL Sacramento Peak Observatory spectral data tape degraded to 2.0A resolution and normalized to Thekaekara's absolute intensities. The spectral absorption coefficients used for NO2 and O3 were tabulated previously.
An atlas of 1339 methane absorption lines in the range 1120 to 1800 reciprocal centimeters, including the nu(4) and nu(2) bands, is presented. Laboratory spectra were obtained by a Nicolet Fourier transform Michelson interferometer with a resolution of approximately 0.06 reciprocal cm and a path length of 6.35 m of 0.98, 4.86 and 19.97 torr. Observed spectra are also compared with spectral intensities calculated line-by-line on the basis of tabulated intensities of the observed spectral lines.
Infrared solar spectra, with .02 per cm resolution, were collected during sunset from a balloon at 40 km on October 27, 1978. Portions of the data obtained during the flight have been compared with theoretical calculations made using the data on the AFGL tape. The results of these comparisons reveal a number of areas of disagreement between theory and experimental results. The areas of disagreement are discussed in detail.
Comparison of infrared solar spectra in the 750 to 950 kayser region obtained during sunrise and sunset shows that a number of features due to the nu-2 NH3 band are present on the sunset spectra but are indicated by only a trace on the sunrise spectra. The sunset path shows approximately 0.007 atm-cm NH3, and the reason for the discrepancy between sunrise and sunset spectra is not known. The ground-based measurements at Denver were obtained with a 0.06 kayser resolution.
Two balloon flights reaching float altitudes of approximately 30 and 40 km respectively, were used to obtain scans of the ultraviolet and visible solar spectra. Both flights covered the UV (2800-3500A) at approximately 0.3A resolution and the visible at approximately 0.6A. Numerous scans were obtained during ascent and from float for both flights. All spectral scans obtained at float, from high sun to low sun, were calibrated in wavelength by using several standard solar spectra for line position references. Comparisons of low sun scans and high sun scans show significant atmospheric continuum extinction and have the potential of being used to identify atmospheric lines superimposed on the attenuated solar spectrum. The resolution was mathematically degraded to approximately 5A to better see the broad band atmospheric extinction. This low resolution is also appropriate for the available low resolution absorption coefficients of NO2 and O3, allowing the identification of NO2 and O3 features on the sunset spectra.
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Infrared solar spectra and infrared atmospheric emission spectra were obtained from the ground, from aircraft and from balloons. The initial detection of most stratospheric molecules was achieved by the solar spectral technique because better resolution helps remove interference from other molecules. Because the sun is an intense source of radiation, the resolution which can be obtained with good signal-to-noise, is greater than with atmospheric emission spectroscopy. Data are generally taken using a method that enhances the number of molecules in the optical path i.e. at large solar zenith angles for solar spectra and at low elevation angles for atmospheric emission spectra. The search for molecules which are predicted to be present but which, the detection of a molecule known to be present from other measurement techniques but observed for the first time in infrared solar spectra, and some further data on the variability of HNO3 are discussed.
Atmospheric infrared emission and absorption spectra obtained from aircraft and balloon-borne spectrometers are presented. From such spectra, mixing ratio vs altitude profiles are derived for several minor constituents. Recent results for HNO3, CF2Cl2, CFCl3, and HF are presented. In addition, the feasibility of infrared detection of other trace constituents, such as HCl, HF, NH3, NO and SO2, against the rest of the atmospheric background is studied. From this study, made on a line-by-line basis for 'state of the art' airborne spectrometers, potential spectral features for detection of the trace constituents are isolated.