Engineering topics

Browell, E. V.

Publications and source records attributed to Browell, E. V..

At least 91 records · Page 5

NASA NTRS1985

The photochemistry of synoptic-scale ozone synthesis Implications for the global tropospheric ozone budget

The oxidation of nonmethane hydrocarbons represents a source of tropospheric ozone that is primarily confined to the boundary layers of several highly industrialized regions. (Each region has an area greater than one million km/sq cm). Using a photochemical model, the global tropospheric ozone budget is reexamined by including the in-situ production from these localized regimes. The results from these calculations suggest that the net source due to this photochemistry, which takes place on the synoptic scale, is approximately as large as the amount calculated for global scale photochemical processes which consider only the oxidation of methane and carbon monoxide. Such a finding may have a considerable impact on our understanding of the tropospheric ozone budget. The model results for ozone show reasonable agreement with the climatological summer distribution of ozone and the oxides of nitrogen at the surface and with the vertical distribution of ozone and nonmethane hydrocarbons obtained during a 1980 field program.

Fishman, J.↗

NASA NTRS1985

Ultraviolet DIAL measurements of O3 profiles in regions of spatially inhomogeneous aerosols

The differential absorption lidar (DIAL) technique generally assumes that atmospheric optical scattering is the same at the two laser wavelengths used in the DIAL measurement of a gas concentration profile. Erros can arise in this approach when the wavelengths are significantly separated, and there is a range dependence in the aerosol scattering distribution. This paper discusses the errors introduced by large DIAL wavelength separations and spatial inhomogeneity of aerosols in the atmosphere. A Bernoulli solution for determining the relative distribution of aerosol backscattering in the UV region is presented, and scattering ratio boundary values for these solutions are discussed. The results of this approach are used to derive a backscatter correction to the standard DIAL analysis method. It is shown that for the worst cases of severe range dependence in aerosol backscattering, the residual errors in the corrected DIAL O3 measurements were less than 10 ppbv for DIAL wavelengths at 286 and 300 nm.

Browell, E. V.↗

NASA NTRS1985

The reservoir of ozone in the boundary layer of the eastern United States and its potential impact on the global tropospheric ozone budget

An analysis of available ozone data in the eastern two-thirds of the United States indicates that a substantial reservoir of ozone is present in the summertime. Five-year mean concentrations range from 40 to 65 ppbv. The reservoir covered an area of several million square kilometers and extends vertically from the surface to 1 to 2 km. The vertical distribution of ozone in the reservoir during midday supports a transport of additional ozone from the boundary layer to the free troposphere. Data are presented demonstrating the potential effect of transport by convective clouds and by the sea breeze circulation - mechanisms by which ozone may be transported out of the boundary layer into the free troposphere. The potential impact of this reservoir on the tropospheric ozone budget is discussed. It is shown that if less than half of the ozone mass in this reservoir is transported to the free troposphere, then the amount of ozone transported out of the boundary layer approximates the amount of ozone transported downward during a tropopause fold event.

Vukovich, F. M.↗

NASA NTRS1985

Cumulus cloud venting of mixed layer ozone

Observations are presented which substantiate the hypothesis that significant vertical exchange of ozone and aerosols occurs between the mixed layer and the free troposphere during cumulus cloud convective activity. The experiments utilized the airborne Ultra-Violet Differential Absorption Lidar (UV-DIAL) system. This system provides simultaneous range resolved ozone concentration and aerosol backscatter profiles with high spatial resolution. Evening transects were obtained in the downwind area where the air mass had been advected. Space-height analyses for the evening flight show the cloud debris as patterns of ozone typically in excess of the ambient free tropospheric background. This ozone excess was approximately the value of the concentration difference between the mixed layer and free troposphere determined from independent vertical soundings made by another aircraft in the afternoon.

Ching, J. K. S.↗

NASA NTRS1985

Influence of meteorological conditions on aerosol vertical distribution and composition off the northeast American coastline

The size distribution and composition of lower tropospheric aerosols were measured off the northeast American coastline under clear air and disturbed meteorological conditions. Under the clear air conditions observed on 5 August 1982, with air flow from west to east, sulfate-rich stratified layers are the dominant feature of aerosol distribution in the lowest 3000 m of the troposphere. The encroachment of a warm frontal system over the study area on 9 August 1982 resulted in dramatic changes in aerosol distribution and composition prior to any precipitation, probably due to increased vertical mixing and dilution of pollutant aerosols. Chloride becomes the dominant water soluble anion in the lower 3000 m, primarily due to a several fold decrease in sulfate. Although these results are limited to only two sets of measurements, the data indicate the variability which can occur in the tropospheric vertical aerosol distributions at remote locations. A knowledge of the structure and stability of these stratified layers is of particular importance to studies of the ocean-troposphere chemistry problem.

Sebacher, D. I.↗

NASA NTRS1985

Cumulus cloud venting of mixed layer ozone

Ching, J. K. S.↗

NASA NTRS1985

Strat-trop exchange

Exchange between the stratosphere and troposphere is important to the chemical composition of both regions. The export of ozone from the stratosphere provides the troposphere with a means of initiating photochemistry. The precursor molecules originating from the planetary surface provide the stratosphere with its chemical feedstock from which the ozone-controlling HO(x), NO(x), and Cl(x) photochemistries are driven. The tropopause is defined both statistically and in a local, synoptic sense by the value P(sub theta) = .000016 K sq m/kg/s, taken from an objective analysis of 8 years of zonal, temporal mean cross sections of potential temperature, wind and potential vorticity.

Tuck, A. F.↗

NASA NTRS1984

Airborne lidar observations of long-range transport in the free troposphere

Airborne lidar measurements of ozone and aerosols in the lower troposphere show the presence of pollutant layers above the mixed layer. Two case studies are analyzed to identify probable source regions and mechanisms for material injection into the free troposphere above local mixed layers. An elevated haze/oxidant layer observed over South Carolina on Aug. 2, 1980, was found to originate in cumulus convection over Georgia on Aug. 1, 1980. An extensive haze/oxidant layer observed over southeastern Virginia on July 31, 1981, is shown to have been in contact with the New England mixed layer on July 30, 1981. This transported air mass is estimated to contribute approximately 30 percent of the ozone maximum measured at the surface in the Norfolk, VA, area on July 31, 1981. Such elevated 'reservoir' layers are transported over long ranges and are not detected by sensors which are confined to the surface.

Shipley, S. T.↗

NASA NTRS1984

Spaceborne lidar investigations of the atmosphere

Atmospheric investigations with a spaceborne lidar system are discussed. Measurements of aerosols, O3, and H2O with the NASA/LaRC airborne DIAL system are presented as examples of data obtained from space. The NASA/CNES study of an autonomous differential absorption lidar system is described. This system is a precursor to a spaceborne lidar system. Simulations of spaceborne lidar experiments are reviewed, and laser requirements for a spaceborne lidar system are presented.

Browell, E. V.↗

NASA NTRS1984

Atmospheric transport of pollutants from North America to the North Atlantic Ocean

Ground-based measurements strongly support the hypothesis that pollutant materials of anthropogenic origin are being transported over long distances in the midtroposphere and are a significant source of acid rain, acid snow, trace metal deposition, ozone and visibility-reducing aerosols in remote oceanic and polar regions of the Norhern Hemisphere. Atmospheric sulphur budget calculations and studies of acid rain on Bermuda indicate that a large fraction of pollutant materials emitted into the atmosphere in eastern North America are advected eastwards over the North Atlantic Ocean. The first direct airborne measurements of the vertical distribution of tropospheric aerosols over the western North Atlantic is reported here. A newly developed airborne differential adsorption lidar system was used to obtain continuous, remotely sensed aerosol distributions along its flight path. The data document two episodes of long-distance transport of pollutant materials from North America over the North Atlantic Ocean.

Harriss, R. C.↗

NASA NTRS1983

NASA multipurpose airborne DIAL system and measurements of ozone and aerosol profiles

The hardware, operational characteristics, data processing system, and applications of the NASA airborne differential absorption lidar (DIAL) system are described. DIAL functions by assessing the average gas concentration over a specified range interval by analyzing the difference in lidar backscatter signals for laser wavelengths tuned on and off of the molecular absorption line of a gas under investigation. The system comprises two frequency-doubled Nd:YAG lasers pumping two high conversion efficiency tunable dye lasers emitting pulses separated by 100 microsec or less. The return signals are digitized and stored on magnetic tape. The signal collector consists of photomultiplier tubes implanted in a cassegrain telescope. Flight tests of the system involved on-measurements at 285.95 nm and off-measurements at 299.40 nm, which yielded a differential cross section of 1.74 x 10 to the -16th sq cm. In situ measurements with another plane at a nominal altitude of 3.2 km for comparison purposes showed accuracy to within 10% in and above the boundary layer. The system is considered as a test apparatus for more developed versions to be flown on the Shuttle

Browell, E. V.↗

NASA NTRS1983

Remote sensing of tropospheric gases and aerosols with airborne DIAL system

The multipurpose airborne DIAL system developed at NASA Langley Research Center is characterized, and the published results of tropospheric O3, H2O, and aerosol-backscatter remote-sensing experiments performed in 1980 and 1981 are summarized. The system comprises two tunable dye lasers pumped by frequency-doubled Nd:YAG lasers, dielectric-coated steering optics, a 36-cm-diameter Cassegrain receiver telescope, gateable photomultiplier tubes, and a minicomputer data-processing unit for real-time calculation of gas concentrations and backscattering profiles. The transmitted energy of the 100-microsec-separated dye-laser pulses is 40, 80, or 50 mJ/pulse at around 300, 600, or 720-nm wavelength, respectively. Good agreement was found between DIAL-remote-sensed and in-situ H2O and O3 profiles of the lower troposphere and O3 profiles of the tropopause region, and the usefulness of DIAL backscattering measurements in the study of boundary-layer and tropospheric dynamics is demonstrated. The feasibility of DIAL sensing of power-plant or urban plume SO2, of urban-area (or rural-area column-content) NO2, and of temperature and H2O (simultaneously using a third laser) has been suggested by simulation studies.

Browell, E. V.↗

NASA NTRS1982

Shuttle lidar resonance fluorescence investigations. I - Analysis of Na and K measurements. II - Analysis of thermospheric Mg/+/ measurements

Optical radar systems (lidar) have a number of advantages compared to passive techniques with respect to applications involving the measurement of alkali atoms (Na and K) in the atmosphere. By using Shuttle-borne optical radar systems, analytical capabilities can be extended to cover wider geographic areas. One of the objectives of the present investigation is to assess the performance and application of a recently defined Shuttle optical radar system for the measurements of sodium and potassium in the 80-110-km region. A second objective is related to a study of the effects of high-intensity laser beams on the optical radar measurements, giving particular attention to the saturation in the atomic absorption of laser photons. A numerical simulation is conducted of the measurements of magnesium ions (Mg/+/) over the 80-500-km altitude range using recently defined Shuttle optical radar system parameters to study the performance of such a system.

Yeh, S.-D.↗

NASA NTRS1982

Airborne lidar investigations of ozone and aerosols in the nonurban troposphere

A description is presented of the first application of an airborne optical radar (lidar) to measurements of ozone and aerosol profiles in regional and global tropospheric investigations. It is pointed out that high spatial resolution measurements of ozone and aerosols are important in studying the relative contribution of chemistry and transport in large scale atmospheric processes. The investigation makes use of an airborne differential absorption optical radar system, which has been developed for the remote profiling of O3 and aerosols in the troposphere. Attention is given to lower tropospheric measurements and upper tropospheric measurements. The obtained results demonstrate the capability of the considered system to measure O3 and aerosol profiles in the troposphere and lower stratosphere.

Browell, E. V.↗

NASA NTRS1982

CO, O3, and aerosol measurements from NASA Global Tropospheric Experiment - Test flights 1981

A series of four instrument test flights was conducted during July 1981 in preparation for the NASA Global Tropospheric Experiment. The purpose of the flights was to demonstrate the feasibility and value of simultaneously measuring several specific atmospheric pollutants over a 25 deg latitudinal range. Carbon monoxide and methane grab samples were obtained simultaneously with nearly continuous in situ ozone and remote ozone and aerosol optical radar measurements. The sampling platform was a NASA Electra, a four engine turboprop aircraft. Attention is given to CO and CH4 sample collection and analysis, ozone measurement methods, the aerosol measurement method, an interpretation of the optical radar display, and a synergistic consideration of results.

Hinton, R. R.↗

NASA NTRS1982

Lidar measurements of tropospheric gases

Measurements of pollutants and water vapor in the troposphere using the differential absorption lidar (DIAL) technique are described. Measurements are made of sulfur dioxide in power plant plumes with a mobile DIAL system operated near 300 nm. Comparisons of sulfur dioxide concentrations determined with the DIAL system and in-stack monitors are found to be in agreement to within 18%. Vertical water vapor profiles with a ground-based lidar system are measured using the water vapor absorption line at 724.3 nm. Rawinsonde and DIAL water vapor profile data are shown to agree within 10% to an altitude of 2.5 km. Simulations are discussed for airborne DIAL measurements of sulfur dioxide, water vapor, and nitrogen dioxide.

Browell, E. V.↗

NASA NTRS1982

Spaceborne lidar measurement accuracy - Simulation of aerosol, cloud, molecular density, and temperature retrievals

In connection with studies concerning the use of an orbiting optical radar (lidar) to conduct aerosol and cloud measurements, attention has been given to the accuracy with which lidar return signals could be measured. However, signal-measurement error is not the only source of error which can affect the accuracy of the derived information. Other error sources are the assumed molecular-density and atmospheric-transmission profiles, and the lidar calibration factor (which relates signal to backscatter coefficient). The present investigation has the objective to account for the effects of all these errors sources for several realistic combinations of lidar parameters, model atmospheres, and background lighting conditions. In addition, a procedure is tested and developed for measuring density and temperature profiles with the lidar, and for using the lidar-derived density profiles to improve aerosol retrievals.

Russell, P. B.↗

NASA NTRS1981

Airborne differential absorption lidar system for water vapor investigations

Range-resolved water vapor measurements using the differential-absorption lidar (DIAL) technique is described in detail. The system uses two independently tunable optically pumped lasers operating in the near infrared with laser pulses of less than 100 microseconds separation, to minimize concentration errors caused by atmospheric scattering. Water vapor concentration profiles are calculated for each measurement by a minicomputer, in real time. The work is needed in the study of atmospheric motion and thermodynamics as well as in forestry and agriculture problems.

Browell, E. V.↗